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Reactions at α-Position In preceding chapters on carbonyl chemistry
Reactions at α-Position In preceding chapters on carbonyl chemistry

... While reacting two different ketones with alkoxide base is impractical due to the variety of products obtained, the desired product would only be obtained in low yield after a difficult separation, there are methods to react two different carbonyls in an aldol reaction efficiently ...
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Substituted Hydrocarbons and Their Reactions

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... acid or the . . . CH2CH2OH chain end of another macromolecule. In some experiments, we observed also the formation of oligo(ethylene glycol)s (mostly di- and tri-) in the macromolecular backbones. These most likely are formed by the wrong addition with nucleophilic attack on the carbon atom, resul ...
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... constant of reaction in sec-1. (L∞-Lt): concentration of product at any time. The value of k for each temperature was evaluated from the slope of the linear plots of ln(L∞-Lt) against (t), the data plots are shown in the fig. (3) and the summary of findings of k, t1/2, and R2 are given in the table( ...
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Full Article - PDF - Brandeis University

... a first-order dependence on methanol, the substrate (2a) and either (10) See Supporting Information for a detailed description of the extractive workup of the preparative-scale kinetic resolution of 2a. ...
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Alcohols - Structure - University of Nebraska Omaha

catalytic activity of modified silicates: i. dehydration of ethanol
catalytic activity of modified silicates: i. dehydration of ethanol

jDonvert the following Fischer projections to dimensional formulas
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... 4.4.1 Motion on the PES The topology of the Born-Oppenheimer PES determines the dynamics of a chemical reaction. Even in the absence of exact QM reactive-scattering calculations, important insight into chemical dynamics can be gained from analysing classical collision trajectories on the BO-PES. Con ...
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... 12. Solid HgO, liquid Hg, and gaseous O2 are placed in a glass bulb and are allowed to reach equilibrium at a given temperature. 2HgO(s) 2Hg(l) + O2(g) H = +43.4 kcal The mass of HgO in the bulb could be increased by a) adding more Hg. b) removing some O2. c) reducing the volume of the bulb. d) inc ...
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Pincer Complexes. Applications in Catalysis

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AP Chemistry - cloudfront.net

... 8.37 Which group in the periodic table has elements with high IE1 and very negative first electron affinities (EA1)? What is the charge on the ions that these atoms form? 8.59 Write the charge and full ground-state electron configuration of the monatomic ion most likely to be formed by each of the f ...
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M.Sc - I Syllabus w.e.f. June 2015

... Symmetry elements and operations, Symmetry planes, reflections, inversion centre, proper / improper axes of rotation, equivalent symmetry elements and atoms, symmetry elements and optical isomerism, symmetry point groups of some molecules H 2O, NH3, C2H2Cl2, (cis& trans) , BF3, PCl5, H2O2 (trans), X ...
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Some uses of mischmetall in organic synthesis

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... 2 CH3MgBr + (CH3)2CHCOCH3 ...
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Kinetics and mechanism of oxidation of alcohols

... benzyl alcohols by chromic acid (q = -1.16) [17] and nitrous acid (q = -1.07) [18]. The better correlation with r? indicates the development of the positive charge in the transition state on a carbon atom adjacent to the benzene nucleus which can be delocalized into the nucleus itself. This mechanis ...
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Carboxylic Acid Derivatives and Nucleophilic Acyl Substitution

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ISOMERISM - A general survey
ISOMERISM - A general survey

Synthesis of first row transition metal carboxylate complexes by ring
Synthesis of first row transition metal carboxylate complexes by ring

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Asymmetric induction



Asymmetric induction (also enantioinduction) in stereochemistry describes the preferential formation in a chemical reaction of one enantiomer or diastereoisomer over the other as a result of the influence of a chiral feature present in the substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis.Asymmetric induction was introduced by Hermann Emil Fischer based on his work on carbohydrates. Several types of induction exist.Internal asymmetric induction makes use of a chiral center bound to the reactive center through a covalent bond and remains so during the reaction. The starting material is often derived from chiral pool synthesis. In relayed asymmetric induction the chiral information is introduced in a separate step and removed again in a separate chemical reaction. Special synthons are called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand. This method of asymmetric synthesis is economically most desirable.
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