Carbohydrates
... 1. Ketoses (Sugars with Ketone groups) vs Aldoses (Sugars with Aldehyde groups) 2. Fischer projections a. Aldose D family: triose – tetrose - pentose – hexose (Figure 23-3) b. Erythro and Threo: History as hydroxyl groups on same or opposite side of Fischer projection in tetroses (Section 23-4) c. D ...
... 1. Ketoses (Sugars with Ketone groups) vs Aldoses (Sugars with Aldehyde groups) 2. Fischer projections a. Aldose D family: triose – tetrose - pentose – hexose (Figure 23-3) b. Erythro and Threo: History as hydroxyl groups on same or opposite side of Fischer projection in tetroses (Section 23-4) c. D ...
NaBH4 Reduction of Vanillin
... Aside from a lack of selectivity, LAH reacts violently with water and other hydroxylic compounds, and reductions using this reagent must be carried out under non‐protic, anhydrous conditions. This not only limits the solvents with which LAH can be used, but it presents greater challenges in th ...
... Aside from a lack of selectivity, LAH reacts violently with water and other hydroxylic compounds, and reductions using this reagent must be carried out under non‐protic, anhydrous conditions. This not only limits the solvents with which LAH can be used, but it presents greater challenges in th ...
Organic Nomenclature
... Ketones have two hydrocarbon groups attached to the carbonyl group, C=O. The suffix for ketones is one. Choose the longest continuous carbon chain that contains the C=O group. Number the chain from the end that will give the C=O group the lowest number. This sets the direction and order of the numbe ...
... Ketones have two hydrocarbon groups attached to the carbonyl group, C=O. The suffix for ketones is one. Choose the longest continuous carbon chain that contains the C=O group. Number the chain from the end that will give the C=O group the lowest number. This sets the direction and order of the numbe ...
PPT
... • Find the longest chain that contains C=O. • Using the root alkane name, drop the –e ending and change to –one. • Number the longest carbon chain so the C=O group has the lowest number. • Name and number other substituents as before. Examples: ...
... • Find the longest chain that contains C=O. • Using the root alkane name, drop the –e ending and change to –one. • Number the longest carbon chain so the C=O group has the lowest number. • Name and number other substituents as before. Examples: ...
WHAT IS MORPHINE -- ACTIVITY #1 What is morphine? What is it
... cis-Alkene - cis-Alkenes are 1,2-disubstituted functions with the two R, X or other groups on the same side of the C=C function. Due to the non-rotation of the C=C bond, cis and trans geometric isomers are not [thermally] Interconvertion. Ether - Ethers have a pair of alkyl or aromatic groups attach ...
... cis-Alkene - cis-Alkenes are 1,2-disubstituted functions with the two R, X or other groups on the same side of the C=C function. Due to the non-rotation of the C=C bond, cis and trans geometric isomers are not [thermally] Interconvertion. Ether - Ethers have a pair of alkyl or aromatic groups attach ...
Electophilic Aromatic Substituion - Towson University
... Controlled by electronegativity and the polarity of bonds in functional groups, i.e. halogens, C=O, CN, and NO2 withdraw electrons through s bond connected to ring. Alkyl group inductive effect is to donate electrons. ...
... Controlled by electronegativity and the polarity of bonds in functional groups, i.e. halogens, C=O, CN, and NO2 withdraw electrons through s bond connected to ring. Alkyl group inductive effect is to donate electrons. ...
10. Alkyl Halides
... 10.2 Structure of Alkyl Halides C-X bond is longer as you go down periodic table C-X bond is weaker as you go down periodic table C-X bond is polarized with slight positive on carbon ...
... 10.2 Structure of Alkyl Halides C-X bond is longer as you go down periodic table C-X bond is weaker as you go down periodic table C-X bond is polarized with slight positive on carbon ...
Review Sheet - Phillips Scientific Methods
... Alcohols are “bent” in shape and tetrahedral about the oxygen atom Alcohols hydrogen bond with one another and thus have higher boiling and melting points that similar molecular weight hydrocarbons The most important physical property of an alcohol is the polarity of the –OH group Low molecu ...
... Alcohols are “bent” in shape and tetrahedral about the oxygen atom Alcohols hydrogen bond with one another and thus have higher boiling and melting points that similar molecular weight hydrocarbons The most important physical property of an alcohol is the polarity of the –OH group Low molecu ...
Alcohols - Science Skool!
... know the mechanism of this as it is very complex. Smaller esters tend to smell like most organic solvents (that gluey smell) though larger esters have the smell of “pear drops”. ...
... know the mechanism of this as it is very complex. Smaller esters tend to smell like most organic solvents (that gluey smell) though larger esters have the smell of “pear drops”. ...
functional group
... 6) Halogenation of alkanes: reactivityselectivity principle, radical stability and chain reactions Minto - Lectures 7-8 ...
... 6) Halogenation of alkanes: reactivityselectivity principle, radical stability and chain reactions Minto - Lectures 7-8 ...
Objectives - Mercer County Community College
... o To calculate the percentage composition of the mixture o Build and analyze models of simple and complex organic compounds Gas Chromatography (GC) EXPERIMENTAL: The GC experiment consists of graphing the GC data obtained from standard solutions with known concentrations. This graph is called a cali ...
... o To calculate the percentage composition of the mixture o Build and analyze models of simple and complex organic compounds Gas Chromatography (GC) EXPERIMENTAL: The GC experiment consists of graphing the GC data obtained from standard solutions with known concentrations. This graph is called a cali ...
replacing the - Shasha iSeminar
... Reaction with phosphorus(V) chloride, PCl5 Solid phosphorus(V) chloride (phosphorus pentachloride) reacts violently with alcohols at room temperature, producing clouds of hydrogen chloride gas. It isn't a good choice as a way of making chloroalkanes, although it is used as a test for -OH groups in o ...
... Reaction with phosphorus(V) chloride, PCl5 Solid phosphorus(V) chloride (phosphorus pentachloride) reacts violently with alcohols at room temperature, producing clouds of hydrogen chloride gas. It isn't a good choice as a way of making chloroalkanes, although it is used as a test for -OH groups in o ...
Nucleophilic Substitution Reactions
... ■ The polarity in halogenoalkanes is due to the fact that the halogen atom is more electronegative than carbon, and so exserts a stronger pull on the shared electrons in the carbon-halogen bond. ■ As a result, the halogen gains a partial negative charge and the carbon gains a partial positive charge ...
... ■ The polarity in halogenoalkanes is due to the fact that the halogen atom is more electronegative than carbon, and so exserts a stronger pull on the shared electrons in the carbon-halogen bond. ■ As a result, the halogen gains a partial negative charge and the carbon gains a partial positive charge ...
synthesis, chemistry and optical resol
... conditions are given in Scheme II.'3a Surprisingly, the hydroboration rate seems more affected by ring size than by ring stereochemistry. Epoxidation, on the other hand, showed the expected steric dependence. Reaction with excess m-chloroperoxybenzoic acid ( N a H C 0 3 buffer) in methylene chloride ...
... conditions are given in Scheme II.'3a Surprisingly, the hydroboration rate seems more affected by ring size than by ring stereochemistry. Epoxidation, on the other hand, showed the expected steric dependence. Reaction with excess m-chloroperoxybenzoic acid ( N a H C 0 3 buffer) in methylene chloride ...
Weekly Review Lecture
... c. Dehydration to nitrile using P2O5 10) Reactions of Weinreb amides a. (single) Grignard addition b. LAH reduction to produce aldehyde 11) Reactions of nitriles a. Hydrolysis b. Reduction with LiAlH4 ...
... c. Dehydration to nitrile using P2O5 10) Reactions of Weinreb amides a. (single) Grignard addition b. LAH reduction to produce aldehyde 11) Reactions of nitriles a. Hydrolysis b. Reduction with LiAlH4 ...
How to Name Alcohols
... A group of covalently bonded elements that when bonded to a carbon chain give it a unique quality. Compounds with similar functional groups will have similar qualities and properties. ...
... A group of covalently bonded elements that when bonded to a carbon chain give it a unique quality. Compounds with similar functional groups will have similar qualities and properties. ...
Alkanes Chapter 1.1
... molecules that have the same chemical formula and structural backbone, but with a different arrangement of atoms in space • Cis isomer: a stereoisomer in which the groups of interest are located on the same side • Trans isomer: a stereoisomer in which the groups of ...
... molecules that have the same chemical formula and structural backbone, but with a different arrangement of atoms in space • Cis isomer: a stereoisomer in which the groups of interest are located on the same side • Trans isomer: a stereoisomer in which the groups of ...
Chapter 4 Full PPT
... Concept 4.1: Organic chemistry is the study of carbon compounds • Organic chemistry is the study of compounds that contain carbon • Organic compounds range from simple molecules to colossal ones • Most organic compounds contain hydrogen atoms in addition to carbon atoms ...
... Concept 4.1: Organic chemistry is the study of carbon compounds • Organic chemistry is the study of compounds that contain carbon • Organic compounds range from simple molecules to colossal ones • Most organic compounds contain hydrogen atoms in addition to carbon atoms ...
Alcohols
... The longest chain contains six carbon atoms, but it does not contain the carbon bonded to the hydroxyl group. The longest chain containing the carbon bonded to the —OH group is the one outlined by the green box, containing five carbon atoms. This chain is numbered from right to left in order to give ...
... The longest chain contains six carbon atoms, but it does not contain the carbon bonded to the hydroxyl group. The longest chain containing the carbon bonded to the —OH group is the one outlined by the green box, containing five carbon atoms. This chain is numbered from right to left in order to give ...
reactions of alcohols
... The longest chain contains six carbon atoms, but it does not contain the carbon bonded to the hydroxyl group. The longest chain containing the carbon bonded to the —OH group is the one outlined by the green box, containing five carbon atoms. This chain is numbered from right to left in order to give ...
... The longest chain contains six carbon atoms, but it does not contain the carbon bonded to the hydroxyl group. The longest chain containing the carbon bonded to the —OH group is the one outlined by the green box, containing five carbon atoms. This chain is numbered from right to left in order to give ...
Alkene
In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond. Alkene, olefin, and olefine are used often interchangeably (see nomenclature section below). Acyclic alkenes, with only one double bond and no other functional groups, known as mono-enes, form a homologous series of hydrocarbons with the general formula CnH2n. Alkenes have two hydrogen atoms less than the corresponding alkane (with the same number of carbon atoms). The simplest alkene, ethylene (C2H4), which has the International Union of Pure and Applied Chemistry (IUPAC) name ethene is the organic compound produced on the largest scale industrially. Aromatic compounds are often drawn as cyclic alkenes, but their structure and properties are different and they are not considered to be alkenes.