Quiz 3 – Aldehydes and Ketones 1 Which of the following reactions
... 7 You have two C6H10O ketones, I and II. Both are optically active, but I is racemized by treatment with base and II is not. Wolff-Kishner reduction of both ketones gives the same achiral hydrocarbon, formula C6H12. What reasonable structures may be assigned to I and II? A) I is 3-methyl-4-penten-2- ...
... 7 You have two C6H10O ketones, I and II. Both are optically active, but I is racemized by treatment with base and II is not. Wolff-Kishner reduction of both ketones gives the same achiral hydrocarbon, formula C6H12. What reasonable structures may be assigned to I and II? A) I is 3-methyl-4-penten-2- ...
Lecture 5: Biotrans_detox_biodegrade_lecture
... (a.) occur mostly in the liver (b.) mediated by MFOs called cytochromes P450 (c.) occur in endoplasmic reticulum (liver microsomes) (d.) mechanism (e.) very broad range of substrates accomodated -- aliphatic hydroxylation -- aromatic hydroxylation -- aliphatic epoxidation -- aromatic epoxidation -- ...
... (a.) occur mostly in the liver (b.) mediated by MFOs called cytochromes P450 (c.) occur in endoplasmic reticulum (liver microsomes) (d.) mechanism (e.) very broad range of substrates accomodated -- aliphatic hydroxylation -- aromatic hydroxylation -- aliphatic epoxidation -- aromatic epoxidation -- ...
Hydrocarbons - calciochemist
... Homologous series- a group of compounds that have a constant increment of change In alkanes, it is: -CH2- (methylene) ...
... Homologous series- a group of compounds that have a constant increment of change In alkanes, it is: -CH2- (methylene) ...
Atomic Structure (27 Jan 2004) • What is matter? • Dalton`s Atomic
... • Alkane family: methane, ethane, propane, butane, pentane, hexane. • Cyclic alkanes • Physical and chemical properties of alkanes • Structural formula and Molecular formula • Isomerism in alkanes • Alkene family: ethene, propene, ... • Isomerism in alkenes cis-trans isomerism • Chemical reactions o ...
... • Alkane family: methane, ethane, propane, butane, pentane, hexane. • Cyclic alkanes • Physical and chemical properties of alkanes • Structural formula and Molecular formula • Isomerism in alkanes • Alkene family: ethene, propene, ... • Isomerism in alkenes cis-trans isomerism • Chemical reactions o ...
oxidation and reduction
... Singlet oxygen is a reactive intermediate which does many pericyclic reactions. For example, with cyclopentadiene at -78oC, a Diels-Alder reaction gives a strained endoperoxide which, as it warms to room temperature, fragments the weak O-O bond. ...
... Singlet oxygen is a reactive intermediate which does many pericyclic reactions. For example, with cyclopentadiene at -78oC, a Diels-Alder reaction gives a strained endoperoxide which, as it warms to room temperature, fragments the weak O-O bond. ...
Types of Reactions
... you may take a NEW quiz on Tuesday, after school, or before school by Tuesday. ...
... you may take a NEW quiz on Tuesday, after school, or before school by Tuesday. ...
Organic Chem Class #2
... 28. ALKANES: hydrocarbons with only single C-C bonding. Only contain carbon and hydrogen atoms. Chains of 1 to 10 labeled with prefixes in table P. All end in –ane. 29. AKLENES: hydrocarbons with only one double C=C bond. Only contain carbon and hydrogen atoms. Chains of 1 to 10 labeled with prefix ...
... 28. ALKANES: hydrocarbons with only single C-C bonding. Only contain carbon and hydrogen atoms. Chains of 1 to 10 labeled with prefixes in table P. All end in –ane. 29. AKLENES: hydrocarbons with only one double C=C bond. Only contain carbon and hydrogen atoms. Chains of 1 to 10 labeled with prefix ...
Unit 2A Organic Chem. Intro
... create polymers by dehydration synthesis. All unlinked monomers have H atoms at one end and hydroxyl groups (OH) at other end. When a monomer is added… an H and OH is removed. This ...
... create polymers by dehydration synthesis. All unlinked monomers have H atoms at one end and hydroxyl groups (OH) at other end. When a monomer is added… an H and OH is removed. This ...
Answers
... of hydroxide is needed. Draw a full mechanism to explain. (Hint: Before the elimination takes place, another reaction type we have learned takes place more quickly.) ...
... of hydroxide is needed. Draw a full mechanism to explain. (Hint: Before the elimination takes place, another reaction type we have learned takes place more quickly.) ...
enthalpy - winterk
... What is a polymer? What, then, is a monomer? Give an example of a synthetic (man-made) polymer and a naturally-found polymer. Name the monomer that makes up each. Give an example of an addition polymer and be able to explain how it forms. Name the two types of condensation polymers and give an examp ...
... What is a polymer? What, then, is a monomer? Give an example of a synthetic (man-made) polymer and a naturally-found polymer. Name the monomer that makes up each. Give an example of an addition polymer and be able to explain how it forms. Name the two types of condensation polymers and give an examp ...
Lecture #1
... O double bonded to C to hydroxyl; carboxylic acids; covalent bond between O and H; polar; dissociation, H ion ...
... O double bonded to C to hydroxyl; carboxylic acids; covalent bond between O and H; polar; dissociation, H ion ...
Chapter 5-alcohol
... as the parent alkane and number it from the end that gives the OH the lower number. 2. Change the ending of the parent alkane from -e to -ol and use a number to show the location of the -OH group; for cyclic alcohols, the carbon bearing the -OH group is carbon-1. 3. Name and number substituents and ...
... as the parent alkane and number it from the end that gives the OH the lower number. 2. Change the ending of the parent alkane from -e to -ol and use a number to show the location of the -OH group; for cyclic alcohols, the carbon bearing the -OH group is carbon-1. 3. Name and number substituents and ...
Chapter 1 Structure and Bonding
... 1) Reduction reactions can be reversed to give the aldehydes or ketones 2) Oxidizing Reagent is Cr(VI) a) (Na2Cr2O7 or K2Cr2O7 or CrO3) and H2SO4 and H2O R' CH OH R ...
... 1) Reduction reactions can be reversed to give the aldehydes or ketones 2) Oxidizing Reagent is Cr(VI) a) (Na2Cr2O7 or K2Cr2O7 or CrO3) and H2SO4 and H2O R' CH OH R ...
Document
... Hydrocarbon: - compounds containing only hydrogen and carbon Carbon backbone: - the longest carbon chain in a compound Saturated hydrocarbon: - hydrocarbon with only single bonds (i.e., the molecule contains a maximum number of hydrogen atoms) ...
... Hydrocarbon: - compounds containing only hydrogen and carbon Carbon backbone: - the longest carbon chain in a compound Saturated hydrocarbon: - hydrocarbon with only single bonds (i.e., the molecule contains a maximum number of hydrogen atoms) ...
Organometallic Organometallic Chemistry
... binds the last traces of water in the reaction mixture. Schlenk equilibrium, equilibrium Grignard reagents form varying amounts of diorganomagnesium compounds (R = organic group, X = halide): ...
... binds the last traces of water in the reaction mixture. Schlenk equilibrium, equilibrium Grignard reagents form varying amounts of diorganomagnesium compounds (R = organic group, X = halide): ...
Mass Spectrometry and Infrared Spectroscopy
... IR spectrum has lower energy region characteristic of molecule as a whole (“fingerprint” region) ...
... IR spectrum has lower energy region characteristic of molecule as a whole (“fingerprint” region) ...
STUDY GUIDE FOR CHAPTER 4 1. Functional Groups – these are
... Functional Groups – these are specific atoms or (more often) groups of atoms in the molecule, which largely determine the chemical behavior of the molecule (and the compound). According to their functional groups compounds are conveniently classified as alcohols, amines, carboxylic acids, aldehydes, ...
... Functional Groups – these are specific atoms or (more often) groups of atoms in the molecule, which largely determine the chemical behavior of the molecule (and the compound). According to their functional groups compounds are conveniently classified as alcohols, amines, carboxylic acids, aldehydes, ...
(a) Structural isomers
... Concept 4.1: Organic chemistry is the study of carbon compounds • Organic chemistry is the study of compounds that contain carbon • Organic compounds range from simple molecules to colossal ones • Most organic compounds contain hydrogen atoms in addition to carbon atoms ...
... Concept 4.1: Organic chemistry is the study of carbon compounds • Organic chemistry is the study of compounds that contain carbon • Organic compounds range from simple molecules to colossal ones • Most organic compounds contain hydrogen atoms in addition to carbon atoms ...
The Core Principles of Chemistry
... (i) Draw a dot and cross diagram to show the electronic structure of the compound magnesium chloride (only the outer electrons need be shown). Include the charges present. ...
... (i) Draw a dot and cross diagram to show the electronic structure of the compound magnesium chloride (only the outer electrons need be shown). Include the charges present. ...
Alkene
In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond. Alkene, olefin, and olefine are used often interchangeably (see nomenclature section below). Acyclic alkenes, with only one double bond and no other functional groups, known as mono-enes, form a homologous series of hydrocarbons with the general formula CnH2n. Alkenes have two hydrogen atoms less than the corresponding alkane (with the same number of carbon atoms). The simplest alkene, ethylene (C2H4), which has the International Union of Pure and Applied Chemistry (IUPAC) name ethene is the organic compound produced on the largest scale industrially. Aromatic compounds are often drawn as cyclic alkenes, but their structure and properties are different and they are not considered to be alkenes.