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Thermodynamic Systems and State Functions
Thermodynamic Systems and State Functions

... through a series of measurable parameters or functions called “state functions” or “state variables.” Such functions can be defined as “extensive” or “intensive” ones. The extensive functions are additive, and among them the system volume V, its mass m, and the number of moles ni of each species con ...
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... In conclusion, it is worth noting that the essential feature of the considered phenomenon has been discovered. It is about the quantum nature and it appears that the reality, as considered in the macroscopic scale, also possesses quantum energetic nature. Thus not only the microscopic world is quant ...
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Thermodynamics of ideal gases

... The factor 3 stems from the three independent translational degrees of freedom available to pointlike particles. The above formula thus expresses that there is an internal kinetic energy 12 kT associated with each translational degree of freedom. Whereas monatomic gases like Argon have spherical mol ...
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AP Physics – Thermodynamics Wrapup
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... For a given system, the driving force therefore is not energy minimization (as in geometry optimization), since the energy is constant due to the first law, but the maximization of the entropy! To introduce Temperature in the framework of Statistical Mechanics, two ways can be ...
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... pipes are currently showing as a progressive cooling system. These devices are structurally and materially to the relatively simple and affordable devices capable of very efficiently dissipate heat in a wide temperature range. Heat pipes are used for cooling equipment with a wide range of cooling pe ...
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... Recall that exothermic reactions give out heat and that endothermic reactions take in heat Recall the equation used to calculate heat energy- q=mcT Know that foam calorimeters are used to measure temperature changes for displacement, dissolving and neutralisation reactions Calculate heat energy for ...
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... direct current is passed through one or more pairs of nand p-type of semiconductor materials. Figure 1 is a diagram of a single pair consisting of n- and p-type semiconductor materials. In the cooling mode, direct current is allowed to passes through n and p junction of a semiconductor material. The ...
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... molecules. This form of energy consists of two parts: the internal kinetic energy due to the velocity of the molecules, and the internal potential energy due to the attractive forces between molecules. Changes in the average velocity of molecules are indicated by temperature changes of the substance ...
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... reactor (or exiting from the reactor) if the amounts of substances expressed in the reaction equation react at constant temperature, and both the reactants and the products are pure substances at po pressure. ...
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... which cannot change no matter what processes occur”  The total energy of the universe cannot change for any process.  During a process, energy of system changes and this change is accounted for in terms of internal energy.  The change in internal energy of a system can only be done by transferrin ...
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... Grades of Energy, cont. • If form A can be completely converted to form B, but the reverse is never complete, A is a higher grade of energy than B • When a high-grade energy is converted to internal energy, it can never be fully recovered as high-grade energy • Degradation of energy is the conversi ...
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Heat



In physics, heat is energy in a process of transfer between a system and its surroundings, other than as work or with the transfer of matter. When there is a suitable physical pathway, heat flows from a hotter body to a colder one. The pathway can be direct, as in conduction and radiation, or indirect, as in convective circulation.Because it refers to a process of transfer between two systems, the system of interest, and its surroundings considered as a system, heat is not a state or property of a single system. If heat transfer is slow and continuous, so that the temperature of the system of interest remains well defined, it can sometimes be described by a process function.Kinetic theory explains heat as a macroscopic manifestation of the motions and interactions of microscopic constituents such as molecules and photons.In calorimetry, sensible heat is defined with respect to a specific chosen state variable of the system, such as pressure or volume. Sensible heat transferred into or out of the system under study causes change of temperature while leaving the chosen state variable unchanged. Heat transfer that occurs with the system at constant temperature and that does change that particular state variable is called latent heat with respect to that variable. For infinitesimal changes, the total incremental heat transfer is then the sum of the latent and sensible heat increments. This is a basic paradigm for thermodynamics, and was important in the historical development of the subject.The quantity of energy transferred as heat is a scalar expressed in an energy unit such as the joule (J) (SI), with a sign that is customarily positive when a transfer adds to the energy of a system. It can be measured by calorimetry, or determined by calculations based on other quantities, relying on the first law of thermodynamics.
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