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Multiplets in Polymer Gels. Rare Earth Metal Ions Luminescence Study
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... surrounded by three carboxylate groups. In the ref 11 it was demonstrated that linear PMAA cannot easily form the tris-coordinate complex with Eu3+ because of the steric hindrance of the polymer chain. The analogous high values of Θ (Θ ) 0.40-0.41) were obtained previously for the complexes of RE io ...
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... solvent reorganization events are important for the hydrolysis of Si–O–Si linkages. An outer-sphere surface complex needs to lose one coordinated water molecule to form the monodentate inner-sphere surface complex. In addition, the inner-sphere surface complexes can be exchanged into the solution by ...
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Marcus theory

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