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QUANTUM THEORY OF ATOMS AND MOLECULES
QUANTUM THEORY OF ATOMS AND MOLECULES

... etc.) represents the number of C atoms in the chain. The number of electrons is thus also Nc and by the Pauli principle the lowest Nc/2 levels will be doubly occupied in the ground state. How will the wavelength of the lowest energy electronic transition associated with the promotion of  electrons ...
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... absorbed by the electrons, they are promoted to a higher energy state (excited state). When an electron in an excited state returns to a lower energy state, it emits a photon of energy, which may be observed as light. ...
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... Light composed of tiny particles, called quanta (photons) ...
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Chemistry: The Basics

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PHY4604–Introduction to Quantum Mechanics Fall 2004 Practice

... ii. deuterium (mass of nucleus 2× that of H). The mass which appears in the Bohr formula is the electron mass m, which is replaced by the reduced mass µ = mmp /(m+mp ) if one allows for the proton motion. Changing mp → 2mp doesn’t change much, so to a good approximation the photon wavelength doesn’t ...
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... The second quantum number, the angular momentum quantum number, l, can have integral values from 0 to (n-1) for each value of n.  This quantum number defines the shape of the orbital.  The value of l is generally designated by the letters, s, p, d and f, corresponding to l values of 0, 1, 2 and 3 ...
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... of the positively charged nucleus for the negatively charged electrons and repulsion between the electrons. The outer electrons (valence electrons) do not experience the full attraction of the positive nucleus because of the presence of inner electrons. They are shielded from the nucleus and repelle ...
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topic 03 outline YT 2010 test

... Line spectrum: very specific wavelengths of light that atoms give off or gain o Each element has its own line spectrum, which can be used to identify that element. o The line spectrum must be related to energy transitions in the atom o ...
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Electron configuration



In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. For example, the electron configuration of the neon atom is 1s2 2s2 2p6.Electronic configurations describe electrons as each moving independently in an orbital, in an average field created by all other orbitals. Mathematically, configurations are described by Slater determinants or configuration state functions.According to the laws of quantum mechanics, for systems with only one electron, an energy is associated with each electron configuration and, upon certain conditions, electrons are able to move from one configuration to another by the emission or absorption of a quantum of energy, in the form of a photon.Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements. The concept is also useful for describing the chemical bonds that hold atoms together. In bulk materials, this same idea helps explain the peculiar properties of lasers and semiconductors.
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