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Chapter 1 Chemistry: The Study of Matter 1 What is Chemistry? 2 - the branch of science that deals with the composition, structure and properties of matter, with the changes that matter undergoes in composition and with the energy changes that occur during these transformations. Applied Chemistry is the using chemistry to attain certain goals, in fields like medicine, agriculture, and manufacturing (technology) Pure chemistry gathers knowledge for knowledge sake (academics) Types of Chemistry Analytical Chemistry studies composition of substances. Inorganic Chemistry substances without carbon Organic Chemistry compounds containing carbon Biochemistry- Chemistry of living things Physical Chemistry studies behavior of substances 3 Chemistry is A natural science. a language with its own vocabulary. a way of thinking. a body of knowledge. What are the types of knowledge? 4 TYPES OF KNOWLEDGE Scientific knowledge is empirical in origin. 5 EMPIRICAL KNOWLEDGE 6 - Knowledge gained using the primary senses – seeing, tasting, feeling, hearing or smelling. Sometimes instruments are used as aids to our senses. Authoritative Knowledge 7 - knowledge we gain from experts e.g. lawyers, doctors, people with credentials. Rational Knowledge 8 - based on what are considered to be rational truths e.g. If x=y and y=z then x must equal z Revealed knowledge 9 - knowledge we accept on faith e.g. All living animals today are descended from those on board Noah’s Ark. Intuitive Knowledge 10 - knowledge possessed without knowing where it comes from e.g. a mother instinctively knows when her baby is in need. OBSERVATION VS INTERPRETATION Observations are always empirical. Qualitative observations involve simple descriptions. Quantitative Observations involve amounts Interpretations involve reasoning based on observations 11 Scientific Method A way of solving problems or answering questions. Starts with observation- noting an recording facts Hypothesis- an educated guess as to the cause of the problem or answer to the question. 12 Scientific Method Experiment- designed to test the hypothesis only two possible answers – hypothesis is right – hypothesis is wrong Generates data observations from experiments. Modify hypothesis - repeat the cycle 13 Observations Hypothesis Experiment 14 Cycle repeats many times. The hypothesis gets more and more certain. Becomes a theory A thoroughly tested model that explains why things behave a certain way. Theory can never be proven. Useful because they predict behavior Help us form mental pictures of processes (models) Observations Hypothesis Experiment 15 Another outcome is that certain behavior is repeated many times Scientific Law is developed Description of how things behave Law - how Theory- why Observations Hypothesis Experiment 16 Observations Hypothesis Theory (Model) Modify Experiment Prediction Law 17 Experiment What is Matter? Matter is anything that takes up space and has mass. Mass is the amount of matter in an object. 18 Types of Matter Pure Substance- made up of one kind of matter Mixture- more than one kind of matter Homogeneous matter – looks the same throughout (uniform composition) examples silver, sugar, salt solution Heterogeneous matter – has parts with different properties (composition is not uniform) e.g. pizza, sand, salad 19 Properties 20 Words that describe matter (adjectives) Physical Properties- a property that can be observed and measured without changing the composition of the substance. (Identifying Properties) Examples of Physical properties – color, luster, malleability, ductility, transparency, density, conductivity, hardness, solubility, phase at room temperature, melting temp., boiling temp. etc Chemical Properties Chemical Properties- a property that can only be observed by changing the composition of the substance which occurs during a Chemical Change (a loss of the identity of the substance - a new substance is produced). Chemical properties – describes the tendency to react e.g. sodium reacts with water; helium is non-reactive with oxygen 21 States of matter Solid- matter that has definite shape (can not flow) and has definite volume. Liquid- definite volume but takes the shape of its container (flows). Gas- a substance without definite volume or shape (can flow). Vapor- a substance that is currently a gas but normally is a liquid or solid at room temperature. 22 States of Matter Definite Definite Temperature Volume? Shape? increase Solid Liquid Gas 23 YES YES NO Compressible? YES Small Expansion NO NO Small Expansion NO NO Large Expansion YES Solid 24 Freeze Condense Melt Evaporate Liquid Sublimation Gas Physical Changes A change that alters the appearance without changing the composition. (A change in physical properties) Examples? Boiled water is still water. Chemical changes - a change where a new form of matter is produced. Examples? Iron rusting 25 Mixtures Made up of two or more substances. Has variable composition Each substance keeps its properties. Mixtures can be: Heterogeneous- mixture is not the same from place to place (No uniform composition). Chocolate chip cookie, gravel, soil. Homogeneous- mixture is the same from place to place (has uniform composition). Kool-aid, air. 26 Solutions Homogeneous mixture with molecules mixed uniformly Solutions occur between any state of matter. Solid in liquid- Kool-aid Liquid in liquid- antifreeze Gas in a liquid – carbonated beverages Gas in gas- air Solid in solid - brass Liquid in gas- water vapor 27 Solutions Like all mixtures, the components keep their own properties. Components can be separated by physical means Has one phase (uniform composition and properties). 28 Classification of Matter Pure Substances Elements - simplest kind of matter only one kind of atom present. Element cannot be broken down into simpler substances Compounds - are substances that contain two or more different kinds of atoms. The atoms are held together by bonds to form molecules. Molecules can be broken down by chemical methods. When compounds are broken down, the components have completely different properties than the compound. 29 Compound or Mixture Compound One kind of matterMolecule or atom More than one kind of matter- different molecules or atoms Made during a Made through a chemical change physical change Definite and uniform composition 30 Mixture Variable in composition Which is it? Mixture Element Compound 31 Chemical symbols There are 112 elements Each has a 1 or two letter symbol First letter always capitalized second never Don’t need to memorize Some from Latin of other languages 32 Chemical Reactions When one or more substances are changed into new substances. Reactants- stuff you start with Products- What you make NEW PROPERTIES (New substance) Not easily reversed 33 Indications of a chemical reaction Energy absorbed or released Color change Gas produced Precipitate- solid that separates from solution Not easily reversed ALWAYS THERE IS A NEW SUBSTANCE! 34 Conservation of Mass Mass can not be created or destroyed in ordinary chemical or physical changes (not true for nuclear changes. ) All the mass can be accounted for. 35 What about nuclear? E = mc2 2 energy = mass x (speed of light) 8 speed of light = 3 x 10 A little mass can make a lot of energy Law of Conservation of Mass - Energy the total of the mass and energy remains the same in any change 36 Energy The ability to do work. Work - cause a change or move an object (Apply a force through a distance). Many types- all can be changed into the other. 37 Types of energy 38 Potential- stored energy Kinetic Energy- energy something has because its moving Heat- the energy that moves because of a temperature difference. Chemical energy- energy released or absorbed in a chemical change (a change in chemical bonds). Electrical energy - energy of moving charges Types of Energy Radiant Energy- energy that can travel through empty space (light, UV, infrared, radio) All types of energy can be converted into others. If you trace the source far enough back, you will end up at nuclear energy. 39 Energy Change during physical or chemical change changes – are those processes that involve a loss of energy to the surroundings (temperature of surroundings goes up). Endothermic changes – are those processes that absorb energy from the surroundings (temperature of the surroundings goes down). Exothermic 40 Conservation of Energy Energy can be neither created or destroyed in ordinary changes (not nuclear), it can only change form. Its not just a good idea, its the law. 41