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History of the Atom Scientists and Their Discoveries Democritus (460 BC – 370 BC) • Proposed an Atomic Theory which states that all atoms are small, hard, indivisible and indestructible particles made of a single material formed into different shapes and sizes. • Aristotle did not support his atomic theory Image taken from: https://reichchemistry.wikispaces.com/T.+Glenn+ Time+Line+Project Antoine Lavoisier (1743 – 1794) Image taken from: www.ldeo.columbia.edu/.../v1001/geo time2.html Known as the “Father of Modern Chemistry” Was the first person to generate a list of thirty-three elements in his textbook Devised the metric system Married to a 13-year old MarieAnne Pierette Paulze; she assisted him with much of his work Was guillotined during the French Revolution Discovered/proposed the Law of Conservation of Mass John Dalton (1766 – 1844) In 1803, proposed an Atomic Theory which states: o All substances are made of atoms; atoms are small particles that cannot be created, divided, or destroyed. o Atoms of the same element are exactly alike, and atoms of different elements are different o Atoms join with other atoms to make new substances Calculated the atomic weights of many various elements Image taken from: chemistry.about.com/.../JohnDalton.htm J.J. Thomson (1856 – 1940) Image taken from: www.wired.com/.../news/2008/04/d ayintech_0430 Proved that an atom can be divided into smaller parts Discovered electrons Stated that the atom is neutral In 1897, proposed the Plum Pudding Model which states that atoms mostly consist of positively charged material with negatively charged particles (electrons) located throughout the positive material Won a Nobel Prize Ernest Rutherford (1871 – 1937) In 1909, suggested the following characteristics of the atom: o Has a nucleus that contains most of the mass of the atom and is made up of particles called protons, which have a positive charge o The protons are surrounded by negatively charged electrons, but most of the atom is actually empty space Did extensive work on radioactivity and was referred to as the “Father of Nuclear Physics” Won a Nobel Prize Was a student of J.J. Thomson Image taken from: http://www.scientificweb.com/en/Physics/Biographies/Er nestRutherford.html Niels Bohr (1885 – 1962) Image taken from: commons.wikimedia.org/wiki/File:Ni els_Bohr.jpg In 1913, proposed the Bohr Model, which suggests that electrons travel around the nucleus of an atom in orbits or definite paths. Additionally, the electrons can jump from a path in one level to a path in another level (depending on their energy) Won a Nobel Prize Worked with Ernest Rutherford Erwin Schrodinger (1887-1961) • In 1926, he further explained the nature of electrons in an atom: – The exact location of an electron cannot be stated – It is more accurate to view the electrons in regions called electron clouds; electron clouds are places where the electrons are likely to be found • Won a Nobel Prize Image taken from: nobelprize.org/.../1933/schrodinger -bio.html James Chadwick (1891 – 1974) Realized that the atomic mass of most elements was double the number of protons discovery of the neutron in 1932 Worked on the Manhattan Project Worked with Ernest Rutherford Won a Nobel Prize Image taken from: www.wired.com/.../news/2009/02/d ayintech_0227 The Building Blocks of Matter: Atoms - ++ + + + + + + - - - - Matter • Anything that has mass and takes up space (volume) – Examples: • • • • A brick has mass and takes up space A desk has mass and takes up space A pencil has mass and takes up space Air has mass and takes up space All of the above examples are considered matter because they have mass and take up space. Can you think of anything that would not be considered matter? Atoms • Atoms- smallest possible unit into which matter can be divided, while still maintaining its properties. - + + + + - • Made up of: - For example, what is the + – protons smallest possible unit into which a long essay can be – neutrons divided and still have some meaning? – electrons • The solar system is commonly used as an analogy to describe the structure of an atom Atoms are so small that… • A stack of 50,000 aluminum atoms = the thickness of a sheet of aluminum foil from your kitchen. www.deckersfoods.com • If you could enlarge a penny until it was as wide as the US, each of its atoms would be only about 3 cm in diameter – about the size of a ping-pong ball C-C-C-C-C-… + 999,995 more • Human hair is about 1 million carbon atoms wide. 1 trillion atoms • Typical human cell contains roughly 1 trillion atoms. . Is made of approximately 3 trillion atoms • A speck of dust might contain 3x1012 (3 trillion) atoms. • It would take you around 500 years to count the number of atoms in a grain of salt. Just one of these grains Let’s Experiment In order to try to gain an idea of how small an atom really is, you will complete the following activity. 1. 2. 3. 4. Cut a strip of 11 in. paper in half. Discard one half. Cut the remaining piece in half. Continue cutting the pieces in half and discarding the strips as many times as you can, counting the number of cuts you make Results • How many cuts were you able to make? • Do you think you could keep cutting the paper forever? Why or why not? You would have to cut the paper in half around 31 times to get to the size of any atom. http://www.miamisci.org/af/sln/phantom/papercutting.html Protons (+) • Protons- positively charged particles • Make up part of the nucleus of the atom • Identify the atom • Equal to the atomic number of the atom • Contribute to the atomic mass • Equal to the number of electrons - ++ + + + + + + - - - + - - Neutrons - ++ + + + + + + - - - - - • Neutrons- neutral particles; have no electric charge • Help make up the nucleus of the atom • Contribute to the atomic mass Electrons (-) • Electrons- negatively charged particles • Found outside the nucleus of the atom in electron orbits/levels • Each orbit/level can hold a maximum number of electrons 1st = 2, 2nd = 8, 3rd = 8 • When the orbitals are full, the atoms are stable! • This Octet Rule for atoms with < 20 electrons is 2, 8, 8, 8 • > 20 disregard - ++ + + + + + + - - - - - - Electrons (-) •Move so rapidly they create an electron cloud •Mass is insignificant •Equal to the number of protons •Valence electrons- the outermost electrons involved in the formation of chemical bonds The Atom’s “Center” • Protons and neutrons are grouped together to form the “center” or nucleus of an atom. Notice that the electrons are not apart of the nucleus - + - + + - QUARKS • Particles that make up protons and neutrons Notice the smaller particles that make up this neutron after you take a closer look. + Notice the smaller particles that make up this proton after you take a closer look. What do you notice about the number of quarks in the neutron and proton? Sub-Atomic Particles Weight Comparison (protons, neutrons, electrons) Neutron = 1.6749286 x10-27 kg Proton = 1.6726231 x10-27 kg Electron = 9.1093897 x10-31 kg - - - - - - - - - - - - - - - - - - - - - - - - - - - - 1839 electrons = 1 neutron + 1836 electrons = 1 proton + How do you think the mass of a neutron compares to that of a proton? 1 neutron ≈ 1 proton Sub-atomic Particles Size Comparison (protons, neutrons, electrons, & quarks) Size in atoms - Size in meters (m) - Atom 1 10-10 Nucleus __1__ 10,000 10-14 Proton or Neutron ___1___ 100,000 10-15 ++ + + + + + + Electron or Quark _____1____ 100,000,000 10-18 - - - (at largest) - - Something to Think About • You’ll never see life the same way again Elements • Element- made up of one kind of atom that can’t be broken down into simpler substances by physical or chemical means • 90 occur naturally on Earth • 25 were synthesized (made) by scientists 1 2 3 4 5 6 7 1 18 1 H 2 13 14 15 16 17 1.008 2 He 4.003 3 4 5 6 7 8 9 10 Li Be B 15.999 F 9.012 14.007 O 6.941 12.001 N Ne 10.811 C 18.998 11 12 13 14 15 16 17 18 Na Mg 22.990 24.305 Al 26.982 Si 28.086 P 30.974 S 32.066 Cl 35.453 Ar 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Sc 40.078 44.956 Ti 47.87 V 50.942 Cr Mn 39.098 Ca 51.996 54.938 Fe Co Ni 58.69 Cu 63.546 Zn 65.39 Ga 69.723 Ge 72.61 As 74.922 Se 78.96 Br 79.904 Kr 37 38 39 40 41 42 43 45 46 47 48 49 50 51 52 53 54 Rb Sr Zr Nb Mo 95.94 Rh Pd Ag Cd In Sn Sb Te I Xe 87.62 92.906 Tc 85.468 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 55 56 Cs Ba 132.905 3 Y 88.906 71 72 Hf 174.967 103 87 88 Ra (223) (226) 91.224 Lu 137.327 Fr 4 Lr (262) 178.49 5 73 Ta 180.95 6 7 (98) 8 55.845 44 Ru 101.07 74 75 76 W Re Os 183.84 186.207 190.23 9 10 11 12 58.933 77 Ir 192.217 78 79 80 Pt Au Hg 112 Uub 195.078 196.967 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) (268) 200.59 (285) 81 82 Tl Pb 204.383 207.2 20.180 39.948 83.80 83 84 85 86 Bi Po At Rn 116 Uuh 117 118 Uus Uuo 208.980 113 114 115 Uut Uuq Uup (284) (289) (288) (209) (292) (210) (222) 57 58 59 60 61 62 63 64 65 66 67 68 69 70 La Ce Pr Nd Pm Sm Dy Er 158.925 164.930 167.26 168.934 Yb 151.964 162.50 Ho 140.908 157.25 Tb 140.116 (145) Gd 138.906 150.36 Eu Tm 144.24 173.04 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) The Periodic Table Elements • Boxes in the periodic table contain a lot of information. To understand this information, it is necessary to refer to the periodic table’s key 8 O Oxygen 15.999 Atomic Number Element Symbol (a capital letter or a capital followed by a lower case letter) Element Name Atomic Mass Atomic Number • Atomic number- the number of protons in the nucleus of an atom • Equal to the number of electrons to make an atom neutral - - + ++ - What would be the atomic number of this atom? Atomic Mass • Atomic mass- the total number of protons and neutrons in an atom’s nucleus • Expressed in Atomic Mass Units (amu) • Each proton or neutron has a mass of 1 amu What would be the atomic mass of this atom? + - 3 4 + ++ 3 protons + 4 neutrons = an atomic mass of 7 amu Why did we not account for the electrons when calculating the atomic mass? - - How to Obtain the Number of Sub-Atomic Particles in an atom using a Periodic Table - + - ++ + + + + + + = 8 = 8 - - = 8 - Protons Neutrons + Electrons - Equal to the atomic # on the Periodic Table Equal to the atomic mass (rounded to a whole #) minus the # of protons Equal to the # of protons Example: Determine the # of protons, neutrons, and electrons in an atom of oxygen. Protons = 8 (Atomic #) Neutrons = 8 (Rounded atomic mass minus atomic #) Neutron Calculations = 16 (P + N) – 8 (P) = 8 N Electrons = 8 (# of P) Building Atoms Atoms Carbon Beryllium Oxygen Lithium Sodium Protons 6 4 8 3 11 Neutrons Electrons 6 6 5 4 8 8 4 3 12 11 Hydrogen (H) Atom • Bohr electron diagrams- show ALL the electrons in an atom. Notice the 1 electron in the 1st orbital • The rule is 2 in the first orbital, then 8, 8 = full and stable (unreactive) + =1 - =0 - =1 + Even though there are no neutrons present, Hydrogen is still considered an atom How many more electrons can fit in the 1st orbital/ level? Oxygen (O) Atom • Notice the two electrons in the first orbital/level and the six in the second + =8 =8 - - =8 ++ + + + + + + - - - - How many more electrons can fit in the 2nd orbital/ level? Sodium (Na) Atom • Notice the two electrons in the first orbital/level, eight in the second, and one in the third - + = 11 = 12 - - = 11 ++ + + + + + + - - - - - How many more electrons can fit in the 3rd orbital/ level? Lewis Structure (Electron Dot Diagram) • Valence electrons- the electrons in the outermost shell that are responsible for how an atom will behave chemically • Lewis Dot Structure- way of drawing ONLY the valence electrons of an atom • Element symbol surrounded by as many dots as there are valence electrons • Examples Al : Aluminum . .N : . . Nitrogen Mg : Magnesium How many valence electrons do each of these atoms have? Counting Valence Electrons - - - + - + + ++ + + + + + + + + - - + + - - + + - + - - - - - - Carbon Oxygen Beryllium 4 valence electrons 6 valence electrons 2 valence electrons Check for Understanding How Many Valence Electrons? • Hydrogen • Potassium • Neon • Sulfur • Calcium 1 Valence Electron 1 Valence Electron 8 Valence Electrons 6 Valence Electrons 2 Valence Electrons Making an Electron Dot Diagram Element “X” has 8 valence electrons Write down the element’s symbol and place the first two dots on any side of the symbol. . X X: If this were an atom of an element from group 1, you would just place the one dot on any side of the element. . .X : . .. .X : . . X: . .X : Place the rest of the dots in either a clockwise or counter clockwise manner around the symbol, with no side receiving two dots until each side gets one. .. : X. : .. :.X.: Check for Understanding 1 Valence Electron 6 Valence Electrons H O How many valence electrons does each atom have? Ne 8 Valence Electrons Mg 2 Valence Electrons Ion • Charged particle that typically results from a loss or gain of electrons • Two types: – Anion = negatively + charged particle – Cation = positively charged particle - - = 8 - ++ + + + + + + - - = 8 = 968 Now Now that that three this atom electrons ofof oxygen were just lost, Currently, this atom oxygen is gained the number an electron, of electrons it is no (6) longer and neutral because it has an equal protons neutral (8) an is atom. still (8) unbalanced; It is protons now number of or electrons and considered therefore, an it is ionstill (anion). but ion nowhas it (8).an ion,This ismore specifically electrons referred (9) thantoprotons as a cation. (8). - - 2+ Symbol Symbol == O O1- Building Ions Ions Protons Neutrons Electrons Carbon (C³¯) 6 6 9 Hydrogen (H¹+) 1 0 0 Oxygen (O²¯) 8 8 10 Lithium (Li³+) 3 4 0 Sodium (Na¹¯) 11 12 12 Be aware that the atomic and atomic mass are not impacted by the loss or gain of electrons. Isotopes • Isotopes- atoms that have the same number of protons, but have different numbers of neutrons • Examples Notice that each of these atoms have one proton; therefore they are all types of hydrogen. They just have a different atomic mass + Hydrogen (Protium) + - Hydrogen (Deuterium) + Hydrogen (Tritium) Isotopes • Recall that the atomic mass is the number of neutrons and protons in an atom • Example - + Hydrogen (Protium) Atomic mass # = 1 amu + - Hydrogen (Deuterium) Atomic mass # = 2 amu + - Hydrogen (Tritium) Atomic mass # = 3 amu FORCES IN THE ATOM • Gravitational Force • Electromagnetic Force • Strong Force • Weak Force Gravitational Force • The force of attraction of objects due to their masses • The amount of gravity between objects depends on their masses and the distance between them Do you think this force plays a significant role in holding the atom together? Electromagnetic Force • The force that results from the repulsion of like charges and the attraction of opposites • The force that holds the electrons around the nucleus Why are neutrons not pictured above? + + + - - Notice how the particles with the same charge move apart and the particles with different charges move together. Strong Force • The force that holds the atomic nucleus together • The force that counteracts the electromagnetic force • This force is only strong if the protons and neutrons are close together Notice how the electromagnetic force causes the protons to repel each other but, the strong force holds them together. + + + + Would an atom have a nucleus if the strong force did not exist? Weak Force • Plays a key role in the possible change of subatomic particles. – For example, a neutron can change into a proton(+) and an electron(-) Notice how the original particle changes to something new. n - + • The force responsible for radioactive decay. – Radioactive decayprocess in which the nucleus of a radioactive (unstable) atom releases nuclear radiation. If you need help remembering weak force, just think of… Atoms Forces and Elements • Forces video The Periodic Table of Elements 1 1 18 1 H 2 13 14 15 16 17 1.008 2 3 6 4 5 6 7 8 9 10 Be B C N O F Ne 6.941 9.012 11 12 Na Mg 24.305 3 4 5 6 7 8 9 10 11 12 10.811 12.001 14.007 15.999 18.998 20.180 13 14 15 16 17 18 Al 26.982 Si 28.086 P 30.974 S 32.066 Cl 35.453 Ar 39.948 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc 44.956 V Cr Mn 40.078 Ti Fe Co Ni Cu Zn Ga Ge As Se Br Kr 47.87 50.942 51.996 54.938 37 38 39 40 41 42 43 Rb Sr Y Zr Nb Mo 85.468 87.62 92.906 95.94 Tc 55 88.906 91.224 56 71 72 73 Cs Ba Lu 137.327 174.967 Hf Ta 87 88 103 Fr Ra (223) (226) 132.905 7 4.003 3 39.098 5 He Li 22.990 4 2 Lr (262) 55.845 44 Ru 72.61 74.922 78.96 79.904 83.80 45 46 47 48 49 50 51 52 53 54 Rh Pd Ag Cd In Sn Sb Te I Xe 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 74 75 76 77 78 79 80 81 82 83 84 85 86 Tl Pb Bi Po At Rn 116 Uuh 117 118 Uus Uuo Os 104 105 106 107 Rf Db Actinides 69.723 106.42 Re Lanthanides 65.39 102.906 W (262) 63.546 101.07 183.84 (261) 58.69 (98) 180.95 178.49 58.933 186.207 192.217 195.078 Pt Au Hg 108 109 110 111 Mt 112 Uub 190.23 Sg Bh Hs (266) (264) (269) Ir (268) 196.967 Ds Rg (269) (272) 200.59 (285) 204.383 207.2 208.980 113 114 115 Uut Uuq Uup (284) (289) (288) (209) (292) (210) (222) 57 58 59 60 61 62 63 64 65 66 67 68 69 70 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm 140.116 140.908 164.930 167.26 168.934 Yb 138.906 144.24 Pm 173.04 (145) 150.36 151.964 157.25 158.925 162.50 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) Periodic Table • Something “periodic” occurs at regular or generally predictable intervals • Periodic law - physical and chemical properties of the elements are periodic functions of their atomic numbers • Periodic Table of Elements – a table of the elements, arranged by atomic number, that shows the patterns in their properties; based on the periodic law Can you think of anything that is periodic? Element • A pure substance made up of one kind of atom that cannot be broken down into simpler substances by physical or chemical means • 90 occur naturally on earth • 25 were synthesized (made) by scientists • The Element Song http://www.privatehand.com/flash/elements.html Dmitri Mendeleev • In the 1860’s he devised a periodic table where the elements were ordered by their atomic masses • He did this by grouping elements together according to their similarities • Draft of Mendeleev's Periodic Table Image taken from: http://jscms.jrn.columbia.edu/cns/2006-04-18/fido-luxuriantflowinghair/mendeleev/ Mendeleev’s Published Periodic Table of Elements Why do you think there are question marks here? Image taken from: http://www.chemsoc.org/networks/learnnet/periodictable/post16/develop/mendeleev.htm Mendeleev’s Predictions • Although Mendeleev’s Periodic Table of Elements had missing elements or “gaps,” he was able to predict the characteristics of these missing elements because of Periodic Law. “Ekasilicon” Date Predicted Atomic Mass 1871 72 Germanium Date Discovered 1886 Atomic Mass 72.6 Density 5.5 g/cm3 Density 5.47 g/cm3 Bonding Power 4 Bonding Power 4 Color Dark Gray Color Grayish White Notice how Mendeleev’s predictions (orange column) were very accurate when compared to Germanium’s actual characteristics (green column) Henry Moseley • In 1914, his work led to a revision of the periodic table by rearranging the elements by their atomic numbers • He concluded that the number of protons in an atom is its atomic number Image taken from: http://dewey.library.upenn.edu/sceti/smith/ 3 Classes of Elements 1 1 1 H 2 1.008 2 3 3 4 Li Be 6.941 9.012 11 12 Na Mg 22.990 4 6 4 5 6 7 8 9 10 17 2 He 4.003 5 6 7 8 9 10 B C N O F Ne 10.811 3 15 16 11 12 20.180 12.001 14.007 15.999 18.998 13 14 15 16 17 18 Al Si P S Cl Ar 26.982 28.086 30.974 32.066 35.453 39.948 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc 44.956 V Cr Mn 40.078 Ti Fe Co Ni Cu Zn Ga Ge As Se Br Kr 47.87 50.942 51.996 54.938 37 38 39 40 41 42 43 Rb Sr Y Zr Nb Mo 85.468 87.62 92.906 95.94 Tc 88.906 91.224 (98) 55.845 44 Ru 101.07 58.933 58.69 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80 45 46 47 48 49 50 51 52 53 54 Rh Pd Ag Cd In Sn Sb Te I Xe 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba Lu Ta 137.327 174.967 Hf W Re Os 190.23 Ir 192.217 Pt 195.078 Au Hg 200.59 Tl 204.383 Pb 207.2 Bi 208.980 Po At Rn 103 112 Uub 113 114 115 117 118 Uut Uuq Uup 116 Uuh Uus Uuo (284) (289) (288) 68 69 70 132.905 7 13 14 19 39.098 5 24.305 18 Classas a guide, Color color Using this Metal code your periodic table to Non-Metal show the three classes. Start Metalloid by highlighting the “zig-zag.” 87 88 Fr Ra (223) (226) Lr (262) 178.49 180.95 183.84 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) 57 58 186.207 59 60 Nd La Ce Pr 138.906 140.116 140.908 144.24 (268) 61 62 Pm Sm (145) 150.36 196.967 63 Eu 151.964 (285) 64 Gd 157.25 65 Tb 158.925 66 Dy 162.50 67 (209) (292) (210) (222) Er Tm 164.930 167.26 168.934 173.04 Ho Yb 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) 3 Classes of Elements Metals Location • Found on the left of the zigzag line/staircase on the periodic table (exception Hydrogen) Chemical Properties • Have few electrons in their outer energy level, thus lose electrons easily Physical Properties • Ductile, good conductors, malleable, shiny, most are solid @ room temperature 79 Au 196.967 11 Na 22.990 Image taken from: http://chemistry.about.com/od/periodictableelements/ig/E lement-Photo-Gallery.--98/Sodium.htm What metal is not a solid @ room temperature? Metals’ Chemical Properties Notice: only 1 electron in outer level - + - + + - ++ + + ++ + + ++ + - Notice: only 2 electrons in outer level - - Be 22.990 - - 9.012 Na - + 4 11 - - - Metals’ Physical Properties • Good conductorelectrons (electricity) flow easily through the substance • Malleable- able to be hammered or pressed out of shape without breaking Non-Metals Location • Most found to the right of the zigzag line/staircase on the periodic table Chemical Properties • Most have almost full outer energy levels, thus they tend to gain electrons; some have completely full outer level Physical Properties • Not ductile or malleable, not shiny, poor conductors, most are solid, but some are gas at room temperature 17 Cl 35.453 Image taken from: http://nobel.scas.bcit.ca/resource/ptable/cl.htm 16 S 32.066 Image taken from: https://www.dmr.nd.gov/ndgs/rockandmineral/sulfur.asp Non-metals’ Chemical Properties 8 - O - 15.999 - ++ + + + + + + - - - - Notice: 2 electrons in outer level – FULL - + + - 2 - He - 4.003 - Notice: 6 electrons in outer level – almost full +++ + + + ++ + - 9 F 18.998 - - Notice: 7 electrons in outer level – almost full Metalloids Location • Border the zigzag line/staircase on the periodic table Chemical Properties • Most atoms have ½ (≈) complete set of electrons in outer level Physical Properties • have properties of both metals and nonmetals 14 Si 28.086 Image taken from: http://library.thinkquest.org/C0113863/bios.shtml 5 B 10.811 Image taken from: http://library.thinkquest.org/C0113863/bios.shtml Metalloids’ Chemical Properties Notice: only 4 electrons in outer level 5 B - - 10.811 ++ + + + - - - - Notice: only 3 electrons in outer level - + +++ + + ++ + + + + ++ - - - - 14 Si - 28.086 - - Important Features of the Periodic Table • Period- each horizontal row of elements on the periodic table 1 18 1 1 H 2 13 14 15 16 17 1.008 2 3 4 5 6 7 8 9 10 Li Be B C N O F Ne 6.941 9.012 11 12 Na Mg 4 5 6 7 8 9 10 11 12 14.007 15.999 18.998 13 14 15 16 17 18 Al Si P S Cl Ar 26.982 28.086 30.974 32.066 35.453 39.948 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 40.078 37 38 Rb Sr 87.62 44.956 47.87 50.942 51.996 54.938 39 40 41 42 43 Y Zr Nb Mo 92.906 95.94 Tc 88.906 91.224 (98) 55.845 44 Ru 101.07 58.933 58.69 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80 45 46 47 48 49 50 51 52 53 54 Rh Pd Ag Cd In Sn Sb Te I Xe 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 102.906 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba Lu Ta 137.327 174.967 Hf W Re Os Ir Pt Au Hg 200.59 Tl 204.383 Pb 207.2 Bi 208.980 Po At Rn 103 112 Uub 113 114 115 117 118 Uut Uuq Uup 116 Uuh Uus Uuo (284) (289) (288) 132.905 7 3 20.180 12.001 K 85.468 6 24.305 10.811 19 39.098 5 4.003 3 22.990 4 2 He 87 88 Fr Ra (223) (226) Lr (262) 178.49 180.95 183.84 190.23 192.217 195.078 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) 186.207 (268) 196.967 (285) (209) (292) (210) (222) 57 58 59 60 61 62 63 64 65 66 67 68 69 70 La Ce Pr Nd Sm Dy Er 158.925 164.930 167.26 168.934 Yb 151.964 162.50 Ho 140.908 157.25 Tb 140.116 150.36 Gd 138.906 (145) Eu Tm 144.24 Pm 173.04 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) FROM LEFT TO RIGHT OR RIGHT TO LEFT How many periods (rows) are on the Periodic Table Of Elements? Period (Row) Properties • Seven periods on a periodic table (numbered from the top down) • Atomic numbers and atomic masses increase as you move from the left to the right in a period • All atoms of the elements in the same period have the same number of orbitals/levels • All atoms of the elements in a specific period have that respective number of orbitals/levels – Example • Period 1 = 1 orbital • Period 2 = 2 orbitals • Period 3 = 3 orbitals • Etc… Examples of Period (Row) elements having the same number of orbitals/levels in their atoms - - - In what period (row) do you think these atoms reside? - + +++ ++ + + - - - + ++ + - - - - - - In what period (row) do you think these atoms reside? - - - - - - +++ + ++ + + ++ + ++ + + +++ ++ + ++ ++ - - - - - - - - - - - Important Features of the Periodic Table •Group- each column of elements on the periodic 1 18 How manytable groups (families) 1 1 H 2 1.008 2 3 4 3 4 Li Be 6.941 9.012 2 He 4.003 5 6 7 8 9 10 B C N O F Ne 10.811 20.180 12.001 14.007 15.999 18.998 13 14 15 16 17 18 Al Si P S Cl Ar 12 Mg 22.990 24.305 26.982 28.086 30.974 32.066 35.453 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 40.078 37 38 Rb Sr 87.62 3 44.956 4 47.87 5 50.942 6 51.996 7 54.938 39 40 41 42 43 Y Zr Nb Mo 92.906 95.94 Tc 88.906 91.224 (98) 8 55.845 44 Ru 101.07 9 58.933 10 58.69 11 12 63.546 65.39 69.723 72.61 74.922 78.96 79.904 39.948 83.80 45 46 47 48 49 50 51 52 53 54 Rh Pd Ag Cd In Sn Sb Te I Xe 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 102.906 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba Lu Ta 137.327 174.967 Hf W Re Os Ir Pt Au Hg 200.59 Tl 204.383 Pb 207.2 Bi 208.980 Po At Rn 103 112 Uub 113 114 115 117 118 Uut Uuq Uup 116 Uuh Uus Uuo (284) (289) (288) 132.905 7 17 11 85.468 6 15 16 Na 39.098 5 13 14 are on the Periodic Table Of Elements? 87 88 Fr Ra (223) (226) Lr (262) 178.49 180.95 183.84 190.23 192.217 195.078 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) 186.207 (268) 196.967 (285) (209) (292) (210) (222) 57 58 59 60 61 62 63 64 65 66 67 68 69 70 La Ce Pr Nd Sm Dy Er 158.925 164.930 167.26 168.934 Yb 151.964 162.50 Ho 140.908 157.25 Tb 140.116 150.36 Gd 138.906 (145) Eu Tm 144.24 Pm 173.04 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) FROM TOP TO BOTTOM OR BOTTOM TO THE TOP Group (Family) Properties • Eighteen groups on the periodic table (numbered from left to right) • Atomic numbers and atomic masses increase as you move from the top down in a group (family) • Atoms of elements in the same group have the same number of electrons in the outer orbitals of their atoms (known as valence electrons) – Exceptions: • Transition elements (3-12) • Helium (actually has 2 valence electrons) • Elements in groups usually have similar physical and chemical properties Determining the Number of Valence Electrons by Using the Periodic Table *Atoms of elements in Groups 1 and 2 have the same number of valence electrons as their group number. *Atoms of elements in Group 3-12 do not have a general rule relating their valence electrons to their group number. However, they typically have between 1 or 2 valence electrons. *Atoms of elements in Groups 13-18 have 10 fewer valence electrons than their group number. (Exception - helium atoms have only 2 valence electrons, even though they are in group 18) Examples of Group Elements with the same # of valence electrons How many electrons do each of these atoms have in their outer orbital/level? - 1 H 1.008 + 3 Li 6.941 11 Na - 22.990 - - 19 - K - 39.098 - ++ + ++ + + + ++ + - + 37 Rb - + + - 85.468 55 Cs 132.905 87 - - Fr (223) - What group (family) do these elements reside in? Group (Family) Names Alkali Alkaline MetalsEarth Noble Boron Nitrogen Carbon Oxygen Gases GroupGroupGroupGroup Halogens Metals Transition Metals 1 1 1 H 18 2 13 14 15 16 17 1.008 2 3 3 4 5 6 7 8 9 10 Be B C N O F Ne 6.941 9.012 11 12 Na Mg 6 3 4 5 6 7 8 9 10 11 12 20.180 12.001 14.007 15.999 18.998 13 14 15 16 17 18 Al Si P S Cl Ar 26.982 28.086 30.974 32.066 35.453 39.948 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc 44.956 V Cr Mn 40.078 Ti Fe Co Ni Cu Zn Ga Ge As Se Br Kr 47.87 50.942 51.996 54.938 37 38 39 40 41 42 43 Rb Sr Y Zr Nb Mo 85.468 87.62 92.906 95.94 Tc 88.906 91.224 (98) 55.845 44 Ru 101.07 58.933 58.69 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80 45 46 47 48 49 50 51 52 53 54 Rh Pd Ag Cd In Sn Sb Te I Xe 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba Lu Ta 137.327 174.967 Hf W Re Os 190.23 Ir 192.217 Pt 195.078 Au Hg 200.59 Tl 204.383 Pb 207.2 Bi 208.980 Po At Rn 103 112 Uub 113 114 115 117 118 Uut Uuq Uup 116 Uuh Uus Uuo (284) (289) (288) 68 69 70 132.905 7 24.305 10.811 19 39.098 5 4.003 Li 22.990 4 2 He 87 88 Fr Ra (223) (226) Lr (262) 178.49 180.95 183.84 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) 57 58 186.207 59 60 Nd La Ce Pr 138.906 140.116 140.908 144.24 (268) 61 62 Pm Sm (145) 150.36 196.967 63 Eu 151.964 (285) 64 Gd 157.25 65 Tb 158.925 66 Dy 162.50 67 (209) (292) (210) (222) Er Tm 164.930 167.26 168.934 173.04 Ho Yb 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) Identify the Element 1 1 18 1 H 2 13 14 15 16 17 1.008 2 3 5 6 3 4 5 6 7 8 9 Be B 14.007 O 15.999 F 9.012 12.001 N 6.941 10.811 C 18.998 11 12 13 14 15 16 17 18 Na Mg Al Si P S Cl Ar 24.305 3 4 5 6 7 8 9 10 11 12 26.982 28.086 30.974 32.066 35.453 10 Ne 20.180 39.948 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Sc 40.078 44.956 Ti 47.87 V 50.942 Cr Mn 39.098 Ca 51.996 54.938 Fe Co Ni 58.69 Cu 63.546 Zn 65.39 Ga 69.723 Ge 72.61 As 74.922 Se 78.96 Br 79.904 Kr 37 38 39 40 41 42 43 45 46 47 48 49 50 51 52 53 54 Rb Sr Y Zr Nb Mo Pd Ag Cd In Sn Sb Te I Xe 87.62 95.94 Rh 85.468 92.906 Tc 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 88.906 91.224 (98) 55.845 44 Ru 101.07 58.933 83.80 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba Lu Ta 137.327 174.967 Hf W Re Os Ir Pt Au Hg 200.59 Tl 204.383 Pb 207.2 Bi 208.980 Po At Rn 103 112 Uub 113 114 115 117 118 Uut Uuq Uup 116 Uuh Uus Uuo (284) (289) (288) 132.905 7 4.003 Li 22.990 4 2 He 87 88 Fr Ra (223) (226) Lr (262) 178.49 180.95 183.84 190.23 192.217 195.078 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) 186.207 (268) 196.967 (285) (209) (292) (210) (222) 57 58 59 60 61 62 63 64 65 66 67 68 69 70 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm 140.116 140.908 164.930 167.26 168.934 Yb 138.906 144.24 Pm 173.04 89 90 91 Ac Th 232.038 (227) (145) 150.36 92 93 Pa U Np 231.036 238.029 (237) 151.964 157.25 94 95 Pu Am (244) (243) 158.925 162.50 96 97 98 99 100 101 102 Cm Bk Cf Es Fm Md No (257) (258) (259) (247) (247) (251) (252) Carbon - C Strontium Astatine - At - Sr- Rf Period 4 Group 17 2 –––Period 5 Group Period2 14 76 Rutherfordium Using the Periodic Table • The boxes that make up the periodic table contain a significant amount of information. To understand this information, it is necessary to refer to the periodic table’s key(s) 8 Atomic Number O Element Symbol Oxygen Element Name 15.999 Class Metal Non-Metal Metalloid Color Which class does Oxygen fall into? (Number of protons) (Written with a capital letter or a capital followed by a lower case if two letters ) Atomic Mass (Rounded to a whole number, equals the number of protons and neutrons) State (@ Room Temp.) Solid Liquid Gas Symbol Color What is Oxygen’s physical state of matter? Compare: He H Fr Check for Understanding • What is the smallest atom in regards to mass in the periodic table? Circle it. • What is the largest atom (in size in atomic radius) in the periodic table? Put a dot by it. • What is the most massive atom in the periodic table? Put a star by it. • What is the most metallic element? Put a box around it. Check for Understanding • What is the smallest atom in regards to mass in the periodic table? H • What is the largest atom (in size) in the periodic table? Fr • What is the most metallic element? Put a box around it. Fr