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UNIT 1 & 2 Review First Quarter Exam Material Periodic Table The Periodic Table of Elements shows all of the known elements, arranged by Increasing atomic number The Atom The smallest particle of an Element is an Atom To the right are the atoms in the Element Gold http://www.chem.utoronto.ca/staff/DHIRANI/stm-np.jpg Atomic Models Democritus Basic shapes to identify “atoms” No subatomic particles Atomic Models Dalton Invisible and Indivisible No subatomic particles Atomic Models Thomson Plum Pudding Positive substance containing negative particles Atomic Models Rutherford Protons in Nucleus Electrons around Nucleus Atomic Models Bohr Protons and Neutrons in Nucleus Electrons around Nucleus in Orbits N Atomic Models Electron Cloud Protons and Neutrons in Nucleus Electrons around Nucleus in a cloud formed my probability N Subatomic Particles Particle Charge Mass Location Proton +1 1 amu nucleus Neutron 0 1 amu nucleus Electron -1 0 Outside the nucleus Isotope An Isotope is an atom with the same number of protons, but a different number of neutrons. Changing the neutrons changes the mass of the atom. Isotope Examples Carbon-13 and Carbon-12 The 13 and the 12 represent different masses for each atom. The “-” is a dash, not a negative sign. 13C and12C are also ways to indicate different masses Protons Atomic number = # Protons Carbon has 6 Protons Electrons Atomic number = # Electrons Unless there is a charge Fluorine has 9 electrons F-1 has 10 electrons Sodium has 11 electrons Na+1 has 10 electrons Neutrons Atomic mass - # protons = # neutrons Carbon-12 (mass)12 – (protons)6 = 6 neutrons Carbon-13 (mass)13 – (protons)6 = 7 neutrons Drawing Bohr Models Protons and Neutrons in nucleus Electrons in rings outside of nucleus Ring Ring Ring Ring Ring Ring Ring 1 2 3 4 5 6 7 = = = = = = = 2 electrons 8 electrons 8 electrons 18 electrons 18 electrons 32 electrons 32 electrons Chemical Formulas Represents the number of each type of element bonded together in a compound Remember to Multiply when there are parenthases Calcium Phosphate, Ca3(PO4)2 Ca-3, P-2, O-8 13 total atoms in one molecule of the compound. Kinetic Theory Kinetic Theory states that atoms and molecules are in constant Motion Phase Changes Point C = Boiling from Liquid to Gas Point B = Liquid Form Point A = Melting from Solid to Liquid Temperature Time The plateau (flat part of the graph) represents the phase change. The temperature of the substance does not rise (or fall) until all of it has changed phases A B C Moles Amedeo Avagadro came up with the “Chemist’s Dozen” 1 mole contains 6.02 x 1023 Particles Mole Continued The mass of one mole of any element is the same as the molar mass. Example: 1 mole of C = 12.011 grams This means that 6.02 x 1023 atoms of Carbon has a mass of 12.011 grams. Sig Figs Placeholders are NOT significant figures. With Addition/Subtraction line up the decimals. With Multiplication/Division the number of sig figs is based on the number that has the least number of sig figs. Refer to the sig fig worksheet for complete rules. Answers to sig fig problems Determine the number of significant figures in each measurement. 508.0 L ________4____________ 0.008204 g_________4___________ Round all numbers to four significant figures. Write the answers to e-h in scientific notation. 847950 kg ___847900_________ 38.5421 g____38.54__________ Complete the following addition and subtraction problems. Round off the answers when necessary 43.62 + 51.0 + 8.73 = ______103.3_________ 258.3 - 257.11 =_____1.2__________ Complete the following calculations. Round off the answers to the correct number of significant figures. 24 x 3.25 = _____78__________ 120 / 10 = ________10__________ Density Density is a ratio of mass and volume. How tightly packed? D = Density = Mass Volume Separating Mixtures In the separating mixtures lab the four methods of separation were listed. Filtration Decanting Evaporation Distillation Mixtures A Heterogeneous mixture is one where the different parts can be easily seen. o A Homogeneous mixture is one where the particles are mixed so well that the separate parts cannot be seen. Saturated vs Unsaturated Saturated: Contains the maximum amount of dissolved solute for a given amount of solvent at a specific temperature and pressure. • Unsaturated: Contains less dissolved solute for a given temperature and pressure than a saturated solution; has further capacity to hold more solute. Changes A Chemical change occurs when atoms interact and rearrange to form new substance. A Physical change occurs when properties of the substance changes, but the identity of the substance does not change. Making and Breaking Bonds When a bond is broken energy is required. When a bond is made energy is released.