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Chapter 4 Carbon and the Molecular Diversity of Life Organic Chemistry The study of carbon compounds. Urea Carbon’s versatility Forms 4 covalent bonds. Molecular shape is tetrahedral. Bonds easily to itself. Major Elements Of Organic Molecules Carbon: +4 or Hydrogen: +1 Oxygen: -2 Nitrogen: -3 -4 The valences are the “rules” for building organic molecules. Hydrocarbons Organic molecules made of only carbon and hydrogen. Examples Isomers Compounds with the same molecular formula but have different structures. Result: Different molecular and chemical properties. Types Of Isomers 1. 2. 3. Structural Geometric Enantiomers Structural Isomers Different in covalent arrangements of their atoms. Butane Isobutane Geometric Isomers Same covalent partnership but differ in spatial arrangements. Arise from the inflexibility of double bonds. Enantiomers Molecules that are mirror images of each other. Usually involve an asymmetric carbon. Comment Organisms are sensitive to even the most subtle variations in molecular architecture. Example - Thalidomide Cells can distinguish between two isomers. One is an effective drug. The other causes birth defects. Functional Groups A group of atoms attached to a carbon skeleton. Have consistent properties. Their number and kind give properties to the molecule. Importance of Functional Groups What to focus on: Structure of the functional group Properties of the functional group Examples of molecules with the functional group Aldehydes A carbonyl group at the end of a carbon skeleton. Ex. - C=O | H Sometimes written as - CHO Ketones A carbonyl group in the middle of a carbon chain. Ex. -C-C-C|| 0 Carboxylic Acids H+ (acid). Form many weak organic acids. Donate Summary Be able to recognize isomers. Know the seven functional groups and what properties they give to molecules.