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Other Organic Compounds • Table R – for most of these you will use Table R for examples Organic Alcohols: General Formula R-OH • .Monohydroxyl alcohol: a. contains one -OH group(s) b. to name: use alkane name, drop the e and add –ol *most alcohols are monohydroxyl • Example: • Structure Molecular Name Primary Alcohol: • one with the –OH group attached to an end carbon (attached to a carbon that is attached to only one other carbon) • ex: Secondary Alcohol • one with the –OH group attached to a carbon that is attached to two other carbons • ex: • • • To name a secondary alcohol, you must name the longest carbon chain and everything that is attached to that chain is named as you would name the alkenes and alkynes. • Ex: Tertiary Alcohol • one with the –Oh group attached to a carbon that is attached to three other carbons. • Ex: • • • • *name the same way you would name secondary alcohols! Dihydroxyl Alcohols • a. contains two -OH group(s) • b. to name: use alkane name, drop the e and add –diol *also include the carbon #’s the – OH groups are attached to. • c. you should know: • Structure Stock Name C2H4(OH)2 Common Name Trihydroxyl Alcohols • a. contains three -OH group(s) • b. to name: use alkane name, drop the e and add –triol *also, name the carbon #’s the –OH groups are attached to. • c. you should know: C3H5(OH)3 • Structure Stock Name Common Name Organic Acids (Carboxylic Acids) *weak electrolytes* • The only organic electrolytes – General Formula: R-COOH • to name: use alkane name, drop the e and add –oic acid • Molecular Form Structure Name • 1 • 2 Aldehydes • General Formula R-CHO • a. to name: use the alkane name, drop the e and add al • • Molecular Form Structure Name • 1 • • • 2 • • **be careful, name is close to alcohol name!!! Ketones • General Formula R-C-R • a. to name: use the alkane name, drop the e and add –one, also name the # of the carbon containing the =O • Molecular Form Structure Name Esters • The product of a combination reaction between an acid and an alcohol. • General Formula R-COOR’ • a. to name: use the beginning of the alcohol name and the ending of the acid name. Change the acid name by dropping –ic and adding –ate. • Molecular Form Structure Name Ethers • • • • • • • • General Formula R-O-R’ a. to name: name the groups attached to the –OMolecular Form Structure Name *Diethyl ether is commonly used as a solvent and anesthetic* • B. Amines: • 1. General Formula group –NH2 R-NH2; functional – a. to name: drop the e off the alkane name, add amine • Molecular Formula Name Structure • B. Amino Acids: the building blocks of proteins, they are the combination of acids and amines. • 1. Simple amino acids are named using the IUPAC system, but most are complex and common names are used. • Example: • B. Amides: the combination of an amine and an aldehyde • 1. General Formula R-C-NH2 – a. to name: drop the e from the alkane name and add -amide • Molecular Formula Structure Name