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Rechargeable Batteries What is a Rechargeable Battery? • A rechargeable battery (also known as a storage battery or secondary cell) is technically a group of two or more secondary cells, such as a laptop battery containing six individual cells. • The term rechargeable batteriey can also refer to a single cell, such as a NiMH (nickel metal hydride) AA - D battery. These batteries can be restored to full charge by the application of electrical energy, such as through a battery charger. • In other words, they are batteries in which the electrochemical reaction that releases energy is readily rechargeable. What is a Rechargeable Battery? • Rechargeable batteries come in many different sizes using different chemicals. Commonly used secondary cell ("rechargeable battery") chemistries are lead acid, nickel cadmium (NiCd), nickel metal hydride (NiMH), lithium ion (Li-ion), and lithium ion polymer (Li-ion polymer). • The batteries we recharge in our labs are NiMH batteries. How do Batteries Recharge? • CYCLING By reversing electrical current flow through the battery the chemical process is reversed, thus charging the battery. The cycle of discharging and charging is repeated continuously and is called "battery cycling". Battery Cycling • Battery in use vs. charging How do Batteries Recharge? • During charging, the positive active material is oxidized, producing electrons, and the negative material is reduced, consuming electrons. • These electrons constitute the current flow in the external circuit. How are Solar Batteries Reusable? • Photovoltaic (PV) cells are made of special materials called semiconductors such as silicon, which is currently the most commonly used. • Basically, when light strikes the cell, a certain portion of it is absorbed within the semiconductor material. This means that the energy of the absorbed light is transferred to the semiconductor. How are Solar Batteries Reusable? • The energy knocks electrons loose, allowing them to flow freely. PV cells also all have one or more electric fields that act to force electrons freed by light absorption to flow in a certain direction. This flow of electrons is a current, and by placing metal contacts on the top and bottom of the PV cell, we can draw that current off to use externally. • For example, the current can power a calculator. This current, together with the cell's voltage (which is a result of its built-in electric field or fields), defines the power (or wattage that the sun can produce) Why Buy Rechargeable Batteries? • Rechargeable batteries can offer economic and environmental benefits compared to disposable batteries. • Some rechargeable battery types are available in the same sizes as disposable types. Why Buy Rechargeable Batteries? • While the rechargeable cells have a higher initial cost, rechargeable batteries can be recharged many times. • Proper selection of a rechargeable battery system can reduce toxic materials sent to landfills compared to an equivalent series of disposable batteries. For example, battery manufacturers of NiMH rechargeable batteries claim a service life of 100-1000 charge cycles for their batteries.