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Page: 1 of 9 Revision Date: 27.03.2009 Print Date: 02.06.2011 MSDS Number: R0525029 Version: 2.1 SAFETY DATA SHEET Amergy™ 5200 FUEL OIL TREATMENT Conforms to Regulation (EU) No. 1907/2006 - MSDS_NL 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Ashland P.O. Box 8619 NL3009 AP, Rotterdam The Netherlands Emergency telephone +1-800-ASHLAND (+1-800-274-5263/+1-606-3295701) , or contact your local emergency telephone number at 112 [email protected] Product Information +31 10 497 5000 (in the Netherlands), or contact your local CSR contact person Product name Product code Product Use Description Amergy™ 5200 FUEL OIL TREATMENT 341217 no data available 2. HAZARDS IDENTIFICATION Hazard Summary Harmful Irritant Dangerous for the environment Risks Harmful: may cause lung damage if swallowed. Limited evidence of a carcinogenic effect. Irritating to skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness. 3. COMPOSITION/INFORMATION ON INGREDIENTS Components Dichloromethylbenzene Solvent naphtha (petroleum), heavy arom. Fuel oil, no. 2 ALCOHOLS, C6-12, ETHOXYLATED CAS-No. 29797-40-8 64742-94-5 EINECS-No. 249-854-8 265-198-5 68476-30-2 68439-45-2 270-671-4 Concentration >=40 - <50% >=25 - <40% >=15 - <25% >=1 - <2.5% Symbol(s) Xi, N Xn, N R-phrase(s) R38, R51/53 R65, R66, R67, R51/53 Xn, N Xi R40, R65, R66, R51/53 R36/38 Page: 2 of 9 Revision Date: 27.03.2009 Print Date: 02.06.2011 MSDS Number: R0525029 Version: 2.1 SAFETY DATA SHEET Amergy™ 5200 FUEL OIL TREATMENT Components ALCOHOLS, C9-11, ETHOXYLATED CAS-No. 68439-46-3 EINECS-No. Concentration >=1 - <2.5% Symbol(s) Xi R-phrase(s) R38, R41 For the full text of the R-phrases mentioned in this Section, see Section 16. 4. FIRST AID MEASURES General Information Consult a physician. Show this safety data sheet to the doctor in attendance. Eyes Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists. Remove contact lenses. Skin Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Obtain medical attention. Inhalation Move to fresh air. Consult a physician after significant exposure. Call a physician or poison control centre immediately. Keep patient warm and at rest. If unconscious place in recovery position and seek medical advice. Keep respiratory tract clear. In case of shortness of breath, give oxygen.If breathing is irregular or stopped, administer artificial respiration. Notes to physician Treatment: No information available. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media ABC powder, Water mist, Carbon dioxide (CO2), Dry chemical Unsuitable extinguishing media DO NOT USE: Halons Hazardous combustion products carbon dioxide and carbon monoxide, nitrogen oxides (NOx) Thermal decomposition no data available SAFETY DATA SHEET Amergy™ 5200 FUEL OIL TREATMENT Page: 3 of 9 Revision Date: 27.03.2009 Print Date: 02.06.2011 MSDS Number: R0525029 Version: 2.1 Precautions for fire-fighting Do not allow run-off from fire fighting to enter drains or water courses. Keep containers and surroundings cool with water spray. Prevent fire extinguishing water from contaminating surface water or the ground water system. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Personal protective equipment In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Ensure adequate ventilation. Pay attention to the spreading of gases especially at ground level (heavier than air) and to the direction of the wind. Environmental precautions Prevent further leakage or spillage if safe to do so. Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. Other information Comply with all applicable federal, state, and local regulations. 7. HANDLING AND STORAGE Handling Avoid formation of aerosol. Do not breathe vapours or spray mist. Avoid contact with skin and eyes. For personal protection see section 8. Provide sufficient air exchange and/or exhaust in work rooms. Avoid exceeding of the given occupational exposure limits (see section 8). Smoking, eating and drinking should be prohibited in the application area. Keep away from heat and sources of ignition. Storage Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Stable under recommended storage conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Page: 4 of 9 Revision Date: 27.03.2009 Print Date: 02.06.2011 MSDS Number: R0525029 Version: 2.1 SAFETY DATA SHEET Amergy™ 5200 FUEL OIL TREATMENT General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities. Keep away from food, drink and animal feedingstuffs. When using do not eat, drink or smoke. Ensure that eyewash stations and safety showers are close to the workstation location. Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below level of overexposure (from known, suspected or apparent adverse effects). Eye protection Safety glasses with side-shields Skin and body protection Wear as appropriate: Safety shoes Wear resistant gloves such as: Nitrile rubber butyl-rubber Respiratory protection no data available 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Form Colour Odour Boiling point/boiling range Melting point/range pH Flash point Evaporation rate Lower explosion limit/Upper explosion limit Vapour pressure Vapour density Density Solubility Partition coefficient: n-octanol/water liquid liquid dark orange hydrocarbon-like (>) 180.00 °C (<)-20 °C (+/- 1.4) 7.0 (>) 71.00 °C, Pensky Martens closed cup no data available no data available 35.00 hPa @ 25 °CCalculated Vapor Pressure no data available (+/- 0.01) 1.035 g/cm3 @ 77 °F / 25 °C no data available no data available Page: 5 of 9 Revision Date: 27.03.2009 Print Date: 02.06.2011 MSDS Number: R0525029 Version: 2.1 SAFETY DATA SHEET Amergy™ 5200 FUEL OIL TREATMENT log Pow Autoignition temperature Viscosity, dynamic no data available no data available no data available Viscosity, kinematic < 7 mm2/s @ 40 °C 10. STABILITY AND REACTIVITY Stability Stable under recommended storage conditions. Conditions to avoid None known. Incompatible products Strong oxidizing agents, Do not use with aluminum equipment at temperatures above 120 degrees F. Hazardous decomposition products carbon dioxide and carbon monoxide, nitrogen oxides Hazardous reactions Hazardous polymerisation does not occur. 11. TOXICOLOGICAL INFORMATION Routes of exposure Skin contact, Eye Contact, Ingestion, Inhalation Eye contact May irritate eyes. Skin contact Causes skin irritation.Causes skin irritation. Ingestion Aspiration hazard if swallowed - can enter lungs and cause damage.Harmful: may cause lung damage if swallowed. Inhalation Harmful if inhaled and may cause delayed lung injury.Not known to be harmful if inhaled. Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material: Skin, lung (for example, asthma-like conditions) Page: 6 of 9 Revision Date: 27.03.2009 Print Date: 02.06.2011 MSDS Number: R0525029 Version: 2.1 SAFETY DATA SHEET Amergy™ 5200 FUEL OIL TREATMENT Symptoms Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways) Target Organs Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans: cataracts, eye damage Component data Acute oral toxicity Dichloromethylbenzene LD 50 Rat: 2,400 mg/kg Solvent naphtha (petroleum), heavy arom. LD 50 Rat: 3,000 mg/kg Fuel oil, no. 2 LD 50 Rat: 12,000.000000 mg/kg ALCOHOLS, C6-12, ETHOXYLATED LD 50 Rat: 528 mg/kg ALCOHOLS, C9-11, ETHOXYLATED LD 50 Rat: 1.4 g/kg Acute inhalation toxicity Dichloromethylbenzene no data available Solvent naphtha (petroleum), heavy arom. LC 50 Rat: 3,800 mg/m3 , 4 h Fuel oil, no. 2 no data available ALCOHOLS, C6-12, ETHOXYLATED no data available ALCOHOLS, C9-11, ETHOXYLATED no data available Acute dermal toxicity Dichloromethylbenzene no data available Solvent naphtha (petroleum), heavy arom. LD 50 Rabbit: 3,000 mg/kg Fuel oil, no. 2 LD 50 Rabbit: 4,085.000000 mg/kg ALCOHOLS, C6-12, ETHOXYLATED no data available ALCOHOLS, C9-11, ETHOXYLATED LD 50 Rabbit: 5 g/kg 12. ECOLOGICAL INFORMATION Product information Aquatic toxicity Page: 7 of 9 Revision Date: 27.03.2009 Print Date: 02.06.2011 MSDS Number: R0525029 Version: 2.1 SAFETY DATA SHEET Amergy™ 5200 FUEL OIL TREATMENT no data available Environmental fate and pathways Biodegradation no data available Bioaccumulation The bioaccumulation potential cannot be determined. Component data ALCOHOLS, C9-11, ETHOXYLATED (CAS 68439-46-3) 96 h LC 50 Fathead minnow (Pimephales promelas) Renewal: 8.5 - 17 mg/l 48 h EC 50 Water flea (Daphnia magna) Renewal: 2.9 - 8.5 mg/l 13. DISPOSAL CONSIDERATIONS Waste disposal methods Dispose of in accordance with the European Directives on waste and hazardous waste. Do not contaminate ponds, waterways or ditches with chemical or used container. Container hazardous when empty. Dispose of in accordance with local regulations. Empty packaging Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. European Waste Catalogue The Waste code should be assigned in discussion between the user and the waste disposal company. 14. TRANSPORT INFORMATION ADR UN 3082 ADNR UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DICHLOROTOLUENE, AROMATIC PETROLEUM DISTILLATES) 9 III ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 9 III Page: 8 of 9 Revision Date: 27.03.2009 Print Date: 02.06.2011 MSDS Number: R0525029 Version: 2.1 SAFETY DATA SHEET Amergy™ 5200 FUEL OIL TREATMENT (DICHLOROTOLUENE, AROMATIC PETROLEUM DISTILLATES) RID UN 3082 ENVIRONMENTALLY 9 III HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DICHLOROTOLUENE, AROMATIC PETROLEUM DISTILLATES) INTERNATIONAL MARITIME DANGEROUS GOODS UN 3082 ENVIRONMENTALLY 9 III HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DICHLOROTOLUENE, AROMATIC PETROLEUM DISTILLATES) INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO UN 3082 Environmentally hazardous 9 III substance, liquid, n.o.s. (DICHLOROTOLUENE, AROMATIC PETROLEUM DISTILLATES) INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER UN 3082 Environmentally hazardous 9 III substance, liquid, n.o.s. (DICHLOROTOLUENE, AROMATIC PETROLEUM DISTILLATES) Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. 15. REGULATORY INFORMATION Product Use Description professional use Hazard symbols Harmful R-phrase(s) R38 R40 Dangerous for the environment Irritating to skin. Limited evidence of a carcinogenic effect. Page: 9 of 9 Revision Date: 27.03.2009 Print Date: 02.06.2011 MSDS Number: R0525029 Version: 2.1 SAFETY DATA SHEET Amergy™ 5200 FUEL OIL TREATMENT R51/53 R65 R67 S-phrase(s) S9 S23 S36/37 S38 S51 S62 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness. Keep container in a well-ventilated place. Do not breathe vapour. Wear suitable protective clothing and gloves. In case of insufficient ventilation, wear suitable respiratory equipment. Use only in well-ventilated areas. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Contains Solvent naphtha (petroleum), heavy arom. Fuel oil, no. 2 CAS 64742-94-5 CAS 68476-30-2 16. OTHER INFORMATION Full text of R-phrases referred to under sections 2 and 3 R38 Irritating to skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R40 Limited evidence of a carcinogenic effect. R65 Harmful: may cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness. R66 Repeated exposure may cause skin dryness or cracking. R36/38 Irritating to eyes and skin. R41 Risk of serious damage to eyes. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (+31 10 497 5000).