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Minerals Minerals: Building blocks of rocks To be considered a mineral, a substance must: • be a naturally occurring solid • be formed by inorganic processes • have a crystalline structure (orderly molecular arrangement • have a specific chemical composition • An element is a substance that cannot be broken down into simpler substances by chemical means • Minerals are made up of one or more elements Most abundant elements of the continental crust • Common rockforming minerals are mostly chemical compounds made up of these elements • How do these elements combine to make minerals? Atoms, molecules and ions • Atoms are the smallest individual particle that retains the distinctive chemical properties of an element. • Molecules are the smallest individual particle that retains the distinctive chemical properties of a chemical compound. Molecules consists of 2 or more atoms. • Ions are atoms or molecules that have a net electrical charge. They attract oppositely-charged ions to form chemical compounds. Crystalline Nature of Minerals • Crystal: any substance whose atoms are arranged in a regularly repeating pattern • Crystal growth is often interrupted due to: – lack of space – rapid cooling rate Luster: Appearance of a mineral in reflected light • Metallic (ex: pyrite) Nonmetallic – glassy (hornblende) Luster: Appearance of a mineral in reflected light • Nonmetallic- waxy (ex: chert) • Nonmetallic –dull (another chert) • Color Physical properties of minerals • Generally an unreliable diagnostic property to use for mineral identification • Often highly variable for a given mineral due to slight changes in mineral chemistry Quartz (SiO2) exhibits a variety of colors Figure 2.21 • Streak Physical properties of minerals • Color of a mineral in its powdered form • Helpful in distinguishing different forms of the same mineral • Hardness • Resistance of a mineral to abrasion or scratching • All minerals are compared to a standard scale called the Mohs scale of hardness Streak – the color of a powdered mineral Figure 2.10 Hardness • Resistance of a mineral to abrasion or scratching • All minerals are compared to a standard scale called the Mohs scale of hardness Physical properties of minerals • Cleavage • Tendency to break along planes of weak bonding • Produces flat, shiny surfaces • Described by resulting geometric shapes – Number of planes – Angles between adjacent planes Common cleavage directions Three examples of perfect cleavage – fluorite, halite, and calcite Copyright © 2006 Pearson Prentice Hall, Inc. Classification of Minerals Rock-forming minerals • Common minerals that make up most of the rocks of Earth’s crust • Only a few dozen members • Composed mainly of the 8 elements that make up over 98% of the continental crust Elemental abundances in continental crust Figure 2.15 Classification of Minerals • In most cases, minerals are grouped according to the major “building block” in the chemical structure. • Silicates (SiO44-) • Oxides (O22-) • Sulfides (S2-) • Sulfates (SO42- ) • Carbonates (CO32-) • Halides (Cl1- , F1- Br1- ) • Native Elements (single element) Rock-forming Minerals – The Silicate Group • Most common mineral group due to large amounts of silicon and oxygen in Earth’s crust • Basic building block is the silicate ion: Four oxygen ions surrounding a much smaller silicon ion. • Polymerization: process by which silicate ions bond to form more complex ions, such as rings, chains, sheets or 3 dimensional frameworks. Common Silicate minerals • Olivine Group – High temperature Fe-Mg silicate – Individual silicate linked together by iron and magnesium ions – Forms small, rounded crystals with no cleavage Common Silicate minerals • Pyroxene Group – Single chain structures involving iron and magnesium – Two distinctive cleavages at nearly 90 degrees Common Silicate Minerals • Amphibole Group – Double chain structures involving a variety of ions linking the silicate ion – Two perfect cleavages at non right angles Hornblende is the most common mineral in the amphibole group Common Silicate Minerals • Mica Group – Sheet structures that result in one direction of perfect cleavage – Biotite is the common dark colored mica. Common Silicate Minerals • Mica Group – Sheet structures that result in one direction of perfect cleavage – Muscovite is the common light colored mica. Classification of Minerals • Common Silicate minerals • Feldspar Group – Most common mineral group – 3-dimensional framework that exhibits two directions of cleavage at 90 degrees – Orthoclase (potassium feldspar) and Plagioclase (sodium and calcium feldspar) are the two most common members Feldspar Minerals Potassium feldspar - Orthoclase Copyright © 2006 Pearson Prentice Hall, Inc. Calcium-rich plagioclase feldspar labradorite Quartz Consists entirely of silicon and oxygen (SiO2). This is a material called silica. Strong bonds in all directions – cleavage absent. Naturally clear, but impurities cause colors. Chert – Cryptocrystalline Quartz Nonsilicate Rock-forming mineral groups • Carbonatesminerals found in exoskeletons of marine organisms. Calcite (calcium carbonate – CaCO3) is the most important carbonate mineral. Nonsilicate Rock-forming mineral groups • Sulfates – minerals containing the sulfate ion • Gypsum (Calcium sulfate: CaSO4 – 2H2O. A product of rapid evaporation of ancient seas.