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NORTH MAHARASHTRA UNIVERSITY, JALGAON M.Sc. (Part II) Inorganic Chemistry SEMESTER – III AND IV PROPOSED SYLLABUS Revised Syllabus From June- 2011 NORTH MAHARASHTRA UNIVERSITY, JALGAON M.Sc. (Part II) SEMESTER – III AND IV Inorganic Chemistry Revised Syllabus From June 2011 PROPOSED SYLLABUS COURSE STRUCTURE SEMESTER III CH-330:-Co-ordination Chemistry (I) CH-331:-Inorganic Polymer Chemistry CH-332:-Solid State Chemistry CH-333:-Some Selected Topics In Inorganic SEMESTER - IV CH-430: Co-ordination Chemistry (II) CH-431:-Physical Methods In Inorganic Chemistry CH432:-Organometalic metallic Chemistry and catalysis. Practical Courses CH-I-2:-Inorganic Chemistry Practical Annual CH-I-3:-Inorganic Chemistry Practical Annual CH-I-4:- A Short Research Project Note: 1. There are in all four theory courses for Third Semester And three theory courses for fourth semester and Three annual practical courses including one short research project. 2. Each theory course should be covered in 6 periods each of 6o minutesper week. 4 periods for lectures and two periods for tutorials,seminars etc.to be completed in 60 lectures of 60 min duration each. 3. The marks for each paper (theory and practical) are distributed as external (80 marks) and internal (20 marks) examinations. For internal assessment of each theory course 3 written test /tutorial will be taken in which best of two will be considered for internal marks. 4. Each practical course and a requires 6 hours of laboratory work per week and curse will be extended over two semesters and the candidate the candidate will be examined at the end of the year. 5. There should not be more than 10 students in a batch of a practical course.Each practical course is having weightage Six Hours per week. 6. Student have to submit a journal certified by the Head of the Department /Head of the Institution.And student will not be permitted to appear at the practical examination unless he /she produce a certified journal. If the journal is lost ,the student should produce a certificate from Head of the department / Head of the Institution stating that he /she has satisfactorily completed the practical work. SEMESTER III COURSE STRUCTURE CH-330:-Co-ordination Chemistry (I) Sr. Name of the chapter/topic No. No.of periods Weightage Weightage without with option(80) option(120) 40 60 1 Inorganic Reaction Mechanism 30 2 Biological Inorganic Chemistry 05 07 11 3 Biological role of 'S' block elements 06 08 12 Biological role of transition elements 12 16 24 Metals in Medicine 07 09 13 4 5 CH-331:-Inorganic Polymer Chemistry Sr. Name of the chapter/topic No. 1 Zeolites 2 3 4 5 Supramolecular Chemisrty Metal Clusters Isopoly and heteropoly acids and salts. Macrocyclic complexes No.of periods 24 Weightage without option 32 Weightage with option 48 08 11 16 18 04 24 05 36 08 06 08 12 CH-332:-Solid State Chemistry Sr. No. Name of the chapter/topic No.of periods 1 2 Defects of solids Mechanical properties of material Amorphous solids Ceramic material Composite material Semiconductor devices Electrical conductivity of solid Magnetic Behavior of material 3 4 5 6 7 8 08 06 Weightage without option (80) 11 08 Weightage with option (120) 16 12 06 03 03 08 12 08 04 04 11 16 12 06 06 16 24 14 18 28 CH-333:-Some Selected Topics In Inorganic Chemistry Sr. Name of the chapter/topic No. 1 2 3 4 5 6 7 Group Theory Group Theory Group Theory The chloroalkali industry Noble gases Nano Particles Metal – ligand equillibria in solution No.of periods 08 10 12 06 06 10 08 Weightage without option (80) 10 14 16 08 08 14 10 Weightage with option (120) 15 21 24 12 12 21 15 M.Sc. (Part II) Inorganic Chemistry SEMESTER – III – SYLLABUS CH 330 Coordination chemistry I Inorganic Reaction Mechanism (30L) • Type of Mechanisms: Basic concepts as stability and lability, stability constants; HSAB principle, chelate effect, Macrocyclic effect. • Substitution Reaction of Octahedral Complexes: The nature of Substitution Reaction, Theoretical approach to Substitution mechanism, Nucleophilic reactivity, Nature of central atom, Kinetic application of crystal field theory, Substitution reaction of Co(III) complexes, Replacement of co-ordinated water, Acid catalysis. Substitution in octahedral complexes: SN1, SN2 SN1CB mechanisms, • Stereochemical changes in Octahedral Complexes: Molecular rearrangement of complexes, Reaction of geometrical and optical isomers, Isomerisation and recemisation of octahedral complex, Ligand stereo specificity. • Substitution Reaction of Square-Planer Complexes: Trans effect and its theories, Mechanism of substitution reaction of Platinum (II) complexes Oxidation-Reduction Reaction: Outer sphere mechanism, Inner sphere mechanism, one and two electron transfer reactions. Bioinorganic Chemistry Chapter -1 Biological Inorganic Chemistry Defination, (5L) functional role of biological inorganic elements, some important biological ligands, crown ethers. Chapter – 2 Biological role of 'S' block elements (6L) As electrolytes, Channels & Pumps, Charge carriers, chlorophyll, energy production, Activation of enzymes, blood coagulation, endo & exo skeletons. Chapter- 3 Biological role of transition elements (12L) Biological role of – Fe Biological role of – Cu Biological role of – Zn Biological role of – Co Biological role of – Mn Chapter – 4 Metals in Medicine (7L) Deficiency & over dose of metal disease, source of metal content, metal in drug. References:th 1) 1. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 5 Edn., John-Wiley & Sons, New York. th 2) James E. Huheey, Inorganic Chemistry, 4 Edn., (1993), Addison Wesley Pub. Co., New York 3) R.H. Crabtree, The Organometallic Chemistry of the Transition Metals, st 1 Edn.(1988), John-Wiley & Sons, New York. 4) Comprehensive Coordination Chemistry”, Pergamon G. Wilkinson, R. D. Gillard and J. A. McCleverty, , Vol. 1, pp 281-322, 331- 379, 385-411, 415-458 (Chapt. 7.4) and 463-471, (1987). 5) Inorganic Reaction Mechanism, J.O. Edwards, Benjamin. 6) Mechanism Of Inorganic Reactions, F.Basolo & R.G.Pearson, Wiley New York. 7) Biological inorganic chemistry by Robert R. Crichton. 8) Bioinorganic Chemistry by Harry B. Gray & Steephen J. Lippard 9) Trace elements emerging As important in Human nutrition by Forrest H. Nielsen & Janet R. Hunt. 10) Inorganic Chemistry by Shriver, Atkins. 11) Bioinorganic Chemistry by R.M. Hay. CH-331- Selected Topics In Inorganic Polymers 1.Zeolites: (24L) A.Basic concept of Zeolites:Introduction, definition, natural and synthetic Zeolites or aluminosilicates,the primary and secondary building blocks,final framework structures, Lowenstein’s rule,sodalite and other structures.Nomenclature:atlas of Zeolites,structural distinctions,novel Zeolites,examples of small,medium,large and extralarge pore Zeolites,general properties and applications of Zeolites. B.Synthesis of Zeolites:Methods of synthesis,hydrothermal Zeolites synthesis,factores affecting Zeolite formation,Oswald’s rules of successive transformation,crystallization and identification,factors affecting crystallization,template theory,organic additives,crystallizing zeolite, ZSM-5 from an organic free solvent system,synthesis in non aqueous solvents. C.Characterization of Zeolites:XRD,SEM and other techniques,FTIR and solid state NMR,sorption capacity,surface area by BET method,pore volume and pore structure. D.Applications of Zeolites: Softening of water,agriculture.Applications in organic synthesis with at least five reactions. 2.Supramolecular Chemisrty: (8L) Concept of supramolecular Chemistry chemistry,molecular recognition,nomenclature,design of supramolecule through non covalent interactions and their applications in transport processes. 3.Metal Clusters: (18L) Higher boranes,carboranes,metallocarboranes.Metal carbonyl and halide clusters,low nuclearity clusters,isoelectronic and isolobal relationship.High nuclearity carbonyl clusters-synthesis and structural pattern.Heteroatomes in clusterscarbides,nitrides.Electron counting in high nuclear carbonyl clusters. High nuclearcarbonyl clusters of Ge,Ru,Os,Co,Rh,Ir,Ni,Pd and Pt.Halide and chalcogenide clusters.Cheveral phases,triangular clusters.Solid state extended arrays. 4.Isopoly and heteropoly acids and salts. (4L) 5.Macrocyclic complexes: (6L) Types of macrocyclic ligands,design and synthesis by co-ordination template effect,di and polynuclear macrocyclc complexes,applications of macrocyclc complexes. • Suggested Bookes: 1. Introduction to Zeolite Science and Practice,H.Van Bekkum, E.M.Flanigen,P.A.Jacobs and J.C.Jansen(Elsevier pub. Amsterdam,2001) 2. Verified Synthesis of Zeolite material, (Elsevier science pub,2001) 3. Atlas of Zeolite framework types 5th edn.,Ch.Bbaerlocher,W.M.Meier and D.H.Olson. 4. Jean-Marie Lehn ,Supramolecular Chemistry, (1995) VCH, Weinheim. 5. F.A.Cotten andG.Wilkinson Advanced Inorganic Chemistry 6th Edn. (1999),John-Wiley &Sons,New York. CH-332 Solid State Chemistry 1. Defects of solids (08) Defects of solids, classification of imperfections, Electronic defects, atomic defects, Lattice imperfections, thermodynamics of schettkey defect and frenkel defect, problems 2. Mechanical properties of material (06) Mechanical behaviours,mechanical properties,fractures of metal,ductile fracture,brittle fracture,toughness and impact testing. 3. Amorphous solids Amorphous (06) solid, glass transition temperature, oxide glasses, chalcogenide glassess,amorphous carbon,graphite,diamond,alkaline graphite compounds 4. Ceramic material (03) Defination,types,polarization,polarizibility,electric properties ceramics,dielectric properties,piezoelectric,pyroelectric and ferroelectric effect. 5. Composite material (03) Defination,fiber,concrete,asphalt,wood,several other types of composite material. 6. Semiconductor devices (08) Diodes, p-n junction, transistor, some other state materials, interstitial compound,cheveral compound, superconductivity compound, properties of superconductivity compound, storage battery material. 7. Electrical conductivity of solid (12) Electrical conductivity, origin of valence and conduction band in solids, classification of material, types of semiconductor, time dependent of conductivity, mobility of charge carriers, metal-metal junction, metal– semiconductor junction, optical properties of material, refractive index, inorganic colored solid,LASER,photolumnisences. 8. Magnetic Behavior of material (14) Magnetic properties of material,atomic magnetism in solid,the exchange interaction,classifation of magnetic material,dimagnetics,langevin paramagnetic,pauli paramagnetic,ferromagnetism,antiferromagnetism,ferrimagnetism,sperparam agnetism,ferromagnetic domain, hysteresis loop, types of hysteresis loop,problem,ferrities,hard and soft ferrities,application of magnetic material. Reference Books : 1. A. F. Wells, Structural Inorganic Chemistry – 5th edition (1984) 2. J H Huheey, Inorganic Chemisry - Principles, structure and reactivity, Harper and Row Publisher, Inc. New York (1972) 3. J. D. Lee, Concise Inorganic Chemistry, Elbs with Chapman and Hall, London 4. A. R. West, Plenum, Solid State Chemistry and its applications 5. N. B. Hanney, Solid State Physics 6. H. V. Keer, Principles of Solid State 7. S. O. Pillai, Solid State Physics 8. W. D. Callister, Wiley, Material Science and Engineering: An Introduction 9. R. Raghwan, First Course in Material Science 10. R. W. Cahan, The coming of Material Science 11. A. R. West, Basic Solid State Chemistry, 2nd edition 12. U. Schubest and N. Husing, Synthesis of Inorganic Materials, Wiley VCH (2000) 13. M. C. Day and J. Selbin, Theoretical Inorganic Chemistry, Reinhold, EWAP 14. A. H. Hanney, Solid State Chemistry, A. H. Publications 15. O. A. Phiops, Metals and Metabolism 16. Cullen Dolphin and James, Biological aspects of Inorganic Chemistry 17. Williams, An Introduction to Bioinorganic Chemistry 18. M. N. Hughes, Inorganic Chemistry of Biological Processes 19. Ochi, Bioinorganic Chemistry 20. John Wulff, The structure an properties of materials 21. L. V. Azoroff, J. J. Brophy, Electronic processes in materials, Mc Craw Hill 22. F. A. Cotton, R. G. Wilkinson. Advanced Inorganic chemistry 23. Willam L. Jooly, Modern Inorganic Chemistry 24. Manas Chanda, Atomic Structure and Chemical bonding 25. N. N. Greenwood and A. Earnshaw, Chemistry of elements,. Pergamon 26. Chakraburty, Soild State Chemistry, New Age International CH- 333 : Some selected Topics in Inorganic Chemistry (A) - Group Theory : 1) Products of symmetry operations, Group multiplication table : C2V, C2h, C3V, C4V, D2h point groups. Matrics notations for geometric transformations, properties of a group, law of reciprocal proportion, classes for C2V, C2h, C3V, C4V and D2h point groups (8 L) REF : 1,2,3 2) Reducible and irreducible representations, The Great orthogonality theorm and its rules, construction of character table; Mulikan’s symbolism for irreducible representations, Molecular term symbols, character tables for C2V, C2h, C3V, C4V, D2h,D3h and D2d point groups (10 L) REF : 1,2,3,10. 3) Reduction of reducible representation into its irreducible representation on the basis of character table, Sigma bond scheme : Hybrid orbitals with 6 bonding for tetrahydral (Td), D3h,D4h,C4V point groups. Hybrid orbitals with Pi ( ∏ ) boinding for D3h,D4h point groups, constructing symmetry adapted for linear combination (SALC) for C2V and C3V point groups. Molecular orbital approach to analyse bonding in H2O, NH3 and BF3 molecules, Transformation properties of atomic orbitals. REF : 1,2,3. (12 L) B) Basic & applied Chemistry : 1) The chloroalkali industry : (6L) Introduction, LeBlanc process, Weldon and decon processes, electrolytic process, diaphragm cell, Mecury cathode cell, solvay (ammonia soda) process REF : 7 2) Noble gases : (6L) Introduction, electronic structure, clatherate compounds, structure and bonding in XeF2, XeF4 and XeF6 compounds REF : 7 3) Nano Particles : (10L) General Introduction and objectives study, synthesis of nano material by physical, Chemical and Biological methods, Chemical thethods : Coprecipitation method – Theory and Thermodynamic of co-precipitation, Synthesis of metal from aqueous solution, Precipitation of metal by reduction from non aqueous solution, precipitation of metal by electrochemical method, precipitation of metal by radiation assisted reduction method, precipitation of metal by decomposition of metalloorganic precursor REF : 4,5,6 4) Metal – ligand equillibria in solution. (8L) Stepwise and overall formation constants and their interaction, trends in stepwise constants, Factors affecting the stability of metal complexes with reference to nature of metal ion and ligand,chelate effect and its thermodynamic origin, determination of formation constants by PH- Metry, spectrophotometric method REF : 8,9,10,11 Reference Books: 1. Chemical applications of Group theory by F-Albert cotton second edition, wiley Eastern limited New Delhi. 2. Group theory and its chemical applications by P.K. Bhattacharya Himalaya publishing House. 3. Concept and application of Group theory by Kishor Arrora Anmol publications Pvt.Ltd., New Delhi 4. Nanotechnology : Principles and particles – Sulabha K. Kulkarni (Capital Publication Co.) 5. Recent Advances in the liquid phase synthesis of Inorganic Nano particles B.L. Cushing, V.L. Kolesnichenko and C.J.O” connor chemical Review 104, 38933946 (2004) 6. Nano – The text revolution – Mohan sundara Rajan (National book trust India) 7. Concise Inorganic Chemistry fifth edition, J.D.Lee 8. Inorganic Chemistry by A.G. Sharpe third edition. 9. Advanced Inorganic Chemistry Fifth edition by F.A. Cotton and Wilkinson. 10. Inorganic Chemistry by J.E. Huhey 11. Electrons & Chemicals bonding by H.B. Gray. ***************** M.Sc. (Part II) Inorganic Chemistry COURSE STRUCTURE SEMESTER – IV CH-430: Co-ordination Chemistry (II) Sr. No. Name of the chapter/topic No.of periods 1 Molecular orbital theory of Metal Complexes Electronic Spectroscopy of metal complexes Infra-red and Raman Spectroscopy Magneto Chemistry Structural and thermodynamic consequences of partly filled shells 2 3 4 5 Weightage with option(120) 10 Weightage without option(80) 14 14 17 27 10 14 20 16 10 21 14 32 21 20 CH-431:-Physical Methods In Inorganic Chemistry Sr. No. Name of the chapter/topic No.of periods 1 Nuclear Magnetic Resonance Spectroscopy (NMR) 2 Nuclear Quadruple Resonance Spectroscopy(NQR) Electron Spin Resonance Spectroscopy (EPR/ESR) Mossbaur Spectroscopy Mass Spectrometry 3 4 5 14 Weightage without option(80) 18 Weightage with option(120) 27 04 06 09 12 16 24 05 07 07 09 10 14 6 Thermal Methods 18 24 36 CH432:-Organometalic metallic Chemistry and catalysis. Sr. No. Name of the chapter/topic No.of periods 1 Transition metal compounds with bonds to hydrogen Compounds of transition metals with single, double and triple bonds to carbon Compounds of transition metals with alkenes, alkynes and delocalize hydrogen system Oxidative addition and migration (insertion) reactions Heterogeneous catalysis Inorganic photochemistry and reactions 2 3 4 5 6 10 Weightage without option(80) 14 Weightage with option(120) 20 10 14 20 10 13 20 10 13 20 10 10 13 13 20 20 M.Sc. (Part II) Inorganic Chemistry Syllabus SEMESTER – IV CH- 430 Co-ordination Chemistry and Spectroscopy (10L) 1) Molecular orbital theory of Metal Complexes : Classification of metal, ligand orbitals in cubic and non cubic environment, octahedral, tetrahedral, square planer, square pyramidal, trigonal bipyramidal geometries – concept of ligand group orbitals – construction of molecular energy level diagrams for octahedral, tetrahedral and square planer metal complexes with sigma (6) and Pi ( ∏) bonding contribution from the ligands REF : 1,2,3 2) Electronic Spectroscopy of metal complexes : (14L) Strong ligand field configurations : The method of descending symmetry, splitting pattern of co-ordination no. 2 to 9 metal complexes, Tanabe sugano diagrams for d2 and d8 configurations. Classification of electronic spectra for metal complexes : Electric dipole transitions, Magnetic dipole transitions, relaxation in selection rules- Nature of electronic spectral bands : Band widths, Band intensities and factors influencing Band Shapes – Jahn Teller effect – Spectrochemical Series – Naphelauxetic effect – crystal Field Spectra of ‘Oh’ and ‘Td’ complexes of 3d metals – calculation of 10 Dq values, Racah parameters (B) and nephelauxetic Tatio (β) – charge transfer spectra REF : 1,2,3 3) Infra-red and Raman Spectroscopy : (10 L) Conditions for Infrared and Raman Spectroscopies, symmetry Based selection rules of infrared and Raman, complementary Nature of infra-red and Raman spectroscopies, symmetry requirement for overtone binary and ternary combination bands – Fermi Resonance- Prediction of Diagnostic Fundametals in isomers of Metal complexes, structure fitting : Determination of co-ordination sites and linkage isomers, Assigning denticity of ligands and distinguishing isomers of metal complexes – effect of co-ordination on ligand vibrations : Examples involving mono, bi or Polydentate ligands of oxygen, sulphur, nitrogen, Phosphorus, Arsenic, carbon and halogen donors. Application of Resonance Raman Spectroscopy to structural elucidation of the active sites of Heme and non heme oxygen carriers . REF : 4,5 4) Magneto Chemistry : (16L) Diamagnetic correction, single and multielectron system, types of magnetic behaviour, diamagnetism, paramagnetism ferromagnetism, Ferri, antiferro and magnetic interaction, the origin of para magnetism, magnetic behaviour of complexes, simplification of van velck equation magnitude of magnetic moments, determination of magnetic susceptibility of Gouy and Faraday method. ) Magnetic properties of complexes, paramagnetism, 1st and 2nd orderd Zeeman effect, quenching of orbital angular momentum by ligand fields, Magnetic properties of A,E,T ground terms in complexes, spin free – spin paired equillibria REF : 6,7,8,11,12,13,14,15. 5) Structural and thermodynamic consequences of partly filled shells : (10L) Ionic radii,origin of magnetic behaviour , thermodynamic effects of d- orbital splitting, magnetic properties of chemical compounds, large multiplet separation small multiplet separation, spin only, heavy atoms, high spin-low spin cross overs. REF : 7,9,10 Reference Books : 1. Symmetry and Spectroscopy of molecules K.Veera Reddy, second edition, New Age international P Limited publishers (2009) 2. Electronic Spectroscopy by A.B.P Lever 3. Intoduction to ligand fields by B .N.Figgis.. 4. Infrared and Raman Spectroscopy of Inorganic and co-ordination compounds, K. Nakamoto. 5. Infrared Spectroscopy of Inorganic Compound Bellamy. 6. Ligand Field theory and its application by B.N.Figgis and M.A.Hitchman Wiely VCH publication (2000) 7. Inorganic Chemistry D.F.Shriver and P.W.Atkins Oxford (1999) 8. Inorganic Electronic Spectroscopy : A.B.P Lever 2nd Edition Elsevier science publishers, New York (1984) 9. Advanced Inorganic Chemistry by Cotton and Wilkinson (3rd, 4th ,5th edition) 10. Theoretic al Inorganic Chemistry by Day and Selbin. 11. Introduction to Magneto Chemistry by Earnshow. 12. Mabbs and Machin Magnetism and transition metal complexes chamman Hall. 13. Calvin, Magnetic properties of transition metal complexes. 14. Magneto Chemistry by L.N. Maley. 15. Elements of Magneto Chemistry by Datta and Shymal. CH-431 Physical methods in Inorganic Chemistry 1.Nuclear Magnetic Resonance Spectroscopy (NMR) (14L) Principal of NMR spectroscopy.Chemical shift,mechanism of electron shilding and factors affecting the magnitude of chemical shift.Volume diamagnetic susceptibility, Chemical shifts for which the local diamagnetic term does not predominate,spin-spin spilitting, spin-spin coupling mechanism for transmitting nuclear spins,applications of spin-spin coupling to structure determination,applications involving magnitude of coupling constants,complex spectra,chemical exchange and the factors affecting line width,effect of chemical exchange on spectra and the evaluation of reaction rates for fast ractions,study od exchange reactions between ligands and metal ions.the double resonance technique,NMR of paramagnetic complexes –contact shift.applcations of NMR to Inorganic problems. 2.Nuclear Quadruple Resonance Spectroscopy(NQR) (4L) Introduction,effect of magnetic field on the spectra,relationship between the electric field gradient q.and molecular structure,applications involving –the interpretation of eQq data,the effects of crystal lattice on the magnitude of eQq,Structural information from NQR spectra. 3.Electron Spin Resonance Spectroscopy (EPR/ESR) (12L) Introduction,Presentation of the spectrum,hyperfine splitting in some simple systems, hyperfine splitting in various structures,factors affecting the magnitude of the g values,intractions affecting the energies of unpaired electrons in transition metal complexes ,zero-field splitting and Kramer’s degeneracy,anisotropy in hyperfine coupling constant,the nuclear quadruple intraction,the spin Hamiltonian,line widths in solid state ESR,electron delocalization,at least five different applications. 4.Mossbaur Spectroscopy (5L) Principle,Doppler broadening,resonance line shift from change in electron environment,quadruple and magnetic interactions, applications. 5.Mass Spectrometry (7L) Principle,presentation of spectra,process occuring due to combination of a molecule and a high energy electron,applications-fingerprint application and the interpretation of mass spectra,effect of isotops on the appearance of a mass spectrum,molecular weight determinations exact masses of nuclides, molecular ions, isotope ions, fragment ions of odd and even electron types, rearrangement ions.Factors affecting cleavage, cleavage patterns,simple cleavage, cleavages at a heteroatom, multicentre fragmentation rearrangements, Diels – Alder fragmentation.. 6.Thermal Methods (18L) A.Thermogravimetry(TGA):Defination,types of TGA, Instrumentation, information from TGA curve, factors affecting TGA curves (instrumental as well as characteristics of sample factors);applications TGA,calculation of percent decomposition and percent composition of compounds,limitations and adventages of TGA. B.Dervative Thermogravimetry(DTG) and its adventages. C.Differential Thermal Analysis(DTA): Definition, therotical basis of DTA, instrumentation of DTA apparatus, factors affecting DTA curves, applications of DTA, adventages and disadventages of DTA,applications of DTA D.Differential Sanning Calorimetry(DSC): Defination,comparison of DTA and DSC technique,instrumentation of DSC,factors affecting DSC curves,applications of DSC. Suggested Reference Books: 1. Physical methods in Inorganic Chemistry, R.S.Drago, Renhold Puublishing CorporationR.S.Drago 2. Instrumental Methods of Analysis,6th edition,Willard,Merit,Dean. 3. Instrumental Methods of Chemical Analysis,5th edition,Golden W.Ewing 4. Principals of Instrumental Analysis,3rd edition,Douglas A.Skoog 5. Instrumental Methods of Chemical Analysis,Anand,hatwal 6. Quantative Inorganic Analysis,A.I.Vogel CH-432 Organ metallic Chemistry and Catalysis 1. Transition metal compounds with bonds to hydrogen [10L] 2. Compounds of transition metals with single, double and triple bonds to carbon. [10L] 3. Compounds of transition metals with alkenes, alkynes and delocalize hydrogen system. [10L] 4. Oxidative addition and migration (insertion) reactions [10L] 5. Heterogeneous catalysis [10L] 6. Inorganic photochemistry and reactions [10L] Reference Books 1. Advance inorganic chemistry by Cotton and Wilkinson (5th edition) 2. Inorganic chemistry principles and applications by Butler and Harrod 3. Organo transition metal chemistry-Applications to organic synthesis by S.G.Davies(Pergamon) M.Sc.(Part II) Inorganic Chemistry Practical Courses Practical Course - CH-I-2 1.Analysis ore/alloy (any three) i)Analysis of Cement Ii)Analysis of Eleminite iii)Analysis of Haematite iv)Analysis of Steel Fe,Cr – alloy. v)Analysis of Bronze – alloy. 2. Vitamin ‘C’ from Lamon juice. 3.Estimation of Fe from Soap Bar. 4.Analysis of pigment.(Zn & Cr) 5.Analysis of Plaster of Paris 6. Preparation and photochemical analysis of Fe(III) oxalate complex. 7.To study the kinetics & hydrolysis of Co(III) complex By (a) conductance measurement (b) Spectrophotometrically. 8 .Complexometric of bismuth titration. 9. To study rate of aquation of spectrophotometry. 1,10 Phenanthroline Fe(II) in acid solution by 10To study the rate of aqation of complex trans-dichloro bis-ethylene diamine Co (II) chloride 10 Determination of Cd+2 ion conc in a given sol n polarographically following (I) calibration (II) std. addition (III) the pilot-Iron procedures. 11 Determination of Zn+2 ions present at the ppm level in the sol n employing conventional D.C.& pulse polarographic techniques. 12. Amperometric determination of Zn with std. EDTA soln . 13. To study the current –potential character.ristics of Cd+2 ions using DC polarography, sampled DC, cyclic voltammetry & pulse polarographic techniques. 14.Flame photometry Practical Course : CH-I-3 1.Synthesis, purification & analysis of co-ordination complexes of simple & chelating ligands. (Any-4) i)Bis (acetylacetonato complex of Cu (II), Co(II) & VO (IV) (any – one) ii)[ Cr(NH3 )6] Cl3 III)[Ti (urea)6] I3 iv)Ni-8 – hydroxy quinoline. v)Salicyladoxime (Fe or Cu) vi)Prussion – blue Fe4 [Fe(CN)6 ]3 2.Magneto Chemistry : Magnetic susceptibility measurements of the following complexes. i)Ni(II) -8 hydroxy quinoline. ii)Salicylladoxime (Fe of Cu) iii)Ti [(urea)6 ] I3 3.Turbidity determination- Determination of chloride in tap water by turbidity. 4.Phase diagram : Study of phase diagram of Sn-Sb alloy system. 5.Electronic spectra. : Analysis of electronic spectra of Ni(II),Co(II),Cu(II) & Cr (III) complexes. 6.TGA (Thermogravimetric analysis ) two samples. 7.Determination of no. of water molecules from the given hydrated compound. 8.Stability constant of metal complex by Bjerrum (potentiometry) method/ pH metry. 9.Kinetic masking.: 1) Determination of Cr(III) & Fe(III) in a mixture. 10.Estimation of dissolved NO3⎯ /F⎯ /Cl⎯ in the given sample by colorimetry. 11.Ion exchange method. : Separation & estimation of Zn & Cd mixture or Zn & Mg mixture. 12Preparation and characterization of cadmium sulphide nanoparticles using thioglycerol as a capping agent and calculate particle size using UV spectra.. 13Preparation of nickel nanoparticles using hydrazine hydrate as a reducing agent and determine λmax using UV spectra. Practical Course : CH-I-4 A short Reasearch Project The course includes : Literature survey, Research methodology and Industrial tour. Practical AND/ OR Oral Presentation. Desertation Report – 10 marks. I)Presentation – 30 marks. Practical – 30 marks OR II)Oral Presentation -60 marks Industrial Visit and Report – 10 marks. Reference Books: 1.Advanced Practical Inorganic Chemistry , Goel Publishing House,Unit of Krishna Praskashan Media (P) Ltd. 2.Post Graduate Practical Chemistry Part I,Himalaya Publishing House. 3.Advanced Physical Chemistry Experiments ,A Publication of Pragati Prakashan,Meerut. 4 Nano technology: Principles and Practices-Sulbha K. Kulkarni 5. A Text book of Quantitative Inorganic Analysis; A. I. Vogel 6. Practical inorganic chemistry; Pass Geoffrey and haydn Sutcliffe. 7. Advanced Practical inorganic chemistry; Gurudeep Raj. 8. Vogel’s Qualitative Inorganic Analysis, D. Svehla, VII Edn. Orient Longman Ltd..) ********