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Solved Assignment of Unit IST for Class 10 Subject: Science, Mathematics, English, History, Hindi,Urdu: SCIENCE CLASS 10TH CH: 1 LIFE PROCESSES LIFE PROCESSES Life Processes are those basic functions of living beings which are essential for their survival. They are the same in all types of living forms whether unicellular or multicellular, plants or animals. 1. Maintenance:- All living beings are made of protoplasmic structures. They have to be kept in functional state whether an organism is active or inactive. Functional state of protoplasmic structures is maintained only if they are kept in dynamic state with breakdown and build-up processes going on simultaneously. 2. Metabolism:- It is the sum total of all chemical reactions which occur in a living being due to interaction amongst its molecules. All functions of organisms are due to metabolism. Metabolism has two components, anabolism and catabolism. Anabolism orconstructive metabolism consists of build-up reactions where complex molecules are formed from simpler ones, e.g., formation of glycogen from glucose or proteins from amino acids. Energy is required for anabolicreactions. Catabolism or destructive metabolism consists of breakdown reactions where complex substances are broken down into simpler substances, e.g., respiration (breaks glucose into carbon dioxide and water). 3. Nutrition:- It is required by all living beings for providing energy and body building materials. Body building materials are usually carbon based so that food sources are also carbon based. Plants manufacture their own food in the process of photosynthesis. Animals obtain food from outside. Food obtained from outside is first broken down into simpler soluble substances for absorption. Inside the cells, the simple substances are converted into various complex bio-chemicals to form components of protoplasm. 4. Respiration:- Every living being requires energy for working of body machinery, its maintenance, repair, replacement and bio-synthesis. Energy is obtained by break down of carbon based molecules in the process of respiration. Oxidation-reduction reactions are common chemical reactions involved in respiratory break down of molecules. Most organisms use oxygen obtained from outside for the process of respiration. 5. Growth:- It is irreversible increase in body cells that occurs in young organisms prior to reaching maturity. Plants have the ability to continuously grow. Growth is possible if build-up reactions (Anabolism) are more abundant than break down reactions (Catabolic reactions). For this, the organisms must prepare or obtain food materials more than their requirement for maintenance. 6. Exchange of materials:- There is a regular exchange of materials between the living organisms and their environment. Living beings obtain nutrients, water and oxygen from their environment. They give out undigested materials, carbon dioxide and waste products. Single-celled organisms have the entire surface in direct contact with the environment. They do not possess any specific structures for intake and explosion of materials. Diffusion, facilitated transport and active transport are involved for movement of substances across the cell membrane. In multicellular organisms specialized structures have been formed for different functions e.g., ingestion, egestion, exchange of gases. 7. Transportation:- In multicellular organisms, all the cells are not in direct contact with the environment. They have specific structures for exchange of gases, ingestion and digestion of food materials. However, every cell of the body has to be provided with food, water and oxygen. Similarly, carbon dioxide and wastes have to be taken away from every cell. Therefore, a mechanism of transportation is found. It is circulatory system in animals and vascular tissues in plants. 8. Excretion:- A number of waste products are formed as by-products of metabolism. They are usually toxic and are removed from the body. The process of removal of waste products from the body is called excretion. 9. Irritability:- Every living organism is aware of its surroundings. It responds to changes in the environment. NUTRITION Nutrition may be defined as a collective phenomenon in which an organism is capable of capturing food essential not only for maintaining vital life processes, but also for repair and growth of tissues. The whole process of nutrition involves introduction of food, its digestion by various juices and enzymes and break down into smaller simpler and soluble molecules, absorption of the soluble food and lastly expulsion of undigested matter formed during the process. MODES OF NUTRITION: - The nutrition of all the organisms may broadly be grouped into three categories, which are:a) Autotrophic Nutrition Or Holophytic:- It is a mode of nutrition in which organisms are able to build up their own organic food from inorganic raw materials with the help of energy. The organisms performing Autotrophic nutrition are called Autotrophs, Auto meaning self and trophe meaning nourishment. Autotrophic nutrition is a characteristic feature of all the green coloured pigments called as chlorophyll. These plants have an ability to synthesise all the essential organic compounds. From inorganic compounds like CO2 and H2O in presence of sunlight with the help of a process called Photosynthesis. Some animals, that contain chlorophyll in their bodies also, show this property of synthesizing their own food material e.g.; Euglena and some green bacteria like sulphur and methane bacteria. b) Heterotrophic Nutrition:- It is a mode of nutrition in which organisms obtain readymade organic food from outside source. The organisms that depend upon outside sources for obtaining organic nutrients are called heterotrophs, (hetero or heteros and trophe meaning nourishment). It is a characteristic feature of all animals and non green plants, that are unable to utilize carbon and synthesis organic compounds necessary for life, but depends upon organic sources of carbon. They are thus dependent upon autotrophic organisms (Plants) and are called as heterotrophs. It is of the following types:1) Saprophytic Nutrition:-In this type of nutrition, an organism lives upon dead organic sources such as dead plants and dead animals. These usually secrete dissolving and digesting enzymes and absorb the liquidified molecules so formed e.g.; yeast, bread moulds and dung moulds etc. 2) Parasitic Nutrition:-In this type of nutrition, an organism lives totally at the expense of others and derives its food material and shelter from the other .These organisms which derive food material are called parasites and the organism from which food is derived is called as host. This type of nutrition is termed as parasitic or holozoic nutrition .It is also known as parasite-host relationship e.g. Cuscuta, Ascaris etc. 3) Holozoic Nutrition:- It is a mode of heterotrophic nutrition which involves intake of solid pieces of food. Since solid food is taken in, Holozoic nutrition is also called ingestive nutrition. Holozoic nutrition (GK. Holo-Whole, Zoon-Animal) is found in animals and protozoan protists. The food may consist of another animal, plant or its parts. Depending upon the source of food, Holozoic organisms are of three typesHerbivores, Carnivores, Omnivores. Steps in Holozoic Nutrition:There are five steps in holozoic nutrition- ingestion, digestion, absorption, assimilation and egestion. 1. Ingestion (L.ingestus-taken in.):-It is taking in of solid food with the help of temporary or permanent mouth. Different animals use different organs for catching, holding and putting the food into mouth. Cutting and tearing the solid food into small pieces is common for ingestion. 2. Digestion:-The ingested food consists of complex insoluble organic substances. The conversion of complex insoluble food ingredients into simple absorbable form is called digestion. It is a catabolic process which occurs with the help of digestive enzymes. 3. Absorption:- The digestive food is absorbed from the digestive tract and transported to all body parts. It is picked up by all the living cells. 4. Assimilation:- Inside the living cells, the absorbed food materials are used in obtaining energy and formation of new components for repair and growth of cells. Assimilation is an anabolic process as it takes part in synthesis of proteins, polysaccharides, fats and other macromolecules. 5.Egestion:- (L. egestus-discharge):- The whole of ingested food is seldom digested. The undigested components of food are thrown out of the body as faecal matter. The process is called egestion. DIFFERENCE BETWEEN AUTOTROPHIC AND HETEROTROPHIC NUTRITION Autotrophic Nutrition 1. Food is self manufactured. Heterotrophic Nutrition 1. Food is obtained readymade from outside. 2. An external source is not required. The 2. An external source of energy is required required energy is present in the food for synthesis of food. obtained from outside 3. Inorganic substances are not much required. 3. Inorganic substances constitute the raw materials for manufacturing food. 4. An external or internal digestion is 4. Digestion is absent. required for conversion of complex organic materials into simpler and soluble ones. 5. Chlorophyll is absent. 5. Chlorophyll is present for trapping light energy. 6. Organisms performing autotrophic nutrition function as producers. Examples : Green plants, Some bacteria and some protists. 6. Organisms performing heterotrophic nutrition function as consumers. Examples: Animals, Many protists and Monerans. DIGESTION Digestion may be defined as hydrolysis or breakdown of complex organic macromolecules into their diffusible and simpler organic micromolecules by certain mechanical and biochemical changes with the help of bio-catalytic enzymes so that they can be absorbed in the gastrointestinal tract for further utilization. It starts in the mouth and continues into small intestines. TYPES OF DIGESTION :Digestion is of two types: - Intracellular and Extracellular 1) Intracellular Digestion: - In unicellular organisms like Amoeba the food is taken through its surface (Endocytosis) and the digests it within the cell. This type of digestion occurring within the cell is known as Intracellular Digestion. 2) Extracellular or Intercellular Digestion:- In higher multicellular organisms the food is put into a cavity or canal called alimentary canal or digestive tract or Gut or GIT where food is digested and then absorbed into the blood to reach the different parts of the body for proper utilization. The undigested food if any is passed out of the body through the other end of the alimentary canal. This type of digestion (outside the cell) is known as Extracellular or Intercellular digestion. DIGESTION IN MAN:- Digestion of food material ingested by a man does not take place in a particular region of the digestive tract or alimentary canal. It is completed in different parts which may be described as under 1. Digestion of food in Mouth (buccal cavity):- In man the process of digestion starts in the mouth which prepares food material for the digestion. (i) Mechanical Digestion:- In mouth, food is subjected to grinding action of teeth called as mastication. It is brought about by movement of lower jaw against upper jaw. Food is broken into small pieces to increase the surface area and to make enzymatic action efficient. (ii) Chemical Digestion :-Three pairs of salivary glands i.e., parotids, sub-maxillary (sub-mandibular) and sub-lingual are activated by the stimulus of sight, smell and touch (conditional reflex) and they release saliva. Saliva is a watery fluid with ph 6.8. It contains large number of enzymes, of which salivary amylase (ptyalin) is of great importance, causing chemical digestion of starch and maltose into isomaltose. The masticated and partially digested food is then rounded off in a form of small balls called as bolus with the help of tongue and is passed through the oesophagus or food pipe or gullet into the stomach by the peristaltic movements of the oesophagus. 2. Digestion in Stomach:- During digestion, stomach performs following functions:(i) Storage:- Food is stored for some time in the stomach. This is very important function as it makes continuous feeding unnecessary. (ii) Chemical Digestion:- As food reaches stomach, a group of cells called G-cells (gastrin producing cells) in its walls produce hormone gastrin. This hormone activates gastric glands which release gastric juice. The partially digested food material is acted upon by gastric juice containing HCl, pepsin, rennin, and gastric lipase enzymes. The gastric juice is a watery acidic fluid with ph 1-2 is a composite secretion of at least three different types of cells - parietal cells, chief cells and mucous cells. The parietal cells secrete HCL, The chief cells supply pepsin and other enzymes like rennin etc. and the mucous cells secrete mucin in the stomach HCl acts as preservative and does not allow putrefaction of food. It changes inactive pepsinogen into active pepsin. It lowers ph in the stomach and provides low ph (acidic medium) for the action of pepsin. Pepsin breaks down the proteins into smaller molecules known as peptidase. Renin causes coagulation of milk by changing soluble caesinogen into insoluble caesin. Caesin reacts with calcium to form calcium paracaesinate. Gastric lipase cause fat digestion in the stomach. Mucin protects the lining of stomach against the action of HCl. (iii) Mechanical Digestion :- The walls of stomach show slight churning movements which breaks food into fine paste and mix with various juices in stomach turning the food into soup called chyme. This chyme moves towards pyloric end of stomach where pyloric sphincter contracts and juts of food pass into the duodenum for further action. 3. Digestion in Duodenum: - Digestion in duodenum can be explained as follows:(i) Inhibition of secretion of gastric juice:- As food reaches in duodenum, a group of cells in its walls called mucosal cells secrete a hormone called enterogastrone which Inhibits secretion of gastric juice. (ii) Release and functions of Bile :- Another group of cells in the walls of duodenum called I-cells secrete hormone cholecystokinin which cause gall bladder to contract and release bile in the duodenum. Functions of Bile:It causes emulsification of fat i.e., breaks fat globules into small fat droplets. It neutralizes acidic medium in food and forms an alkaline medium. It acts as antiseptic and laxative. The fat soluble vitamins are dissolved in cholesterol of Bile and then they are absorbed in blood. (iii) Release of pancreatic juice:- Another group of cells in the walls of duodenum called S-cells secrete hormone secretin which stimulates pancreas and release pancreatic juice. Pancreatic juice is a watery alkaline fluid with ph 7.8. It contains following enzymes: i. Trypsin :- It occurs in an inactive form called trypsinogen. It is rendered active by enterokinase (an enzyme secreted by mucosa cells of duodenum). Trypsin changes proteins into peptides. Trypsin can digest variety of proteins like collagen, fibrinogen etc. but not keratin. ii. Amylase :- It changes starch into maltose and isomaltose. iii. Lipase :- It changes fat into fatty acids and glycerol. iv. Chymotrypsin:- It causes coagulation of milk and changes soluble caesinogen into insoluble caesin. The peristaltic movements of walls of duodenum push food into small intestine (ileum). 4. Digestion in small intestine (ileum):- The intestinal glands i.e., Brunner's glands and Crypts of Lieberkuhn release intestinal juice or succus entericus. Intestinal juice is a watery yellowish alkaline fluid with ph 8.6. It contains following enzymes: i. Enterokinase :- It changes inactive trypsinogen into active trypsin. ii. Diamino peptidases :- They break peptides into smaller peptides. iii. Carboxy peptidases :- They break small peptides into amino acids. iv. Maltase :- It breaks maltose into glucose. v. Sucrase :- It breaks sucrose into glucose and fructose. vi. Lactase :- It breaks lactose into glucose and galactose. vii. Lipase :- It breaks fats into fatty acids and glycerol. viii. Nucleases :- They include D-nuclease and R-nuclease. They break nucleic acids into nucleotides. ix. Nucleotidases :- They break nucleotides into nucleosides and phosphates. The fully digested food in small intestine contains water, amino acids, glucose, fructose, galactose, fatty acids, glycerol, phosphates, nucleosides etc. and is called chyle. This fully digested food is then diffused through the epithelial cells of the intestinal villi (finger like projections of the intestine) into the blood vessels which carries it to the cells. 4. Digestion in large intestine:- The process of the digestion does not take place in this region. It simply secrets mucus, which serves as a lubricant for easy passage of the undigested matter in the form of faeces. The intestinal walls also absorb water from the undigested food material passed into it which is ultimately egested through the anus. Dental Caries: -It is localized softening and destruction of enamel and dentine of teeth forming cavities that reach the pulp. Dental caries is also called dental decay. It is caused by bacterium streptococcus mutans. It feeds on food particles especially sugars and produces acids. The acids are growing on food particles streptococcus mutans multiplies rapidly and forms a dental plaque. The plaque covers the teeth. Its bacteria secrete the acids that cause dental caries. Saliva which normally neutralises the acid and kills the bacteria is unable to protect the teeth because of the plaque. Brushing of teeth after meals removes the plaque. Bacteria are unable to multiply and produce acids. However, if plaque formation is allowed to persist, softening of enamel and dentine will allow the micro-organisms to reach the pulp of the teeth. This results in inflammation and infection resulting in acute pain, total decay and falling of teeth. OPENING AND CLOSING OF STOMATA It occurs due to turgor pressure of guard cells. When turgor pressure increases in guard cells, these walls are stretched apart and stomata open. When the turgor pressure falls in guard cells, these walls come close and stomata closes. Mechanism of opening and closing of stomata:Starch-Sugar Hypothesis :- Phosphorylase This theory has been put forward by Sayre and Scarth to explain the mechanism of opening and closing of stomata. According to this theory during day time CO2 in guard cells is released by the process of respiration and is utilized in photosynthesis. This increases ph of guard cells. Under high ph starch in guard cells changes into sugars in the presence of enzyme phosphorylase. Starch Glucose-6-PO4 Sugar increases osmotic pressure of guard cells. They absorb water from subsidary cells. This increases turgor pressure of guard cells. Their walls are stretched outwards and stomata opens. During night, CO2 in guard cells released in respiration is not utilized in photosynthesis. It accumulates in guard cells dissolves in water to form carbonic acid. This reduces ph of guard cells. Under low ph , conversion of starch into sugar does not occur. This reduces osmotic pressure of guard cells. They loose water by ex-osmosis. Their turgor pressure decreases and stomata close. PHOTOSYNTHESIS (Photos-Light, Synthesis-putting together) Photosynthesis may be defined as an anabolic process in which green plants manufacture complex organic food substances (carbohydrate) from simple inorganic compounds like carbon dioxide and water in presence of sSunlight unlight with the aid of chlorophyll and evolve out oxygen as a byproduct of the process. Thus photosynthesis is a process in which radiant energy is converted into chemical energy 6CO2+ 6H2O Chlorophyll C6H12O6 + 6O2 Sunlight In other words photosynthesis is a series of oxidation- reduction reaction in which CO2 is reduced and H2O is oxidized to produce carbohydrates and oxygen. Mechanism of Photosynthesis:Sunlight Photosynthesis is formation of organic food from carbon dioxide and water with the help of sunlight inside chlorophyll containing cells. Oxygen is produced as byproducts. 6CO2+ 12H2O Sunlight Glucose chlorophyll C6H12O6 + 6H2O + 6O21 Oxygen comes from water. Hydrogen of water is used to reduce carbon dioxide to form carbohydrate. light Energy 2H2O 2H2 + O2 Chlorophyll CO2 + 2H2 Energy [CH2O] + H2O Carbohydrate Actually, photosynthesis occurs in two steps, photochemical and biochemical. 1. Photochemical phase (Light or Hill Reaction):- The reactions of this phase are driven by light energy. They are of two steps- photolysis of water and formation of assimilatory power. a. Photolysis of water: - Light energy splits up water into two components. The step requires an oxygen evolving complex (formerly called z-complex) having manganese ions. Calcium and chlorine are also required. 2H2O OEC O2+ 4H+ + 4e- Mn, Ca, Cl b. Formation of Assimilatory power: - Electrons released by photolysis of water are picked up by chlorophyll a molecules. On absorption of light energy, each chlorophyll a molecule throws out an electron with gain of energy. This is primary reaction of photosynthesis which converts light energy into chemical energy. Electrons travel along an electron transport system, releasing energy in the process. The energy is used in the formation of ATP (adenosine triphosphate) from ADP and inorganic phosphate. Synthesis of ATP and ADP and inorganic Phosphate (pi) with the help of light energy is called Phototophosphorylation. ADP + Pi + energy ----------- ►ATP The electrons ultimately activate NADP (nicotinamide dinucleotide phosphate) and makes it combine with hydrogen to form NADPH2. NADP+ + 2e- + 2H+ ------------ ► NADPH + H+ (NADPH2) Both ATP and NADPH2 together form assimilatory power. 2. Biosynthetic phase (Dark or Blackman's Reaction):- It is actually light independent reaction which can occur both in light as well as in dark. It requires the energy and reducing power contained in assimilatory power of light reaction. Common pathway of biosynthetic phase is Calvin cycle. Carbon dioxide combines with ribulosebiphosphate in the presence of enzyme ribulosebiphosphate carboxylase or rubisco. It produces two molecules of phosphoglyceric acid (PGA). RuBP + CO2 rubisco 2PGA In the presence of ATP, phosphoglyceric acid is reduced by NADPH2 to form Glyceraldehydes phosphate (GAP). PGA + ATP + NADPH2 ------------ ► GAP + NADP + ADP + Pi A part of glyceraldehydes phosphate is changed into dihydroxyacetone phosphate. The two condense and form glucose. Ribulosebiphosphate is regenerated to combine with carbon dioxide again. Glucose undergoes condensation to form starch. Raw material of the photosynthesis:- The process of photosynthesis requires various raw materials essential to synthesize energy complex compounds called carbohydrates. These include: (1) Chlorophyll:-The chlorophyll or green pigment of the plant are the most active and important pigments of the photosynthesis. These are regarded as key pigments of the photosynthesis because of their remarkable ability of absorbing light energy, which is then converted into chemical energy during the process of photosynthesis. All the green plants contain chloroplasts, which give the coloring material and are accordingly called as photosynthetic- organelles of the plants. (2) CO2:- All green plants utilize free atmospheric carbon dioxide during the process of photosynthesis to synthesis energy rich complex organic molecules called carbohydrates. These photosynthetic plants fix free atmospheric carbon dioxide during daytime when light energy is available to them. But during the night, the process stops. (3) Water:- Water is another raw material for the process of photosynthesis. Plants absorb the required amount of water by root hairs and pass it on to the leaves through xylem, where it is utilized during the process of photosynthesis to synthesis energy organic compounds. (4) Light:- The sunlight is a natural and prime source of energy for photosynthesis. It has been verified by experiments that the rate of photosynthesis remains highest in red light. Ordinary light consists of seven colors (VIBGYOR) and during photosynthesis; chlorophyll does not use all the seven colors. It absorbs mostly red and violet portions only. However, the green color reflects back which gives chlorophyll a greenish appearance. Factors affecting photosynthesis:1.Temeperature:- It is one of the most important factor which affects rate of photosynthesis. Photosynthesis starts at a temperature as low as 0 degree centigrade. It is called minimum temperature. As the temperature increases, rate of photosynthesis also increases. For every increase in temperature by 10 C, rate of photosynthesis doubles. Photosynthesis is maximum at 30C - 35C. It is called optimum temperature. An increase in temperature above 35C again decreases rate of photosynthesis till at 50 C 55 C, photosynthesis stops completely, it is called maximum temperature. The three ranges of temperature are called cardinal points. Temperature has no effect on photochemical reaction of photosynthesis; however, it has a definite effect on enzyme controlled dark reaction of photosynthesis. Temperature also controls opening and closing of stomata and thus affects diffusion of CO2 in the leaves of plants. 2. Light: - Light is another factor which affects rate of photosynthesis. Infact photochemical reaction of photosynthesis is dependent on light. Both quality as well as intensity of light affects rate of photosynthesis. Photosynthesis is maximum in red and blue light, as they have longer wavelength. An increase in the intensity of light increases rate of photosynthesis. An increase in light intensity increases temperature and also causes the opening and closing of stomata. However, a very high increase in intensity of light decreases rate of photosynthesis as it causes closure of stomata. It is for this reason, that rate of photosynthesis is maximum during dusk and dawn hours when compensation point is reached i.e., amount of CO2 released in respiration is equal to the amount of CO2 utilized in photosynthesis. 3.CO2 :-It is one of the raw materials in the process of photosynthesis. Infact dark reaction utilizes CO2 for synthesis of sugars. Plants obtain CO2 from atmosphere through their stomata. Hydrophytes obtain CO2 from water in the form of carbonates and bicarbonates. Concentration of CO2 in atmosphere is only 0.03% while as plants utilize more amount of CO2 and increases rate of photosynthesis. If CO2 yyconcentration in atmosphere is raised to 1%, rate of photosynthesis will increase 20 times. This on nature CO2 always acts as a limiting factor. 4. Availability of water:- It is the raw material in the process of photosynthesis. Infect water provides protons and electrons for photochemical reactions. It increases turgor pressure of guard cells and causes stomata to open. It also hydrates protoplasm as chemical reaction of photosynthesis can occur only in hydrated state. Plants absorb water from soil by their roots; only 1% of this absorbed water is required in the process of photosynthesis. Thus under natural conditions, Water is not a limiting factor in the process of photosynthesis. However, it becomes a limiting factor during mid summer day when rate of transpiration is excessive. 5.Content of chlorophyll :- According to some authors, an increase in the content of chlorophyll increases rate of photosynthesis. However, some authors maintain that there is a relation between the content of chlorophyll and the rate of photosynthesis. Shade plants have more content of chlorophyll than sun plants, but still sun plants have higher rate of photosynthesis than the shade plants. Activities to demonstrate:- 1) Importance of Chlorophyll:- Take a variegated leaf of a garden plant that has been exposed to sunlight for few hours. Test it for starch with iodine test. Only green parts of the plant leaf will turn blue, showing that chlorophyll is necessary for photosynthesis. 2) Importance of Light:- Take a destarched potted plant, which has been kept in dark for 3 to 4 days. Cover one of its leaves completely with a carbon paper so that no light falls on it. Keep the plant in light for 4 to 6 hours. Test the covered leaf and uncovered leaf for starch with iodine test. The covered leaf will show negligible amount of starch, while the uncovered leaf will give positive test for starch. The process clearly shows that light are necessary for photosynthesis. 3) Necessity of Carbon dioxide:- Take two de starched potted plants and cover them with transparent polythene bags, so that no fresh air enters into them. Keep NaoH (Soda lime) that would absorb CO2 in one pot and NaHCO (Sodium Bi-Carbonate) solution that would produce more CO2 in the other pot. Keep both the pots in the sunlight for 4 to 6 hours and test one leaf from each for starch. The leaf from the first Pot will show no starch due to the absence of CO2, while the leaf from the second pot will give positive test for the starch, thereby showing that CO2 is necessary for photosynthesis. 4) Evolution of oxygen:- Take a beaker filled with water . Add a pinch of baking soda (NaHC03) to it and put a Hydrilla plant (Aquatic plant) in it. Cover the plant with a funnel. Invert a test tube containing water over the stem of the funnel. Keep this apparatus in the bright sunlight. After some time bubbles start emerging out from the plant, which gets collected in the upper part of the test tube. Remove the test tube and test the gas with a lighted splinter, it keeps on glowing showing that the gas is a supporter of combustion. Thus, the experiment clearly shows that O2 is evolved during photosynthesis. RESPIRATION Respiration is a biochemical process of stepwise oxidative breakdown of organic compounds inside living cells releasing small packets of energy at various steps. Respiration is an essential physiological activity of all living organisms by which they obtains energy for carrying out various vital metabolic activities of the body. However, it is a chemical activity taking place within the protoplasm of a cell, which results in the liberation of energy. Energy liberated during oxidative breakdown of respiratory substrate is partly stored in ATP. The rest is dissipated as heat. The process of respiration involves the following steps. C6H12O6 Enzymes 6CO2 + 6H2O + 38ATP 1) External Respiration or Breathing:- It refers to those mechanism by which air is brought into the body from the atmosphere and expulsion of CO2 from the body into the atmosphere. The exchange of the gases takes place at the respiratory surface such as gills, tracheae or lungs. 2) Transport of Respiratory gases:- This phase involves transport of oxygen from respiratory surface to the body tissue and CO2 from the tissues to the respiratory surface. In higher animals it takes place mainly through blood. 3) Internal or Tissue Respiration:- This phase of respiration involves consumption of oxygen by the body cells and production of CO2 as a result of oxidative processes resulting in the liberation of energy necessary for the biological work of the body. The distinct phases of respiration are represented in the diagram. AEROBIC AND ANAEROBIC RESPIRATION ENZYMES Sachs (1890) discovered that respiration can occur with or without oxygen. Therefore, there are two types of respiration, aerobic and anaerobic. 1. Aerobic Respiration (Gk. Aer-air, bios-life) It is a multi step complete oxidative breakdown of respiratory substrate into carbon dioxide and water with the help of oxygen acting as a terminal oxidant. Aerobic respiration is the usual mode of respiration in all higher organisms and most of the lower organisms. The reason is that it yields maximum amount of energy. C6H12O6 enzymes 6CO2 + 6H2O + 686 kcal or 2870 kj The energy is stored in some 38 molecules of ATP. Aerobic respiration occurs in two steps, glycolysis and Krebs cycle. a.Glycolysis (Gk. Glykys- sugar, lysis-breakdown):- Glycolysis or EMP (Embden, Meyerhof and Parnas) pathway is the first step of respiration which is common to both aerobic and anaerobic modes of respiration. It occurs in cytoplasm. Respiratory substrate is double phosphorylated before it undergoes lysis to produce 3-carbon compounds glyceraldehydes phosphate. NADH2 and ATP are produced when glyceraldehyde is changed to pyruvate. The net reaction of glycolysis is: C6H12O6 + 2ADP + 2Pi + 2NAD+ Enzymes 2C3H4O3 + 2ATP + 2NADH2 In cytoplasm b. Krebs cycle (Krebs, 1940):- It is also known as citric acid cycle or tricarboxlic acid cycle (TCA cycle). Pyruvic acid or pyrovate enters mitochondria. It undergoes oxidative decarboxylation to produce acetyl CoA, carbon dioxide and NADH2. Acetyl CoA enters Krebs cycle. Here two d ecarboxylation, four dehydrogenations and oneenzymesphosphorylation or ATP synthesis occur. Pyruvate + NAD+ + CoA oxidative Acetyl CoA + NADH2 + CO2 decarboxylation Acetyl CoA + 3NAD++ FAD CoA + 3NADH2 + FADH2 + 2CO2 Krebs cycle NADH2 and FADH2 liberate electrons and hydrogen ions. They are use in building up ATP molecules and activating oxygen molecules to combine with hydrogen for forming water. Water formed in respiration is called metabolic water. As oxygen is used at the end of Krebs cycle for combining with hydrogen, the process is called terminal oxidation. The overall equation of aerobic respiration using glucose as substrate is Glucose in cytoplasm Pyruvate in mitochondria CO2 +H2O + Energy (38 ATP) no O required O required 2 2 2. Anaerobic Respiration (Gk. An-without, Aer-Air, BOIS- Life):- It is a multi step breakdown of respiratory substrate in which atleast one end product is organic and which does not employ oxygen as an oxidant. Anaerobic respiration occurs in many lower organisms, e.g. certain bacteria, yeast. In human body it occurs regularly in red blood cells and during heavy exercise in muscles (striated muscles). Anaerobic respiration occurs entirely in the cytoplasm. It has two steps. The first step is glycolysis. Here, respiratory substrate glucose breakdown into two molecules of pyruvate, ATP and NADH2. Pyruvate is converted into ethyl alchol (C2H50H) in yeast and certain bacteria. It is changed to lactic acid (CH3CHOH.COOH). In muscle cells when oxygen utilization is faster than its availability as during vigorous exercise. It creates an oxygen debt inin cytoplasm the body. No such change occurs in blood corpuscels. In Yeast Glucose in cytoplasm C3H4O3 in cytoplasm no O2 required Pyruvate no O2 requiredz C2H5OH + CO2 + Energy (2 ATP) Ethanol In Muscle cells Glucose in cytoplasm C3H4O3 in cytoplasm CH3CHOHCOOH + Energy (2 ATP) no O2 required Pyruvateno O2 required Lactic acid DIFFERENCE BETWEEN AEROBIC AND ANAEROBIC RESPIRATION Aerobic Respiration 1. It is common method of respiration. 2. It is completed in three steps-glycolysis, Krebs cycle and terminal oxidation. 3. It requires oxygen. 4. Respiratory substrate is completely broken down. 5. They are inorganic. 6. End products show little toxicity. 7. It occurs partly in cytoplasm and partly in mitochondria. 8. An electron transport chain is required. 9. It releases 686 kcal or 2870 kj energy per mole of glucose. 10. The liberated energy is used in forming 36-38 ATP molecules per mole of glucose. Anaerobic Respiration 1. It occurs permanently only in few organisms. In other it may occur as a temporary measure to Overcome shortage of oxygen. 2. There are two steps-glycolysis and anaerobic breakdown of pyruvic acid. 3. Oxygen is not required. 4. Respiratory substrate is incompletely broken down. 5. Atleast one end product is organic. Inorganic products may or may not be present. 6. The organic end product is generally toxic. 7. It is carried out entirely in cytoplasm. Mitochondria is not required. 8. Electron transport chain is not required. 9. Energy liberated is 36-50 kcal or 150-210 kj per mole of glucose. 10. The liberated energy is used in synthesis of 2ATP molecules per mole of glucose. Mechanism of Respiration:- There are different mechanisms for process of respiration in different form of organism. The mechanisms of respiration in some of organisms may be described as under:1. Respiration in Simple organisms:- In the simplest forms of life like Amoeba, Euglena, Paramecium, Algae and Spirogyra, the respiratory gases may diffused in and out of the body through general body surface. 2. Respiration in Insects: - In insects, respiration of gases takes place through a system of internally air filled tubules called trachea. These opens into the exterior environment by paired apertures called as spiracles these tissues carry air directly into the tissues of the body and bring out carbon dioxide out from them. 3). Respiration in Aquatic animals: - In majority of higher aquatic animals like prawns and fish, the process of respiration or gaseous exchange takes place by a special respiratory organ called as gills. The gills are made up of a large number of gill plates, which increase surface area of the gills. Each gill is provided with a large number of membranous gill lamellae the bold of gills absorb dissolved oxygen from water when it mover over them and carbon dioxide from blood goes out into the water i.e., from the higher concentration of oxygen and carbon dioxide towards their lower concentration. 4). Respiration in plants: - In plants the gaseous exchange or respiration takes place through the stomata of the leaves, lenticels of woody stems and surface of the roots. The diffused air passes through the stomatal opening into the mesophyll cells of the leaves. Similarly air is diffused inn through the small microscopic openings in stem and roots of a plant and carbon dioxide is diffused out into the outer atmosphere or soil. MECHANISM OF BREATHING IN MAN Human beings like other land animals breathe through their noses with the help of pair of lungs located in an airtight thoracic cavity. The lungs are spongy, air filled sac's, which do not have any muscle tissue and thus cannot expand or contract at their own. The process of breathing is accomplished through changes in volume and air pressure of the thoracic cavity. The lungs respond passively to the pressure changes within a chest cavity due to contraction and relaxation of muscles of ribs and movements of diaphragm during inspiration and expiration. In normal breathing, air enters into the nasal chamber through nose, where it is cleaned and warmed by the ciliated epithelium. The warmed and cleaned air then passes into the windpipe or tracheae through larynx and epiglottis. The tracheae at its lower portion bifurcate into two bronchi, each entering into a lung lobe, where a bronchus divides extensively by giving out various small branches called bronchioles. Finally the air is deposited in microscopic air sacs called alveoli. These are lined by a layer of epithelial cells and surrounded by a network of blood capillaries. The air in the lungs diffuses through the walls of these blood capillaries into the main blood stream and carbon dioxide in turn diffuses out into the lungs, where from it is expelled out into the external environment. This gaseous exchange is completed within a few seconds, while the blood is passed through the alveoli. Diffusion: -The process of movement of molecules from one region to another in accordance to concentration gradient i.e., from the region of higher concentration to the region of lower concentration is called as diffusion. It takes place in all kinds of matter i e solid, liquid and gas, but the process is faster in gases than solids or liquids. The process of diffusion is a main method of transport of material in unicellular organisms like Amoeba, Euglena, Paramecium, Algae and Chlamydomonas etc. and some of the multicellular organisms like Sponges, Hydra etc. Osmosis: - When two liquids of different densities are separated from each other by a selectively permeable membrane, the water of the liquids flows towards the liquid of higher density. This process in which water moves from a solution of lower density to the solution of lower density to the solution of higher density or from a dilute to a concentrated solution through a selectively permeable membrane is called osmosis. TRANSPORTATION Transportation is the movement of materials from one part to another, usually from the region of their availability to the region of their use, storage or elimination. Transportation occurs in all organisms, from microscopic ones to large sized trees and animals. Transport in plants: - Plants absorb sufficient quantity of water from soil by means of root hairs through the process of osmosis but they also take in minerals by the process of diffusion. Some part of this water is used up by the plant during various processes and the rest evaporates from the stem and roots. The evaporation of this surplus water from the aerial parts of a plant is known as transpiration. In general, transpiration may be cuticular, lenticular or stomatal. The cuticular transpiration takes place through the cuticle found on the surface of the stem and leaves. The lenticular transpiration takes place through the lenticels found on the stem. The stomatal transpiration takes place through the stomata situated on the leaves. It is through the process of transpiration, that the water along with dissolved mineral salts is taken up and transported up through the xylem. Evaporation of water from the leaves through stomata causes a drop in the turgor pressure, which makes the xylem cells to act as a single continues column and cause uptake of water from the soil. Xylem (Wood) :- It is a complex tissue which transports sap (water and minerals). Xylem has four types of cell-xylem fibres, xylem parenchyma, tracheids and vessels. Vessels and trancheids are called tracheary elements because they take part in transport of sap. Vessels are long multicellular tubes which are formed by end to end union of several cells. Trancheids are elongated cells with pointed ends. Both the tracheary elements have lignified walls with pits or other thin unlignified areas for element to element movement of water. Xylem parenchyma takes part in lateral flow of water. Trancheids are conducting elements of non-flowering plants. Vessels occur mostly in angiosperms where they form the main conducting elements. The number of tracheids is small in angiosperms. Phloem :- It is complex tissues which takes part in transport of food. Phloem has four types of cells-sieve tubes, companion cells, and phloem parenchyma and phloem fibres. Only phloem fibres are dead cells. Others are living cells. Sieve tubes are conducting channels of phloem. They are eleongated multicellular tubular channels formed by end to end union of numerous sieve tube elements. The end walls or septa between adjacent sieve tube elements are bulged out and have pores. They are called sieve plates. Sieve tube elements do not have a nucleus. Their functioning is controlled by adjacent nucleated companion cells. Transport of Water and Minerals:- There is a continuos system of water conducting channels (vessels and tracheids) from near the root tips to near the shoot tips. In the roots the surface cells are in contact with soil particles and soil water. Ions and water are absorbed from the soil. They are pulled and pushed up by various forces to reach every cell requiring the same. The various steps involved in transport of water and minerals are as follows: 1. Mineral Absorption:- It occurs in the growing parts of the root. Both the surface or epiblema cells as well as root hairs take part in mineral absorption. Mineral absorption is an active process which involves expenditure of energy. Being an active process, mineral absorption occurs against concentration gradient. It creates a difference in the concentration of ions between the roots and the soil, with more salts being present inside the root then in the soil StfMren. 2. Absorption of water:- Root hair zone is the region of water absorption. The inside of the root has higher osmotic concentration than the soil solution. Root hairs are in contact with soil interspaces having capillary water. The root hairs pick up water which is transferred inwardly due to still high osmotic concentration. It reaches the cells surrounding the xylem channel. Salts accumulated in the basic part of xylem channel cause osmotic entry of water into xylem and form column of water. It also creates the positive pressure known as root pressure. 3. Development of negative pressure :- Leaves and other aerial parts of the plant are continuously losing water in the vapour form in the process of transpiration. Nearly 99% of the absorbed water is lost during transpiration. Major part of transpiration is stomatal transpiration. Intercellular spaces of the leaves are in contact with mesophyll cells as well as outside air through stomata. Outside air is seldom saturated with water vapours while the intercellular spaces are nearly always saturated with water due to evaporation from the wet walls of mesophyll cells. Therefore, water vapours diffuse from intercellular spaces to outside. More water vapours come from mesophyll cells to replace them. The process continues. Loss of water by mesophyll cells increases their suction pressure. They withdraw water from the xylem channels. As there are billions of mesophyll cells withdrawing water from xylem channels, water column present in the xylem comes under tension or negative pressure. Transport of food and other substances:- Food materials are translocated from the region of their manufacture or storage to the region of their utilisation. The region of supply of food is called source while the area of utilisation is called sink. The direction of translocation can be downward, upward or both. The food manufactured by leaves spaces into the storage region and other sinks in the downward direction as well as towards growing points and developing fruits in the upward direction. The translocating nutrients consist of soluble carbohydrates (mostly sucrose), amino acids, organic acids, hormones and other organic solutes. Translocation occurs thorough phloem. The channels of transport are sieve tubes (sieve cells in non flowering plants). Sieve tubes are specialised for this purpose. They are devoid of nuclei and internal membranes. The cytoplasm of one tube cells is continuous with that of adjacent sieve tube cells through sieve plates. The force required for translocation is produced by companion cells which live adjacent to sieve tube cells. Translocation: - Translocation is the movement of dissolved substances from one part of plant to another through the xylem in accordance to the concentration gradient of various mineral salts present in the soil. BLOOD Blood is described as a connective tissue, which provides one of the means of communication between the cells of different parts of a body and the external environment. It is a fluid containing living cells, which are capable of doing metabolic changes. It performs several vital functions of the body and hence is usually referred as the seat of the soul. Blood constitutes about 7% of the body weight (about 5.6 Lts in an 80 kg man). This proportion is les in women and considerable greater in children and gradually decreasing until the adult level is reached. Composition of the blood: - Blood of higher animals including man is a viscous complex fluid tissue of red colour. It is made up of two main components viz. 1) Plasma: - Plasma represents an intercellular substance of straw colour. It constitutes about 55% of the total volume of the blood. Chemically plasma is composed of water (90 - 92%) plasma proteins, inorganic and organic in salts and a liquid called serum. It also contains a coagulative substance called fibrinogen and an anticoagulant called heparin or hirudin. 2. Formed elements: - The cellular elements constitute about 45% of the total volume of the blood. These are short and their destruction and replacement goes on constantly during the life of an animal. These include. i) Red blood cells of Erythrocytes: - The erythrocytes are produced in the bone marrow of bones. Each erythrocyte is a round biconvex disc shaped, thinnest at the centre having no nuclei at maturity. The average diameter of each erythrocyte is 106m. The individual erythrocytes are pale yellow in colour, but in aggregation they appear to be reddish in colour. Each erythrocyte is bounded by a thin membrane composed of lecithin and cholesterol, enclosing an elastic substance called as stroma and an iron containing pigment called haemoglobin. The presence of haemoglobinthe red pigment serves as the carrier of oxygen. The average life span of erythrocytes is about 120 days in mammals, after this time they are disposed off either by liver or by spleen. ii) White blood cells or Leucocytes: - White blood cells do not contain any pigment and are therefore colourless. They are larger, and fewer in number than the RBC's (1:600). They are formed in red bone marrow and in the lymph glands. The average life span of human leucocytes is about 12 to 13 days. The chief function of WBC's is to provide immunity to the body by producing special proteins called antibodies, which protects body against the infection of bacteria, viruses and debris etc. The mature white blood cells are grouped in to two main categories, granulocytes or granular leucocytes and agranulocytes or agranular leucocytes depending upon the presence of visible granules in their cytoplasm. The granulocytes are in turn of three types viz. Eosinophil, Basinophil and neutrophil and the agranulocytes are of two types viz lymphocytes and monocytes. iii) Blood platelets: - These are small, flat granular corpuscles or colourless cells, which are smaller than RBC. These are probably formed in the red bone marrow and contain a substance called thromboplast in which it acts as one of the enzymes involved in the series of chemical changes resulting in the clotting of blood at the site of an injury. The life span of these corpuscles is only 2-3 days. Hence these are constantly replenished by red bone marrow cells called as Megakaryocytes. Function of Blood:- Blood has many functions, the most important ones are summarized as under:1. Transport of oxygen and carbon dioxide: - Blood transports oxygen from the respiratory surface and thus helps in respiration. 2. Transport of food: - Blood carries soluble food from the intestine to the liver and body cells, where it is required for cellular activities. The nutritive substances transported by the blood are glucose, amino acids, fats, minerals vitamins and water 3. Transport of waste products: - Blood transports various waste products, produced during the cellular activities of the body. These waste products are harmful and require immediate elimination. 4. Chemical Co-ordination:- Blood distributes various hormones to different parts of the body. These hormones are produced by the endocrine glands of the body and helps in the co-ordination of the body. 5. Maintenance of pH: - The plasma proteins of the blood act as buffer system and prevent any shift in the pH of the blood because of the amphoteric properties of these proteins. 6. Water balance: - Blood maintains water balance in the blood by bringing about constant exchange of water between the circulating blood and the tissue fluids. 7. Transport of heat: - Blood allows transfer of heat energy from the deeper tissue to the surface of the body. 8. Defence against infection: - Blood protects the body from various infections caused by the micro-organisms like bacteria, viruses etc. with the help of WBC's. 9. Temperature Regulation: - Blood maintains the body temperature by distributing heat within the body. 10. Blood loss: - Blood prevents excessive loss of blood in an injury with the process of blood coagulation. THE TUBES-BLOOD VESSELS Human blood flows inside tubes called blood vessels. Blood vessels are of three typesarteries, veins and capillaries. 1.Arteries:- They are blood vessels which carry blood coming from heart to various organs of the body. Blood flows inside the arteries with jerks due to pumping activity of the heart. As the blood is pumped into an artery, it expands. With the flow of blood from it, the artery contracts partially. Arteries, generally, carry oxygenated blood. Only pulmonary arteries transport deoxygenated blood from heart to lungs. The wall of the arteries is thick and elastic. 2.Veins:- They are blood vessels which carry blood from various parts of the body towards the heart. Blood flows smoothly and slowly inside veins. Internal valves prevent back flow. Wall is less thickened and less elastic as compared to that of arteries. Lumen is wide. Veins carry deoxygenated blood except pulmonary veins that bring oxygenated blood from lungs to the heart. Veins are generally superficial. 3.Capillaries:- They are very narrow blood vessels (4-10 um) having a single layered wall (endothelium), which form network inside body organs. Movement of blood is very slow (1 mm/sec) so as to provide time for exchange of materials. The wall has very fine pores for exchange of substances between blood and tissue fluid. DOUBLE CIRCULATION It is a passage of the same blood twice through the heart first on the right side, then on the left side in order to complete one cycle. Double circulation has two components, pulmonary circulation and systemic circulation. (i) Pulmonary Circulation:- It is movement of blood from heat to the lungs and back. Deoxygenated blood of the body enters the right auricle, passes into right ventricle which pumps it into pulmonary arch. With the help of two separate pulmonary arteries the blood passes into the lungs. Here the arteries break up into arterioles and then capillaries for oxygenation. Capillaries join to form venules and then veins. Oxygenated blood comes back to left atrium of heart through four pulmonary veins, two from each lung. (ii) Systemic Circulation:- It is the circulation of blood between heart and different parts of the body except lungs. Oxygenated blood received by left atrium passes into left ventricle. The left ventricle pumps it into aorta for supply to different body parts including walls of the heart with the help of arteries. Inside the organs the arteries break up into arterioles and then capillaries. Capillaries provide oxygen and nutrients to tissues. They receive carbon dioxide and wastes from the tissues. Capillaries unite to form venules which join to produce veins. Veins take the deoxygenated blood which comes back to the heart but now into the right auricle. STRUCTURE OF HEART Position, shape and size of heart:- The human heart is a cone shaped, muscular organ situated under the breastbone and between the lungs inside the thoracic cavity. It is of the size of human fist, measures about 12cm in length and 9cm in breadth and lies slightly towards the left side of the chest cavity. It weighs about 250 gms in an adult female and 300 gms in an adult male. Externally the heart is covered by pericardium (a double-layered membranous sac). It protects the heart from mechanical injury. The space between two pericardial membranes is called the pericardial space, which is filled with the pericardial fluid. The pericardial fluid keeps the heart moist and reduces friction between the heart wall and the surrounding tissues when the heart beats. External Structure of the Heart: The human heart is a four-chambered organ divided by septa into two halves—the right half and the left half. Each half consists of two chambers—the upper, small-sized auricle or atrium and the lower, large- sized ventricle. The ventricles form the larger, lower part of heart. Internal Structure of the Heart: Internally, the heart has the following main components—two atria, two ventricles, great blood vessels that carry blood to the heart and away from it, various apertures and valves, and pacemaker tissues. i. Auricles (atria) the Receiving Chambers:- The auricles or atria are thin-walled chambers and are separated from each other by an inter-atricular septum. The septum has an oval, thin area called the fossa ovalis. It marks the position of an opening, the foramen ovale between the two atria in a foetus. ii. Ventricles the Discharging Chambers:- The ventricles are thick-walled chambers and are separated from each other by an obliquely placed inter-ventricular septum. The wall of the left ventricle is thicker than that of the right ventricle, because the left ventricle has to pump blood into vessels, which in turn carry the blood to the entire body. The right ventricle pumps blood to the pulmonary arteries, which carry it to the lungs. The walls of the atria are thinner than that of ventricles because they only have to pump blood into the ventricles. Great Blood Vessels of Heart : The blood vessels that enter or leave the heart are called great blood vessels. Blood Vessels Entering the Heart: The right atrium receives three blood vessels. i. Superior (Anterior) Vena Cava or Precaval:- Brings deoxygenated blood from the head and upper region of the body. ii. Inferior (Posterior) Vena Cava or Postcaval: - Brings deoxygenated blood from lower region of the body. iii. Pulmonary Veins:- The left atrium receives two pairs of pulmonary veins, one pair from each lung. These bring oxygenated blood from the lungs. iv. Coronary sinus: Brings deoxygenated blood from the heart’s wall itself. It consists of two coronary arteries arising from the base of the aorta. These supply blood to the heart muscles. If coronary arteries get blocked, then it can cause heart attack. Blood Vessels Leaving the Heart: i. Pulmonary Artery:- Arises from the right ventricle and carries deoxygenated blood to the lungs for purification. ii. Systemic Aorta:- Arises from the left ventricle and supplies oxygenated blood to all body parts, except the lungs. Apertures and Valves of Heart : There are four valves in the heart which control the flow of blood within the heart and its passage to various parts of the body through the great blood vessels. i. The bicuspid valve:- It is also called the mitral valve or left atrio-ventricular valve guards the opening of the left auricle into the left ventricle. ii. The tricuspid valve:- It is also called the right atrio- ventricular valve guards the right atrio-ventricular aperture. iii. Semilunar or pulmonary valves:- They are present at the base of aortic and pulmonary arches. These valves check the back flow of blood into the ventricles. iv. Aortic semilunar valve:- It is present at the point of origin of aorta from the left ventricle. In all, there are three semilunar valves in the vessels. Pacemaker tissues of Heart : Certain tissues in the heart, concerned with the initiation (generation of impulse) and propagation (conduction) of the heart beat, are called “Pace- Maker” tissue, such as: 1. Sino Atrial Node (S.A. Node):- It is located at the junction of superior vena cava with right atrium, it initiates and maintains the myocardial activity and its rhythmicity, (called pace maker of heart). 2. Atrio-Ventricular Node (A.V. Node):- Located posteriorly on right side of the interatrial septum near coronary sinus, in the destruction of S.A. Node. The function of pace maker can be taken up by the A.V. Node. 3. Bundle of HIS:- Starts from A.V. Node along interventricular septum at the top. Impulses travel along bundle of HIS on to ventricles. 4. Purkinje Fibers:Located at the terminal divisions of right and left branch of the bundle of HIS. Purkinje fibers transmit the impulse at a fast velocity of 4 mts/sec. Working of Heart (Circulation of blood through heart) :The pumping action of heart starts by the contraction of its muscular walls. The alternate contraction and relaxation (dilation) continues regularly. The waves of contraction is initiated by Sino-atrial node (S.A. Node) situated on inner wall of right atrium. Right atrium is filled with deoxygenated blood, brought through the right and left superior vena cava from right and left side of the head, neck, chest and arm. Right and left inferior vena cava brings deoxygenated blood to right atrium from left and right lower body parts such as abdomen and legs.(Simultaneously left atrium is filled with oxygenated blood) when both atria are filled with the blood, wave of contraction starts from S.A. Node and spreads over both the atrai resulting the contraction of both atria, simultaneously, and blood is pushed into ventricles of their sides through atrio-ventricular valves. Atrio-ventricular valve (tricuspid valve) which is a three flap valve present between the right atrium and right ventricle, stops back flow of blood from ventricles to atrium. Atrio-ventricular valve which is a two flap (bicuspid valve) valve present between left atrium and left ventricle and stops back flow of blood from ventricle to atrium. Just after the filling of ventricles, relaxation starts in the walls of atria due to this, deoxygenated blood rushes from veins to right atrium and oxygenated blood through pulmonary vein into left atrium. Now atrio-ventricular node is excited, (Present near inter auricular septum on the wall of right atrium) wave of contraction of atria, wave of contraction spreads over to wall of ventricles through bundle of HIS and Purkinje Fibers. Now both the ventricles contract simultaneously causing pressure of blood contained in them, blood of right ventricle is forced in pulmonary artery through semilunar valves, (this valve prevent the backflow of the blood) to the lungs for gaseous exchange, (oxygenation and carbon dioxide removal and also provide nutrition to the lungs) after this oxygenated blood comes to left atrium through pulmonary vein. From left atrium oxygenated blood passes into left ventricle through left atrio-ventricular valve. Now from left ventricle oxygenated blood is pumped into aorta through aortic semilunar valve to supply it to all body parts. The heart contracts about 72 times in the similar fashion in one minute and the total volume of the blood pumped out by the heart in every minute varies approximately in between 5 - 6 litres. However, the course of blood circulation in man can be represented as under: Oxygenated blood --------► Left atrium -------- ► Left ventricle ------- ► Aorta ------- ► Arterioles -------- ► Organs ---------- ► Venous capillaries -------► Venules(Deoxygenated blood) -------- ► Veins ------- ► R. Auricle ------- ► R. Ventricle------ ► Pulmonary artery ------ ► Lungs (For oxygenation) -------- ► Pulmonary veins ------- ► Left atrium CARDIAC OUTPUT Cardiac output is the output of the heart per minute. In quantitative terms, it is the amount of blood pumped by each ventricle per minute. The amount of blood pumped by either ventricle during every beat (called stroke volume) is about 70 ml at rest, and the heart beats about 70 times per minute at rest. Hence, cardiac output is expressed as under: Cardiac output = Stroke volume x Heart rate = 70 ml x 70/min = 4900 ml/min = 5 L/min (approx.) Cardiac output varies in day-to-day situations. One every day example of such a situation is exercise, which is associated with an increase in blood flow to the working muscles of the legs, hands and heart. During exercise, the cardiac output may increase up to about five-fold even in untrained persons and up to ten-folds in the trained athlete. CARDIAC CYCLE The cardiac cycle is the sequence of events that occur when the heart beats. There are two phases of cardiac cycle: (1). Diastole - Ventricles are relaxed. (2). Systole - Ventricles are contract.\ The heart follows a regular recurring pattern. One contraction (systole) following by relaxation (diastole) of the heart is known as cardiac cycle. Suppose the heart rate is 75 per minute, If 75 beat take 1 minute, then, 1 beat will take 1/75 min = 1 x 60 sec/75 = 0.8 sec Thus, the duration of the cardiac cycle is 0.8 sec. Out of this, ventricular systole (generally called "the systole") lasts 0.3 sec and ventricular diastole (generally called "the diastole") lasts 0.5 sec. When the heart rate increases, the duration of cardiac cycle decreases. In such a situation, the reduction I'm duration of diastole is greater than that of systole. ARTERIAL BLOOD PRESSURE It is the pressure exerted by the blood on the wall of the blood vessels in which it is present. It is of two types: a) Systolic Blood Pressure (SBP): - It is the pressure which the blood exerts on the wall of the blood vessels at the end of systolic contraction of ventricles. In a normal resting adult, it is about 120 mm Hg. b) Diastolic Blood Pressure (DBP): - It is pressure, which the blood exerts on the wall of the arteries when the ventricles are maximally relaxed. In normal resting adult, it is about 80 mm Hg. blood Note: - (Blood Pressure in a normal person is equal 120/80mm Hg) LYMPH The tissue fluid that bathes the cells is collected in tubes and is then called as lymph. It is filtered the blood plasma through the capillaries. Although partly reabsorbed into the capillaries, most of it flows into a system of fine channels, which repeatedly join together to form a large duct and ultimate the fluid is returned into the blood stream. This additional system of vessels is called as lymphatic system. It runs parallel to the veins and forms another medium of circulation in the human body. The lymph is light yellow in colour and similar in composition to the blood plasma. It is not only found in the lymphatic vessels and bathing the cells of the body, but also in the various cavities of the body, such as the Coelomic cavity, Pleural cavity, Pericardial cavity etc. where it serves as a lubricant. Functions of lymph :- The chief functions of lymph in the human body are mentioned as under: 1. It serves as a lubricant for the cells and tissues of the body. 2. It serves to return the interstitial fluid into blood 3. It gives the blood macromolecules of plasma proteins. 4. It carries absorbed fats and lipids from small intestines to the blood. EXCRETION It is a process of removal of the various toxic waste products from the body, produced in the different metabolic processes, undergoing inside the body of an organism, it eliminates solid, liquid and gaseous waste products produced in the metabolism and thus maintains the relative constancy of the body’s internal environment without which life is impossible. Organs of excretion: - The chief organs of excretion include: 1. Skin: - It excretes out various dissolved salts along with surplus water from the body. The process takes place through the minute microscopic pores of the skin mainly in the form of sweat and is referred to as perspiration. 2.Lungs: - These expel out the gaseous wastes like carbon dioxide produced during the cellular respiration in the body through the process referred to as expiration. 3. Kidneys: - These excrete out nitrogenous wastes produced in the body like ammonia, urea and uric acid during various metabolic processes. These are excreted out mainly in the form of urine. 4. Large intestine: - It excretes out the solid wastes like undigested components of the food material produced during the process of digestion. These excreted or defecated out through the anus. 5. Excretory system of man: - The excretory system of man consists mainly of two kidneys, two ureters, a urinary bladder and a urethra as shown under in the diagram. KIDNEY Structure of human kidneys: - The human kidneys are reddish brown-paired structure, which lie along the posterior side of the abdominal wall on either side of the vertebral column. Each kidney is bean shaped about 10cm long, 6cm wide and 4cm broad. Each kidney is enclosed in a thin, tough, fibrous, whitish capsule. The outer surface of each kidney is convex while the inner one is concave. The inner side of kidney is composed of two main regions, a dark outer region called cortex and a lighter inner zone called medulla. The cortex contains uriniferous tubules or nephron, which manufactures the urine; the medulla contains conical projections called renal pyramids containing tubules, which carry urine from nephron to the pelvis of the kidney. From this region, the urine is taken to the urinary bladder through a long tuber called ureters as shown in the diagram. Structure of Nephron: - The nephron forms the functional unit of the kidneys. Its one end is modified into a cup shaped cavity called Bowman's capsule, which is linked by a small single layer of squamous epithelial cells. The rest of the nephron is differentiated into a coiled proximal convoluted tubule, a U-shaped loop of henle and a distal convoluted tubule. The distal tubule opens into a branching system of collecting tubules, which finally opens into a funnel shaped renal pelvis. Each nephron maintains a close contact with the blood vessels. It filters and removes the wastes from the blood, which is partially stored in renal pelvis. The urine so formed is then passed out through a long narrow tube called ureters and stored in a sac called urinary bladder, where from it is excreted out of the body through urethra. Process of Mechanism of excretion: - The entire process of excretion involves three main processes viz. 1.Glomerular filtration: - When the blood enters into the glomerulus through the afferent arteriole, a part of the water and some dissolved constituent of the blood of low molecular weight like nitrogenous waste, glucose and mineral salts filter out through the capillary walls into the surrounding Bowman's capsule by a process referred to as Glomerular filtration. The filtered fluid or glomerular filtrate resembles the blood plasma in its chemical composition except for the absence of large molecules. In man, about 180 liters of fluid is filtered from the blood plasma through glomerular capillary walls every 24 hours. 2.Tabular Reabsorption: - The glomerular filtrate flows on through the convoluted tubes, collecting tubule and then into the pelvis of the kidney and down the ureters into the urinary bladder. As the filtrate flows the proximal convoluted tubule soume water and physiologically important salts like glucose, amino acids, sodium chloride and sodium bicarbonate are reabsorbed into the blood through the capillaries around this portion leaving only the wastes to be excreted out. 3.Active secretion: - As the glomerular filtrate flows through the distal convoluted tubule, the unwanted substances, which could not be filtered out in the glomerular are actively secreted out by the tubular walls into the filtrate from the blood. As a result of this entire process, homeostasis of the blood is maintained and all the waste products remained in the tubular fluid constitute the urine, which is ready for excretion from the body. Haemodialysis: - In patients suffering from renal failure or nephritis, artificial measures are adopted for removing the accumulated waste products like urea from the blood. This process is called Haemodialysis and the apparatus used in this process as artificial kidney. In Haemodialysis, the blood of the patient is taken out from the main artery and cooled to 30C, then an anticoasulant (heparin) is mixed with it and Dumped into the apparatus. Inside the apparatus blood flows through tubes bounded by cellophane membrane, which is permeable to only small molecules like urea, uric acid, creatanin and mineral ions. The dialyzing fluid used in the apparatus a salt solution isotonic to blood plasma, so that the blood flowing through the channels or tubules containing wastes like urea, uric acid, creataninetc diffuses out in the dialyzing fluid across the cellophane membrane. This process is called dialysis. Finally the blood coming out of artificial kidney is warmed to body temperature and mixed with ant- heparin to restore its normal coagulability and then pumped into the body of the patient through a vein. MECHANISM OF EXCRETION IN PLANTS Plants do not have any mechanism to collect, transport and throw out their waste products. They have adopted varied strategies to protect their living cells from waste products, (i) Old leaves :- Waste products are stored in older leaves which soon fall off. (ii) Old Xylem:- Resins, gums, tannins and other waste products are deposited in the old xylem which soon becomes nonfunctional, e.g., heart wood. (iii) Bark:- Bark consists of dead cells which are peeled off periodically. Tannins and other wastes are deposited in the bark. Incidentally, tannins are raw material for dyes and inks. (iv) Central Vacuole:- Most plant waste products are stored in central vacuole of their cells. They are unable to influence the working of cytoplasm due to presence of a selectively permeable membrane called tonoplast. (v) Root Excretion:- Some waste substances are actually excreted by the plant in the region of their roots. (vi) Detoxification:- The toxic oxalic acid is detoxified by formation of calcium oxalate which getscrytallised into needles (raphides), prisms (prismatic crystals), stars (sphaeraphides) and crystal sand. Excess of calcium is also precipitated as calcium carbonate crystals, e.g., Cystolith. (vii) Salt Glands:- They excrete excess salts obtained from the habitat. Hydathodes also have an excretory function. Chemical Reactions & Equations: Introduction: - We are familiar with many chemical changes accessing around us in our daily life. Some of these are:i) ii) iii) iv) v) vi) A freshly apple exposed to atmosphere becomes brown after some time. Iron articles such as pan, or nail hammer etc, gets rusted when left exposed to humid atmosphere for a long period. Burning of candle gives CO2. Food gets digested in our body. Milk left at room temperature during summer becomes sour and is converted into a curdy thick mass. Grapes get fermented. In all the above cases, the nature and identity of the initial substance changes. We may also say that during such changes substances are undergoing permanent changes and new substances are formed. When different substances react and new substances having different nature and identity are formed, we say a chemical reaction has occurred. In the permanent unit we shall learn as to what is actually meant by a chemical reaction. How do we know that chemical reaction has taken place? Chemical reaction:- the evaporation of water, desolation of salt in water or melting of ice are the processes in which the new chemical substances are formed and hence are termed as physical changes. However the processes in which the original substances lose their nature and identity and form new chemical substances with different propositions are called chemical changes. The process involving a chemical changes is called a chemical reaction. For example (a) Respiration (b) Burning of candle wax, burning of fuels likes petrol, diesel, kerosene oil etc. Reactions & Products:- The substances which take part in a chemical reaction are called reactants, whereas the substances which are formed as a result of chemical reactions are called products, e,g. consider the following chemical reaction:AgNO3 + Silver Nitrate NaCl AgCl sod. Chloride + Silver Chloride Reactions Na NO3 Sod. Nitrate Products Chemical reactions involve breaking of old chemical bands which exist between the atoms of reacting substances another making of new chemical bands between the rearranged atoms of new substances. During a chemical reaction, atoms of one element do not change into those of another element. Only rearrangement of atoms takes place in a chemical reaction. Again in a chemical reaction, reactants are transformed into products. The products thus formed have properties which are entirely different from those of the reactants. Examples of some Chemical Reactions:1. Burning of magnesium Ribbon in air:- The magnesium metal is generally available in the laboratory in the form of a ribbon on a wire. It has a shining surface. However, due to attack of moist air, it is coated with a white layer of MgO. Now take a strip of Magnesium ribbon about 2-3cm long clean the magnesium ribbon by rubbing it with a sand paper. Hold it with a pair of tongs in the flame using a sprit lamp. We observe that magnesium burn with a dazzling light and a white powder is obtained in the china dish. The white powder is found to be that of magnesium oxide. Thus, magnesium has combined with oxygen of the air to form a new chemical reaction-MgO. Hence we say that a chemical reaction has taken place in which magnesium and oxygen are the reactants while as magnesium oxide is the product. 2Mg + O2 2MgO 2. Reaction between lead nitrate and potassium iodide:- Prepare lead nitrate solution in one test tube and potassium iodide in another test tube and then mix the two solutions, a yellow precipitate of lead iodide is obtained. Another substance formed is potassium nitrate but we cannot observe it as it remains in the solution. Again to say that a chemical reaction has taken place in which lead nitrate and potassium iodide are the reactants while lead iodide and potassium nitrate are the products. Lead nitrate + Potassium iodide Lead iodide + Potassium nitrate Reactants Products 3. Reaction Between Zinc & Dilute Sulphuric Acid:- Take a few pieces of granulated zinc in a small conical flask or a test tube and add dilute H2SO4 into it. We will observe that the reactions between two reactants will produce H2 gas. To test the gas evolved, the flask is fitted with a test tube on bringing a lighted candle near the upper end of the tube, the gas is found to burn with a popping sound. Thus, the gas evolved is hydrogen. Another substance formed is zinc sulphate which we cannot see as it remains in the solution. Again we can say that a chemical reaction has taken place in which zinc & suphuric acid are the reactants while hydrogen gas & zinc sulphate are the products. Zn + H2SO4 ZNSO4 + H2 Dilute Reactants Products Characteristics Of Chemical Reaction:- when a chemical reaction takes place, some changes are observed=. The easily observable changes that take place in chemical reaction are called the characteristics of the chemical reaction. These changes help us to check that a chemical reaction has taken place. Some important characteristics of chemical reactions are as follows:i) ii) iii) iv) v) Some chemical reactions are accompanied by the evolution of a gas. Some chemical reactions are accompanied by change in state. Some chemical reactions are accompanied by change in temperature. Some chemical reactions are accompanied by change in colour. Some chemical reactions are accompanied by the formation of precipitate. Chemical Equations:- A chemical equation is a statement used on chemistry to represent a chemical reaction. (Or) The short hand method representing a chemical reaction in terms of symbols and formulae of the different reactants and products is called a chemical equation. There are two ways of representing a chemical reaction:a) The reaction between silver nitrate and sodium chloride can be represented in terms of word equation as under:- Silver Nitrate + Sodium Chloride Silver Chloride+ Sodium Nitrate Therefore, the names of the reactants are written on the left hand side with a (+) sign between them, whereas the names of the products are written on the right hand side with (+) sign between them. An arrow (→) is put between the reactants and the products. The arrow sign indicates that the substances written on the left side are combining to give the substances written on the right hand side in the equation. b) In terms of symbols and formulae, the reactions between silver nitrate and sodium chloride may be represented as under:AgNO3 + NaCl AgCl + Na NO3 Reactants Products This is called a chemical equation. Infect this is the most common method of representing a chemical reaction. Steps For Writing A Chemical Equation:For writing a chemical equation, the following point use kept in mind:i) ii) iii) The symbols and formulae of reacting substances-i.e reactants are written on the left hand side with plus (+) sign between them. The symbols and formulae of various products are written on the right hand sign with plus (+) sign between them. An arrow ( ) sign or sign of equality (=) is put between the reactants and products. For example, consider a reaction between zinc and dilute sulphuric acid to produce zinc sulphate iron solution and hydrogen gas. Zn + H2 SO4 ZnSO4 +H2 Balanced & Unbalanced Chemical Equation:Consider the equation of reaction of magnesium & oxygen to form magnesium oxide:Mg + O2 MgO Let us count the number of atoms of each element on the LHS and RHS of the arrow. It is clear from the above reaction, that the numbers of atoms of each element are not the same on both sides. Such on equation is called unbalanced equation. It is also called as skeletal equation. Again consider the following chemical reaction Zn + H2 SO4 ZnSO4 +H2 It is clear from the above chemical reaction, that the numbers of atoms of each element on the two sides of equation are equal. Therefore, such a chemical equation is called a balanced chemical equation. Balancing of a Chemical Equation:We know that mass can neither be created nor destroyed in a chemical reaction. Therefore, the total mass of the elements present the product of a chemical reaction has to be equal to the total mass of the elements present in the reactants. In other words, the number of atoms of each element remains the same, before and after a chemical reaction. Thus, balancing of a chemical equation means making the number of atoms of each element equal on both sides of the equation. The importance of a balanced chemical equation lies in the fact that it satisfies the law of conservation of mass i.e, in a chemical reaction; total mass of all the products is equal to the total mass of all the reactants. Steps involved in the balancing of a Chemical Equation:Step-I:- write down the equation in the word form by writing the names of the reactants on the left side and those of products on the right side. This step is not required if the equation is given in terms of symbols and formulae. Step-II:- write down the symbols and formulae of the various reactants and products. This gives the skeletal chemical equation. Step-III:- Enclose the formulae of each reactant and product in a box. This is done to remember that during balancing of the chemical equation, the formula of and reactant or product cannot be changed. Step-IV:- List the number of atoms of different elements on reactant side and product side. Step-V:- Now start the process of balancing by choosing the compound which has maximum number of atoms, irrespective of the fact whether it is a reactant or a product. Step-VI:- After selecting the compound with the biggest formula as above, first balance the element of this compound which has the highest number of atoms. Then balance other elements one by one, to balance the atoms of an element, put a small whole number co-efficient before the formula of the compound. Step-VII:- Atoms of elementary gases such as hydrogen, oxygen nitrogen etc, are balanced last of all. Sometimes, these are first changed to atomic state. After balancing, these are changed back to molecular form. Step-VIII:- Finally check the correctness of the balanced equation by counting the number of atoms of each element on both sides of the equation. The above method of balancing of chemical equation is called ‘Hit & Trial Method’ as we keep on trying to balance the equation using smallest whole number coefficient. Let us try to balance the following chemical reaction:When steam is passed over heated iron, iron oxide and hydrogen gas is obtained. Step-I:- write the equation in word form as:Iron + Steam Iron Oxide + Hydrogen. Step-II:- Write the skeletal chemical equation and enclose the formulae in boxes:Fe H2O Fe3O4 H2 Step-III:- count the number of atoms of different elements on both sides of the equation. Element No. of atoms on LHS No. of atoms on RHS Fe 1 3 H 2 2 O 1 4 Step-IV:- Start balancing with the compound which contains maximum number of atoms. It may be a reactant or a product. Now in that compound select the element which has maximum number of atoms. According to this rule, select Fe3O4 & the element oxygen in it. There are 4-0 atoms on the RHS and only 1-0 atoms on the LHS. To balance 0-atoms, multiply H2O on LHS by 4, we get. Fe +4 H2O Fe3 O4 + H2 Step-V: - There are 3-Fe atoms on RHS & 1-Fe atom on LHS. To balance Fe atoms, multiply Fe on LHS by 3, we get. 3 Fe + 4H2O Fe3O4 + H2 Step-VI: - There are 8-4 atoms on LHS & 2H – atoms on RHS. To balance Hatoms, multiply H2 by 4, we get. 3 Fe + 4H2O Fe3O4 + 4H2 Step-VII: - Now check the correctness of the balanced equation:Atom LHS RHS Fe 3 3 H 8 8 O 4 4 Hence, the equation is balanced –i.e. the final balanced equation may be written as:3 Fe + 4H2O Fe3O4 + 4H2 Example 2:- Let us illustrate these rules by considering one more example. When magnesium nitride is treated with water Ammonia gas & magnesium hydroxide are produced. Step – I: - Write equation in word form as:Magnesium nitride + water Ammonia Magnesium hydroxide + Step – II: - Write the skeletal chemical equation and enclose the formulae in boxes. Mg3N2 + H2O Mg (OH)2 + NH3 Step – III: - Count the number of atoms of different elements on both side of the equation. Element RHS No. of atoms LHS atoms No. of atoms on Mg 3 1 N 2 1 H 2 5 O 1 2 Step – IV: - Let us seleat Mg3 N2 and balance Mg atoms in it. To balance Mg atoms on both sides, multiply Mg (OH) 2 + NH3 Mg3N2 + H2O 3 Mg (OH)2 + NH3 Step – V: - Now to balance N-atoms, multiply NH3 on RHS by 2, we get. Mg3N2 + H2O 3 Mg (OH)2 +2 NH3 Step – VI: - to balance 0-atoms, multiply H2O on LHS by 6, we get. Mg3N2 + 6H2O 3 Mg (OH)2 + NH3 Step – VII: - Check the correctness of the balanced equation. LHS RHS Mg-atoms 3 3 N-atoms 2 2 H-atoms 12 12 O-atoms 6 6 Making of chemical equation more informative:- The chemical equation which gives more information about the chemical reaction is known as more informative or information giving equation. The chemical equations can be made more informative by following 4 – ways:i. Physical state of the reactants and the products: - The physical state of any substance is represented by using the symbol(S) for solid, (l) for liquids, (g) for gaseous and (aq) for aqueous solution. These symbols are written in brackets after the symbols or formulae of the reactants and products. This will become more clear from the following examples:a) Zinc metal reacts with dilute sulphuric acid to form zinc sulphate solution and hydrogen gas Zn + H2 SO4 ZnSO4 + H2 Zn(s) + H2 SO4(aq) ZnSO4 (aq) + H2(g) or b) When calcium hydroxide solution reacts with carbon dioxide gas, a while precipitate of calcium carbonate is formed along with water. Ca (OH)2 (aq) + CO2 (g) CaCO3(s) + H2O(l) (Lime water) (cal. Carbonate water) ii) Concentration of the acid: - If acid is present as the one of the reactants, it may be dilute or concentrated. The symbol (dil) is used for dilute acid. Whereas symbol 'conc' is used for concentrated acid, e.g Zn(s) + H2 SO4 Cu(s) + 4HNO3 ZnSO4(aq) + H2(g) Cu(NO3)2 (aq) + 2NO2(g) + H2 O(l) (Conc.) (nitrogen dioxide) iii) Heat changes accompanying the chemical reaction: There are two types of reactions on the basis of heat charges involvedexothermic and endothermic. Exothermic Reaction:- These are those reactions in which heat is evolved during the reaction, e.g when carbon (coke) burns in oxygen to form CO2, a lot of heat is produced. C (s) + O2(g) CO2(g) + Heat When natural gas mainly methane burns in oxygen of air, it forms CO2 & H2O. A large amount of heat energy is also produced. (↓ which is). CH4(g) + 2O2(g) CO2(g) + 2H2 O(l) + Heat During respiration, glucose combines with oxygen in the cells of our body to form CO2 and H2 O along with production of energy. C6 H12 O6(aq) + 6O2(g) 6H2 O(l) + Energy The burning of a magnesium wire in air to form magnesium oxide is also an exothermic reaction because heat & light energy are given out during this reaction. 2Mg (s) + O2 (g) 2MgO(s) + Heat & light. Endothermic Reactions: - These are those reactions in which heat is absorbed during the reaction. An endothermic reaction is usually indicated by writing '+ Heat' or "+ Heat energy" or just "+ Energy" on the reactant side of the equation. Example:a) The reaction between nitrogen and oxygen to form nitrogen monoxide is an endothermic reaction because heat is absorbed in this case. N2 (g) + O2 (g) + Heat 2NO (g) b) When calcium carbonate is heated it decomposes to form calcium oxide and carbon dioxide. CaCO3 (s) + Heat CaO(s) + CO2 The decomposition of calcium carbonate is an endothermic reaction, because heat energy is absorbed in this reaction. c) The electrolysis of water to form hydrogen and oxygen is also an endothermic reaction. This is because electric energy is absorbed during this reaction. 2H2O (l) + Heat 2H2 (g) + O2 (g) d) Photosynthesis is an endothermic reaction. This is because sunlight energy is absorbed by the green plants during the process of photosynthesis. 6CO2 (g) + 6H2O (l) C6H12O6 iv) Conditions under which the reaction takes places: - The conditions of temperature, pressure and the presence of catalyst, if any may be represented by writing these conditions above or blew the arrow drown between the reactants & the products e.g. 500C 200 atm. N2 (g) + 3H2 (g) 2NH3 (g) fe This shows that to get maximum yield of NH3, the most suitable condition for the above reaction are - a temperature of 500 C, pressure of 200 atmosphere and presence of iron as catalyst. Similarly, if a reaction takes place on heating, the sign delta (∆) is put on the arrow,e.g. ∆ 2 KclO3 (s) 2 Kcl(s) + 3O2 (g) Mn O2 Again, if a reaction takes place in the presence of light, the word "light" is written on the arrow, e.g. H2 (g) + Cl2 (g) Sun light 2Hcl (g) TYPES OF CHEMICAL REACTION:Depending upon the nature of the reaction - i.e. the type of chemical change taking place, the various chemical reactions have broadly classified into the following type:1) Combination reactions (2) Decomposition reactions (3) Displacement reactions (4) Double Displacement reacts 5) Precipitation reaction (6) Neutralization reactions (7) Oxidation - Reduction reactions 1) Combination reactions:- The reactions in which two or more substances combine to form a single substance are called the combination reactions. Example 1:- Magnesium and oxygen combine when heated to from magnesium oxide. 2Mg(s) + O2 (g) 2MgO(s) In the above reaction, two elements, magnesium and oxygen are combining to form a single compound magnesium oxide. Therefore, it is a combination reaction. Example 2:-Hydrogen burns in oxygen to form water is a combination reaction. 2H2 (g) + O2 (g) 2H2O Example 3:- If we take a small amount of quick lime - i.e calcium oxide in a beaker and add water to it slowly, they combine vigorously to form slaked lime - i.e calcium hydroxide. CaO(s) + H2O (l) Ca(OH)2 (aq) The combination reactions are the three types:a) Combination of two elements to form a compound. b) Combination of an element and a compound to form a new compound. c) Combination of two compounds to form a new compound. a)Combination of two elements to form a compound:i) Carbon or coal burns in air to produce CO2. C(s) + O2(g) CO2(g) ii) Hydrogen combines with chlorine in the presence of light to give hydrochloride acid. H2(g) + Cl2(g) 2HCl(g) iii) Sodium combines with chlorine gas to form sodium chloride 2Na(s) + Cl2(g) 2NaCl(s) b) Combination of an element and a compound to form a new compound:i) ii) iii) Nitric oxide combines with oxygen of the air to form nitrogen 2NO(g) + O2(g) 2NO2(g) When sulphur dioxide combines with oxygen to form sulphur trioxide is obtained. 2SO2(g) + O2(g) 2SO3(g) When carbon monoxide reacts with oxygen, carbon dioxide is formed. 2CO(g) + O2(g) 2CO2(g) C) Combination of two compounds to form a new compound:i) ii) iii) Ammonia and hydrogen chloride are colourless gases. They combine to form a solid ammonium chloride. NH3(g) + HCl(g) NH4Cl(s) Calcium oxide reacts with sulphur trioxide to form calcium sulphate. CaO + SO3 CaSO4 When ammonia reacts with sulphuric acid, ammonium sulphate is formed. 2NH3(g) + H2SO4(aq) (NH4)2 SO4 (aq) Decomposition Reactions:- the reactions in which a compound breaks up into two or more simpler substances are known as decomposition reactions. Thus, these reactions are just opposite of combination reactions. These reactions generally take place when energy is supplied in the form of heat, light, electricity or catalyst. Thus, there are three types of decompositions. A) Decomposition reactions which take place by absorption of heat are called thermal decomposition reactions. Experiments:i) Thermal decomposition of ferrous sulphate:Take a small amount of green coloured crystals of ferrous sulphate in a dry test – tube. Hold the test tube in a test tube holder. Now heat the test tube over a spirit lamp or burner. We observe that the green coloured ferrous sulphate crystals on heating first lose water and the colour changes to form anhydrous ferrous sulphate. FeSO4 + 7H2O(s) 7H2O(g) ∆ FeSO4(s) + This on further heating gives out characteristic smell o burning sulphur leaving behind a reddish brown residue of ferric oxide. This is due to following decomposition reaction:2FeSO4(s) ∆ Fe2O3(s) + SO2(g)↑ + SO3(g)↑ Ferric oxide reddish brown. ii) Decomposition of limestone:- When calcium carbonate is heated, it decomposes to give calcium oxide and carbon dioxide CaCO3(s) ∆ CaO(s) + CO2(g) In this reaction on substance calcium carbonate is heated and so it gets broken down into two simpler substances of calcium oxide and carbon dioxide, so it is a decomposition reaction. iii) Decomposition of Lead Nitrate:- Take a small amount of powdered lead nitrate in a test tube. Heat it over a flame. Brown fumes of nitrogen dioxide are found to evolve and a yellow residue of lead oxide is left behind in the test tube. This is due to the following decomposition reaction. 2Pb(NO3)2 (s) ∆ 2PbO(s) + 4NO2(g) + O2(g) (B) The decomposition reactions which take place when electric current is passed through the compound in the molten state or in aqueous solution. These are called electrolytic decomposition reactions or simply electrolysis. i) Experiment Electrolysis of Water: - Take a plastic mug. Drill two holes at its base and fit rubber stoppers in these holes. Now put two carbon electrodes in these rubber stoppers and seal the holes with some adhesive to prevent leakage of water. Now connect the electrodes to a 6 volt battery fill the mug with water such that the electrodes get immersed in water, add a few drops of dil. H 2SO4 to water. Take two graduated that tubes fill with water and invert them over carbon electrodes. Switch on the current and leave the apparatus undisturbed for some time. It is observed that bubbles of gases starts rising from both the electrodes and the levels of water in the two test – tubes start freeing. Allow it to run till sufficient amounts of gases have been collected in the two test tubes. Now switch off the battery we will observe that the test tube covering the cathode, the amount of gas collected is double than that of the gas collected in the testtube covering the anode. On testing the gases, the gas in the test tube covering the cathode is found to be hydrogen – a combustion gas and in the test-tube covering the anode, it is found to be oxygen – a supporter of combustion. The above experiment shows that on supplying electrical energy, water decomposes into hydrogen and oxygen as shown below: 2H2O(l) 2H2(g) + O2(g) ii) Electrolytic decomposition of molten sodium chloride:On passing electric current through molten sodium chloride, it decomposes to give sodium metal and chlorine gas. 2NaCl 2Na + Cl2↑ This reaction is used to obtain sodium metal on a large scale iii). Electrolytic decomposition of molten Alumina: - On passing electric current through molten alumina, it decomposes to give aluminum metal and oxygen gas. 2Al2O3 Electric Current 4Al + 3O2↑ This reaction is used for the extraction of Aluminum metal. C) The decomposition reactions which take place on absorption of light. These are called photo-decomposition reactions or simply photolysis. Example-I:- Place about 2g of silver chloride in a china dish under sunlight for some time, we observe that silver chloride is white is colour. Its colour will turn grey in sunlight. This is because of decomposition of silver chloride to silver & chlorine by light. 2AgCl(s) Sunlight 2Ag(s) + Cl2(g) II) Photolysis of Hydrogen Iodine: - Hydrogen iodide decomposes in the presence of ultra violet light into hydrogen and iodine. 2HI UV-Light H2 + I2 III) Photolysis decomposition of Hydrogen peroxide: - In the presence of light, hydrogen peroxide decomposes into water & oxygen. H2O2 2H2O + O2 Displacement Reactions: - The chemical reactions in which one element takes the place of another element in a compound are called displacement reactions. The chemical reactions in which a more active element displaces a less active element from its compound are called displacement. In these reactions, an atom or group of atoms in a molecule is replaced by another atom or group of atoms. These reactions are very common in chemistry. These reactions occur mostly in solution form and a more active metal displaces less active metal or a more active non-metal may displace a less active non-metal form its compound. Experiment-1:- Take about 10ml of CuSO4 solution in two test tubes A and B. Also take iron nails and clean them by rubbing with a sand paper. Tie a thread on one iron nail and suspend it in test-tube A. Wait for about 20-30 minutes. Now take out the nail and observe the change in the colour of the solution of test-tube A by comparing with the solution of test-tube B and the change in colour of the nail that remained suspended in the test-tube A by comparing with the 2nd nail. The following changes are observed:i) ii) Blue colour of copper sulphate solution fades and it changes into light green colour. The iron nail that remained suspended has a brownish coating on its surface. These changes show that the following reaction has taken place:Fe(s) + CuSO4(aq) (Blue solution) FeSO4 + Cu(s) (light green solution) Thus the more active metal, iron displaces less active metal copper from copper sulphate. Experiment-2:- Take AgNO3 solution in a beaker. The solution of AgNO3 is clear and colourless. Place a copper wire in the solution and keep the beaker undisturbed for some time. It will be observed that the solution becomes blue and a shiny coating of silver gets deposited on the wire. This suggests that when copper wire is added to the solution, copper nitrate is formed and therefore. The solution becomes blue, the reaction may be written as:Cu + 2AgNO3 Cu(NO3)2 + 2Ag Example-1:- when zinc reacts with dilute H2SO4 or dilutes HCl, hydrogen gas is evolved. The reaction is as under:Zn(s) + H2SO4 ZnSO4(aq) + H2(g)↑ Zn(s) + 2HCl(aq) ZnCl2(aq) + H2g)↑ This shows that Zn is more reactive than hydrogen hydrogen from sulphuric acid or hydrochloric acid. it displaces Example-2:- when a strip of zinc metal is placed in copper sulphate solution, then zinc sulphate and copper obtained. CuSO4(aq) + Zn(s) ZnSO4(aq) + Cu(s) Thus, zinc being more reactive than copper *** copper from CuSO4 solution. Example-3:- when a piece of Mg metal is placed in CuSO4 solution, the MgSO4 solution and copper metal are formed. CuSO4(aq) + Mg(s) MgSO4(aq) + Cu(s) Double Displacement Reactions: - The reactions in which two compounds react to form two other compounds by mutual exchange of atoms or group of atoms are called double displacement reactions. (or) Those reactions in which two compounds react by an exchange of ions to form two new compounds are called double displacement reactions. Experiment: - Take about 3ml of sodium sulphate solution and barium chloride solution in two test tubes. Both the solutions are clear and colourless. Now add sodium sulphate solution to barium chloride. We will observe that a white substance which is insoluble in water is formed. This insoluble substance due to the formation of insoluble barium sulphate. The reaction may be written as:Bacl2(ag) + Na2SO4 BaSO4(ag) + 2NaCl(ag) Example 1:- When dilute H2SO4 is added to pieces of iron sulphide, hydrogen sulphide gas is produced and soluble ferrous sulphide is formed. Hence it is a double displacement reaction. Fe S(s) + H2SO4 FeSO4(aq) + H2S(g)↑ Example 2:- When Ag NO3 solution is added to NaCl solution, and then a white precipitate of AgCl is formed along with sodium nitrate solution. Ag NO3 + NCl(aq) AgCl(s)↓ + NaNO3(aq) (white ppt.) In this double displacement reaction, two compounds silver nitrate and sodium chloride react to form two new compounds river chloride and sodium nitrate. 5. Precipitation Reaction:- Those reactions in which aqueous solutions of two compounds on mixing react to form an insoluble compound which separates out as a solid called precipitate or such an insoluble compound is formed when gas compound is called precipitation reactions. Example 1:- When barium chloride solution is added to sodium sulphate solution, then a white precipitate of barium sulphate is formed along with NaCl solution. BaCl2(aq) + Na2SO4(ag) BaSO4(s)↓ + 2NaCl(ag) (white ppt.) Example 2:- When Copper sulphate in aqueous form reacts with hydrogen sulphate gas, a black precipitate of copper sulphide & sulphuric acid is formed. CuS↓ + H2SO4(ag) CuSO4(ag) + H2S(g) (black ppt.) Example 3:- When Aluminum chloride reacts with an aqueous solution of ammonium hydroxide, a white precipitate of aluminum hydroxide and ammonium chloride are formed. Al(OH)3↓ + 3NH4Cl AlCl3(ag) + 3NH4OH(ag) (White ppt.) 6. Neutralization Reactions:- A reaction in which an acid reacts with a base to form salt & water is called a neutralizatiom reaction - i.e. Acid + Base Salt + water Examples:i) When a base sodium hydroxide reacts with an acid like hydrochloride, sodium and water are formed. Na OH + HCl (Base) ii) KOH (acid) + HCl (Base) iii) (acid) NH4OH + (Base) iv) NaCl + H2O NaOH (salt) (water) KCl + H2O (salt) HCl (water) NH4Cl + H2O (acid) + CH3COOH (Base) (Acid) CH3COONa + H2O (Sod. Acetate) 7. Oxidation - Reduction Reactiom:- Oxidation is a reaction which involves the addition of oxygen or removal of hydrogen e.g, 4Na + O2 2Na2O 2Mg + O2 2Mgo 4H2S + O2 2H2O + 2S 4HCl + MnO2 MnCl + 2H2O + Cl2 On the other hand, reduction is a reaction which involves the addition of hydrogen or removal of oxygen, e.g Or H2 + S H2S Cl2 + H2S 2HCl2 + S ZnO +C Zn + CO CuO + H2 Cu + H2O These oxidation or reduction reactions cannot occur alone. This is because if one substance loses oxygen, these must be another substance which gains oxygen. Similarly, if one substance which gains hydrogen. Thus, if one sustaince iss oxidizea, the othet must be reduced. This means that oxidation and reduction always go side by side - i.e they occur simultaneously in a reaction. Thus, for this reason, the oxidation - reduction reactions are also called as redox reactions. Example-1:- When copper oxide iss heated with hydrogen, then copper metal and water are formed. CuO + H2 Heat Cu + H2O Now in this reaction, CuO is changing into Cu - i.e oxygen is being removed from copper oxide. Now by definition, removal of oxygen from substance is called reduction, so we can say that copper oxide is being reduced to copper. Also in this reaction, Hydrogen is changing into H2O - oxygen is being added to hydrogen. Now by definition, addition of oxygen to a substance is called oxidation, so we Can say that hydrogen is being oxidised to water. Now from the above reaction, we find that hydrogen is being oxidised to water and at the same time, copper oxide issue being reduced to copper. This shows that oxidation reduction occur together. The oxidation reduction reaction between copper oxide & hydrogen Can be shown more clearly as follows:- CuO + H2 Cu + H2O Example-2:- when ferric oxide reacts with aluminium, iron & aluminium oxide are obtained. Fe2O3 + 2Al 2Fe + Al2O3 Example3:- When hydrogen sulphide reacts with chlorine, then sulphur and hydrochloride acid are formed. H2S(g) + Cl2(g) S(s) + 2HCl(g) Oxidation Removal of hydrogen H2S + Cl2 S + 2HCl Addition of hydrogen (reduction) In this reaction:a) His has lost hydrogen to format S- hence H2 S has been oxidised. b) Cl2 has gained hydrogen to formed HCl hence Cl2 has been reduced. Effects of Oxidation Reaction is Everyday Life:Oxidation has damaging effects on metals as well as on food. The damaging effect of oxidation on metals is studied as corrosion and that on food is studied as rancidity. Thus there are two common effects of oxidation reactions which we observe in daily life. These are:i) Corrosion ii) Rancidity i) Corrosion:- The process of slowly eating up of the metals due to attack of the atmospheric gases such as oxygen, CO 2, H2 S, water vapor etc. on the surface of the metals so as to convert the metal into oxide carbonate, sulphide etc. is known as corrosion. The most common example of corrosion is rusting i. e, corrosion of iron when an iron article remains exposed to moist air for a long time, its surface is covered with a brown & non-sticky substance called rust. It is mainly hydrate ferric oxide (Fe2O3. XH2O). It is formed due to attack of oxygen gas and water vapour present in the air on the surface of iron. 2Fe(s) + 3/2 O2(g) + xH2O Fe2O3 . xH2O(s) Rust Similarly, copper lose its luster and shine after sometime. The surface of these objects acquires a green coating of basic copper carbonate. CuCO3. Cu(OH)2 when exposed to air. This is due to attack of O2, CO2 & water vapour present in the air on the surface of copper. 2Cu(s) + CO2(g) + H2O(l) CuCO3 ‘ Cu(OH)2 Likewise silver tarnishes i.e loses lustre and becomes dull on exposure to air. This is due to the formation of a ting of black silver sulphide ( ) on its surface by the corrosion of H2S gas present in the air lead or stainless steel lose their lustre due to corrosion. The corrosion causes damage to car bodies, bridges, iron railings ships and many other articles especially made of iron. The corrosion of iron is a serious problem; every year on enormous amount of money is spent to replace damaged iron objects. ii)Rancidity:When food materials containing fats and oil are left from sometime, they get spoiled and give foul smell and unpleasant taste. This is because when fats and oils are oxidised they become rancid and their smell as well as taste change. This change in odour and flavour of oily and fatty foods by oxidation is called rancidity. To prevent, this usually substances which prevent oxidation are added to food containing fats and oils. These substances are called 'antioxidants'. Keeping food in air tight containers also help to slow down oxidation and this increases the life if food materials. In some food-stuffs, the air present around them is replaced by nitrogen in the packet containing the food-stuffs. Thus, oxidation of the food-stuff is preventing them from oxidation. TEXT BOOK QUESTIONS:Q1:-When should a magnesium ribbon be cleaned before burning in air? Ans: - When magnesium ribbon remains exposed to moist air, a white layer of MgO is formed on its surface. This hinders the burning of magnesium. Hence this layer is first removed by rubbing with sand paper before burning. Q2:- Write the balanced equation for the following chemical reactions. i) Hydrogen + Chlorine Hydrogen Chloride ii) Barium Chloride + Aluminum Sulphate Barium Sulphate+ Aluminum Chloride iii) Sodium + Water Ans: - i) Sodium hydroxide + Hydrogen. Hydrogen + Chlorine Hydrogen Chloride H2 + Cl2 HCl – (skeletal equation) H2 + Cl2 2 HCl – (Balanced equation) ii) Barium Chloride + Aluminum Sulphate Barium Sulphate+ Aluminum Chloride. BaCl2 + Al2(SO4) 3BaCl2 + Al2(SO4)3 iii) Sodium + water Na + H2O 2 Na + 2H2O BaSO4 AlCl3 – (skeletal equation) 3BaSO4 + 2AlCl3 sodium hydroxide + hydrogen. NaOH + H2 - [skeletal equation] 2NaOH + H2 – [Balanced equation] Q3:- Write a balanced chemical equation with state symbols for the following reactions:a) Solution of Barium Chloride and Sodium sulphate in water react to give insoluble barium sulphate and solution of sodium Chloride. b) Sodium hydroxide solution in water reacts with hydrochloric acid solution in water to produce sodium chloride solution & water. Ans: - a) The word equation for the given reaction is:Barium Chloride + Sodium sulphate Chloride BaCl2(aq) + Na2SO4(aq) Barium Sulphate + Sodium BaSO4(s) + NaCl(aq) [skeletal equation] BaCl2(aq) + Na2SO4(aq) BaSO4(s) +2 NaCl(aq) b) the word equation for the given reaction is:Sodium hydroxide + hydrochloric acid NaOH(aq) + HCl(aq) 2NaOH(aq) + 2HCl(aq) sodium chloride + water NaCl(aq) + H2O(l) [skeletal equation] 2NaCl(aq) + H2O(l) [balanced equation] Q4:- A solution of a substance 'X' is used for white washing. i) ii) Name the substance 'X' and write its formula. Write the reaction of the substance 'X' named above with water. Ans: - i) The substance 'X' used for white washing is quick lime or calcium oxide. ii) When quick lime is mixed with water, the following reaction takes place;CaO(s) + H2O(l) Ca(OH)2(aq) Q5:- Why the amount of gas is collected in one of the test tubes in activity 6.7 is doubled of the amount collected in the other? Name this gas. Ans: - Water decomposes on electrolysis to given hydrogen and oxygen as under:- 2H2O(l) 2H2(g) + O2(g) Thus, hydrogen and oxygen are formed in the ratio 2:1 by volume. The double volume of the gas collected by hydrogen. Q6:- Why does the colour of CUSO4 solution change when an iron nail is dipped in it. Ans: - Iron is more reactive then copper. It displaces copper from CuSO4 solution according to the following reaction:Fe(s) + CuSO4(aq) FeSO4(aq) + Cu(s) Thus, as CuSO4 reacts to form copper sulphate solution fades. sulphate, the blue colour of Q7:- Identity the substances oxidized on the substances that are reduced in the following reactions:a) 4Na(s) + O2(g) b) CuO(s) + H2(g) Ans:- i) 4Na(s) +O2(g) 2Na2O(s) Cu(s) + H2O(l) 2Na2O(s) Here, Na had gained oxygen to form Na2O. Therefore, Na has been oxidized to Na2O. Obviously, therefore O2 has been reduced. iii) CuO(s) + H2(g) Cu(s) + H2O(l) Here, CuO has not lost oxygen to form Cu. Hence, CuO has been reduced to Cu. H2 has gained oxygen to form H2O. Hence hydrogen (H2) has been oxidized to H2O. EXERCISE Q1:- What is a balanced chemical equation? Why should chemical chemucal equation be balanced? Ans: - Balanced Chemical Equation: - Already defined. According to low of conservation of mass, the total mass of products must be equal to the total mass of reactants. This is possible only if the number of atoms of each element is same on the two sides of the equation. Q2:- Translate the following statements into chemical equations and then balance them. a) Hydrogen gas combines with nitrogen to form ammonia. b) Hydrogen sulphate gas burns in air to give water and sulphur dioxide. c) Barium chloride reacts with aluminum sulphate to give aluminum Chloride and precipitate of barium sulphate. d) Potassium metal reacts with water to give potassium hydroxide and hydrogen gas. Ans: - a) The word equation for the given statement is:Hydrogen + Nitrogen Ammonia Now the skeletal chemical equation is:H2(g) + N2(g) NH3(g) Therefore, balanced chemical equation is:3H2(g) + N2(g) 2NH3(g) b) The word equation for the given statement is:Hydrogen Sulphide + Oxygen Water + Sulphur dioxide Now the skeletal chemical equation is:H2S(g) + O2(g) H2O(l) + SO2(g) Therefore, the balanced chemical equation is:2H2S(g) + 3O2(g) 2 H2O(l) + 2SO2(g) c) The word equation for the given statement is:Barium Chloride + Aluminium Sulphate Barium Aluminium Chloride + Sulphate Now the skeletal chemical equation is: BalCl2(aq) + Al2(SO4)3(aq) AlCl3(aq) + BaSO4(s) Therefore, the balanced chemical for the given statement is: 3BalCl2(aq) + Al2(SO4)3(aq) 2 AlCl3(aq) + 3BaSO4(s) d) The word equation for the given statement is:Potassium + Water Potassium hydroxide + Hydrogen Now the skeletal chemical equation is: K(s) + H2O(l) KOH(aq) + H2(g) Therefore, the balanced chemical equation us:2K(s) + 2H2O(l) 2KOH(aq) + H2(g) Q3:- Balance the following chemical equations:a) HNO3 + Ca(OH)2 Ca (NO3)2 + H2O The balanced chemical equation is: 2HNO3 + Ca(OH)2 Ca (NO3)2 + 2H2O b) NaOH + H2SO4 Na2SO4 + H2O The balanced chemical equation is:2NaOH + H2SO4 c) NaCl + AgNO3 Na2SO4 + 2H2O AgCl + NaNO3 The above chemical reaction is already balanced. d) BaCl2 + H2SO4 BaSO4 + HCl The balanced chemical equation is:BaCl2 + H2SO4 BaSO4 + 2HCl Q4:- Write the balanced chemical equations for the following reactions:a) Calcium hydroxide + Carbon dioxide Calcium Carbonate + Water Ca(OH)2 + CO2 CaCO3 + H.O b) Zinc + Silver nitrate Zinc nitrate + Silver Zn + AgNO3 Zn(NO3)2 + Ag - [skeletal equation] Zn + 2AgNO3 Zn(NO3)2 + 2Ag – [Balanced equation] c) Aluminium + Copper Chloride Aluminium Chloride + Copper. Al + CuCl2 AlCl3 + Cu – [skeletal equation] 2AlCl3 + 3Cu – [Balanced equation] Or 2Al + 3CuCl2 d) Barium chloride + Potassium sulphate Barium sulphate + Potassium Chloride BaSO4 + KCl – [skeletal equation] BaSO4 + 2KCl – [Balanced equation] BaCl2 + K2SO4 BaCl2 + K2SO4 Q5:- Write thee balanced chemical equation for the following and identify the type of reaction in each case. a) Potassium bromide (aq) + Barium iodide (aq) KBr(aq) + BaI2(aq) Potassium iodide (aq) + Barium Btomide(s) KI(aq) + BaBr2 This is a skeletal equation. The balanced equation is as under:2KBr(aq) + BaI2(aq) 2KI(aq) + BaBr2(aq) In the above reaction since two compounds on reacting from two new compounds of potassium iodide and barium bromide therefore it is a double displacement reaction. b) Zinc Carbinate(s) ZnCO3(s) Zinc oxide (s) + Carbon dioxide(g) ZnO(s) + CO2(g) The reaction is already balanced. Now as a single compound decomposes in this case to form two simpler substances, therefore it is a decomposition reaction. c) Hydrogen(g) + Chlorine (g) Hydrogen Chloride (g) H2(g) + Cl2(g) HCl(g) - [skeletal equation] H2(g) + Cl2(g) 2HCl(g) – [Balanced equation] In the above reaction, as two substances combine to form a single compound, so it is a combination reaction. d)magnesium + Hydrochloric acid (g) Magmesium Chloride(aq) +Hydrogen Mg(s) + HCl(aq) MgCl2(aq) + H2(g) This is a skeletal equation. The balanced Chemical equation is: Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g) As Mg displaces hydrogen from HCl, therefore the above reaction is a displacement reaction. Q6:- Why respiration is considered as exothermicreaction? Expain. Ans:- During reapiration we need energy. We get this energy from food we eat. During digestion food is broken simpler substances. For example rice, bread, contain carbohydrates. These carbohydrates are broken down to form to glucose. This glucose combines with oxygen in the cells of our body producing energy. C6H12O6 + 6O2 6CO2 + 6H2O + Energy The above reaction is called respirationreaction. Thus, during respiration energy is released and hence, it is considered as an exothermic reaction. Q7:- In the refining of silver the recovery of silver from AgNO3 involved displacement by copper metal. Write down the reaction involved. Ans: - Cu(s) + 2Ag NO3(aq) Cu (NO3)2(aq) +2Ag(s) Copper(II) nitrate Q8:- A shiny brown colourd element 'X' on heating in air becomes black in colour.Name the element 'X' and the black coloured compound formed. Ans: - The element 'X' must be copper because copper is a shiny brown colourd element which on heating in air combines with oxygen of the air to form black copper oxide. 2Cu(s) + O2(g) 2CuO(s) Thus, black coloured compound is copper (II) Oxide - CuO. 1.Light - Reflection & Refraction Introduction:- We see a variety of objective in the world around us However, we are to unable to see anything in a dark room. On lighting up the room, things become visible. Also during the day, we are able to see the world around us due to the light from the sun. Infact sunlight falling on the objects is reflected or scattered by them in our eyes and we are able to observe them. We may therefore consider light as a form of energy which produces in us the sensation of sight. Thus, light is an indispensable tool to explore the colorful beauty of nature such as blue color of sky, white color of clouds, red sunshine, and sunset, rainbow, beautiful colors of birds etc. A small source of light casts a sharp shadow of an opaque object become very small, light has tendency to bend around it. This effect is known as Diffraction of light. Moreover, an object reflects light that falls on it. This reflected light, when received by over eyes, enables us to see things. We are able to see through a transparent medium, as light is transmitted through it. There are a number of common wonderful phenomena, associated with light such as image formation of mirrors, the twinkling of stars, bending of light by a medium, so on. A study of the properties of light helps us to explore them by observing the common optical phenomena around us. Some Important Terms reflected with light:- 1. Source:- A source of light is an object , from which light is given out. Some sources of light are natural and many others are manmade sources. For us on earth, Sun is the important source of light. An Electric lamp, an oil lamp, a candle etc. are some of the manmade sources of light. The sources of light are of two kinds:- (a) Self Luminous: - A luminous source is that which possesses light of its own. eg, Sun, Stars, Electric lamps, Candle etc. (b) Non-Luminous:- A source which does not possess light of its own are called Non-Luminous source. It receives light from an external source and scatters it to the surroundings, e.g, the moon, a book, a table, a stone etc. 2. Medium:-A medium is a substance through which light propagates or tries to do so. There are three types of media of light:- a) Transparent:- It is a medium through which light propagates easily e.g, air, water, glass etc. b) Translucent:- It is a medium through which light propagates partially e.g, paper, thick polythene etc. c) Opaque:- It is a medium through which light cannot propagate. E.g., Wood, Metals, Wall etc. 3) Ray:- A ray light is the straight line path along which light travels. It is a represented by an arrow head on a straight line. The arrow head represents the direction of propagation of light. A number of rays combined together from a beam of lights. Reflection of light:- When light traveling in a medium A(say) strikes a boundary leading to another medium B, a part of the incident light is thrown back into the original medium A. This phenomenon is called reflection of light, thus, reflection of light is the phenomenon of bouncing back of light in the same medium on the striking the surface of any object. Law of reflection of light:- First law:- According to this law, the incident ray, the reflected ray and the normal at a point of incidence all lie in the same plane. Here in the figure, light falling on plane mirror MM” along AO is incident ray and OB is reflected ray. ON is normal to the mirror at O. According to first law OA, Ob and ON all lie in the same plane. Neither of the two rays or normal goes down into the paper or cones up out of the paper. Second Law:- According to this law, the angle of incident(i) is always equal to the angle of reflection(r) i.e, <AON=<NOB or <i= <r These laws of reflection are applicable to all types of reflecting surface including spherical surface. Further when a ray of light is incident normally or perpendicularly on a mirror, <i=0. According to the second law of reflection ray would go along the normal itself. Here in the figure the incident ray is along No reflected ray and reflected ray is along ON. It means that a ray of light incident normally on the mirror retraces its path on reflection. Characteristics of Image formed by plane Mirrors:Following are the important characteristics of image formed by plane mirrors:- i) ii) iii) iv) v) The image of a real object is always virtual. Such an image cannot be taken on a screen. The image formed in a plane mirror is always erect i.e, upside of the image is upside of the object and vice-versa. The size of the image in a plane mirror is always the same as the size of the object The image formed in a plane mirror is as far behind the mirror as the object is in front of the mirror. The image formed in a plane mirror is laterally inverted i.e, the left side of the object becomes the right side of the image and vice-versa. Spherical Mirror:- The reflecting surface of a spherical mirror is curved inwards or out wards. Infect a spherical mirror is that mirror whose reflecting surface is a part of a hallow sphere of glass. One side of mirror is well polished and reflecting and the other side of the mirror is opaque. Spherical mirrors are of two types:- (a) Concave Mirror:- It is spherical mirror in reflecting surface is towards the centre of sphere of which the mirror is a past- i.e reflection of light.occures at concave surface or the best in surface. The other which the (b) surface of the concave spherical mirror is opaque or non- reflecting. Convex mirror:- It is that spherical mirror in which reflecting surface is way from the centre of the sphere of which the mirror is apart - i.e, reflection of light occurs at convex surface or bulging out surface. The surface (shaded) of the mirror is opaque or non-reflecting. Some important terms related to Spherical mirror:- (i) Center of curvature:- The centre of curvature of a spherical mirror is the centre of the hallow sphere of the glass of which the spherical mirror is a part. The centre of curvature is usually represented by the letter(C) (ii) Pole: - The pole of spherical mirror is the centre of a mirror. It is also called the vertex of the mirror and is usually denoted by the letter ( P) (iii) Radius of curvature:- The radius of curvature of a spherical mirror is the radius of the hallow sphere of glass of which the spherical mirror is the part. It is usually represented by letter (R) (iv) Principal Axis:- The straight line passing through the centre of curvature (c) and pole ( P) of the spherical mirror produced on both sides is called principal axis. Here in the figure XX` IS THE PRINCIPAL AXIS. Principal axis is normal to the mirror at its pole. (v) Aperture:- The aperture of a spherical mirror is the diameter of the reflecting surface of there mirror. It is also called linear. (vi) Principal focus :- The principal focus of a mirror is a point on the principal axis of the mirror at which rays of light incident on a mirror in a direction parallel to the principal axis actually meet after reflection in case of concave mirror where as in case of convex mirror appear to diverge after reflection from the mirror. It is usually denoted by F. The principal focus (F) of a concave mirror is a real point and always lies in front of the concave mirror where as in case of convex mirror it is virtual point and always lays behind thee convex mirror. vi) Focal length:- the distance of the principal focus ( F) Sign convention for mirrors: In the ray diagrams of canvas as well as convex spherical mirror we use new Cartesian sign conventions for measuring various distances. According to the new Cartesian sign convention, we have:i) ii) iii) iv) v) vi) vii) The principle axis of the mirror is taken along x-axis & poll P of the mirror is taken on the left side of the mirror i.e. light is incident on the mirror from the left hand side. The object is taken on the left side of the side i.e. light is incident on the mirror from the left hand side. All the distance parallel to the principal axis of the spherical mirror measured from the pole of the mirror. The distance measured in the direction of incident light is taken as positive. The distance measured in the direction opposite to the direction of incident light is taken as negative. The heights measured up words –i.e. above the x-axis and perpendicular to the principal axis of the mirror is taken as positive. The heights measured downwards- i-e. below the x- axis and perpendicular to the principal axis of the mirror are taken as negative. Images formed by spherical mirrors using ray diagrams:- When an object is placed in front of a concave mirror, its image is formed by reflection in the mirror. Every point on objects acts like a point source, from which an infinite n, of rays originate. In order to the image of the point object, an arbitrarily large number of rays emanating from the point object can be considered .However for the sake of simplicity, We take any two rays of light, whose paths of simplicity, we take any two rays of light, Whose paths on reflection from the mirror are known to us. The point where these two reflected rays actually meet or appear to come from is the real/natural image of the point object. The fallowing x-rays of light are commonly used, out of which any two can be chosen concave mirrors. →Spherical. Rule-1:- a ray of light following on the mirror parallel to the principal axis after reflection will pass through the principal focus in case of concave mirror or appear to diverge from the principal focus of a convex mirror. Rule2:A ray of light passing through the principal focus of a concave mirror or a ray which is directed towards the principal focus of a convex mirror after reflection will emerge parallel to the principal axis. This rule is just the reverse case of Rule- 1. Rule -3:- a ray of light passing through the center of curvature of concave mirror or directed in the direction of center of curvature of a convex mirror after reflection is reflected back along the same path the rays of light come back along the same path because the incident rays fall in the mirror along the normal to the reflecting surface. Rule 4:- A ray of light incident obliquely towards the pole p on the concave mirror or convex mirror is reflected obliquely. The incident and reflected rays fallow the laws of reflection at the point of incident making equal angles with the principal axis. It is important to note that in all the cases the laws of reflection are followed. At the point of incident the incident ray is affected in such a way that the angles of reflection equal the angle of incident. Image formation by cancave mirror:- The type f image is formed by a concave mirror depends primarily on the position of the object. In front of the mirror As an object approaches from infinity towards the spherical mirror there occurs changed in the nature position and sign of the image in other words if the distance of the object from the mirror is changed, a corresponding change in the nature of position and size of the mage takes place different place different cases involved in case of a concave mirror are as under:- Case-1:- when the objects infinity:- Consider an object AB is situated very for off from the mirror. Two rays Ad and AP from the top A of the abject are parallel to one another and incident to the principal axis. These rays are reflected at points D and p on the mirror and intersect at A` which i8s the real image of the top A of the object. From A` draw A` B` perpendicular to the principal axis of the mirror Therefore A`B` is the image of object A at infinity the image is formed at the focus F. It is real inverted and such smaller in size then the object. Case 2:- When the object is beyond, center of curvature(C):- In this case consider on object AB is placed beyond the center of curvature (C). A ray AD starts from top A of the object and goes parallel to the principal axis. After reflection it passes through the principal focus (F). Another ray AE passing through the center of curvature straights the mirror normally and set races its path after reflection. These reflected rays intersect at A` which is the image of A similarly the image of b is objected at B` Thus the image of the object is formed between the principal focus (F) and center of curvature (c) It is real inverted and smellier in size. Case-3: when the object is at the centre curvature:When the object is placed at the center of curvature, the image A`B` of the object AB is also formed at the center of curvature(C). It is real, inverted and of same size as that the object. Case 4: when the object is placed between focus (f) and center of curvature (C):When the object AB is placed between the principal focus (F) and the center of curvature ( C), the image A`B` of the object is formed beyond the center of curvature ( C). It is real, inverted and very much magnified. (Diagram at page no 9) Case 5: When the object is placed at the focus (F):When the object AB is placed at the center of principal focus (F) of the mirror, the image of the object AB is formed at infinity. However the the image is real, inverted greatly magnified. Case 6:- when the object is placed between the le and focus of the mirror:- When the object is placed between the pole P and the principal focus (F) of the concave mirror, the reflected rays of the object does not meet anywhere in front at the mirror but when these rays are reduced back words meet at A` where a virtual image formed the perpendicular AB on the principal axis gives the position of the image. Hence the image is formed behind the concave mirror. It is virtual each and magnified in A’ size Image formation by concave mirror:- In case of convex mirror the image of an object formed is essentially virtual erect and diminished in size. The different cases formed in case convex mirror are as under. CASE 1 :- When the object is at infinity:- Consider an object lying at infinity the parallel rays coming from the object lying infinity appear to be diverging from the principal focus thus the image is formed at the principal focus . However the image formed is virtual erect and very much diminished in size. Case 2 When the object is placed between pole and infinity:- Consider an object AB placed between the pole P of the convex mirror and the infinity the image is formed between the pole and the principal focus of the mirror. It is virtual erect and smaller in size then that of the object. USES OF SPHERICAL MIRRORS:- Some practical applications of sphrcal mirrors are:(A) Concave mirror:i) ii) iii) iv) v) vi) A concave mirror is used as a reflector in torches search lights, head lights of motor vehicles etc. To get powerful parallel beams of light. A concave mirror is used as doctors head mirror to focus light o body parts like eyes, ears, nose, throat etc to be examined. It is also used as shaving mirror and a makeup mirror as it can form erect and magnified image of the face. The dentist use concave mirrors to observe large images of the teeth of patients. Large concave mirrors are used to concentrate sunlight to produce heat in solar cookers Large concave mirrors are also used in reflecting type telescopes. (B) Convex mirrors:i) ii) It is used as a reflector in street lamps. As a result light from lamp diverges over a large area. Convex mirror is used as rear view mirror in automobiles because:a) It produces erect images of object in front it. b) The size of the image formed is smaller and therefore has wide view of coverage. c) All images are formed between pole and focus. Mirror formula:- In a spherical mirror the distance of the object from its pole is called the object distance and is denoted by U the distance of the image from the pole of the mirror is called the image distance denoted by V. The distance of the principal focus from the pole of the of the mirror is called focal length denoted by F there is a relationship between these three quantities known as mirror formula and expressed as . I I _______ + _______ Object distance I I I Image distance = _______ Focal length I ___ + ___ = ___ u v f Derivation:Consider an object AB placed perpendicular to principal axis beyond the centre of curvature (C) in front of concave mirror. The incident ray BD parallel to the principal axis is reflected from point D such that the ray reflected rays passes through the focus. Another incident ray BCE is reflected back as ECB. Draw a perpendicular DM on principal axis. Now in as ABC=A``C` ∠ACB=∠A`CB-(V.O.∠s) ∠BAC=∠`B`A`C`-(each 90º ) :. ∆ABC= ∆ A`B`C-(AA similarity) :. AB AC ____ = _____ A`B` AB _____ A`C` PA - PC = __________ A`B` PC - PA Also, in ∆s A`B`F` & MDF ∠A`F`B` = ∠MFD −−−− [ V.O. ∠ s ] ∠B’A’F = DMF ------- [ each 90º] :. ∆A`B`F ~ ∆ MDF ----- [ AA similarity ] DM MF ______ = ______ A`B A`F AB MF Or ______ = ________ [ ·.· DM = AB ] A`B` MA` - MF Now if the aperture of mirror is small, than M will almost coincide P, then AB = A`B` PF II PA` - PF .·. From I and II , we get . PA` − PC PF ______________ = PC − PA` Or − u − ( −2f ) __________ PA` − PF = −f ghghghh − 2f − (− V) Or − u + 2f − 2f + V − V − (− f) = − f_____ − V+ f Or − (u − 2f ) _____________ −f = ___________ − (2f − v) −(v−f) Or (u − 2f ) (v − f ) = f (2f − v) uv − uf − 2vf + 2f2 = 2f2 − vf = 2f2 + 2vf + uf − vf − 2f2 uv Or uv = vf + uf Or uv _____ Uvf = vf uf ____ + ____ uvf ------ [†ing b/s by uvf ] uvf Or 1___ f = ___1___ + u ___1___ v Magnification:- The linear magnification produced by a concave mirror is defined as the ratio of height of the image ( h1) to height of the object ( ho). It is represented by `m`. :- Linear magnification(m)= height of image(h2) height of object (ho) or m= h1 ho The magnification (m) of a spherical mirror is also related to the object distance (u) and the image distance (v) as:It is important to that the height of the object is taken to be +ve as the object is usually placed above the principal axis. The height of the image should be taken as +ve for virtual images, but it is to be taken as -ve for real images. A -ve sign in the value of the magnification indicates that the image is real where as a +ve sign in the value of magnification indicates the image is virtual. Relation between radius of curvature 7 focal length of spherical mirrors:- it has been found that the focal length of a spherical mirror –i.e. either concave or convex mirror is equal to half of its radius of curvature. If (f) is the length and R is the radius of curvature, then F=R/2 Derivation:- Consider a ray AB parallel to principal axis falling on a concave mirror at B. After reflection the ray passes through the focus. The dotted line cb is the normal at point b.there fore ∠Abc is the ∠ of incidence ‘i’ and ∠fBc is the ∠ of reflection ‘r’ now according law of reflection. ∠I=∠r Or ∠ FBC = ∠ FCB or ∠ ABC = ∠ FBc {∠ FBC =∠ FCB Att. ∠s} ∠ FBC = ∠ Fcb .FC=FB -------- I { sides opposite to equal ∠ s } Now if the aperture of the cancave mirror is small thenthe ray AB will be very close to P. therefore FB will be approximately equal to Fp. i.e FP = FB -----II :- from I and ii we get. FC =FP Now Fc= Fp = R, where ‘R’ is the radius of curvature. FP + FP = R 2FP = R 2f = R f = R/2 It is important to mole that focal length of a mirror depends only on the radius of curvature. Problem 1:- Find the focal length of a mirror of radius of curvature 1m. Sol. Here focal length, f = ? Radius of curvature, R = 1m We know that F = R/2 =1/2 m => F = 0.5m ans TEXT BOOK Problem 1.1:- A concave mirror8 used for rear- view on an automobile has radius of curvature of 3.00m. If a bus is located at 5.oom from this mirror find the position, nature and size of the image. Sol;- here radius of curvature R= +3.oo m. Object distance, u = - 5.oo m. image distance V=? Height of image hi = ? We know that F = R/2 = 3.oo/2 = 1.5m Also we know that 1/f = 1/u + 1/v 1/1.5 =1/-5 + 1/v => 1/1.5 =- 1/5 + 1/v. 0r 1/1.5 + 1/5 =1/v or 1/15/10 + 1/5 = 1/v. Or 10/15 + 1/5 = 1/v. 10 =3/15 = 1/v => 13/15 = 1/v => V = 15/ 13 = 1.15 m :- the image is formed at the back of the mirror. Again we know that Magnification, m =h1/ ho = - y/u m = -v/u = -1.15/-5.oo = + 0.234 Thus the image is virtual erect and smaller in size. Problem 1.2: An object 4.0 cm in size is placed at 25.0 cm insert of a concave mirror of foal length 15.ocm at what distance from the mirror should screen be placed and size of the image. Sol:- here size of object, ho= + 4.om. Distance of object, u = -25.ocm. Focal length , f = -15.0cm Distance of the image, v = ?. Size of the image, hi = ?. know that 1/f = 1/u + 1/v 1/-15 = 1/-25 + 1/v Or -1/15 = -1/25 + 1/v Or 1/v = -1/15 + 1/25 we Or 1/v = -5+3 = -2/75 75 or -2v = 75 => v = 75/2 = - 37.5 cm Ans. :- screen should be placed at 37.5 cm from the mirror and the image is real. Again we know that Magnification, m = hi/ho – v/u or hi/+4.o = - {-37.5) - 25.o - 25.0hi = 37.5 * 4. `hi = 37.5*4 -25 = -6.0cm. Thus the image is inverted and enlarged. Problem 2:- The radius of curvature of a spherical mirror is 20cm . what is its focal length ? Problem 3:- Find the focal length of a convex mirror, whose radius of curvature is 32 cms. Extra Problem 4:- An object 4cm in size is placed at a distance of 25.0cm from a concave mirror of focal length 15.0cm. Find the position, nature and the size of the image formed. Problem 5:- An erect image 3times the size of the object is obtained with a concave mirror of radius of curvature 36cms. What is the position of the object? Problem 6:- A 2.5cm candle is placed 12cm away from a concave mirror if a focal length 30cm.Give the location of the image and the magnification. REFRACTION OF LIGHT :- When a light travels in an isotropic medium , it propagates in a straight line , but it changes its path while moving from one medium to another . In other words we can say that light bonds at the interface (a line dividing the two mediums) of the two media, when light moves from one medium to another. This phenomenon is called refraction. Thus, refraction is the phenomena of bending of light as it passes from one medium to another .The bending of a light can take place into possible ways. In first case when light travels from a rare to a denser, medium, it bends towards the normal at the interface of two media (fig.1) In the second case when light travels from a denser to a rare medium, it bends away from normal to the interface of two media (fig. I) Laws of reflection:- The bending of a light while traveling from one medium to the another to the other takes place in accordance with certain laws reoffered to as fallows:First law:- The incident ray refracted ray and normal to the surface at the point of incidence of all lie in and the same plane. Second law:- {the incident ray, refracted ray and normal to the to the interface of two media at the point of incidence all} X the period of a refractive index and sine of angles at a point in a medium is constant. i.e. n sin I = constant For the two media in contact, we have n1 sin i1 = n2 sin i2 ______ I Now since i1 = I & i2 = r :- from I we get Ni sin I = n2 sin r Or sin i = n2 sin r n1 = n2 Thus the radio of sine of angle of incidence to the sine of angle of reflection is constant for the pair of media in contact. This constant is written as 1n2 as it. Represents refractive index of media 2 with respect to medium 1. Note: - these relationships were discovered by small experience mentally in 1621 and do this law in is called as Snell’s law of reflection. Third law :- Whenever light goes from one medium to another the frequency of light does not change . However, the velocity of light and the wave light of light change. Refraction through a Rectangular Glass Slab A ray of light AO traveling in air is incident on a glass slab PQRS at point O. On entering the glass slab, it gets refracted and bends towards the normal ON`. A second change of direction takes place when the refracted ray of light OB traveling in glass emerges i.e, comes out into air at point B. Since the ray of light OB now goes from a denser medium ‘glass’ into the rarer medium ‘air’, it bends away from the normal BN’, and goes in the direction BC. From the figure, the incident ray AO and the emergent ray BC are parallel to each other. These are parallel to each other because the extent of bending of the ray of light at points O and B on the opposite. Parallel faces PQ and SR of the rectangular glass slab are equal and opposite. The incident ray AO bends towards THE NORMAL AT POINT o WHERE AS REFRACTED RAY ob BENDS AWAY FROM the normal at point B by an equal amount .Thus, he light emerges from a parallel sides glass slab in a direction parallel with that in which it enters the glass slab action parallel with that in which it enters the glass slab through the emergent ray BC is parallel to the incident ray AO, but the emergent ray has been side displaced or laterally displaced from the original path of the incident ray by a ┴ distance CD, where as the original path of incident light is AOD, but the emergent light goes along BC, the displacement between them being CD. Another point to be noted is that in this case the refraction of light takes place twice---- first at point) and then at point B. The angle which the emergent ray makes with the normal is called the angle of emergence. The case of light falling normally i.e ┴an a glass Slab:- If the incident ray falls normally to the surface of a glass slab, then these is no bending of the ray of light and it goes straight. Here in the figure a ray of light AO traveling in air falls on a glass slab normally or perpendicularly at point O, so it does not bend on entering the glass slab or as coming out of glass slab. It goes straight in the direction AOBC. Since the incident ray goes along the normal to the surface, the angle of incidence in this case is zero. Similarly, if a ray of light falls normally or perpendicularly to the surface of water, even then, there is no bending of light ray and it goes straight through water. Refractive Index: - We know that when a ray of light travels obliquely from one transparent into another changes its direction in the second medium . The extent of the change in direction that takes place in a given pair of media is expressed in terms of the refractive index. The refractive index can be linked to a physical quantity, the relative speed of propagation of light in different media. Light travels the fastest in vacuum with the highest speed of 3x108m in air, the speed of light is only marginally less compared to that in vacuum. It reduces considerably in glass or water. The value of the refractive index for a given water The value of the refractive index of light in the two media. Consider a ray of light traveling from medium 1 into medium 2. Let V1 be the speed of light in medium 1 and V2 be the speed of light in medium 2. The refractive index of medium 2 with respect to medium 1 is given by the ratio of the speed of light in medium 1 and the speed of in medium 2. This is usually represented by the symbol n21 or 1n2. This can be expressed in an equation FORM AS:- 1 n2 = V1 V2 = Speed of light in medium 1 Speed of light in medium 2 By the same argument, the refractive index of medium 1w.r.1 medium 2 is represented asm2 or 2n,. It is given by:2n1 = V2 = Speed of light in medium 2 V1 Speed of light in medium 1 Now if medium 1 is vacuum or air, then the refractive index of medium 2 is considered w.r.t vacuum. This is called the absolute refractive index of the medium. If ‘c’ is the speed of light in air and V is the speed of light in the medium, then the refractive index of the is given by:- nm = Speed of light in air = C Speed of light in medium V The absolute refractive index of a medium is simply called its refractive index. For Example, let us take ‘glass’ as the medium , we know that the speed of light in air is 3x108m/s at the speed of light in common glass is 2x108m/s. ng = speed of light in air = 3x108 Speed of light in glass 2x108 = 3/2 = 1.5 Thus the refractive index of glass w.r.t air is 1.5. This means that the ratio of the speed of light in air or vacuum to the speed of light in glass is equal to 1.5. Similarly, refractive index of water is as under:N water = speed of light in air speed of light in water = 3*108 M/S = 3 =1.33 2.25*108 m/s 2.25 As refractive index is a ratio of two velocities, it has no units. It is a pure number. We know that Refractive index of the medium, nm = c v => v = C nm :Larger the value of `nm` smaller is the value of V. It means in a denser medium, speed of light s smaller and in a rarer medium, the speed of light is larger. Tx.B Q5 the refractive index of diamond is 2.42. What is the meaning of this statement. Ans. He refractive index of diamond is the longest and is = 2.42 :- The optical density of diamond is the largest. V As n = C V => V = C n Therefore, when `n` is largest, v is smaller -i.e. velocity of light in diamond is minimum. Refraction by Spherical Lenses:Spherical Lenses: - spherical lens is a piece of a transparent refracting material, which is bound by two surfaces. Often both the surfaces of a len are spherical. On passing through a lens, light is spherical lenses are two types:(i) (ii) Concave lens or converging lens. Concave lens or diverging lens (i) Convex lens:- The lens which is thick in the middle and thin at the edges is called convex lens. The two surfaces P & Q binding the less are convex – i,e. bulging out having their own centre of curvature & radius of curvature of the two surfaces may be equal or unequal. A convex lens is called an CONVERGING LENS, because it converges the rays of light falling on it. (ii) Concave lens: - The lens which is thin in the lens middle and thick at the edges is known as concave lens. The two surfaces P` and Q` binding the lens are concave i.e` curved in words having their own centre of curvature & radius of curvature. The radii of curvature of the two surfaces may be equal or unequal. A concave lens is called a diverging lens, because it diverges the rays of light falling on it. Some basic terms connected with convex & concave lens :- (i) Centre of curvature: - A lens either convex or concave has two spherical surfaces. Each of these surfaces forms part of a sphere. The Centers of these spheres are called centre of curvature of the lens. They are represented usually by c1 and c2. (ii) Principal axis:- An imaginary straight line passing through centers of curvature of the two surfaces of the lens. The line c1c2 represents the principal axis. (iii) Aperture: - The aperture of a lens is the diameter of the circular edge of the lens. Here in the diagram AB represents the aperture. (iv) Optical Center: - The optical centre of a lens is a point on the principal of axis of the lens, such that a ray of light passing through It goes un deviated - i.e. the ray passing through optical centre of the lens suffer no refraction. Here in the figure the optical centre is represented by the point O. v) Principal focus: - A convex lens has two surfaces and hence it has two principal points. First principal focus:- it is the position of a point object on the principal axis of the lens for with the image formed by the lens is at the infinity. The first principal focus of convex lens is represented by the point F1. The rays starting from an object point at f1, on refraction through convex lens become parallel to principal axis and would form the image of the object point at infinity. Second principal focus: - in the convex lens, it is the position of an image point on the principal axis of the lens, when the point object is situated at infinity. It is represented by the point F. In case of concave lens, the first principal focus is the virtual position of a point object on the principal axis of the lens for which the image formed by the concave lens is at infinity. It is also represented by Fi, where as the second principal focus is the position of image point on the principal axis of the lens. When the point object is situated at infinity, it is again a virtual point and represented by Fi. vi) Focal length: - In case of convex or concave lens, it is the distance between the principal focus of the lens from optical centre O of the lens. It is generally denoted by 'f'. Formation of Images by a convex lens: - A convex lens forms the image of an object placed in front of it. Any point on the object acts as a point source from which an infinite number of rays start. These rays suffer refraction on passing through the lens. We can locate the position of the image, the size and nature of the image by considering any Two of the following special rays:- a) The ray incident on the lens in a direction parallel to the principal focus of the convex lens, on refraction passes through the principal focus of the located on the other side of the lens. b) The ray passing through optical centre of the convex lens passes straight i.e. undeviated after refraction through the lens. c) The rays passing through principal focus of convex lens, incident on the lens becomes parallel to the principal axis of the lens, after refraction through the lens. In case of a convex lens, as the object is brought closer to the lens from infinity, six different cases arise from the consideration of position, nature and size of the image formed. These 6 different cases are as follows:- i) Case-I When the object is at infinity:- When the object is at a considerable distance, we say the object is at infinity. Now when the rays of light coming from the object are parallel to the principal axis of the convex lens. After refraction, these rays meet at the principal focus of the lens on its other side giving rise to the formation of image of the object. Thus, it is clear from the figure that the image is formed at the focus of the lens. It is real, inverted and much smaller than the object. ii)Case-II When the object is beyond 2F1 (object beyond 2f):- When the object is placed beyond 2F1, the image of the object is formed at A'B' and it is formed between F2 and 2F2. It is real, inverted and diminished in size. iii) Case-III When the object is placed at 2F1 (object at 2F):- by placing the object at 2F1, it means that the object is at a distance equal to twice the focal length of the convex lens. In other words, the object is placed at a distance of 2F i.e. twice the focal length of the lens. The image of the object is formed at 2F2 and is formed on the other side of the convex lens. It is real, inverted and of the same size as that of the object. iv) Case-IV When the object is placed between 2F1 and F1:- i.e. object between F and 2F:In this case when the object is placed between 2F1 and F1, the image A'B' of the object is formed beyond 2F2 on the other side of the lens. It is real, inverted and very much magnified. v) Case-V When the object is placed at focus F1:When the object AB is placed at principal focus F1, the image of the object is formed at infinity. It is real, inverted and greatly magnified. vi) Case-VI When the object is placed between optical centre(O) and focus F1:In this case, the object AB is placed between the principal focus F1 and the optical centre(O), the rays after passing the lens does not appear to meet anywhere on the opposite side of the lens. But when these are produced backwards, the rays meet at A'. From A' draw A'B' perpendicular axis of the lens. Hence the image is formed on the same side of the lens. It is virtual, erect and greatly magnified in size. Formation of Images by a concave lens:To locate the position of the image, size and nature of image formed by a concave lens, we use any two of the following three special rays, whose paths after refraction through the lens are shown. a) A ray incident on the concave lens in a direction parallel to the principal axis, after refraction appears to come from principal focus of concave lens. b) A ray passing through optical centre of concave lens passes undeviated after refraction through the lens. c) A ray of light appearing to meet at the principal focus of a concave lens, after refraction will emerge parallel to the principal axis of the lens. The image is formed at a point, where the two refracted rays appear to meet. For all the positions of the object, the image formed by a concave lens is virtual, erect and diminished in size. The exact position and size of the image would depend upon the position of the object. There are only two possible cases in case of concave lens. Case l: - When the object lies between optical centre and infinity:As acts as an object and is held perpendicular to the principal axis of a concave anywhere between its optical centre O and infinity. The image of this object is formed between optical centre O and principal focus F2 on the same side of the lens as the object. It is virtual, erect and smaller in size than the object. Case II: - when the object is at infinity:When the object is at infinity, the image of object is formed at the second principal focus on the same side of the lens as the object. This image is virtual, erect and highly diminished to almost point size. this Sign conventions for lenses:- The new cartisian sign conventions for measuring various distances or heights in case of lens are similar to the one used for spherical mirrors. However, all distances in lenses are measured from the optical centre of the lens. According to new Cartesian sign conventions:i) ii) iii) iv) v) The principal axis of the lens is taken along x-axis of the rectangular Co ordinate system and optical centre O of the lens is taken as the origin. The object is taken on the left side of the lens -i.e. light is incident on the lens from left hand side. All the distances parallel to the principal axis of the lens are measured from the optical centre of the lens. The distances measured in the direction of incident light are taken as positive. The distances measured in the direction opposite to the direction of incident ray are taken as -ve. vi) vii) The heights measured upwards i.e. above the x-axis and perpendicular to the principal axis of the lens are taken as +ve. The heights measured downwards -i.e. below the X axis and perpendicular to the principal axis of the lens are taken as -ve. Lens Formula:- It is a relationship between object distance(u) image distance(v) and focal length(f) of the lens. It is given as:1/v - 1/u = 1/f The lens formula is general and is valid for any spherical lens, wherever the object may be situated. Derivation:- Consider an object AB placed perpendicular to the principal axis. BD is the incident ray parallel to the principal axis which 8 refracted as DB'. Another incident ray passing through, the optical centre, passes through the lens undeviated. Both the refracted rays meet at B'. Where the image A'B' is formed. In triangles ABO and A ' B'S <AOB = <B'OA' ( V. O. <'S) <BAO = <B'A 'O (each 90°) Therefore triangle ABO~ triangle A ' B'S ( AA similarity ) =》 AB/A'B' = OA/OA' ------------(1) Again in triangles DOF and B'A ' <DFO = <B'FA' ( V.O. <'s) <DOF = <B'A'F (each 90°) Therefore triangle DOF ~ triangle B'A'F (AA similarity ) =》OD/A'B' = OF/A'S or, AB/A'B' = OF/A'S ---------(II) Now from I and II, we get OA/OA' = OF/A'F or, OA/OA' = OF/OA'-OF -------(III) By sign convention, we have OA =-u, OF= +f, OA'= +v Therefore, from =n (III) We get, -u/v = f/v or -uv + uf = vf or, uf - vf = uv Dividing b/s by uvf, we get or, uf/uvf - vf/uvf = 1/f or, 1/v - 1/u = 1/f MAGNIFICATION: - The magnification produced by a lens, similar to that for spherical mirrors, is defined as the ratio of the height of the image and the height of the object. It is represented by 'm'. If 'h' is the height of the object and h' is the height of the image given by a lens, then the magnification produced by the lens is given by:m= height of the image/ height of the object =h'/h Magnification produced by a lens is also related to the object distance 'u' and the image distance 'v':m=h'/h = v/u Power of a Lens:The power of a Lens is defined as the ability of the lens to converge the rays of light falling on it. As a convex lens converges the rays of light falling on it, power of lens is said to +ve. On the other hand, a concave lens diverges the rays of light falling on it, so the power of a concave lens is said to be -ve. Further, if the point of convergence of rays of light lies close to the optical centre of convex lens, its converging ability or power is less. Now If 'P' is the power and 'f' is the focal length of the lens, then we have P = 1/f -------(1) clearly from the above equation, smaller the focal length of the lens, greater is its power and vice - versa. The S.I unit of power of a Lens is called diopter which is denoted by D. Thus, when focal length f = 1 Then we have from (1), P= 1/1 = 1 diopter. Therefore, one diopter is the power of a Lens of focal length one metre. Power of a combination of Lenses: - When a number of thin lenses are placed in contact with one another, the power of the combination is equal to the algebraic sum of the power of individual lenses. If Pl, P2, P3,............ are the powers of individual lenses placed in contact with one another, the power P of the combination is:P = P1+P2+P3+.......... The individual powers have to be taken with proper sign, +ve for convex lens of power +5D is placed in contact with a concave lens of power -2D, the power of the combination is P= P1 + P2 = 5D + (-2) = 5D - 2D = 3 Thus, this combination would behave as a convex lens of power +3D. problem:- A thin lens has a focal length of -25cm. What is the power of the lens? is it convex or concave? Sol. Here focal length, f = -25. Power of lens P=? We know that P = 1/f = 1/-25 ×100 P =-4 -ve sign shows that the lens is concave. Text Book Questions Q1:- Name a mirror that can give an erect and enlarged image of an object. Ans: - A concave mirror gives an erect and enlarged image of an object held between pole and principal focus of the mirror. Q2:- A concave mirror produces three times magnified (enlarged ) real image of an object placed at 10 cm in front of it. Where is the image located? Sol: - Here linear magnification, m = -3 Object distance, u = -10 cm Image distance, v =? We know that, m = -v/u Therefore, -3 = -v/-10 or, v = -30am Therefore, the image is located at 30 cms in front of the mirror. Q3:- A ray of light travelling in air enters obliquely into water. Does the light ray bend towards the normal or away from the normal? Why? Ans: - When a ray of light travels from air into water is optically denser than air. On entering water, speed of light decreases and the light bends towards normal. Q4:- you are given kerosene, turpentine and water. In which of these does the light travel faster? (↓ with refractive index 1.44, 1.47 & 1.33 respectively). Ans: - We know that Refractive index = Speed of light in air . Speed of light in medium Or speed of light in medium = speed of light in air Refractive Index. Therefore, it is clear from the above relation that the speed of light will be maximum in that medium or substance, which has the lowest refractive index. Now out of kerosene, turpentine and water, water has the lowest refractive index of 1.33. So, the light will have maximum speed in water or light will travel fastest in water. Q5:- A convex lens forms a seal and inverted image of a needle at a distance of 50cms from it. Where is the needle placed in front of the convex lens if the image is equal to the size of the object? Also find the power of the lens. Sol:- Here image distance, v = 50cm. Object distance, = ? Power of lens, P = ? As the image is of the same size as the object, :. The object must be at a distance equal to twice the focal length of lens. :. We have -u = v = 2f = 50cms. Or 2f = 50 =› f = 25cms Now we know that P = 1/f = 1/25*100 = 4dioptre Exercises Q1:- A spherical mirror and a thin spherical lens have each a focal length of – 15 cm. the mirror and the lens are likely to be- a) b) c) d) Both concave b) Both convex the mirror is concave, but the lens is convex the mirror is convex, but the lens is concave. Ans:- As per new Cartesian sign conventions, the focal length of a concave mirror and focal length of a concave lens, both are –ve. Therefore both are concave. :. (a) Choice is correct. Q2:- We wish obtain an erect image of an object using a concave mirror of focal length 15cm. what should be the range of distance of the object from the mirror? What is the nature of the image? Is the image larger or smaller than the object? Draw a ray diagram to show the image formation in this case. Ans: - To obtain an erect image of an object in a concave mirror, the object is placed between the pole and focus of the mirror. Therefore, the object is to be placed in front of the mirror art any position such that u ‹ 15cms. The nature of the image is virtual and erecdt behind the mirror. The image is larger than the object. Q3:- Name the type of used in the following situations:a) Head lights of a car (b) side rear view mirror of a vehicle. ( c) solar furnace, support your answer with reason. Ans:- (a) For head lights of a concave use a concave mirror. The light source is held at the focus of the mirror. On reflection, a strong parallel beam of light emerges. (b) A convex mirror is used as side rear view mirror, because its field of view is larger and it forms virtual, erect and diminished images of objects behind. C) For solar furnace, we use a concave mirror. Light from the sun on reflection from the mirror is concentrated at the focus of the mirror producing heat. Q4:- one – half of a convex lens is covered with a black – papers will this lens produce a complete image of the object? Verify your answer experimentally. Explain your observations. Ans: - Yes, it will produce a complete image of object. This can be verified experimentally by observing the image of a distance object like a screen, when lower half of the lens is covered with a black paper. However the intensity or brightness of image will reduce. the tee on Q5:- An object 5cm in length is held 25cm away from a converging lens of focal length 10cm. draw the ray diagram and find the position, size and nature of the image formed. Sol: - Here object size, h1 = 5cm Object distance, u = -25cm Also focal length, f = 10cm. Image distance, v = ? Size of image, h = ? We know that 1/v - 1/u = 1/f Or 1/v = 1/f + 1/u = 1/10 – 1/25 = 5-2 50 Or 1/v = 3/50 =⟩ 3v = 50 Or v = 50/3 = 16.67cms As v is +ve, the image formed is real and it forms on the right side of the lens. Now m =h2/h1 = v/u Or h2/5 = 16.67/-25 Or h2 = 16.67/-5 = -3.3cm -ve sign shows that the image is inverted. Q6:- A concave lens of focal length 15cm forms an image 10cm from the lens. How far is the object placed from the lens? Draw the ray diagram. Sol:- Here focal length, f = 15cm Image distance, v = 10cm Object distance, u = ? We know that 1/v -1/u =1/f Or 1/v – 1/f = 1/u Or 1/10 -1/-15 = 1/u =› u= -30cm. Q7:- An object is placed at a distance of 10cm from a convex mirror of focal length 15cms. Find the position and nature of the image? Sol: - Here object distance, u = -10cm. Focal length, f = 15cm Image distance, v = ? We know that 1/v + 1/u = 1/f Or 1/v = 1/f – 1/u = 1/15 – 1/-10 = 1/15 + 1/10 = 2+3/30 = 5/30 = 1/6 =› v = 6cm Now +ve sign of v indicates that the image is at the back of the mirror. It must be virtual, erect and smaller in size than the object. Q8:- The magnification produced by a plane mirror is +1. What that these mean? Ans:- we know that m = h2/h1 Now since m = +1 :. h2/h1 = 1 =›h2 = h1 :. Size of image = size of the object Also + sign of m indicates that the image is erect and hence virtual. Q9:- An object 5.0cm in length is placed at a distance of 20cms in front of a convex mirror of radius of curvature 30cms. Find the position of image, its nature and size. Sol:- here object size, h1 = 5.0cm Object distance, u = -20cm. Image distance, v = ? Radius of curvature, R = 30cm MATHEMATICS Chapters: Number System, Polynomial, Linear equation in one variables and Lines & Angles Students are asked to complete these chapters. History