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Chapter 4: The Carbohydrates: Sugars, Starches, and Fibers Key points Identification of carbohydrates Types of carbs Digestion and absorption of carbs Roles of carbs in the body Blood glucose regulation Glycemic response Recommendations Types of sweeteners Guidelines to groceries What is a carbohydrate? Contains C, H, O (C6H12O6) Provides 4 kcal/g Polyhydroxyaldehyde Six carbon backbone—hexose OH groups—alcohols Aldehyde group Dietary carbs come from plants Representations of Glucose Types of Carbohydrates Simple sugars Monosaccharides Disaccharides Oligosaccharides Complex carbohydrates or polysaccharides Starch Glycogen Fibers Simple Sugars (1) Monosaccharides—composed of one sugar unit (C6H12O6) Glucose—blood sugar Fructose—fruit, honey—most sweet Galactose—milk—least sweet After absorption, monosaccharides are converted into glucose in liver Simple Sugars (2) Disaccharides—made of two sugar units linked together Sucrose = glucose + fructose Maltose = glucose + glucose table sugar sweetest Malt Metabolism byproduct Lactose = glucose + galactose Milk least sweet How are the sugars linked? Condensation reactions How are they broken apart? Hydrolysis reactions Simple Sugars (3) Oligosaccharides 3-10 sugar units Beans, legumes Not digested very well in some people Beano Complex Carbohydrates (polysaccharides) Most made of at least 100 sugar units linked together Starch Glycogen Fibers Starch Composed of glucoses linked together Found in plants Chains of sugars fairly straight Glycogen Composed of repeating glucose units Made by animals Not found much in food Highly branched for rapid hydrolysis Figure 5.4 Fibers Indigestible polysaccharides Beta linkage History Sylvester Graham J. H. Kellogg William Kellogg C.W. Post Comparing alpha and beta linkages Types of Fibers Water soluble (viscous, fermentable) Water insoluble (nonfermentable) Oats, barley, legumes, fruit Protective against heart disease Grains, bran, veggies Promote G.I. tract health May reduce cancer risk Functional fibers—added to foods Table 5.1 Carbohydrate Digestion Figure 5.6 Carb digestion—step by step Mouth: starches polysaccharides (alpha amylase) Small Intestine: polysaccharides disaccharides (pancreatic enzymes) On villi: disaccharidesmonosaccharides small intestinal enzymes Maltase Lactase sucrase Lactose Intolerance Deficiency of lactase Only about 30% of people are not lactose intolerant Kids have 5-10% of the lactase activity of infants Carbohydrate absorption Monosaccharides villi blood-> liverall converted to glucose Functions of glucose in the body Energy Immediate Stored Glycogen (1/3 in liver) Spare protein Blood glucose Inhibit gluconeogenesis Prevent ketosis Recommended Intakes Total Carbs: 45-65% total kcals Complex: 35-55% total kcals Simple: 10% or less total kcals Fibers: 30-35 grams per day Too much carbohydrate Fiber: phytobezoars Simple sugars: malnutrition, dental caries, possible increase in CVD risk, not hyperactivity Average American eats 150 lbs sugar/year, or 30 teaspoons/day Complex: possibly obesity from too many kcals Too little carb Fiber--Diverticulitis Increased risk heart disease Increased risk cancer 35g/day lessens cancer risk by 40%) Obesity Simple sugars—none Complex muscle wasting ketosis Regulation of blood glucose Normal range 70-120 mg/dl Hormones Insulin—shuttles sugars into cells, lowering blood glucose levels Glucagon—releases glucose from glycogen in liver, raising blood glucose Epinephrine—same as glucagon--faster Disorders of glucose regulation Too high—diabetes (types I, II) Too low--hypoglycemia Glycemic response How quickly glucose is absorbed Low means slow (good) Glycemic index Blood glucose response to a given food compared to a standard like glucose. Low < 55 Intermediate 55-70 High > 70 Relative Glycemic Indices of Selected Foods Types of sweeteners Nutritive Sugars Sugar alcohols Nonnutritive Aspartame (nutrisweet--blue) Saccharin (pink) Acesulfame-K (sunnette, Pepsi 1) Sucralose (splenda—yellow) Stevia Figure 5.13 Guidelines to groceries 1 serving of grain = 15 g carb (starch) 1 serving starch veggie = 15 g carb 1 serving nonstarchy veggie = 5 g carb 1 serving fruit = 15 g carb (sugars) 1 serving milk = 12 g carb (cheeses have no carbs mostly) 1 serving meat = no carbs 1 serving legumes (meat alternative) = 20 g carb (starch) including 7 g fiber