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ATOMIC THEORY Philosophical Idea to Scientific Theory Chapter 3 Section 1 DEMOCRITUS A Greek philosopher Believed that atoms were the smallest particles of matter and that different atoms comprised different materials. 400 B.C. Atom is from the Greek word atomos, meaning, indivisible. Purely philosophical ideas at this point. ARISTOTLE (300 B.C.) Greek philosopher who rejected Democritus’ atom. Proposed that matter was continuous. Called contiuous matter, hyle. ISAAC NEWTON and ROBERT BOYLE 1600 Rejected Aristotle’s hyle theory in published articles. Still did not have proof that atoms existed. LAVOISIER 1700’s The “Father of Chemistry” One of the first scientists to use numeric data to support his hypothesis. Proposed the Law of Conservation of Mass in 1782. Law of Conservation of Mass Matter cannot be created or destroyed during a chemical reaction. Mass of reactants = mass of products. JOSEPH PROUST late 1700’s Observed that specific substances (compounds) always contain the same elements in the same ratio by mass. This is known as the Law of Definite Proportions. Ex. NaCl always consists of 60.66 % chlorine and 39.43 % sodium CLAUDE – LOUIS BERTHOLLET and JOHN DALTON 1790’s Law of Multiple Proportions When multiple compounds of the same 2 elements exist, the masses of the second element combined with a certain mass of the first is always a ratio of small whole numbers. MULTIPLE PROPORTIONS Example: Mass of Oxygen Mass of Ratio of O/N Nitrogen NO 16.00 g 14.01 g 16.00/14.01= 1.14 NO2 32.00 g 14.01 g 32.00/14.01 =2.28 2.28 / 1.14 = 2/1 JOHN DALTON 1800’s Proposed his Atomic Theory in 1808 based on the following: • Democritus’ atom • Law of conservation of mass • Law of definite proportions • Law of multiple proportions 5 Principles of Dalton’s Atomic Theory 1. All matter is composed of extremely small particles called atoms which cannot be subdivided, created or destroyed. 5 Principles of Dalton’s Atomic Theory 2. Atoms of a given element are identical in their physical and chemical properties. 3. Atoms of different elements differ in their physical and chemical properties. 5 Principles of Dalton’s Atomic Theory 4. Atoms of different elements combine in simple, whole number ratios to form compounds. 5 Principles of Dalton’s Atomic Theory 5. In chemical reactions, atoms are combined, separated, or rearranged, but never created destroyed or changed. CURRENT ATOMIC THEORY The first principle of Dalton’s atomic theory has been refuted. Atoms can be created and destroyed. Atoms can be subdivided into subatomic particles: Proton Neutron Electron How were each of these discovered? INTERNET RESEARCH Use the internet to complete the next few pages of your note guide. Name the experiment, read the procedures and determine the major conclusions of each. SCIENTISTS of INTEREST: JJ Thomson, Robert Millikan, and Earnest Rutherford EXPERIMENTS: Cathode Ray Tube, Oil Drop, and the Gold Foil Experiment. ADDITIONAL SUBATOMIC PARTICLES Who discovered the neutron? What is a quark? Find the names and characteristics of the quarks.