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AY2015 NIT Ibaraki College Yoshiharu MIYASHITA Exercise in Physical Chemistry Email: [email protected] Basic Information Course Regular Course Compulsory / Elective Elective Grade 4th Number of Credits 1 Semester Full year Credit Type Normal Class Type Technical Subject Course Objectives This subject is designed to learn chemical thermodynamics. The course objective is to understand chemical thermodynamics through doing exercises and calculation of thermodynamic parameters such as heat, work, internal energy, enthalpy, entropy, and free energy. Topic Outline / Schedule Week 1 2 3 Topic Systems First Law of Thermodynamics Isothermal Process for Ideal Gas 1 Outline Exercises in Types of Thermodynamic Systems Exercises in the First Law of Thermodynamics Exercises in Expansion and Compression of Ideal Gas in Isothermal Irreversible Process 4 Isothermal Process for Ideal Gas 2 5 6 7 8 9 10 Internal Energy for Ideal Gas Enthalpy Mid-term Review on 1st semester Heat Capacity Equipartition of Energy Adiabatic Process for Ideal Gas 1 Exercises in Expansion and Compression of Ideal Gas in Isothermal Reversible Process Exercises in Joule's Law Exercises in an Enthalpy 11 Adiabatic Process for Ideal Gas 2 12 13 Heat of Reaction Enthalpy of Formation 14 15 16 17 18 19 Temperature Dependence of Heat of Reaction Review on 1st semester Second Law of Thermodynamics 1 Second Law of Thermodynamics 2 Entropy Entropy Change 20 Third Law of Thermodynamics Exercises in Heat Capacity and Mayer's Relation Exercises in Law of Equipartition of Energy Exercises in Poisson's Equation Exercises in Expansion and Compression of Ideal Gas in Adiabatic Process Exercises in Hess's Law Exercises in Calculation of Heat of Reaction by Using Standard Enthalpy of Formation Exercises in Calculation of Heat of Reaction at Various Temperature Exercises in the Second Law of Thermodynamics Exercises in Carnot Cycle and Efficiency of Heat Engine Exercises in an Entropy? Exercises in Calculation of Entropy Changes in Some Basic Processes Exercises in Boltzman's entropy Equation and the Third Law of Thermodynamics? 1 AY2015 NIT Ibaraki College 21 22 23 Law of Increasing Entropy Mid-term Review on 2nd semester Free Energy Exercises in Clausius Inequality 24 Gibbs Free Energy Change 25 26 Clausius-Clapeyron Equation 1 Clausius-Clapeyron Equation 2 Exercises in Calculation of Gibbs Free Energy Changes in Some Basic Processes Exercises in Derivation of Clausius-Clapeyron Equation 27 Chemical Equilibrium 1 28 Chemical Equilibrium 2 29 Electromotive Force 30 Review on 2nd semester Exercises in a Free Energy? Exercises in Use and Application of Clausius-Clapeyron Equation Exercises in Relationship between Equilibrium Constant and Free Energy Exercises in Temperature Dependence of Equilibrium Constant Exercises in Relationship between Electromotive Force and Free Energy Textbooks and Other Readings There is no required textbook for this subject. Relevant books will be introduced whenever necessary. Relevant books: G. Sugihara, T. Inoue, H. Akisada, Physical Chemistry Centering around Chemical Thermodynamics (3rd Edition), Gakujutsu Tosho Shuppan-sha, 2011 (in Japanese) P. Atkins, Atkins' Physical Chemistry (10th Edition), Oxford University Press, 2014* * available in our library Relevant Online Resources First Law of Thermodynamics / Internal Energy (YouTube) https://www.youtube.com/watch?v=Xb05CaG7TsQ The Second Law of Thermodynamics (YouTube) https://www.youtube.com/watch?v=4nPGS8xgzKw The Third Law of Thermodynamics (YouTube) https://www.youtube.com/watch?v=hBqcGWzHQbY Using Free Energy (YouYube) https://www.youtube.com/watch?v=MALZTPsHSoo Grading Policy Grading will be based on tests given in every week. To get credit, you need to get 60 or more points in total. Course Description 2 AY2015 NIT Ibaraki College This subject is for studying physical chemistry mainly concerning chemical thermodynamics. To prepare and review each lecture, you need to check the books, papers or websites introduced in class. 3