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Faculty of Science Department of chemistry Time of lectures: Instructor: Office hours: 2015/2016 Semester: Practical Physical Chemistry I )1( كيمياء فيزيائية عملي 11124222 Prerequisite (s): 111241 Lecture room (s) : 1st Text books & References: Physical Chemistry, 4th Edition, by K. J. Laidler, J. H. Text Book Meiser and B.C. Sanctuary, Houghton Mifflin, Boston (2003). (Optional) Experiments in Physical Chemistry" Shoemaker, D.P.; Other References Garland, C.W.; Nibler, J.W. (or any comparable text), Any edition Course Description: The Experiments: We will perform at least 12 experiments in physical chemistry covering Thermodynamics and Equilibrium. Students in the laboratory course will rotate through the list of experiments in 2 groups, designated I and II to best utilize our available equipments. You will be assigned a group designation during the first lecture session. All experiments will be performed in Chem 309 unless otherwise noted. Below is a list of all experiment in this course: Group I 1. Heat of solution using solubility method 2. Heat of solution using calorimetry 3. Indicator constant 4. The apparent enthalpy of proton ionization of a weak acid 5. Phase diagram of a three-component system 6. Binary liquid-vapor phase diagram (azeotropic mixture) 7. Effect of ionic strength on solubility Group II 1. 2. 3. 4. 5. 6. 7. Vapor pressure of a pure liquid Iodide-iodate equilibrium constant The use of NMR spectroscopy to calculate equilibrium constant using chemical shift The use of NMR to calculate equilibrium constant using relaxation time Heat of combustion Enthalpy of reaction in solution Partial molar volume Course outline: Week Topic detailes 1. 2. 3. 4. 5. 6. Attendance Policies: Be Punctual. Attendance is mandatory. Students are not allowed to miss more than 15% of the lectures, without acceptable real cause. If a student misses more that 15 % of the course lectures, she/he will forfeit the course credits. After this, medical reports may be submitted for evaluation, for a total absence of no more than 20%. If student misses more than 20% of lectures, regardless of the cause, the course will be failed. Grading system: Assessment First Exam Second Exam Activities and Evaluation Final Examination Total Grade 25% 25% 10% 40% 100%