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SCHOOL OF PHYSICS AND CHEMISTRY – CHEM 181 - HOWARD COLLEGE – 2013 Tutorial # 2 Scientific notation, Significant figures and Handling numbers from measurements 1. Uncertainty and Scientific Notation The uncertainty associated with a measurement whose value is expressed in scientific notation cannot be obtained directly from the coefficient in the scientific notation. The coefficient decimal point located is not the true location for the decimal point. The value of the exponential term must be taken into account in determining uncertainty. Determining Uncertainty: Calculate the uncertainty for the number 3.753 x 102 10-3 (uncertainty in coefficient) x 102 (exponential term) = 10-1 (uncertainty in value) The uncertainty in the number 3.753 x 102 is 10-1 (±0.1) ( in the tenth’s place) Therefore the number can be rewritten in decimal place to show the uncertainty, that is: 3.753 x 102 = 375.3 Practice Exercise: Calculate the uncertainty of the following numbers and rewrite in decimal form to show this uncertainty. a) 4.200 x 104 b) 4.2 x 105 c) 4.2 x 10-1 d) 4.200 x 10-3 Answers: Uncertainty a) ±10 b) ±10 000 c) ±0.01 d) ±0.000001 SCHOOL OF PHYSICS AND CHEMISTRY – CHEM 181 - HOWARD COLLEGE – 2013 2. 3. Determine the number of significant figures in each of the following numbers: a) 0.43571 b) 0.00621 e) 3300 f) 3300.00 c) 0.505023 d) 0.0000003 Round off the following measured chemical values to: four significant figures: a) 233.3723 b) 33.3723 c) 6.3723 d) 1.03723 c) 67.45 d) 67.35 c) 0.200007 d) 0.356303 three significant figures: a) 42 303 b) 42 360 two significant figures: a) 0.000333 4. b) 0.01234 Carry out the following multiplications and divisions, and express your answers to the correct number of significant figures: a) 4.2337 x 0.00706 b) 3700 x 37.00 c) 4.5 x 4.05 x 4.50 d) 0.100 x 0.001 x 0.010 e) 5671 ÷ 4.44 f) 5.01 ÷ 5.07 g) (1.171 x 106) x (2.555 x 102) h) (4.500 x 1010) ÷ (5.0005 x 10-8) 5. Calculate the following mathematical operations involving both multiplication and division and express your answers to the correct number of significant figures: a) 4.5 𝑥 6.3 7.22 b) 5.567 𝑥 3.0001 3.45 2.322 𝑥 4.00 c) 3.200 𝑥 6.73 5600 𝑥 300 d) 22 𝑥 97.1 SCHOOL OF PHYSICS AND CHEMISTRY – CHEM 181 - HOWARD COLLEGE – 2013 6. Carry out the following addition and subtraction mathematical operations and express your answers to the correct number of significant figures: a) 12 + 23 + 127 b) 3.111 + 3.11 + 3.1 c) 0.06 + 1.32 + 7.901 d) 1237.6 + 23 + 0.12 e) 43.65 – 23.7 f) 4.72 – 3.908 g) 4.111 – 3.07 h) 3.12 – 0.00007 i) 3.245 x 103) + (1.1 x 103) j) (9.870 x 10-2) – (5.7 x 10-3) 7. Carry out the following operations involving both addition and subtraction and express your answers to the correct number of significant figures: a) 999.0 + 1.7 -43.7 8. 9 b) 345 – 6.7 + 4.33 c) 4.3 + 230 – 20 – 13.00 Calculations involving both significant figure rules: a) 1.20 x (2.33 + 4.5) b) 0.300 x (3.73 + 3.0 + 2.777) c) 0.400 x (4.5 + 2.33) d) 4.2 x 5.30 x (28 – 11) e) 3.111 + 5.03 ÷ 100 x 33 f) 5.03 – 3.111 ÷ 100 + 33 What is the uncertainty, in terms of a power of ten, associated with each of the following measured chemical values? a) 3.700 x 104 b) 3.700 x 106 end of tutorial