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R E T H I N K I N G P O S T - 16 P H Y S I C S Eger M 1992 Hermeneutics and science education: an introduction Sci. Educ. 1 (4) 337—48 Lemke J L 1990 Talking Science: Language, Learning and Values (Norwood, NJ: Ablex) Hanson N R 1958 Patterns of Discovery (Cambridge: Cambridge University Press) OFSTED (Office for Standards in Education) 1994 Science and Mathematics in Schools: A Review (London: HMSO) HM Inspectors of Schools 1994 Effective Learning and Teaching in Scottish Secondary Schools: The Sciences (Edinburgh: The Scotish Office Education Department) Piburn M D 1993 If I were the teacher. . . qualitative study of attitude toward science Sci. Educ. 77 (4) 393—406 Hodson D 1990 A critical look at practical work in school science Sch. Sci. Rev. 70 (256) 33—40 Stannard R 1990 The Time and Space of Uncle Albert (London: Faber & Faber) Horton R 1971 African Traditional Thought and Western Science in Knowledge and Control ed M Young (London: MacMillan) pp 208—66 Tallis T 1995 Newton’s Sleep: Two Cultures and Two Kingdoms (New York: St Martin’s Press) Quantum physics in school I Lawrence King’s School, Worcester, UK A teaching route for introducing quantum ideas into the school classroom using modern devices is presented. This has been developed by a team of academics and school-teachers and trialled once. The ideas are quantization, wave–particle duality, nonlocality and tunnelling. This article attempts to map out a minimum approach to quantum ideas as they might be developed for a year 12 group (these students are age 17, in the first year of a two-year pre-university course). The trial group was working on module two of the Nuffield A-level modular course. The important elements of the approach are that: ● ● ● 278 the ideas developed should be of further use and reinforce important ideas already met in physics and elsewhere the style of argument used should be identifiably physics the ideas should have cultural worth ● the skills acquired by the students should be intrinsically useful. The work has grown, and is a part of a larger scheme to make something of quantum ideas starting from devices. Parts of this work have been presented at GIREP in Italy and at the Malvern Update in March 1996. I am indebted to Professor John Jefferson (DRA, Malvern), Mr Mark Ellse, Mrs Marie Arthur (King’s School, Worcester), Dr Ian Sage (DRA, Malvern) and Dr Mike Uren (DRA, Malvern), who have been part of this development team. The central ideas developed in this article are those of: ● quantization ● wave–particle duality ● nonlocality ● tunnelling. Each of these is developed with the help of plausibility arguments which draw on experiences in the laboratory, demonstrations, discussions and prior R E T H I N K I N G P O S T - 16 P H Y S I C S knowledge. The aim is to make the quantum view of the world: ● intelligible ● plausible ● fruitful [1] What follows is a possible route through some simple ideas for introducing these concepts in a way which seems to make them assimilable and challenging. My thanks to my current lower sixth (L6) who admirably fulfilled the roles of guinea-pigs! so that the ideas become part of students’ cultural toolkit and not just a set of standard responses or specialised tools for particular problem situations. Period 1 Figure 1. Apparatus for measuring Planck’s constant using multiple coloured LEDs. Figure 2. Graph of students’ results from the experiment to measure Planck’s constant. The first and central idea to get across is the idea of quantization. To do this I chose a couple of visible props familiar to the pupils from their work to GCSE and from their everyday environment: an incandescent filament lamp and an LED. With these two one can develop a model which suggests that energy only comes in packets. We first established a link between colour and potential difference using the incandescent lamp. (The notion of potential difference is a hard one and this course was trialled with able students in the second term of their L6 — still the revision engendered by this approach was welcomed. Students need to feel comfortable with an idea to use it as the basis for modelling in unfamiliar situations.) This enabled me to move onto the idea of a potential drop and the energy that is available for transfer to light. This idea can be reinforced by looking at the changes in colour of a short length of resistance wire when the pd across it is varied. An LED is then introduced. This has a very different behaviour but the key element to bring out is that there is a minimum potential drop which will produce light and that the resultant light is of one colour only. Some of the reason for this is bound up in the construction of the LED (this is further developed in the work which we have been doing on introducing quantum ideas via devices but did not trouble the students in trials) but the main thrust of the argument is to establish the phenomenological link between the colour and the pd. Discussion smoothly transfers this to a link between energy and Table 1. Tabulated results from the experiment to measure Planck’s constant. Striking pd (V) Energy per electron (aJ) h (10234 J s) LED colour Wavelength (nm) Frequency (PHz) blue 470 0.638 2.38 0.381 6.0 green 563 0.533 1.69 0.270 5.1 yellow 585 0.512 1.63 0.261 5.1 orange 620 0.483 1.48 0.237 4.9 red 650 0.462 1.47 0.235 5.1 279 R E T H I N K I N G P O S T - 16 P H Y S I C S wavelength. Reinforcement follows by getting the class to suggest what the pd might be for a green LED and then trying it out. At this stage there seems to be some grounds for a link between wavelength and pd (energy of emitted light) and it is therefore worth trying these ideas out on a selection of LEDs. (This brought the first 35 minute lesson to a close.) Period 2 The next double period was spent looking at a range of LEDs after a review of the state of play at the beginning of the period. We used LEDs from 470 nm to 650 nm, which are readily available and not too expensive, and I have suggested a way for wiring them up elsewhere (figure 1) which seems to have withstood the destructive integral of sixth formers with respect to time [2]. After a little inspection of the results, plotted using the spreadsheet on a Psion 3a palm-top computer, the well heeled decided that really the graph should be linear, wavelength clearly was not, and so we had better try frequency. They were much happier with this! And so we had to look for a relationship between frequency and energy per electron and found h, Planck’s constant. This double period was a generous time allocation but allowed time for their expectations to play a part, a result with a small but messy amount of data, and a clear-cut consensus to emerge from competing research groups who could walk round, comparing and then modifying and remeasuring, until happy with the graphs on their palm-tops (figure 2 and table 1). We ended with eV 5 hf and the photon hypothesis. Figure 3. Reverse-biased LEDs with a magic wand. 280 At this stage the students are fairly convinced that light is emitted as photons, but showing them that it also arrives as photons can be both entertaining and convincing. The trick is simply to suggest reversing the LED. If reverse polarized, then electrons will not pass through because they have a potential barrier. The hill the electrons dropped down to release the photons now blocks their path in the reverse direction. But this hill can only be surmounted by supplying the electrons with a particular amount of energy — a quantum of energy — equal to the energy that was emitted when a photon was emitted. Such a supply of readily quantized energy happens to be available — a pocket torch. This can then be tried out by directing light from the incandescent filament lamp of the torch though a standard red filter onto red and green LEDs with the expected results (to the teacher not to the students — they should believe before the event that success in this matter is highly unlikely!). The process can then be repeated with a standard green filter and with red and green LEDs. Period 3 The third period starts with explanation and exploration of the photon hypothesis as to how we might explicate changing intensities as well as different colours, and indeed why we do not see light as grainy. Not the 'size' of the photons but a calculation of the number emitted by a 40 W lamp every second is a convincing argument against graininess. This idea of quantization can be embedded further by using an ultra bright LED wired as a magic wand and going along the row of different LEDs used for Figure 4. Using the Quantex Infrared Sensor Card. R E T H I N K I N G P O S T - 16 P H Y S I C S Figure 5. A guide to tasks to link to a more conventional treatment of quantization. measuring Planck’s constant when they are reversebiased (figure 3). Picking out only the matching frequency nicely illustrates the concept of resonance. Further exploration involves the use of an IR sensor which does not apparently produce any output but which, when shone on a Quantex Infrared Sensor Card [3], produces a discernible glow (figure 4). This leads to a nice discussion of visible and invisible photons and where the energy might come from in order to produce the glow. The card must actually be prepared for use before detecting IR light: 'charge this card with regular ambient (or fluorescent) light prior to use)' are the instructions printed on the reverse. Figure 6. A facsimile of the BBC micro screen. Period 4 As a link to more conventional treatments (even the one on the syllabus!) they were then given a series of tasks to wrap up this first section. This BBC Micro simulation (figure 6) is a minimal approach to manipulating variables so as to investigate relationships! When the pd (V to set), Figure 7. The potential drop across an LED. 281 R E T H I N K I N G P O S T - 16 P H Y S I C S wavelength (L to set), metal (M to set) are selected and R is pressed the electron leaves the metal when the photon is incident and heads off towards the cathode for appropriate values of L and M. You then adjust V until the electron only just makes it across the gap, and this gives you the kinetic energy of the electron. behave. This is a metal–insulator–metal (MIM) junction which is used in some displays. If we join a metal to an insulator then the electrons are free to move within the metal but cannot move into the insulator. This a very similar situation to electrons not moving from right to left in the LED above. We can represent this as a potential barrier (figure 8). This sequence of activities established quantization firmly: light has both wavelike and particle-like properties. If what are held to be waves have particle like properties, might it not be the case that particles also have wavelike properties? The next phenomenon we looked at was tunnelling, which gave evidence for this idea as well as introducing the two important ideas of nonlocality and the superposition of states. To look at the nature of electrons we will look at a thin insulator sandwich, the metal–insulator–metal junction. The easiest way to do this in the school laboratory is with a capacitor (figure 9). Period 5 The first period started with recapitulation. Coming from the work on LEDs students have the idea that changes in the electron’s energy levels can be related to a potential jump (figure 7). For electrons travelling from the right to the left the step is a potential barrier: energy must be supplied to the electrons in the form of photons for the electrons to surmount the barrier. To explore the behaviour of electrons we need a readily controllable supply of electrons — the best source is a metal wire! We chose an arrangement that helped us to develop our current understanding of how electrons Figure 8. The energy map for a metal-insulator junction. So we try it out: The result is quite surprising — as we increase the pd we find a small current, which then rises nonlinearly instead of what we might have expected: no current at all then suddenly plenty of current. There is a stage where some of the electrons get though and some do not. This is in spite of the fact that the simple expectation is that all the electrons are at the same energy level. To understand this we must first look at what is happening to the energy map that we drew above as the pd is increased. The pd drop can only happen across the capacitor — wires have no resistance — and so as we increase the pd the map changes as shown in figure 10. Notice that we are not altering the structure of the metal or the insulator and therefore the electrons are incident on the barrier at the same height and the barriers between metal and insulator are also the same height. The effect of increasing the pd is Figure 9. The potential map and circuit for a MIM junction. Figure 10. How the energy map changes as the pd increases. 282 R E T H I N K I N G P O S T - 16 P H Y S I C S therefore to make the barrier appear thinner to the electrons. As we make the barrier thinner an increasing number of electrons seem to leak through. Classical physics, i.e. the physics of electrons as small particles, has carried us a long way but has no answer to this. In the same way that when we were stuck with light as a wave we looked at the particle model, so now we could look at the wave model for help with particles. Figure 11. Apparatus for looking at exponential decay of microwaves through a barrier. At this stage it is a nice illustration of having the right idea at the right time to introduce the (then) relatively unknown, Prince Louis de Broglie, who produced this very novel idea in 1924 as part of his PhD thesis: that electrons should display wavelike behaviour. The suggested relationship for the wavelength of particles is Table 2. Table of results from exponential decay of microwaves through a barrier. Books Reading (mA) Ratio 15 0.9 0.82 14 1.1 0.79 13 1.4 0.82 12 1.7 0.81 11 2.1 0.78 10 2.7 0.71 9 3.8 0.88 8 4.3 0.80 7 5.4 0.86 6 6.3 0.82 5 7.7 0.86 4 9.0 standard deviation 0.05 l 5 h/mv. Anything with a momentum that is very much larger than h will not display wavelike effects that are readily observable. We are then left with the problem of illustrating what it might be like for an electron to have wavelike properties. The things that we know about electrons in a wire at this stage (low Figure 13. Locating an electron. Figure 12. Results of exponential decay of microwaves through a barrier. 283 R E T H I N K I N G P P O S T - 16 P H Y S I C S Figure 14. Simulating the interaction of an electron with a potential barrier. velocity, small mass) make it likely that electrons will have a small momentum, which will of course help us. This is where the MIM barrier helps. This was the end of the first period. Period 6 The next double period needs to resolve the puzzles at the end of the last. A good place to start is with propagation of waves through a barrier to see if they behave in a way that will help us to understand the leaking of electrons through a potential barrier. Microwaves seemed to be a suitable source of waves and we found a use for school physics texts by utilizing them as a variable thickness barrier (figure 11). The decay of intensity (remember that this is proportional to the square of the amplitude) with the thickness of the barrier is exponential. The results obtained by my students are shown in figure 12 and table 2. To pull things together we introduced the idea of locating an electron. We have never been able to pinpoint an electron — it was only the earlier arrogance of physicists that suggested electrons might be a point. We therefore can position an electron more truthfully by saying where it is likely to be (figure 13). We drew a probability wave to show where it is likely to be. The evolution of this probability wave over time then determines where the electron is likely to be found. To find out how an electron is likely to behave when it collides with a barrier we need to know what happens to a wave that is incident on a barrier. We had some experimental knowledge of this already and compared this with a simulation of the interaction of a probability wave describing the Figure 15. The interaction of an electron with a wider potential barrier. 284 R E T H I N K I N G P O S T - 16 P H Y S I C S position of an electron with a barrier [4]. I have extracted the frames shown in figure 14. The exponential decay as the wave is incident on the barrier was spotted by the students (honest!). Uncertainty in position, the electron 'being in two places at once', particle likeness, wave likeness, incomplete picture models were all buzzing around. Time for a break! This is a model of a single collision of an electron with a MIM barrier. Note that there is a definite probability that the electron goes through and a definite probability that it does not. This is not as a result of our lack of knowledge about the system — as far as we can tell this is really what happens. The electron is said to be in a superposition of states: it is on both the left and the right hand sides of the barrier. Interpreting this state of affairs for a single electron is hard work and led to discussions of paradoxes such as Schrödinger’s Cat, but for an assembly of electrons fired at the barrier the problem is easier — only a fraction will get through. If we make the barrier thicker (figure 15) then more of the waveform has decayed by the time the other side is reached and therefore fewer electrons penetrate. This resulted in a fairly heated discussion — there was some feeling that the student had been led up the garden path but they began to see a coherent picture for the quantum world emerging. Period 7 Figure 16. Simulating the interaction of an alpha particle with a fixed nucleus. Figure 17. A nuclear potential. Again to complete the picture, for the penultimate period we built in historical links for this work. Starting with de Broglie, whose opinion was regarded as a little extreme by the examining committee which had to refer to Einstein for a second opinion, we then showed the diffraction of electrons [5]. He was shown to be right in 1927 by streams of electrons showing diffraction patterns; these could only be convincingly explained by wave ideas. It was in fact these very patterns that had led to the rejection of the particle model of light in the 19th century. Period 8 We then allowed some time for exploration and development in the final period of the two weeks. Development 1. The reason why ordinary particles such as humans, cars, buildings, cricket balls do not display wavelike properties is linked to Planck’s constant h. A lively discussion followed Gamow in allowing Planck’s constant to grow. Tunnelling is a nice basis on which to discuss this phenomenon and allows plenty of room for lively engagement and (fairly!) disciplined use of the imagination. Development 2. Tunnelling and alpha emission. Another process that has a fixed probability of occurring but the actual occurrence of which is unpredictable is the emission of particles from radioactive nuclei. Here again we cannot say with certainty what the outcome will be for any one alpha particle in any one atom but we can say with a great deal of certainty what the outcome will be when aggregated over a large number of particles. An additional problem which points to tunnelling is that the emitted alpha particles are of approximately 5 MeV whereas the bombardment of atoms with alpha particles shows that the energy needed to penetrate a nucleus is greater than 9 MeV. Geiger and Marsden’s experiment — about which a reminder was issued by using a simulation (home-grown simulation utilizing Interactive Physics [6], as advertised in Physics Education!) — provided the evidence for this when Rutherford was 285 R E T H I N K I N G P O S T - 16 P H Y S I C S postulating his nuclear atom (see figure 16). Conclusion The idea of quantum tunnelling allowed this paradox to be resolved. The alpha particle can tunnel through the barrier shown in figure 17. Now that we know more about the nucleus we can calculate the height of the potential barrier. The classical equivalent of this is any roller coaster. If it has enough energy to climb a hill then it should be emitted with a kinetic energy equal to the potential energy at the top of the hill. In this account I have sought to give not only an outline of a route but also a feeling for the achievability of the route in a UK school with live(ly) year 12 students. The opportunities are there in this material, not only to develop quantum ideas without too much historical detritus, but also to utilize the material in a way that fits into the current syllabus structure. Many students might well want to take these ideas further. There are two more layers of the onion under preparation — a more rigorous development of the treatment of semiconductor devices, and a treatment of the band theory of solids. These impart all the depth and rigour one could hope for and are part of the complete development which was alluded to at the beginning. In year 13 it may well be appropriate to reinforce some of this work by looking at: ● the wave nature of electrons again using electron diffraction ● interference of single photons ● electron waves in atoms ● more complex devices such as laser and resonant tunnelling diodes, which incorporate plenty of physics. The first three of these are well covered by the Nuffield A-level Physics course [7]; the last one has been the concern of the development group. Another way of looking at this problem is to regard it as an extension of the uncertainty principle: you can borrow a bit of energy for a while — the more energy the shorter the while. In this the case the trade-off is between the trip time to get through the barrier and the energy that is needed to climb over the barrier. This is often quoted as DEDt 5 h. Note that a simple qualitative prediction from this model is that the higher energy alpha particles should come from the more radioactive nuclei — this is the case. Development 3. The scanning tunnelling electron microscope. Scanning tunnelling microscopy is a technique developed in the 1980s and allows the imaging of solid surfaces with high resolution. The operation of a scanning tunnelling microscope (STM) is based on a tunnelling current, which starts to flow when a sharp tip approaches a conducting surface at a distance of approximately one nanometre. This current varies very sensitively with the insulating gap through which it tunnels and therefore we must control the tip position in such a way that the tunnelling current and, hence, the tip–surface distance are kept constant The tip is mounted on a piezoelectric crystal which expands a small amount when a voltage is applied at its electrodes. The tip scans a small area of the sample surface whilst maintaining this constant distance. This three-dimensional movement is recorded and can be displayed as an image of the surface. Under ideal circumstances, the individual atoms of a surface can be resolved and displayed. Any of these last three can be used as a starter for a brief research report. The first requires a disciplined imagination and the second two can link strongly with other areas of the curriculum. 286 Received 24 May 1996 References [1] Osborne R and Freyberg P 1985 Learning in Science (Auckland: Heinemann) p 47 [2] School Science Review December 1993 75 (271) p111 [3] Available from Quantex, 2, Research Court, Rockville, MD 20850, USA [4] Quantum Scattering from Physics Academic Software, NCSU, Box 8202, Raleigh, NC 276958202, USA [5] Revised Nuffield A-Level: Teachers Guide 2 1986 (Harlow: Longman) experiment L7 [6] Interactive Physics from Knowledge Revolution, 66 Bover Road, Suite 200, San Mateo, CA 94402, USA [7] Revised Nuffield A-Level: Teachers Guide 2 1986 (Harlow: Longman)