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EOCT ReviewPhysical Science The Structure of the Atom The Structure of the Atom The NUCLEUS contains: Protons-positively charged, mass of 1amu Neutrons-no charge, mass of 1amu All of the mass of an atom can be said to come from the nucleus How do we know the number of protons? It is equal to the atomic number How do we know the atomic number? We look on the periodic table! The Structure of the Atom The number you see at the top of each square on your table is the ATOMIC NUMBER, or the number of PROTONS. It will always be a whole number. Notice that as you go across the table, the atomic numbers go up by one each time you go over one element. No two elements have the same atomic number or the same number of protons. The atomic number gives the identity of the element. The Structure of the Atom The number you see near the middle of each square on your table is the ATOMIC MASS, weighted average of the isotopes of an element. ISOTOPES are two atoms of the same element with different numbers of neutrons. Some Boron atoms have 5 protons and 5 neutrons (MASS NUMBER=10). Other Boron atoms have 5 protons and 6 neutrons (MASS NUMBER=11). The ATOMIC MASS is the average of all of the elements different MASS NUMBERS. Some questions might ask you to calculate neutrons based on the atomic mass. In this case your answer would be 10.811 - 5 = 5.811, or A.M. – P = N The Structure of the Atom Isotopes have a certain notation Name Notation: The name of the element followed by the mass number Ex: Carbon-12 (N=6), Carbon-13 (N=7), and Carbon-14 (N=8) Symbolic Notation 12 6 C 13 6 C 14 6 C In the symbolic notation, the mass number is always on top, and the atomic number is always on the bottom The Structure of the Atom The Electrons are NOT found in the nucleus Electrons are negatively charged The mass of an electron is so much smaller than that of protons and neutrons that they are insignificant to the mass of the atom They are found surrounding the nucleus in an Electron Cloud The electron cloud has different energy levels; as you go farther away from the nucleus, the energy level has a higher number Electrons fill the energy levels according to the pattern: 2, 8, 8, 18, 18, 32, 32 The Structure of the Atom In an electrically neutral atom, the electrons will be equal to the number of protons. You can find electrons by looking at the periodic table and the atomic number. You can use the periodic table to determine how the electrons will fill the energy levels. The series of numbers at the very bottom tell you how many electrons will fill into each level as you go out. Valence electrons are the electrons in the outermost level: Boron has 3 valence electrons. The Structure of the Atom You always start filling in electrons in the lowest, innermost level first You fill according to the pattern: 2, 8, 8, 18, 18, 32, 32. Boron has five electrons, 2 in the innermost level, then three in the next. The Structure of the Atom Valence electrons are the outermost electrons Look on your periodic table and find the number of outermost electrons for oxygen You should find there are six A Lewis Dot Diagram shows only the valence electrons, in a box type format You put one on each of the sides; once you cover four sides you start pairing them. The Structure of the Atom Remember, ISOTOPES are atoms with the same number of protons and different number of neutrons Mass # – Atomic # (# of Protons) = # of Neutrons Atomic Mass – Atomic # (# of Protons) = # of Neutrons When two atoms have the same number of protons, but a different number of electrons, they are called IONS Ions are either positively or negatively charged, depending on whether you’ve lost or gained electrons The Structure of the Atom Taking away electrons: Boron is most likely to lose 3 electrons The negative electrons and positive protons will no longer be balanced Do you think it will be a positive ion, or negative? Positive: B+3 Boron Atom and Ion 6 5 ## of of Subatomic Subatomic Particles Particles 4 Protons Electrons 3 2 1 00 Boron Boron Boron Ion Boron+3 Adding electrons: Fluorine is most likely to gain 1 electron The negative electrons and positive protons will no longer be balanced Do you think it will be a positive ion, or negative? Negative: F-1 Fluorine Atom and Ion 10 9 8 # of Subatomic Particles 7 6 Protons 5 Electrons 4 3 2 1 0 Fluorine Fluorine Ion The Structure of the Atom The OCTET Rule Atoms will gain or lose electrons in order to have a full outer shell of electrons This means 8 electrons, or an octet (noble gases) You have to look at the element to see whether it is more likely to gain electrons to have eight, or to lose electrons and have the eight from the level below Ex: Mg has 12 electrons, is it closer to the noble gas Ne which has 10 electrons, or the noble gas Ar which has 18? Neon, so magnesium is going to lose 2 electrons to be like Ne. Will this be a positive ion or a negative ion? Positive! It will be Mg+2 The Structure of the Atom MEMORIZE these groups Group 1: H-Fr will be +1 Group 2: Be-Ra will be +2 Group 15: N-Bi will be -3 Group 16: O-Po will be -2 Group 17: F-At will be -1 Notice that those to the left are likely to be positive (lose electrons), those on the far right are likely to be negative (gain electrons) The Periodic Table The Periodic Table The Periodic Table is an orderly arrangement of all of the discovered elements, as well as some predicted elements The first periodic table was arranged according to atomic mass by Dmitri Mendeleev; he used index cards to teach his students the elements The modern periodic table was arranged by Henry Mosely, in order of increasing atomic number The table has 18 groups, or columns, also called families It has 7 rows, or periods Periodicity is the term that means when the elements are placed in order, you see periodic, or repeating, trends in their properties Alkaline Earth Metals Noble Gases The Periodic Table Group 1-Alkali metals The most reactive metals on the table, react readily with water Charge of +1 Metals conduct electricity and have luster Group 2-Alkaline Earth Metals Reactive, but less than alkali metals Charge of +2 The Periodic Table Groups 3-12-Transition metals These metals have different charges, some metals even having two possible charges Group 17-Halogens The most reactive non-metals Charge of -1 Are found as diatomic molecules F2, Cl2, if not in a salt with a metal, NaCl, KF Group 18-Noble Gases Filled valence shell Also called inert gases, because they are so stable The Periodic Table Atomic Radius: the size of an atom As you go across the table in one period, the radius gets smaller, because the increasing number of protons pulls the electrons in tighter As you go down a group the radius gets bigger because the electrons start filling energy levels that are farther and farther out Electronegativity: the likelihood an element will gain an electron Goes up as you go across, because the elements get closer to having a full octet Goes down as you go down a group, because the electrons are farther from the nucleus Matter and its Properties Matter and its Properties Matter is anything that has mass and takes up space (volume) The relationship between mass and volume is called density Density=mass/volume, or mass divided by volume Matter and its Properties Mass is found by using a balance Volume can be found either by using the formula l x w x h for a cubic rectangle, or by using a graduated cylinder for liquids The volume of an irregularly shaped solid can be found by using the water displacement method First you measure the volume of an amount of water Second, you drop in the solid you need to know the volume of Last, you subtract the original volume and the volume from the volume of the water plus the solid, the difference is the volume of the solid Matter and its Properties Matter and its Properties Homogeneous mixtures are also called solutions Solutions are when one thing is dissolved in something else The substance that is dissolved is called the solute The substance the solute is dissolved in is called the solvent Example: Sugar in coffee Solute: sugar Solvent: coffee Example: Air Solutes: oxygen, argon, carbon dioxide Solvent: nitrogen Matter and its Properties Solutions have a measure called concentration Concentration means how much solute is dissolved in the solvent Saturated means that the solution can not hold any more solute, any extra would sink to the bottom Unsaturated means that you could dissolve more solute without any sinking Supersaturated means that the conditions are such that you could actually dissolve more than what “should” go in A different approach: Concentrated-a lot of solute in the solvent Dilute-not much solute in the solvent Electrolytes are solutions which conduct electricity; these include salts, acids, and bases Matter and its Properties Solubility Curves can compare the solubility of different salts at a range of temperatures Which salt has the highest solubility at 10 degrees? KI Which salt has the lowest solubility at 40 degrees? Ce2(SO4)3 Matter and its Properties Acids and Bases Both are electrolytes, which means they conduct electricity The pH scale is a range that tells you how strong an acid or base is pH less than seven are acids, with the strongest being close to zero pH higher than seven are bases, with the strongest being close to fourteen Matter and its Properties Acids Contain an H+ ion Taste sour Turn litmus red pH less than 7 Start with H: HCl, HNO3, H2SO4 Bases Contain OH- ion Taste bitter Turn litmus paper blue pH greater than 7 Turns phenolphthalein fuschia End with OH: NaOH, KOH, Mg(OH)2 Matter and its Properties Neutralization An acid plus a base will give you a neutral salt in water Example: HCl + NaOH = NaCl + HOH (H2O) This is called a neutralization reaction; the positive ion from the base combines with the negative ion from the acid to form the salt Bonding Bonding There are two main types of compounds Ionic a metal and a non-metal electrons are gained and lost Covalent between two or more non-metals electrons are shared Another type of bond is metallic, where electrons are pooled Bonding Ionic Bonds a metal from the left side of the table, joins with a non-metal from the right side they can be shown using Lewis dot diagrams the metals lose electrons to form an octet non-metals gain the electrons sometimes you might have to use more than one of either the metal or the non-metal to get the dots to cancel out Bonding NaCl MgO Since they both have two, you reduce the formula to one each CaCl2 Bonding Ionic formulas can be found by using the crossover method Bonding Naming Ionic Compounds: For Binary Compounds (two elements): First, write the name of the metal Then, write the negative ion with the ending changed to – ide Example: Na+1 and Cl- becomes sodium chloride For Tertiary Compounds (two or more elements): First, write the name of the positive ion Then, write the name of the polyatomic ion, or if the negative ion is a single element, change the ending to –ide Examples: Mg+2 and NO2- become magnesium nitrite NH4+ and Cl- become ammonium chloride Bonding Some metals have more than one charge Their formula and name will depend on the charge Ex: Copper can either be +1 or +2 Cu+1 would be CuCl, or Copper (I) chloride Cu+2 would be CuCl2, or Copper (II) chloride If you have the formula and not the name, you must use the reverse crossover to find which charge is correct Bonding Covalent Compounds come from sharing electrons Bonding Covalent compounds-you know a compound is covalent if the first element is a non-metal Ex: CCl4 Covalent compounds use prefixes in their names 1 2 3 4 5 6 7 8 9 10 mono di tri tetra penta hexa hepta octa nona deka Bonding The prefixes can be used either to find the name from a formula, or the formula from a name You don’t use mono on the first element Example: NO2 Nitrogen dioxide Example: diphosphorus trisulfide P2S3 Reactions Reactions The left side of a reaction is called the reactants On the right side of the arrow, you find the products These are what you start with These are what you finish with The Law of Conservation of Matter states that all atoms on the right must be balanced with the atoms on the left Reactions There are five main types of reactions that involve electrons Reactions involving electrons are called chemical reactions Synthesis-when two or more small things make one larger compound A + B → AB 2H2 + O2 → 2H2O Analysis/Decomposition-when one larger thing breaks down into smaller parts AB → A + B 2NaCl → 2Na + Cl2 Reactions Single Replacement-when an individual element reacts with a compound and two ions switch places A + BC → AC + B Zn + 2HCl → ZnCl2 + H2 Double Replacement-when two compounds react together and two ions switch places AB + CD → AD + CB KOH + NaCl → KCl + NaOH Combustion-this is a specific type of synthesis reaction in which one reactant is always oxygen A + O → AO 2Mg + O2 → 2MgO Reactions Balancing Chemical Reactions The main function is multiplying Ex: Fe + S → Fe2S3 1 1 2 3 2Fe + S → Fe2S3 2 1 2 3 2Fe + 3S → Fe2S3 2 3 2 3 Reactions Sometimes you have to add if an element is in more than one place on the same side of the arrow Ex: NO + O2 → NO2 Total O 3 2 Total N 1 1 Try to even up any odd numbers by multiplying by 2, then balance 2NO + O2 → 2NO2 Total O 4 4 Total N 2 2 Radioactivity Radioactivity Nuclear radioactivity comes from nuclear reactions Nuclear reactions are those that involve the protons and neutrons in radioactive isotopes Isotopes with equal protons and neutrons are the most stable Nuclear radiation gives off very high energy compared to chemical (electron) reactions This radiation can be harmful if you aren’t careful, but it can also be very useful! Radioactivity There are three main types of nuclear radiation Alpha radiation-lowest in energy, can be stopped by paper or a few cm of air 238 92U 4 → 2He 234 + 90Th Beta radiation-higher in energy, can be stopped by metal or thick clothes 14 6C 0 -1e 14 + 7N 238 92U 4 → 2He → Gamma radiation-accompanies either alpha or beta, highest in energy, can be stopped by thick steel or concrete 234 + 90Th 0 + 0 Radioactivity Nuclear fusion is when two or more nuclei join together to make one larger nucleus high temperature is required, this is where we get energy from the sun Nuclear fission is when nuclei split apart occurs with elements with atomic number higher than 90 causes a nuclear chain reaction and gives off high energy This is what happens in nuclear power plants Radioactivity Half-Life A half-life is the amount of time that it takes a radioactive substance to lose half of its mass due to decay Ex: a 10g sample of a radioactive substance with a half-life of 5 days In 5 days you have 5g In 10 days you have 2.5g In 15 days you have 1.25g And so on and so on Mass vs. Time 12 10 8 Mass (g) 6 4 2 0 0 5 10 15 Time (days) 20 25 Radioactivity Radiation Exposure Benefits of radiation We are exposed to radiation everyday; from the sun, from natural radioactive isotopes, and others This kind is called background radiation Tracers and therapy in medicine Irradiation of food to make it last longer In smoke detectors Carbon-14 dating of fossils Clean power source Dangers Radiation can be dangerous if you are exposed to very high levels Radiation sickness can vary depending on the time, amount, and type of radiation There will be a warning sign on any high radiation area Energy Transformations Energy Transformations Energy is the capacity to do work Energy can be transferred but is not lost; this is the Law of Conservation of Energy The form may change, but is not created or destroyed There are many different types of energy Kinetic-energy of motion Mechanical-energy due to matter in motion Electromagnetic-energy due to moving electrons Thermal (heat) energy-energy due to the internal motion of atoms Sound energy-energy due to matter vibrating and traveling in a wave Light energy-energy of certain wavelengths of the electromagnetic spectrum Energy Transformations Potential Energy-stored energy Chemical energy-the energy stored in chemical bonds, is released when bonds are formed or broken Gravitational energy-energy due to having the ability to fall, once the object falls it will have kinetic energy At the top of a roller coaster you have potential energy, as you come down the hills, you have kinetic energy Energy can be changed Turbines turns heat energy from burning fuel into mechanical energy Generators turn mechanical energy into electricity Energy Transformations Heat is a measure of the energy of particles (or the movement of particles) Temperature is a measure of the average kinetic energy They are not exactly the same thing Energy transfer, or heat flow, goes from higher energy to lower, or hotter to colder What you are studying is called the system, everything around it is called the surroundings Energy Transformations Conduction-when heat is transferred by contact and the collision of particles Convection-when heat is spread out by differences in density and currents warm air mixing in the environment due to currents Radiation-when heat is transferred through empty space by means of electromagnetic waves a pot on a stove a heating pad The sun warming up the surface of the earth The microwave cooking your lunch Insulators like styrofoam and ceramic prevent the flow of heat Energy Transformations A heating curve shows the change in temperature vs time as heat is added As you go across the x-axis, heat is added Heat can be calculated using the change in temperature, the mass, and the specific heat Specific heat is the amount of heat energy needed to raise 1g of a substance by 1 degree Celcius or Kelvin A calorimeter is a devise used to measure heat Energy Transformations Phase diagrams show how a substance can change from solid, liquid, or gas due to pressure or temperature The triple point is the specific T and P where all three phases exist simultaneously The critical point is the point where a substance can no longer exist as a liquid Waves Waves Waves provide a means of transferring energy from one place to another without transferring matter The wave moves through a medium Longitudinal waves have matter which vibrate in the same direction as the disturbance-think of a slinky Rarefaction-parts where the coils are spread out Compression-parts where the coils are close together Wavelength-distance between one compression to the next Amplitude-half the distance between two compressions Frequency-the number of waves per second, the unit is Hz Waves Transverse Waves-matter moves perpendicularly to the direction of the disturbance Crest-the highest point of the wave Trough-the lowest point of the wave Wavelength-the distance from one point on a wave, to the same point on the next wave Amplitude-the height of the wave from the midpoint to the crest Frequency-the number of waves per second Waves The speed of a wave is the wavelength times the frequency The speed of ALL light waves is the same, the speed of light=3x108m/s Waves Light waves are special in that they do not need a medium to travel through; they can move through empty space They are called electromagnetic waves because they have alternating electric and magnetic fields Light behaves like waves and particles; the particle is called a photon the photon is a bundle of light energy; it has wavelike behavior Waves Light waves are special in that they do not need a medium to travel through; they can move through empty space Reflection-the bouncing back of a wave from a surface such as a mirror Refraction-the bending of light when it hits a new medium The angle that it bounces back will be equal to the angle that it hit the surface Such as light bending when it goes from air to water Diffraction-the scattering of light as it hits the edges of a boundary or tiny opening Interference is when two or more waves are moving through a medium at the same time They can amplify each other (constructive interference) They can distort or muffle each other (destructive interference) Waves Objects that emit their own light are luminous Objects that only reflect light are illuminated Lenses bend light: Convex lenses bend light to make the light rays converge to a single point Concave lenses bend light to make the rays diverge and go in opposite directions Waves Sound waves are longitudinal, or compressional, waves Matter is necessary for sound waves to carry They can’t travel in the vacuum of space Amplitude gives the sound its intensity, or loudness measured in decibels (dB) Frequency gives it its pitch, or highness or lowness, measured in hertz (Hz) Sound that is irregular or unpleasant is called noise Sound that has a pleasing quality with regular patterns is called music Force, Mass, and Motion Force, Mass, and Motion Speed-also called velocity=distance/time Velocity describes speed and direction Ex: if you are driving to California at 50mi/h, then the velocity is 50mi/h west Force, Mass, and Motion Acceleration is the change in velocity over time Ex: if you are at a red light, your velocity is 0mph; the acceleration has to do with changing your velocity and the amount of time it takes to change it Acceleration can be negative if you slow down, or drive in the opposite direction Force, Mass, and Motion An object has mass, but weight is a measure of the gravitational force on the object Free fall is what happens when something is under the influence of gravity Gravity has an acceleration of 9.8m/s2 Everything falls at the same rate, unless there is something that causes air resistance such as a parachute Other things may affect velocity, such as friction when moving something across carpet, or wind acting with or against an airplane Force, Mass, and Motion Newton’s First Law Law of Inertia-an object at rest will remain at rest and an object in motion will remain in motion, unless acted upon by an outside force Inertia is an object’s resistance to move When you slam on the brakes, your body keeps moving; until the seatbelt stops you Newton’s Second Law Law of Acceleration-when an unbalanced force causes an object to accelerate, the acceleration is directly proportional to the force and inversely proportional to the mass F=m*a Force, Mass, and Motion Newton’s Third Law Law of Conservation of Momentum-For every action (force), there is an equal and opposite reaction Momentum (P) is mass times velocity P=m*v Ex: if a 20kg cart travels at 5m/s and runs into a 10kg cart going in the opposite direction at 10m/s what will happen They will stop where they meet, the momentum of each will cancel the other out Force, Mass, and Motion Work-when a net force causes an object to change its state of motion or rest, causing it to speed up, slow down, or change direction Work = force times distance The unit is Joules (J) 1J = 1N*m Holding a 100lb box is not work, but moving it is A machine makes work easier by Decreasing the required input force Increasing the distance the resistance force moves Changing the direction of the input force Force, Mass, and Motion The advantage of using a machine is called mechanical advantage; when MA is large, less effort is needed You need to know the resistance force and the effort force Actual mechanical advantage = resistance force/effort force Effort force is the force you put in The resistance force is what you’re working against (sometimes the weight of the object you’re moving) AMA = Fr/Fe Ideal mechanical advantage=effort length/resistance length IMA = effort length/resistance length Force, Mass, and Motion If you work against friction your work input includes friction work input = work output + work against friction Efficiency = (work output/work input) *100% There are six types of simple machines Inclined plane-ramp The length of the ramp is the effort length, the height is the resistance length Wedge-ax, nail, chisel The longer and thinner, the better the MA Force, Mass, and Motion Screw-inclined plane wrapped around a cylinder Lever-bar that pivots around a fulcrum The effort length and resistance length are always measured from the fulcrum Wheel and axle-larger circle is the wheel, smaller circle is the axle The closer the threads are together, the higher the MA IMA = radius of wheel/radius of axle Pulley-a rope or chain moves the wheel The more ropes supporting the resistance, the greater the MA Electricity and Magnetism Electricity and Magnetism Electricity is caused by action of charged particles Static electricity comes from the buildup of electric charges on the surface of objects Static means not moving, so this is electricity that does not flow Can come from friction, conduction, or induction When the static charge is suddenly lost, it is called discharge; lightning is an example Grounding protects you from being electrocuted by sending stray charges to the earth or ground Electricity and Magnetism Current electricity is electricity that flows It flows through a circuit, or closed pathway Electromagnetic generators produce current as a coil of wire moves through a magnetic field, this is called alternating current (AC) Electrochemical cells, or batteries, produce current from chemical reactions called direct current (DC) Thermocouples produce current from heat energy Photocells or solar cells produce electricity when light hits photosensitive materials where electrons can be given off Piezoelectric currents are produced due to pressure Electricity and Magnetism Conductors conduct electricity-they have space in the valence shells for electrons to flow freely Insulators do not conduct-their valence shells are too full A fuse is a piece of metal that will melt if the flow of electricity gets too hot, once the fuse melts, the circuit is open and electricity will not flow Circuit breakers work the same way if the electricity exceeds safe levels Circuits can either be in series (one after the other) or parallel (alternate branches) If a series circuit gets interrupted, the flow will stop If a parallel circuit gets interrupted, the flow will follow one of the other paths Electricity and Magnetism Series Circuits-One path: if one bulb goes out, all others will also Electricity and Magnetism Parallel Circuits-More than one path: if one bulb goes out, all others can stay on Electricity and Magnetism Coulomb-unit of charge Ampere-unit of current, coulombs/second, C/s Voltage is the energy V=J/C Resistance is measured in Ohms Watts measure electrical power Ohm’s Law: resistance = voltage/current R=V/I P = voltage * current = VI unit is watts Energy is the kilowatt-hour Energy = power * time = Pt Electricity and Magnetism Magnetism is a force produced by the motion of charged particles The flow of electrons can form an electromagnet If you wrap a copper wire into coils, then as electricity flows from each end, the wire will become a magnet The more coils you have, the stronger the magnetic A magnetic field can produce an electric current An electric motor has a rotating electromagnet that creates electricity This is called electromagnetic induction