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Safety Data Sheet Perfect Alkali Page 1 of 4 Emergency Phone: Other Information: Date Prepared: Latest Revision: 800-424-9300 973-589-2800 5-10-1993 5-19-2015 Section 1 - Product and Company identification Trade name: Perfect Alkali – Powdered Laundry Additive Manufacturer: Metro-Chem, Inc. 24 Pennsylvania Avenue Kearny, NJ 07032 Section 2 – Hazard(s) Identification Classification: Skin Corrosion/Irritation: Specific Target Organ Toxicity Single Exposure Category 1A Category 3 Risk Phrases: R35 Label: Signal Word: Danger GHS Hazard Phrases: H314: Causes severe skin burns and eye damage GHS Precaution Phrases: P103: Read label before use P260: Do not breathe (dust/fume/gas/mist/vapors/spray) P264: Wash hands thoroughly after handling P280: Wear protective gloves/protective clothing/eye protection/face protection Section 3 – Composition/information on ingredients Sodium Hydroxide CAS No: 1310-73-2 OSHA PEL: 2mg/m3 ACGIH TLV: 2mg/m3 Percentage 40%-55% Disodium Trioxosilicate, Anhydrous CAS 6834-92-0 OSHA PEL: n/a ACGIH TLV: n/a Percentage 5%-20% Sodium Carbonate CAS 497-19-8 OSHA TWA: 15 mg/m3 ACGIH TLV: 15 mg/m3 Percentage 30%-45% Section 4 – First Aid Measures GHS Response Phrases: P303, 361, 338: If on SKIN, remove/take off immediately all contaminated clothing; rinse skin with water or use shower. For severe skin burns, get medical attention. P363: Wash contaminated clothing before reuse P305, 351, 338: If in EYES, rinse cautiously with water for several minutes; remove contact lenses, if present and easy to do; continue rinsing P301, 330, 331: If SWALLOWED, rinse mouth; do not induce vomiting P304, 340: If INHALED, remove victim to fresh air and keep at rest in a position comfortable for breathing P310: Immediately call a POISON center/doctor Safety Data Sheet Perfect Alkali Page 2 of 4 Section 5 – Fire Fighting Measures Extinguishing Media: Water spray, carbon dioxide, or other suffocating agents. Unusual Fire & Explosion Hazards: Exercise caution using water as vigorous, possibly violent, exothermic reactions with caustic soda can occur. Hydrogen evolution may also occur if in contact with metals such as zinc and aluminum. Section 6 – Accidental Release Measures Personal precautions, protective equipment and emergency procedures: Avoid breathing dust; for large spills, wear safety googles, rubber gloves and a NIOSH approved respirator. If dry, scoop up powder spills as much as possible into plastic (not metal) container. If wet, lower highly alkaline PH by sprinkling on sodium bicarbonate; then, take up with adsorbent. Waste Disposal Methods: Wear Protective equipment; keep unprotected persons away. If non-reusable, place in a closed container, label and remove for disposal by an approved waste transporter in accordance with Federal State and Local regulations. Section 7 – Handling and Storage Measures Precautions for safe handling: Insure good ventilation/exhaust at the workplace. Avoid moist atmospheres, overheated areas. Avoid mixing or storing close to acids, solvents and bleaches. Precautions for safe storage: Only store in cool, dry locations. Keep containers tightly sealed. Section 8 – Exposure Controls/Personal Protection Control parameters Components with limit values that require monitoring at the workplace: 1310-73-2 Sodium Hydroxide PEL 2mg/m3 REL Short-term value: C 2mg/m3 TLV Short-term value: C 2mg/m3 6834-92-0 Sodium Metasilicate ACGIH TLV : 2mg/m3 OSHA PEL : 2mg/m3 Exposure Controls Personal Protective Equipment: Eye Protection: Tightly sealed safety goggles Protective Gloves: Compatible chemical-resistant gloves Protective Clothing: Long sleeves, lab coats or chemical resistant aprons Respiratory Equipment: NIOSH approved respirator, as conditions warrant General Protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work Avoid contact with eyes and skin Safety Data Sheet Perfect Alkali Page 3 of 4 Section 9 – Physical and Chemical Properties Physical States: Appearance and Odor: Melting Point: Boiling Point: Flash Point: Evaporation Rate Explosive Limits: Vapor Pressure Vapor Density (Air = 1) Specific Gravity (H2O = 1) Solubility in H2O Autoignition Pt: Percent Volatile Solid Off white to yellowish powder No data No data No data No data LEL: No data UEL: No data No data No data 0.52 Fully miscible No data No data Section 10 – Stability and Reactivity Reactivity: Stability: Polymerization Conditions to Avoid: Incompatibility: Materials to Avoid: Hazardous Decomposition Or Byproducts: High temperatures may occur when mixed with water Stable if stored in accordance with Section 7 Will not occur Moisture Acids Aluminum, chlorinated solvents, organic materials, phosphorus, tin/tin oxides, zinc, sodium oxides Hydrogen Section 11 – Toxicological Information Acute Toxicity: 1310-73-2 Sodium Hydroxide 6834-92-0 Disodium Trioxosilicate Anhydrous 8042-47-5 Mineral Oil 497-19-8 Sodium Carbonate Oral LD50: 2000 mg/kg (rat) Oral LD50: 600 mg/kg (rat) Oral LD50 : > 5000 mg/kg ( Rat) Oral LD50: 4090 mg/kg (rat) Primary Irritant effect: On the skin: Strong caustic effect on skin and mucous membranes On the eye; Strong caustic effect Sensitization: No sensitizing effects known Additional Toxicological information: Corrrosive Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach Carinogenic categories IARC – None of the ingredients is listed NTP – None of the ingredients is listed Section 12 – Ecological Information Aquatic Toxicity: Avoid release into the environment. Runoff from fire control or dilution water may cause pollution. Safety Data Sheet Perfect Alkali Page 4 of 4 Section 13 – Disposal Considerations Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Place in a closed, approved container, label and remove for disposal by an approved waste transporter in accordance with Federal State and Local regulations. Section 14 – Transport Information UN Number Proper Shipping Name DOT Proper Shipping Name ADR DOT Hazard Class Packing Group Marine pollutant UN3262 Corrosive solid, basic inorganic, n.o.s. (Sodium Hydroxide) (Disodium Trioxosilicate, Anhydrous) Sodium Hydroxide 1824 Sodium Hydroxide 8 Corrosive Substances II No Section 15 – Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture EPA SARA Lists: Section 302 (extremely hazardous substances): Section 304(RQ): SARA 311/312 Hazardous Categorization Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Section 313 (specific toxic chemical listings): TSCA (Toxic Substances Control Act): Carcinogens: Teratorgens Chemicals causing developmental toxicity: No Sodium Hydroxide 1,000 Lbs. Yes No No No No No Sodium Hydroxide,Sodium Metasilicate, Sodium Carbonate No No No Section 16 – Other Information Disclaimer: This information is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information; and, we assume no liability resulting fro its use. Users should make their own investigations to determine the suitability of the information for their particular purposes.