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Transcript
Spectroscopy, a toolbox for structural information on aerosol particles
Ruth Signorell
Laboratory of Physical Chemistry, ETH Zurich, Vladimir-Prelog-Weg 2,
CH-8093 Zurich, Switzerland
[email protected]
It is well known that light interacts differently with small particles compared with bulk materials
or gas phase molecules, producing spectral signatures that strongly depend on particle properties,
such as size, shape, or architecture. Even nanosized aerosol particles held together by weak
intermolecular interactions can exhibit such characteristic spectral signatures. This talk discusses
absorption and scattering features in aerosol particle spectra from the infrared to the extreme
ultraviolet spectral region, and explains their molecular origin and their use for aerosol
characterization in planetary atmospheres. Various laboratory methods are discussed ranging from
particle ensemble techniques to single-particle studies in optical traps. The role of small clusters
as critical nuclei in the aerosol formation from the gas phase is briefly addressed.