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Chemistry 20 Name: _____________ Unit II: Atoms and Elements 5.2 Quantum Theory and the Atom Pgs. 127-134 I. The learning objectives for this section are: 1. Define and give an example of: ground state, quantum mechanical model of the atom, atomic orbital, principal energy level, energy sublevel. 2. Summarize the contributions made by Bohr, de Broglie, Heisenberg, and Schrodinger. 3. Compare the Bohr and quantum mechanical models of the atom. 4. Explain the impact of de Broglie’s wave-particle duality and the Heisenberg uncertainty principle on the modern view of electrons in atoms. 5. Identify the relationships among a hydrogen atom’s energy levels, sublevels, and atomic orbitals. II. The following questions will help to cover these objectives as you read through the section. Briefly answer each question. 1. What is meant by quantized energy? 2. What did Bohr propose? 3. Differentiate between ground state and excited state. 4. Describe the Bohr model of the atom. 5. a) What did Bohr suggest happened when an electron fell from a higher energy level to a lower energy level within an atom? b) Look up and write down the meaning of “photon”. 6. Describe a real-life analogy which helps to describe the energy states that an electron can have in an atom. 7. What two shortcomings caused scientists to finally reject Bohr’s model of the atom? 8. a) Breifly describe the de Broglie’s revolutionary concept involving the characteristics of moving particles. b) What did the de Broglie equation illustrate? c) Explain why we cannot see the wavelengths emitted by everyday objects such as people, baseballs, etc. 9. What problem occurs when one tries to determine the exact position of an electron in an atom? 10. What is the Heisenberg uncertainty principle? 11. a) What did Schrodinger do? b) Why was Schrodinger’s model of the atom better than Bohr’s model of the atom? c) What is Schrodinger’s model of the atom called? 12. a) What does the Schrodinger equation help to predict? b) What is the probability that an electron will be found within an atomic orbital? 13. Explain the concept of an atomic orbital. 14. a) What is the purpose of principal quantum numbers? b) What is another thing do principal quantum numbers specify? 15. Describe the relationship between energy sublevels and principal energy levels. 16. a) What letters are used for sublevels? b) State and sketch the shape of an “s” orbital. c) State and sketch the shape of a “p” orbital. d) How many electrons can occupy a single orbital? 17. Complete the following chart. Principal quantum number (n) 1 2 3 4 Sublevels (types of orbitals present) Number of orbitals related to sublevel Total number of orbitals related to principal energy level (n2) Total number of electrons related to principal energy level (2n2)