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MODULE FOR INTERNATIONAL STANDARD CLASS TAMBUN SELATAN HIGH SCHOOL Subject Date – Time Teacher Module Code Sub Theme I. : : : : : Chemistry ……. x 45’ CH / BC 1.1 / 1 Atomic Structure Standard Competence To describe atomic structure, some periodic properties chemistry bond of molecule structure and its characteristic. II. Basic Competence 1.1 III. Indicator 1. 2. 3. 4. 5. 6. 7. 8. 9. IV. To define atomic, atomic structure, characteristic of elements atomic relatif mass and periodic character from periodic table To compare growth of periodic system To determine group and period in periodic table To determine atomic structure in periodic table To determine valance electron elements from electron configurations and periodic table To determine the number of protons, neutrons, and electrons To determine isotope, isoton, isobar To determine characteristic of elements periodicity and atomic relatif mass (Ar) from periodic table To analyze table or graph of some periodic properties (atomic radius, ionization energy, electron affinity, and electronegative) To comparer the growth of atomic theory, to begin Dalton atomic Theory until Niels Bohr Teaching Materials A. The growth of periodic system Elements consist of metal elements and non metal elements in ancient Greek Triade Doberenier Law by Johann Wolf Gang Dobereiner Three elements base on increasing atomic mass so atomic mass in center is same or nearly of Average mass element sum for left element and right element Example : Li 6,941 Na Mass Na K 39,10 = 6,941 + 39,10 = 23,02 2 Octav Law by JohnNew land The elements base on increasing atomic mass so elements characteristic appeared after eight element Example : 1 2 3 4 5 6 7 H Li Be B C N O 8 9 10 11 12 13 14 F Na Mg Al Si P S Mendeleev Periodic System The periodic Law State’s that when elements are arranged in order of increasing atomic numbers, elements with similar properties occur at periodic (regularly recurring) intervals. System of Modern Periodic The periodic table consist of 7 periods and 8 groups. A period in the periodic table is a horizontal row of elements. Period Period Period Period Period Period Period 1 2 3 4 5 6 7 = = = = = = = 2 elements 8 elements 8 elements 18 elements 18 elements 32 elements no complete A group in the periodic table is a vertical column of elements. There are two notations is use for designating individual periodic table groups. In the first notation, which has been in use for many years, groups are designated using roman numerals and the letters A and B. Main Group Another Name Elements IA Alkali metals H, Li, Na, K, R, Cs, Fr II A Alkalin Earth Metals Be, Mg, Ca, Sr, Ba, Ra Hologen F, Cl, Br, I, At Noble gases He, Ne, Ar, Kr, Xe, Rn A VIII A B. Interaction of electron configurations and periodic system The place of elements in periodic system can be determined by electron configurations, sum of shells are period and valency electron is group. Example : 11 Na = Sum of shells = 2, 3, 8, 1 period = 3th Cl of shells = sum of shells = 2, 3, 8, 7 period = 3th 17 Exercise : Determine period and group from : a. 12 Mg b. 14 Si c. 16 S d. 13 Ar C. Subatomic particles = elctron, prototn, and neutrons X = Atomic Symbol Z = Atomic Number A = Mass Number A Z Atomic number Mass number Neutron amount = = = = Number of protons = number of electrons Number of protons + number of neutrons Mass number – atomic number A–Z D. Isotope, Isobar, and Isoton Isotop are atoms that have the same number of protons and electrons but have different numbers of neutrons. Example : 16 17 1 2 and , and 8 8 1 1 Isobars are atoms that have the same number of mass but have different atomic number. Example : 14 14 and 6 7 Isotons are atoms that have the same number of neutrons. Example : 16 15 O O C N O N H H 8 7 E. Atomic relative ( Ar ) and molecule relative ( Mr ) Ar X = Mass 1 X atomic 1/12 mass 12C Mr = The sum of the atomic relative of atom X in a formula unit of coumpound Exercise : Calculate the relative molecule of the following coumpounds, using a table of atomic relative. a) H2O b) C6H12O6 Calculation is : a) 2 x Ar of H = 2 x 1 = 2 amu 1 x Ar of O = 1 x 16 = 1 amu Mr of H2O b) 6 12 6 Mr x Ar of C = 6 x 12 = 72 amu x Ar of H = 12 x 1 = 12 amu x Ar of O = 6 x 16 = 96 amu of C6H12O6 180 amu Exercise : Calculate the relative molecule of the following coumpounds a. H2SO4 b. CaCO3 c. CO (NH2)2 F. Growth of Atomic Theory a. Dalton Theory - All matter is made up of small particles called atoms - All atoms of a given type are similar to each other and significantly different from all other types - The relative number and arrangement of the different types of atoms found within o pure substance determines its identity - Chemical change is a union, separation, or rearrangement of atoms to give new substances - Only whole atoms can participate in or result from any chemical change because atoms are considered to be indestructible during these changes b. Thomson Theory The atom is like ball that has positive charge and separate negative charge c. Ernest Rutherford Theory The atoms consist of a nucleus with most of the mass and a positive charge, arround which move enough electrons to make the atom elctrically neutral d. Niels Bohr Theory Electrons is an atom have energy lvels, and when an elctron in a higher energy level drops (or undergous a transition) to a lower energy level, a photon is emitted Thomson Rutherford Bohr G. Some Periodic Properties 1. Atomic Radius - Within each period (horizontal row), the atomic radius tends to decrease with increasing atomic number (nuclear charge). This the larges atom in a period is a group IA and the smallest is a noble gas atom. - within each group (vertical column), the atomic radius tends to increase with the period number 2. Ionization energy The first ionization energy or first ionization potential of an atom is the minimum energy needed to remove the highest energy (that is, the autormost) electron from the neutral atom is the gaseous state 3. Electron affinity Electron affinity is the energy change for the process of adding an elctron to an neutral in the gaseous state to form a negative ion 4. Electronegative Electronegative is an atom tendency for receiving electrons Exercise : 1. Determine the number of protons, neutrons, and electrons present in each of the following atoms. a. 235 b. 28 c. 27 d. 137 d. 31 Tn Si Al Ba P 90 14 13 56 15 2. How about are tendency of atomic radius, ionization energy, and electronegative in periodic system. 3. Calculate the relative molecule for each of the following compounds a. C2 H5 OH b. Mg SO4 c. Na3 po4 d. HNO3 4. How are Dalton atomic theory, Rutherford theory, and Niels Bohr Theory. MODULE FOR INTERNATIONAL STANDARD CLASS TAMBUN SELATAN HIGH SCHOOL Subject Date – Time Teacher Module Code Sub Theme I. : : : : : Chemistry ……. x 45’ CH / BC 1.2 / 1 Chemical Bonding Standard Competence The describe atomic structure, some periodic properties, chemistry bond of molecule structure and its characteristic. II. Basic Competence 1.2 To describe the term chemical bond of using periodic table III. Indicator 1. 2. 3. 4. 5. 6. 7. 8. To explain an element tendency for getting stable of another element bond To describe valence electrons configurations of the nable gases To explain the ionic bond model and give example it To explain the terms single covalent bond, double covalent bond and triple covalent bond To research polar o some compounds and electronegative relationship in experience To explain the coordinate covalent bond on simple example To explain the metal bond and interaction of metal physic characteristic To predict various of bonds on compounds and compare physic characteristic IV. Teaching Materials 1. The electron configurations of the noble gases. 2 He = 2 10 Ne = 2 8 18 Ar = 2 8 8 36 Kr = 2 8 18 8 54 Rn = 2 8 18 18 8 2. The Octet Law The tendency of atoms in molecules have eight electrons in their valence shells. (Ne , Ar , Kr , Xe , Rn) 3. The Duplet Law All of the noble gases except helium possess eight valence elctrons which is the maximum number possible. Helium’s valence electron configuration is 152. 4. Covalent Bond In 1916 Gilbert Newton Lewis proposed that the strong attractive force between two atoms in a molecule result from a covalent bond, a chemical bond formed by the sharing of a pair of electrons between atom. Covalent bonds are formed between similar or even identical atoms. Most often, two non metal atoms are involved. a. A single – Covalent Bond A single – Covalent Bonds is a bond where a single pair of electrons is shared between two atoms. Example : H2 = 1 (needs 1e) = 1 1e 1H 1H Lewis Formula : H .x Line Diagram H H - H b. A Double – Covalent Bond A double – Covalent bond is a bond where two atoms two pairs of electrons Example : O2 8O = 2 6 (needs 2e) = 2 6 2e 8O Lewis Formula : xx Line Diagram . . x x x. x. O . . = O c. A triple – Covalent Bond A triple – Covalent bond is a bond where two atoms share three pairs of electrons. Example : N2 = 2 5 (needs 3e) 7N = 2 5 3e 7N Lewis Formula x x x N xx . . . Line Diagram N Ξ N N .. 5. Coordinate Covalent Bond Coordinate covalent bond is a bond in which both electrons of shared pair come from one of the two atoms involved in the bond NH4+ NH3 NH3 + H+ 7N = = = = 2 1 1 1 H 1 H- N -H H 1H 1H 1H . x H . xN x. H + H + xx Electron donor 3e 1e 1e 1e 5 + 6. A Polar covalent bond and a non polar covalent bond - A Polar covalent bond is one in which there is uniquel of bonding electrons Example : H Cl 1H 17 Cl = = 1 2 8 Or H Cl 7 xx H . x Cl xx xx δ+ δCl atom is more electronegative than the H atom, the bonding electrons in H – Cl are pulled toward Cl. A non polar – covalent bond is one in which there is equal sharing of electrons. Example : H2 , Cl2 , F2 , O2 , etc CO2 , CH4 , CCl4 - 7. A Metal bond The metal consists of metal atoms where has positive can in electrons ocean Posistive Ion Electron Ocean Energy of metal nucleus attraction is connected by electrons ocean will orm of metal bond. V. Competence Test A. Multiple Choice 1. The stable element is … a. 3P b. 8Q 2. c. 10R d. 16S 33T will be stable with tendency of … a. Give one electron d. Form electron pair b. Give two electrons e. bond three electrons c. Receive one electron 20Ca 3. The element atom will form ion bond on 17 X is … a. 6C b. 2O c. 11Na d. 14Si 4. e. 12A a. b. c. d. e. e. 16S and 9B will form compound is … Ion bond on chemistry formula AB2 Ion bond on chemistry formula AB Ion bond on chemistry formula A2B Covalent bond on chemistry formula AB2 Covalent bond on chemistry formula A2B 5. The compound has covalent bond, except … ( 1H, 8O , 6C , 12Mg , 17Cl ) a. H2O b. CH4 c. Cl2 d. MgO e. HCl 6. The following compound is polar covalent compound is ….(35Br) a. CH4 b. O2 c. Cl2 d. H2 e. HBr 7. The elctron valency has oxygen atom is H2O molecul is …. a. 3 b. 2 c. 4 d. 5 e. 6 8. This is …. 1 H H x X N xH XX H 2 The coordinate covalent bond is … a. 1 and 2 b. 1 and 3 c. 4 d. 2 e. 2 and 4 3 4 9. The sum free electron on N atom in NH3 molecule (picture no. 8) is … a. 1 pair c. 3 pairs e. only one b. 2 pairs d. 4 pairs 10. There are electronegative elements on H, F, Cl, Br and I : 2,1 ; 4,0 ; 3,5 ; 2,8 ; and 2,5. The very polar molecule is … a. HF b. HCl c. Hbr d. HI e. IF 11. The compound on NH4Cl is …. a. ion bond d. Covalent and coordinate bond b. covalent bond e. Ion, covalent and coordinate bond c. coordinate bond 12. The following metal characteristic connects to metal bond is … a. Conductor b. The element mass is very huge and hard c. The metal can put off valency electron d. It is easy to form ionic bond on non metal e. The metal has critic boild and high melting point B. Answer the following questions correctly ! 1. Explain to process compound : (12Mg, 8O, 6C, 1H) a. MgO b. C2H4 2. Explain to form H3O+ Keys 1.2: A. 1. 2. 3. 4. C B C 4 5. 6. 7. 8. D E C C 9. A 10. A 11. E 12. A Forming Bond in Compound 1. a. MgO 12Mg = = 8O Mg2+ 2- xx b. C2 H4 xx 6C H = = = = = = H x x C xx 2 2 1 1 1 1 1 1 C C C 1 x 4 4 H x 8 6 MgO x x 6C 1H 1H 1H 1H 2 2 1 H H 2. The forming = H2O + H + 1H = 1 1H = 1 6 8O = 2 H3O + + XX H X X XX H XX H- - H 2 2e 2e MODULE FOR INTERNATIONAL STANDARD CLASS TAMBUN SELATAN HIGH SCHOOL Subject Date – Time Teacher Module Code Sub Theme I. : : : : : Chemistry ……. x 45’ CH / BC 2.1 / 1 Element Symbol Chemical Bonding Balance the Equation Standard Competence To describe basic chemistry law and applied for starchiomtry II. Basic Competence To write unorganic and simple organic on balance the equation III. Indicator 1. To write binari molecule compounds and polyatomic from unorganic and organic compound 2. To interpret balance the equation and give substance name reaction IV. Teaching Materials The using chemistry symbols in IUPAC ( International Union Pure and Applied Chemistry. The chemical equation is the symbolic representation of a chemical reaction in term of chemical formulas. The chemical formula of a substance is a notation that uses atomic symbols with numerical subscript to convey the relative proportions of atom of the different elements in the substance. The chemical formula consist from molecule formula and empirical formula The molecular formula is a chemical formula that gives the exact number of different atoms of an element in a molecule. Example : Compotition on water is 2 Hydrogen atoms and 1 oxygen atom The empirical formula is a simple comparation sum on particel composition substance and applied by element symbol. Example : Glucose, Molecule formula = C6 H12 O6 Empirical formula = ( CH2O )6 The name rules on compounds : 1. A Binary Covalent Compounds a. When the two elements form only one compound, we name the compound by giving the name of the first element, followed by the stem name of the second element with the suffix – ide . Example : HCl H2S = Hydrogen Chloride = Hydrogen Sulfide b. When the two elements form more then one compound, we can distinguish between these compounds by using prefix. One = mono Four = tetra Seven = hepta Two = di Five = penta eight = octa Three = tri Six = hexa Example : NO = nitrogen monooxida NO2 = nitrogen dioxida N2O3 = dinitrogen trioxida 2. A Binary ion compound a. A metal with a monatomic ion + non metal + suffix ,-ide Example : NaCl = natrium chloride MgF2 = magnesium fluoride b. A monatomic cation is given the name of the elementif there is more than one cation of that element, thecharge is denoted in the stock system of nomenclature by a roman numeral in paren theses following the element name. Example : FeCl2 = ferrum (II) cloride FeCl3 = ferrum (III) cloride 3. The acid name rules The acid are substance that yield hydrogen ions, H + in aqueous solution a. non oxoacid (with suffix –ide) Example : HCl = Cloride acid HI = Iodide acid b. Oxoacid (with suffix –ate) Example : H2 SO4 = Sulfuric acid H2 SO3 = Sulfurous acid HCl O4 = Perchloric acid HClO = Hypochlorous acid 4. The base name rules The base are substances that yield OH ions in equeous solution. The base consist from metal and base valency. Example : NaOH Na+ + OH – Base metal ion base valency 5. The Salts The salts are ionic ompounds that contain only negative ion except hydroxide ion and any positive ion except hydrogen ion. The salts are joined together metal ion (base) and acid residue ion (acid) Cation Ca2+ K+ Anion Cl CaCl2 KCl 2SO4 Ca SO4 K2 SO4 Example : Ca Cl2 = Calcium chloride KCl = Kalium Chloride Ca SO4 = Calsium Sulfate K2 SO4 = Kalium Sulfate V. Competence Test A. Multiple Choice 1. The name of Cu S is …. a. Cuprum ( I ) sulfide b. Cuprum sulfide c. Cuprum ( II ) sulfide d. Cuprum e. Cupro sulfide 2. The formula of diclorin oxide is …. a. Cl O b. Cl2 O c. CO d. CO2 e. Cl2 O5 3. The formula of Aluminium Sulfide is ... a. Al2 S3 d. Al S b. Al3 S2 e. Al2 S c. Al S3 4. The following is base formula is …. a. CH3 COOH b. H2 SO4 c. HNO3 d. Mg ( OH )2 e. KNO3 5. The followis is arsenat acid is … a. H2 SO4 b. H3 PO4 c. H2 A5 O3 d. HCl O3 e. H2 S 6. The formula on ferrum ( III ) sulfate is …. a. Fe SO4 d. Fe2 S3 b. Fe2 (SO4)3 e. Fe S c. Fe3 (SO4)2 B. Essay 1. Write the name from : a. SO3 b. P2 O5 2. Write the formula from : a. Magnesium Chloride b. Sulfur heksa fluoride 3. Determine the forming compounds and give their names. Cation Anion OH CO3 2PO43 Al 3+ Mg 2+ NH4+ Keys 2.1 : A. Multiple Choice 1. D 2. B 3. A 4. D 5. C 6. B B. Essay 1. a. SO3 b. P2 O5 = Sulfite = dinitrogen penta oxide 2. a. Magnesium Chloride b. Sulfur heksa fluoride = Mg Cl2 = SF6 3. Cation Anion OH CO3 2PO43 Al 3+ Mg 2+ NH4+ Al (OH)3 Al2 (CO3)3 Al PO4 Mg (OH)2 Mg CO3 Mg3 PO4 NH4 OH (NH4)2 CO3 (NH4)3 PO4 Balancing Chemical Equations Chemical equation : mA + nB A and B : reactan C and D : product m, n, p, q : coefficients Pc + q D Example : KCl O3 ( s ) Kalium chlorate Atom K Cl O 2 KCl O3 ( s ) + 3 O2 ( g ) Kalium chloride Left Right 2 2 2 2 6 6 2 Labels in chemical equation : S = Solid l = Liquid g = Gas aq = Aquaeous (water solution) the method in balancing chemical equations : 1. a trial and error 2. algebra 3. redoks Competence Test 1. Balance the equations and mentions it compounds ! a. Na OH (aq) + H3 PO4 (aq) Na PO4 (aq) + H2O (l ) b. Al (s) + H2 SO4 (aq) Al2 (SO4) aq + H2 (g) c. C2H2 (g) + O2 (g) CO2 (g) + H2O ( l ) 2. Balance the following equation is a. b. c. d. e. Fe2 O3 (s) + 2 Al (s) Al2 O3 (s) + Fe (s) Al (s) + 3H2 SO4 (aq) Al2 (SO4)3 (aq) C2 H5 OH ( l ) + 3 O2 (s) 2 CO2 (g) + 3H2O (l ) Mg (OH)2 (s) + 2 HCl (aq) mg Cl2 (aq) + H2O (l ) 3Cu (s) + 6 HNO3 (aq) 3 Cu (NO3)2 (aq) + NO (g) 3. The correct coefficients for equation : a Fe2 S3 + b H2O c O2 d Fe (OH)9 + e S The coefficients a, b, c, d, and e are : a. 2, 3, 2, 2, 3 b. 2, 6, 4, 2, 3 c. 2, 6, 3, 4, 6 d. 4, 6, 3, 4, 12 e. 2, 6, 6, 4, 6 MODULE FOR INTERNATIONAL STANDARD CLASS TAMBUN SELATAN HIGH SCHOOL Subject Date – Time Teacher Module Code Sub Theme I. : : : : : Chemistry ……. x 45’ CH / BC 2.2 / 1 Basic Chemistry Law Standard Competence To describe basic chemistry law and applied for stoichiometry. II. Basic Competence To demonstrate and to inform about basic chemistry law on experiments III. Indicator 1. To demonstrate Lavoisier Law (before and after on reaction in substance mass in constant) 2. To demonstrate and to describe the data about two elements compounds mass (Proust Law) 3. To demonstrate Dalton Law in some compounds 4. To use experiment data and to prove Gay Lussac Law IV. Teaching Materials A. Lavoisier Law Before and after on substance reaction is constant. Example : H2 + O2 H2 O If 4 gram H2 is reactioned with 32 gr O2 is 36 gr H2O B. Proust Law The elements mass comparation on compounds are constant Exp. No Cu Mass (gr) S mass (gr) Cu S (gr) 1 0,24 0,12 0,36 2 0,31 0,15 0,46 3 0,41 0,20 0,60 4 0,51 0,25 0,75 5 0,64 0,31 0,95 Cu : S = 2 : 1 Constant C. Dalton Law (Multiple Comporation Law) If two elements can form more than a compound, and if an element mass is constant so another element compound comporation is rounding and simple amount. Example : Nitrogen and oxygen can form NO, N2 O, N2 O3, and N2 O4 on the following mass composition. Nitrogen mass Oxygen mass Comparation Compound (gr) (gr) N=O N2 O 28 16 7 : 4 NO 14 16 7 : 8 N2 O3 28 48 7 : 12 N2 O4 28 64 7 : 16 So oxygen mass comparation in N2O : NO : N2O3 : N2O4 = 4 : 8 : 12 : 16 D. Gay Lussac Law Gases volume on reaction and gases volume on product can measured on temperature and pressure standard is rounding and simple amount. V. Vol H2 1 = Vol Cl2 = 1 = Vol Hcl = 2 Vol H2 2 = Vol O2 = 1 = Vol H2O = 2 Competence Test 1. If 18 gr glucose, C6H12 O6 is burned by oxygen so product 26,4 gr CO2 and 10,8 gr H2O. How many grams of oxygen are needed on ombustion ? 2. The comparation on oxygen mass and hydrogen mass in compound is 8 : 1. If 100 gr oxygen can form H2O, how many grams of H2O is produced ? 3. A and B elements can form 2 compounds and are consist of 50 % and 60 % A. Determine comparation of B element mass on A constant ? 4. 4 l C2H6 is burned in balance the following equation is : C S 2(g) + 3 O2 (g) CO (g) + 2 SO2 (g) How many volumes for CO2, H2O are producted in STP. Keys 2.2 : 1. C H12 O6 + 6 O2 6 CO2 + 6 H2O 18 gr 26,4 10,8 (26,4 + 10,8) – 18 = 37,2 – 18 = 19,2 gr O2 2. O : H 100 gr : 3 gr O : 8 : 100 : 24 : 3. (A B) A = 50% B = 50% H2 O is producted 27 gr (A B) A = 60% B = 40% If B = 50gr A = 50gr Comparation A1 = 50 = 10 = 1 = 2 H 1 3 3 If B = 50gr A = 60 x 50 40 = 75gr : : : : : A2, 75 15 1,5 3 B is constant (50gr) 4. 2 C2 H6 + 7 O2 4 CO2 + 6 H2O 4 l Vol O2 is needed Vol CO2 is producted Vol H2O is producted = 7/2 x 4 = 4/2 x 4 = 6/2 x 4 = 14 l = 8l = 12 l REFERENCES 1. Ebbing, 1984. General Chemistry. Houghton Mifflin Company Boston 2. Purba, Michael 2004. Kimia SMA X 1 A Erlangga Jakarta 3. Sudarmo, Unggul 2004. Kimia SMA X Erlangga, Jakarta 4. Stoker, H. Stephen and Edward B Walker. 1939 Fundamentals of Chemistry. Allyn and Bacon. Inc Silakan Klik : Module Chemistry selanjutnya