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Chapter Minerals 2Earth Materials— Minerals and Rocks 9/13 Earth Materials – Minerals • Minerals are the basic units that make up most of Earth’s inorganic materials • Minerals have many essential uses Can you name a few? What is a mineral? What is a mineral? • 1. It is formed naturally What is a mineral? • 1. It is formed naturally • 2. It has a crystalline structure What is a mineral? • 1. It is formed naturally • 2. It has a crystalline structure • 3. It is solid What is a mineral? • • • • 1. It is formed naturally 2. It has a crystalline structure 3. It is solid 4. It has a narrowly defined chemical composition What is a mineral? • • • • 1. It is formed naturally 2. It has a crystalline structure 3. It is solid 4. It has a narrowly defined chemical composition • 5. It has characteristic physical properties What is a mineral? • • • • 1. It is formed naturally 2. It has a crystalline structure 3. It is solid 4. It has a narrowly defined chemical composition • 5. It has characteristic physical properties • 6. It is inorganic -- never living Minerals • Chemical composition: • composed of elements Quartz – SiO2 composed of one silicon atom and two oxygen atoms • Distinct Properties: color, luster, hardness, breakage, streak, taste, odor, magnetic, surface features, reactive with acid Matter and Its Composition • Every substance on earth is composed of “matter” • Matter has mass and volume – (occupies space) solid, liquid, gas composed of elements • Elements are chemical substances • cannot be broken down chemically • composed of atoms Atoms • smallest particle that retains the nature of the element Nucleus contains particles protons: + neutrons: no charge Electrons travel around the nucleus electrons: -- Structure of an Atom • The dense nucleus of an atom – consisting of protons and neutrons – is surrounded by a cloud of orbiting electrons Particles in nucleus • Atomic number: the number of protons This determines the name of the element. • Atomic mass number is the number of protons + number of neutrons The number of neutrons in an atom – may vary without changing the name of the element When neutrons vary • Isotopes of the same element are formed Isotopes have the same atomic number • Isotopes have different atomic mass numbers • Isotopes of the same element behave the same chemically • Isotopes are important in radiometric dating Carbon Isotopes • Carbon atoms (with 6 protons) – have 6 neutrons = Carbon 12 (12C) – have 7 neutrons = Carbon 13 (13C) – or have 8 neutrons = Carbon 14 (14C) – thereby making up three isotopes of carbon. Bonding and Compounds • Bonding: atoms join to other atoms • Compound bonding of two or more elements • Oxygen gas (O2) is an element • Ice (H2O) is a compound • Most minerals are compounds Atomic Bonding • Ionic bonds: electrons are donated or received Atomic Bonding • Common types of bonding among atoms to form minerals: • Ionic bonds: electrons are donated or received Atomic Bonding • Common types of bonding among atoms to form minerals: • Ionic bonds: electrons are donated or received • Covalent bonds: electrons are shared Atomic Bonding • Common types of bonding among atoms to form minerals: • Ionic bonds: electrons are donated or received • Covalent bonds: electrons are shared • Metallic bonds: electrons are located in a “cloud” around nucleus Atomic Bonding • Common types of bonding among atoms to form minerals: • Ionic bonds: electrons are donated or received • Covalent bonds: electrons are shared • Metallic bonds: electrons are located in a “cloud” around nucleus • Vanderwaals bonds: atoms are weakly attracted Ionic Bonding • Ion: atom that has gained or lost one or more electrons It has a negative or positive charge • Ionic bonding – attraction between two ions of opposite charge Goal: atoms are more stable when outer electron shell is filled. Ionic Bonding halite Covalent Bonding • Covalent bonding – results from sharing electrons shared electrons Metallic Bonding Electrons are loosely arranged in a “cloud-like” arrangement. Metals have properties of being good electrical conductors Metals are malleable Minerals—The Building Blocks of Rocks Quartz consists of 1 silicon atom for every 2 oxygen atoms – Potassium Feldspar consists of 1 potassium, 1 aluminum, and 3 silicon for every 8 oxygen atoms Quartz: SiO2 Ratio: 1: 2 KAlSi3O8 1: 1: 3: 8 Native Elements • consist of only one element. • They are not compounds. gold – formula: Au diamond – formula: C Allotropes of carbon “polymorphs” Mineral Properties • controlled by internal arrangement of atoms – Chemical composition – Crystalline structure Color how reliable is color to identify a mineral? Many varieties of quartz Crystal form If given enough room to grow freely – minerals form perfect crystals with – planar surfaces, called crystal faces – sharp corners – straight edges Moh’s Scale of hardness arranged from 1 to 10 • Hardness is a mineral’s resistance to abrasion or being scratched Streak test color of a mineral in its powdered form Breakage yes, they all break, but some break in predictable patterns • Irregular breakage or fracture: random, smooth, round (conchoidal) with no geometric shape or parallel flat sides Breakage • Cleavage: • tendency to break in flat surfaces that are parallel may have one, two, three, even four pairs of flat sides, or planes. Types of mineral cleavage Surface feature - feldspars • Exsolution Lamellae Potassium Feldspar • Striations Plagioclase Feldspar Unique taste, odor halite and sulfur Reaction with dilute hydrochloric acid – carbonate minerals Common rock forming minerals Rock-Forming Minerals • Most rocks are solid aggregates of one or more minerals • Thousands of minerals occur in rocks, but most rocks have common rock-forming minerals Most rock-forming minerals are silicates, but other groups are important Silicates • Silicates are minerals containing silica – Si and O • They make up perhaps 95% of Earth’s crust – and account for about 1/3 of all known minerals • The basic building block of silicates – is the silicon oxygen tetrahedron • which consists of one silicon atom • surrounded by four oxygen atoms Earth’s crust: elements by weight % Types of Silicates • Silica tetrahedra can be – isolated units bonded to other elements – arranged in chains (single or double) – arranged in sheets – arranged in complex 3D networks Types of Silicates • Ferromagnesian silicates (dark) – contain iron (Fe), magnesium (Mg), or both olivine, pyroxene, amphibole, biotite • Nonferromagnesian silicates (light) contain potassium (K), sodium (Na), (Ca)calcium – Quartz, muscovite, feldspar Ferromagnesian Silicates • Common ferromagnesian silicates include olivine amphibole Pyroxene- biotite mica Nonferromagnesian Silicates Quartz Potassium feldspar Plagioclase feldspar Muscovite Other Mineral Groups • Carbonates contain carbonate ion CO3 (CaCO3) calcite Oxides (Fe2O3) Magnetite Halides ( NaCl) Halite Sulfides (PbS) Galena