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Transcript
Simulated Organic Light-emitting Diode Optimization
Michael Skowrons, Michelle Waugh
Dr. Bjorn Lussem
Introduction
Transfer Matrix Algorithm
The optical properties for an organic light-emitting diode (OLED) are modeled by the transfer
matrix algorithm. Using the commercially available software package SimOLED, we adjusted
the dimensions of the organic layers of the OLED to achieve the optimal optic properties for a
red OLED. We also studied the underlying model the program uses for its calculations, and how
it can be used to determine the emission of the OLED at different wavelengths and viewing
angles.
The advantages of using an OLED include high energy efficiency, vibrant color, high contrast,
low cost, and the ability to be placed on flexible substrate. The major disadvantage is the low
optical efficiency. The goal of this sort of optical simulation is to optimize the outcoupling
efficiency, which is usually around 28-29%
E1+
E1+’
E2+
E1-
E1-’
E2-
Results
This graph shows the luminous and
photon fluxes as the thickness of the
ETM layer is adjusted. The shift
between these two fluxes is due to the
change in wavelength (color) of the
light as the cavity changes its
resonance state. It shows a maximum
emission at 50nm and a minimum at
140nm. This is due to the interference
as the OLED is closer or further from its
resonance state. When the ETM layer
is at 50 nm, the light constructively
interferes as a standing wave, with the
node on the emitter. When the ETM
layer is at 140nm, the light
destructively interferes and very little
light is emitted.
E2+’
Organic Light-emitting Diode
Calculation task - Spectral Angular
0.11
0.10
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0.08
Radiance [W sr-1 m-2 nm-1]
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
Var. 1- Organic [5], Thickness [nm]:
25.0
34.0
43.0
53.0
62.0
71.0
80.0
89.0
99.0
108.0
117.0
126.0
136.0
145.0
154.0
163.0
172.0
182.0
191.0
200.0
[1] Meerheim, PhD Thesis 2009
An organic light-emitting diode (OLED) is made up of at least 5 organic layers
The hole-transport layer
The hole-blocking layer
The emission layer
The electron-transport layer
The emission layer
Radiance [W sr-1 m-2 nm-1]
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The transfer matrix algorithm gives the change in electric field as
light propagates through a medium (propagation matrix) and
passes through an interface(matching matrix).
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0.05
0.04
•
0.03
•
•
0.02
•
0.01
•
In order to optimize the optical properties of the OLED, we adjusted the width of the organic
layers to achieve resonance for red light. The OLED acts as a resonance cavity, and the light
acts as a standing wave, with the node positioned on the emitter.
SimOLED
0.00
400
450
500
550
600
Wav elength [nm]
650
700
750
800
Maximum Emission vs ETM thickness
0.12
0.1
The SimOLED program uses the transfer matrix algorithm to
calculate the optical properties of light as it travels through an
OLED. We input the materials that made up each layer of this
particular OLED. We then adjusted the width of the electrontransport layer to achieve resonance and maximize the efficiency
of the OLED.
Maximum Radiance(W sr-1 m-2 nm-1)
Optical Properties
0.08
These graphs show how the
radiance and wavelength of the
emitted light varies as the thickness
of the ETM layer changes. This
shows a peak radiance for the
wavelength of red light, about
650nm. This graph also shows a loss
of radiance and a deviation of the
peak radiance for thicknesses that
differ from the resonance state.
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0.02
0
0
50
100
150
200
250
Thickness of ETM layer (nm)
http://www.giangrandi.ch/optics/eye/eye.shtml
This graph (red curve) shows the relative sensitivity of the human eye with respect to differing
wavelengths, with the peak around 555nm (in the green region).
Radiance: radiant power per solid angle per projected area of a light source
Photon Flux: the number of photons per second per unit area
Luminous Flux: radiant power with respect to the sensitivity of the human eye to light
Luminous Intensity: luminous flux per solid angle
Luminance: luminous intensity per unit projected area, or “brightness”
Future Direction
Future application of this sort of research includes improving the
optical efficiency of OLEDs. They are highly energy efficient, but
only have an optical efficiency of around 28-29%. Another
application would be constructing these OLEDs on flexible
substrates for a wide variety of purposes.
This graph shows how luminance
drops as the viewing angle
increases. This is because the OLED
is a Lambertian emitter, that is, it
obeys Lambert’s emission law. The observed radiance, or luminance, is
the same from any angle since the
apparent size (solid angle) of the
surface corresponds to the
decreased emission.