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Chemistry 11HL Unit 1 / IB Topic 1 Working With Numbers 1 Significant Figures Chemistry is an “empirical” subject – and that means understanding the chemical world by doing experiments. One very important aspect of experimentation is MEASUREMENT. Knowing how to make precise and reliable measurements, how to record those measurements in a clear organized manner and how to work with and use the measurements to find relationships will make your life as an IB Chemistry student much easier. Really. Honestly. Truly. “SIG FIGS” ARE BIG! “Sig figs” really means SIGNIFICANT FIGURES or SIGNIFICANT DIGITS. They are very important to scientists when they communicate their findings to the world. So why do we care about “sig figs” so much? One answer lies in a question many students ask when doing calculations. Try this calculation: 26.5 ÷ 29 = ___________ What are you going to do with this answer? A more important reason for lovin’ sig figs has to do with how we measure things. We will look at this idea in more detail in the next class. But for a sneak preview, think about how you would record the measurement at the arrow: your reading: acceptable readings: unacceptable readings: The number of digits you write in a measured value tells you how PRECISE your measurement is. Is it just “close to” a certain value, or is it really really “exact”? The number of significant figures in your measurement helps others decide how precise your value is. p. 1 Chemistry 11HL Unit 1 / IB Topic 1 SIG FIG RULES! Use these rules to decide how many significant figures are in a numerical value: 1. Digits from 1 – 9 are always significant. Examples: 23 kg 79.42 mL 923 m 2. Anything you count is significant. Examples: 1725 students 40 classrooms 18 cookies 3. Zeros between two other non-zero digits are always significant. Examples: 30.5 cm 2009 years 3.0205 h 4. Zeros after the decimal are significant if a digit between 1 and 9 precedes it. Examples: 9.00 g 37.0 ˚C 5. Zeros at the end of a whole number are NOT significant. Examples: 800 m 30 L 6. Leading zeros are not significant (they are only there to indicate the location of the decimal point). Examples: 0.82 g 0.003 s How many significant digits are in the following? State the rule you use to help you decide on your answer. a) 23.7 cm b) 107 L c) 40 chairs d) 4301.0 mm e) 0.00045 g f) 600 years g) 00.00200 V h) 100.0001010 g p. 2 Chemistry 11HL Unit 1 / IB Topic 1 CALCULATIONS AND SIGNIFICANT FIGURES RULE 1: MULTIPLICATION AND DIVISION When multiplying or dividing, round your answer to the least number of SIGNIFICANT FIGURES in the values used in the calculation. eg: 22.378 cm x 3.10 cm ÷ 85.75 cm = RULE 2: ADDITION AND SUBTRACTION When adding or subtracting numbers, round your answer to match the least number of DECIMAL PLACES in the values used in the calculation. eg: 3.76 g + 14.83 g + 2.1 g = TRY THESE: a) 4.64 + 3.2 = b) 22.4420 + 56.981 = c) 67.5 – 0.009 = d) 50.0 x 2.63 = e) (2.3)(3.45)(7.42) = f) 1.0007 ÷ 0.009 = g) 51 ÷ 7.4 = h) 208 ÷ 9.036 = i) (8.852 x 9.2) ÷ (4.821 x 7) = p. 3 Chemistry 11HL Unit 1 / IB Topic 1 PRACTICE PROBLEMS 1. 2. 3. Give the number of significant digits in each of the following measurements: a) 3.782 g b) 0.00390 s c) 75.2 mL d) 19,000 J e) 6.022 x 10 f) 23 students g) 53.50 mL h) 2.0703 x 10 23 -10 mol Round off the following numbers to three significant digits. Express your answers in scientific notation where appropriate. a) 120 000 b) 43.619 c) 5.0457 d) 2.8029 x 10 e) 0.000 82057 f) 6.00098 x 10 -3 4 Calculate these values and record the final answer to the correct number of significant figures: a) 23.4 x 14 b) 0.005 - 0.0007 c) 7.895 + 3.4 d) 7.895 ÷ 34 e) 0.0945 x 1.47 f) 0.2 ÷ 0.0005 g) 0.0050 – 0.0007 h) (3.1 x 10 ) x (4.821 x 10 ) i) 15.0 – 7.2 j) 0.25 ÷ 28.02 3 -2 p. 4