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Chemistry 1020, Skills Module 2-Rounding Name Study Guide for Skills Module 2—Review of Rounding Rules ■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■ Reading Assignment: The reference manual which came with your calculator (if needed). Guide for Your Lecturer: ✔ ✔ ✔ ✔ ✔ ✔ 1. 2. 3. 4. 5. 6. Quick Review of Algebraic Manipulation The Calculator: Raising a Number to a Power or Obtaining the Root of a Number Rounding Rules for Multiplication and Division (Review from Module 1) Rounding Rules for Addition and Subtraction (Review from Module 1) Rounding Rules When Taking Logs or Antilogs (Review from Chem 1020 Skills Module 1-Logs) Practice Using All of the Rounding Rules ■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■■ Homework Note: ✔ indicates problems to be stressed on drill quizzes and hour exams. ✔✔✔■Quick Review of Algebraic Manipulation 1a) S. Given 0.612m/(4.1n + 2.1m) = 0.42, solve for m. 0.612m/(4.1n + 2.1 m) = 0.42 Starting Equation 0.612m = 0.42(4.1n + 2.1 m) Obtained by multiplying both sides by (4.1n + 2.1 m) 0.612m = 1.72n + 0.882m Obtained by multiplying through by “0.42” 0.612m - 0.882m = 1.72n Obtained by subtracting "0.882m" from both sides So -0.27m = 1.72n which can be reduced to m = 6.4n ----------------------------------------------------------------------------------------------------------------------------------------------A. Given 1.24n /(4.23n + 1.37m) = 1.25, solve for n. ----------------------------------------------------------------------------------------------------------------------------------------------B. Given 1.9n /(2.5n + 3.9m) = 1.48, solve for m. ----------------------------------------------------------------------------------------------------------------------------------------------C. Given 2.05r /(4.93r + 3.72m) = 0.308, solve for r. ----------------------------------------------------------------------------------------------------------------------------------------------D. Given 2.9r/(4.34r + 2.3m) = 7.89, solve for m. ----------------------------------------------------------------------------------------------------------------------------------------------E. Given 9.7n/(6.5n + 4.2m) = 0.521, solve for m. ----------------------------------------------------------------------------------------------------------------------------------------------- Xavier University of Louisiana 73 Chemistry 1020, Skills Module 2 ✔✔✔■Quick Review of Algebraic Manipulation (continued) 1a) F. Given 4.5n/(6.7n + 7.6m) = 9.6, solve for n. ----------------------------------------------------------------------------------------------------------------------------------------------G. Given 1.20r/(6.88x + 4.78r) = 8.21, solve for r. ----------------------------------------------------------------------------------------------------------------------------------------------H. Given 0.65r/(3.6x + 4.8r) = 8.3, solve for x. ----------------------------------------------------------------------------------------------------------------------------------------------b) A. Given 2.1x /(2.05n - 8.3x) = 4.62, solve for x. ----------------------------------------------------------------------------------------------------------------------------------------------B. Given 9.70x /(5.60n - 0.11x) = 7.8, solve for n. ----------------------------------------------------------------------------------------------------------------------------------------------C. Given 2.7r /(3.4r - 6.1m) = 9.8, solve for r.. ----------------------------------------------------------------------------------------------------------------------------------------------D. Given 9.88r /(1.20r - 3.43m) = 4.03, solve for m. ----------------------------------------------------------------------------------------------------------------------------------------------E. Given 7.8m/(4.1n - 9.1m) = 1.11, solve for m. ----------------------------------------------------------------------------------------------------------------------------------------------F. Given 3.15m/(2.44n - 3.97m) = 2.30, solve for n. ----------------------------------------------------------------------------------------------------------------------------------------------- 74 Xavier University of Louisiana Chemistry 1020, Skills Module 2-Rounding Name ✔✔✔■Quick Review of Algebraic Manipulation (continued) 1b) G. Given 3.10r/(2.92r - 0.314x) = 2.81, solve for r. ----------------------------------------------------------------------------------------------------------------------------------------------H. Given 3.9r/(5.2r - 4.3x) = 9.7, solve for r. ----------------------------------------------------------------------------------------------------------------------------------------------✔✔✔■The Calculator: Raising a Number to a Power or Obtaining the Root of Number 2a) Determine the value of x in the given expression and then round off using the rules above. R S. x = (2.1)5(1.8)7/(6.3)4 = 1.587003231 = 1.6 --------------------------------------------------------------------------------------------------------------------------------------------A. x = (6.9)4(1.05)5/(7.1)3 --------------------------------------------------------------------------------------------------------------------------------------------B. x = (1.72)8(4.32)4/(6.82)6 --------------------------------------------------------------------------------------------------------------------------------------------C. x = (5.23)7(1.01)3/(2.1)4 --------------------------------------------------------------------------------------------------------------------------------------------D. x = (1.09)6/(6.4)4*(7.3)5 --------------------------------------------------------------------------------------------------------------------------------------------E. x = (2.9)5/(1.4)3*(9.3)4 --------------------------------------------------------------------------------------------------------------------------------------------F. x = (6.5)5(2.7)3/(3.7)4 --------------------------------------------------------------------------------------------------------------------------------------------G. x = (4.9)6/(3.5)4*(7.2)8 --------------------------------------------------------------------------------------------------------------------------------------------H. x = (7.6)3(8.9)4/(2.6)6 --------------------------------------------------------------------------------------------------------------------------------------------- Xavier University of Louisiana 75 Chemistry 1020, Skills Module 2 ✔✔✔■The Calculator: Raising a Number to a Power or Obtaining the Root of Number (continued) 2b) Determine the value of x in the given expression and then round off using the rules above. R S. x4 = (4.2)(3.15)/(17.1) = 0.937866305 = 0.94 --------------------------------------------------------------------------------------------------------------------------------------------A. x3 = (6.9)(1.05)/(7.1) --------------------------------------------------------------------------------------------------------------------------------------------B. x6 = (1.72)(4.32)/(6.82) --------------------------------------------------------------------------------------------------------------------------------------------C. x5 = (5.23)(1.01)/(2.1) --------------------------------------------------------------------------------------------------------------------------------------------D. x5 = (1.09)/{(6.4)*(7.3)} --------------------------------------------------------------------------------------------------------------------------------------------E. x4 = (2.9)/{(1.4)*(9.3)} --------------------------------------------------------------------------------------------------------------------------------------------F. x3 = (6.5)(2.7)/(3.7) --------------------------------------------------------------------------------------------------------------------------------------------G. x6 = (9.1)/{(2.5)*(8.2)} --------------------------------------------------------------------------------------------------------------------------------------------H. x7 = (5.7)(4.3)/(4.8) --------------------------------------------------------------------------------------------------------------------------------------------✔✔✔■Rounding Rules for Multiplication and Division (Review from Module 1) 3. How to Round Off a) State the rules for rounding off numbers. (If the portion to be dropped is greater than or equal to five, round up. If it is less than five, leave it alone.) b) Round off one digit from each of the following numbers using the rules above. |Number | Number rounded off ||Number | Number rounded off | S. | 0.0075 | 0.008 || 8745 8750 or 8.75*10 3 | | || | | | 0.00172 | 0.0017 || 308*10-5 3.1*10 -3 | | || | | A. | 0.00325 | || 786 | | || | | | 0.00217 | || 239*10-3 | | || | | B. | 0.0256 | || 4732 | | || | 76 Xavier University of Louisiana Chemistry 1020, Skills Module 2-Rounding Name ✔✔✔■Rounding Rules for Multiplication and Division (Review from Module 1) 3b) Round off one digit from each of the following numbers using the rules above. |Number | Number rounded off ||Number | Number rounded off | | 0.0475 | || 489*10-4 | | || | | C. | 0.02765 | || 4435 | | || | -1 | | 0.00198 | || 412*10 | | || | c) Uncertainty: Significant Digits It is important that we indicate the uncertainty in measured numbers. One way of doing so is to count the number of significant digits. Define significant digits. d) It is easy to determine the number of significant digits in a number which has only nonzero digits because, by convention, all nonzero digits in a number are always significant. When a number contains zero’s, however, it is not quite so easy because zero’s may or may not be significant depending on their placement in the number. There are three rules for determining whether or not zeros in a number are signficant. State them (pp. 13). Rule 1: Zero’s to the left of nonzero digits Rule 2: Zero’s between nonzero digits Rule 3: Zero’s to the right of nonzero digits e) f) Indicate the number of significant figures in each of the following numbers |Number | Number of significant figures ||Number | Number of significant figures S. | 0.0075 | 2 || 8745 | 4 -5 | | 0.00172 | 3 || 308*10 3 A. | 0.0000325 | || 7.90 | | 0.027 | || 239*10-3 | B. | 0.0206 | || 4732 | -4 | 0.000045 | || 489*10 | C. | 0.000005 | || 4.04 | | | 0.00098 | || 42*10-1 D. | 10.0 | || 213 | -2 | 200 | || 3.05*10 | Determining the uncertainty in numbers obtained by multiplying or dividing State the rule used to determine the uncertainty in answers obtained by multiplying or dividing measurements (The number of significant figures in the result is the same as the number in the least precise measurement in the calculation.) Xavier University of Louisiana 77 Chemistry 1020, Skills Module 2 ✔✔✔■Rounding Rules for Multiplication and Division (Review from Module 1, continued) 3g) Indicate the number of significant digits in each of the given numbers and then use this information to round off the result obtained by multiplying the two or dividing one by the other. (p. 15) |Number |Significant Figures in Number ||Number |Significant Figures in Number -1 | S. | 0.00541 | 3 || 9.1*10 2 | | || | Multiply the two numbers above and round off using the rule in e. R -1 (0.00541)*(9.1*10 ) = 0.0049231 = 0.0049 = 4.9*10-3 |Number |Significant Figures in Number ||Number A. | 0.0023 | || 8.23*10 2 | | || Multiply the two numbers above and round off using the rule in e. |Significant Figures in Number | | | B. | 8.02 | || 1.2*10 2 | | || | Divide the first of the two numbers above by the second and round off using the rule in e. |Number |Significant Figures in Number ||Number C. | 8.020 | || 5.81*10 2 | | || Multiply the two numbers above and round off using the rule in e. |Significant Figures in Number | | |Number |Significant Figures in Number ||Number |Significant Figures in Number D. | 0.0072 | || 9.346*10 2 | | | || | Divide the first of the two numbers above by the second and round off using the rule in e. |Number |Significant Figures in Number ||Number |Significant Figures in Number | E. | 0.0732 | || 4.3*10 -4 | | || | Divide the first of the two numbers above by the second and round off using the rule in e. |Number |Significant Figures in Number ||Number |Significant Figures in Number | F. | 0.123 | || 4.33*10 3 | | || | Divide the first of the two numbers above by the second and round off using the rule in e. 78 Xavier University of Louisiana Chemistry 1020, Skills Module 2-Rounding Name ✔✔✔■Rounding Rules for Addition and Subtraction (Review from Module 1) 4. Determining the uncertainty in numbers obtained by adding or subtracting a) State the rule used to determine the uncertainty in answers obtained by adding or subtracting measurements (p. 15) b) Indicate the absolute uncertainty in each of the given numbers and then use this information to round off the result obtained by adding the two or subtracting one from the other. (p. 14) |Number |Absolute Uncertainty in Number ||Number |Absolute Uncertainty in Number | S. | 0.00541 | ±0.00001 || 0.0023 ±0.0001 | | || | Add the two numbers above and round off using the rule in g. R 0.00541 + 0.0023 = 0.00771 = 0.0077 = 7.7*10-3 |Number |Absolute Uncertainty in Number ||Number |Absolute Uncertainty in Number | A. | 0.0023 | || 0.822 | | || | Subtract the first of the two numbers above from the second and round off using the rule in g. |Number |Absolute Uncertainty in Number ||Number B. | 8.02 | || 121 | | || Add the two numbers above and round off using the rule in g. |Absolute Uncertainty in Number | | |Number |Absolute Uncertainty in Number ||Number C. | 3.020 | || 0.23 | | || Add the two numbers above and round off using the rule in g. |Absolute Uncertainty in Number | | |Number |Absolute Uncertainty in Number ||Number |Absolute Uncertainty in Number | D. | 0.0072 | || 0.09333 | | || | Subtract the first of the two numbers above from the second and round off using the rule in g. |Number |Absolute Uncertainty in Number ||Number E. | 0.0732 | || 0.0043 | | || Add the two numbers above and round off using the rule in g. |Absolute Uncertainty in Number | | |Number |Absolute Uncertainty in Number ||Number |Absolute Uncertainty in Number | F. | 0.123 | || 4.3 | | || | Subtract the first of the two numbers above from the second and round off using the rule in g. Xavier University of Louisiana 79 Chemistry 1020, Skills Module 2 ✔✔✔■Rounding Rules When Taking Logs or Antilogs (Review from Chem 1020 Skills Module 1-Logs) 5a) How is the uncertainty in “x” related to the uncertainty in “log x?” (The number of digits after the decimal point in a common log is equal to the number of significant figure in the orignal number. See A5 in the text.) b) What are the logarithms of the following numbers?____________ S. •log (1.2*10 -13) = -12.92 •ln (4.81*10 2) = 6.186 c) 80 •log(6.444*10 -7) = -6.1908 A. •log (1.9*10 -11) = •log (3.43*10 -8) = •ln (9.00*10 6) = B. •ln (6.51*10 -4) = •ln (2*10 2) = •log (9.2*10 -1) = C. •log (9.83*10 3) = •ln (8.02*10 -7) = •log (8.8*10 17) = D. •ln (1.89*10 -3) = •log (1.12*10 3) = •ln (7*10 27) = E. •log (4.2*10 -6) = •log (8.233*10 4) = •ln (1.92*10 19) = What are the antilogarithms of the following numbers?____________ S. •104.12 = 1.3*10 4 •e3.113 = 2.25*10 1 •10-6.4123 = 3.870*10 -7 A. •101.911 = •e-3.43 = •109.0 = B. •e-6.514 = •102.1 = •e-9.223 = C. •109.833 = •e-8.027 = •10-8.87 = D. •e1.893 = •1011.2 = •e-4.94 = E. •105.87 = •e9.2122 = •10-9.234 = Xavier University of Louisiana Chemistry 1020, Skills Module 2-Rounding Name ✔✔✔■Practice Using All of the Rounding Rules 6. Determine the answer after each step in the following algorithm using the rounding rules above and carrying one extra digit until you get to the final answer. S. Step 1: Add 2.31 to 1.8213 Answer to step 1: __4.121*__________ (*one extra digit kept) Step 2: Multiply the result from step 1 by 8.2314*102 Answer to step 2: __3.392*10 3 *______ Step 3: Take the log of the result from step 2 Final answer: __3.531___________ -----------------------------------------------------------------------------------------------------------------------------------------------------A. Step 1: Multiply 2.31*103 by 4.12*10-3 Answer to step 1: ___________________ Step 2: Subtract the result from step 1 from 9.731 Answer to step 2: ___________________ Step 3: Take the ln of the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------B. Step 1: Take the log of 6.21*10-6 Answer to step 1: ___________________ Step 2: Multiply the result from step 1 by 8.2*10-1 Answer to step 2: ___________________ Step 3: Add 3.124 to the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------C. Step 1: Subtract 152.034 from 212.3 Answer to step 1: ___________________ Step 2: Multiply the result from step 1 by 3.11*10-2 Answer to step 2: ___________________ Step 3: Take the antilog of the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------D. Step 1: Take the inverse ln of 2.682 Answer to step 1: ___________________ Step 2: Divide the result from step 1 by 2.1*10-1 Answer to step 2: ___________________ Step 3: Add 14.11 to the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------E. Step 1: Subtract 14.211 from 153.1 Answer to step 1: ___________________ Step 2: Divide the result from step 1 by 6.23*102 Answer to step 2: ___________________ Step 3: Take the antilog of the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------F. Step 1: Add 0.012 to 0.368 Answer to step 1: ___________________ Step 2: Multiply the result from step 1 by 3.21*101 Answer to step 2: ___________________ Step 3: Take the inverse ln of the result from step 2 Final answer: ___________________ ------------------------------------------------------------------------------------------------------------------------------------------------------ Xavier University of Louisiana 81 Chemistry 1020, Skills Module 2 ✔✔✔■Practice Using All of the Rounding Rules (continued) 6. Determine the answer after each step in the following algorithm using the rounding rules above and carrying one extra digit until you get to the final answer. G. Step 1: Take the inverse ln of 3.681 Answer to step 1: ___________________ Step 2: Multiply the result from step 1 by 1.12*10-2 Answer to step 2: ___________________ Step 3: Add 10.1 to the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------H. Step 1: Divide 16.21 into 101 Answer to step 1: ___________________ Step 2: Add 0.21 to the result from step 1 Answer to step 2: ___________________ Step 3: Take the antilog of the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------I. Step 1: Divide 17.22 by 1.21*103 Answer to step 1: ___________________ Step 2: Add the result of step 1 to 1.62 Answer to step 2: ___________________ Step 3: Take the inverse ln of the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------J. Step 1: Take the antilog of -2.11 Answer to step 1: ___________________ Step 2: Multiply the result from step 1 by 4.36*102 Answer to step 2: ___________________ Step 3: Add 14 to the result to step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------K. Step 1: Subtract 8.121 from 8.08 Answer to step 1: ___________________ Step 2: Divide the result from step 1 by 2.18 Answer to step 2: ___________________ Step 3: Take the antilog of the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------L. Step 1: Subtract 1.8213 from 2.31 Answer to step 1: ___________________ Step 2: Multiply the result from step 1 by 8.248*10-3 Answer to step 2: ___________________ Step 3: Take the log of the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------M. Step 1: Divide 3.21*103 by 4.121*103 Answer to step 1: ___________________ Step 2: Subtract the result from step 1 from 14.2 Answer to step 2: ___________________ Step 3: Take the ln of the result from step 2 Final answer: ___________________ -----------------------------------------------------------------------------------------------------------------------------------------------------N. Step 1: Take the log of 4.21*10-5 Answer to step 1: ___________________ Step 2: Multiply the result from step 1 by 8.2*103 Answer to step 2: ___________________ Step 3: Add 2.361*103 to the result from step 2 Final answer: ___________________ ------------------------------------------------------------------------------------------------------------------------------------------------------ Generated by JWC in Spring, 2000; Revised 2002 & 2003 SJB 82 Xavier University of Louisiana