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Agenda Dec 7, 2016 Slip quiz 1 Some Chemical Reactions - using your notes from lab time Teacher demonstrations and Writing and Balancing Chemical Equations Homework Slip Quiz 1. Write out each question. 1. Equation for use when converting temperatures from Celsius to Kelvin. 2. a) Equation for density b) Density of an object that has a mass of 5.00g and a volume of 2.50mL. 3. Relationship between cm3 and mL for use when working with volumes of liquids. 4. Prefix milli stands for? 5. Set up converting xmL to L using a conversion factor. Slip Quiz 1. 1. Equation for use when converting temperatures from Celsius to Kelvin. K = ℃ + 273 Kelvin Absolute temperature Starts at Absolute zero 0K Slip Quiz 1. 2. a) Equation for density b) Density of an object that has a mass of 5.00g and a volume of 2.50mL. Density = mass = 5.00g = 2.00 g/mL volume 2.50mL Slip Quiz 1. 3 3. Relationship between cm and mL for use when working with volumes of liquids. 3 1 cm = 1 mL (page 27). Just a handy relationship to remember. Slip Quiz 1. 4. Prefix milli stands for? one thousandth (a mL is a milliliter, one thousandth of a liter) 5. Set up converting xmL to L using a conversion factor. 1L = 1000 mL so x mL . 1L = x L = 0.00x L 1000mL 1000 Chemical Reactions - typical pathway Energy released by the reaction system into the surroundings = an exothermic reaction At which station did you observe heat being released by the reaction system? You would have observed the outside of the container feeling warmer during the reaction than it was before the reaction started. Blue station: Magnesium and hydrochloric acid (dilute) What else did we observe and do at this station? Blue station: Magnesium and hydrochloric acid (dilute) Saw bubbles Heard fizzing Trapped the gas and then “popped” it with a lighted splint - demonstrating that the gas being given off was hydrogen Magnesium all disappeared New piece of paper MLA heading Chemical Equations Word equation Solid Magnesium reacts with dilute hydrochloric acid to produce hydrogen gas and a solution of... Word equation Solid Magnesium reacts with dilute hydrochloric acid to produce hydrogen gas and a solution of ________________ (and heat). Skeleton equation - translate the substances that are matter into formula units or molecular formulas, reactants on left of reaction arrow Mg(s) + HCl(aq) H2(g) + ? (aq) Word equation Solid Magnesium reacts with dilute hydrochloric acid to produce hydrogen gas and a solution of magnesium chloride (and heat). Skeleton equation - translate the substances that are matter into formula units or molecular formulas, reactants on left of reaction arrow Mg(s) + HCl(aq) H2(g) + MgCl2(aq) Skeleton equation - will not necessarily show the correct relationship (ratio) between the substances that are reacting and the products that are made during the reaction. Mg(s) + HCl(aq) H2(g) + MgCl2 (aq) Law of conservation of matter: Matter cannot be created or destroyed during chemical reactions. Mg(s) + HCl(aq) H2(g) + MgCl2 (aq) A chemical equation should show us the simplest ratio of materials that can react to form the given products so that matter is conserved. Mg(s) + HCl(aq) H2(g) + MgCl2 (aq) We need to take steps to find the simplest ratios of these materials. - Step 1 - take an inventory of individual atoms shown in skeleton equation. Step 1 - take an inventory of the atoms Mg(s) + HCl(aq) H2(g) + MgCl2 (aq) 1Mg 1Mg 1H 2H 1Cl 2Cl Keep reactants on Left Keep products on right Mg(s) 1Mg + HCl(aq) H2(g) + MgCl2 (aq) 1Mg 1H 2H 1Cl 2Cl We have billions of atoms in our samples, we only want the simplest ratio of each substance, so we just need to think of factors that might help us “balance” the relationships. Mg(s) 1Mg + HCl(aq) 1H 1Cl H2(g) + MgCl2 (aq) 1Mg 2H 2Cl Step 2 - look for factors that will make it so that no atoms are created or destroyed during the reaction, (but are moved around like pieces of Lego). Mg(s) 1Mg + 2HCl(aq) 2H 2Cl H2(g) + MgCl2 (aq) 1Mg 2H 2Cl Step 3 - Write in the factor as a coefficient in front of the relevant substance and, in this case, BINGO! A balanced equation. Cu(s) + HCl(aq) No reaction H2(g) + ? product? What did we react the hydrogen with to make the pop we used to identify it? What was the product of this new reaction? Word Equation: Hydrogen gas reacts with oxygen gas, if given a spark of energy, to produce water vapor Skeleton Equation: H2(g) + O2(g) H2O(g) What do we do to avoid violating the law of conservation of matter? (As written we’ve lost an oxygen atom somewhere.) Take inventory of atoms under Skeleton Equation: H2(g) + O2(g) H2O(g) 2H 2O 2H O Remember we have billions of particles of each substance in our samples - even a drop of water H2(g) + O2(g) H2O(g) 2H 2O 2H O Balanced Chemical equation: 2H2(g) + O2(g) 2H2O(g) 4H 2O 4H 2O Now use what we know to predict the product of this reaction and write a balanced equation for the reaction: Word Equation: Solid Magnesium reacts with oxygen gas, if heated to get the reaction started, to produce _____________ ? Skeleton equation: Mg(s) + O2(g) ? Ionic or covalent compound? Word Equation: Solid Magnesium reacts with oxygen gas, if heated to get the reaction started, to produce magnesium oxide (an ionic compound, likely to be a solid). Skeleton equation: Mg(s) + O2(g) MgO (s) 1 Mg 1Mg 2O 1O Mg(s) + O2(g) 1 Mg 2O MgO (s) 1Mg 1O When we find factors that work - we call them coefficients when writing chemical equations Skeleton equation becomes balanced Eqaution: 2Mg(g) + O2(g) 2MgO (s) 2 Mg 2Mg 2O 2O Demonstrate reaction to see if MgO is solid. Write you observations in the space on the Chemical Reactions worksheet Magnesium has to be heated before it will start to react with oxygen in the air, but once it starts reacting it produces lots of heat and a bright white light (another form of energy). When the reaction is over a white powdery substance has replaced the shiny, malleable metal. This white powder is Magnesium oxide. Exothermic reaction. Solid copper reacts with oxygen when the copper is heated to glowing red, a black powdery oxide forms on the surface of the metal (copper(II) oxide). Cu(s) + O2(g) CuO (s) Solid copper reacts with oxygen when the copper is heated to glowing read, a black powdery oxide forms on the surface of the metal (copper(II) oxide). Skeleton Equation Cu(g) + O2(g) CuO (s) 1Cu 1Cu 2O 1O Solid copper reacts with oxygen when the copper is heated to glowing read, a black powdery oxide forms on the surface of the metal (copper(II) oxide). Skeleton Equation becomes Balanced Equation 2Cu(s) + O2(g) 2CuO (s) 2Cu 2Cu 2O 2O When we use a Bunsen Burner: CH4 methane gas burns in oxygen producing carbon dioxide gas, water vapor and giving out lots of heat and light energy into the surroundings. A very exothermic reaction. Skeleton equation CH4(g) + O2(g) → CO2(g) + H2O(g) Skeleton equation CH4(g) + O2(g) → 1C 4H 2O CO2(g) + H2O(g) 1C 2H 2O + 1O = 3O Skeleton equation CH4(g) + O2(g) → 1C 4H CO2(g) + 4H 2O + 2O = 4O 1C 2O 2H2O(g) Skeleton equation becomes Balanced Equation CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) 1C 4H 4H 2O + 2O = 4O 1C 4O Skeleton equation becomes Balanced Equation CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) 1C 4H 4H 2O + 2O = 4O 1C 4O Hydrogen peroxide - decomposition reaction demonstration - predict products will be ... Skeleton Equation: H2O2(aq) → (g) + (l) Hydrogen peroxide - decomposition reaction demonstration - predict products will be oxygen gas (which supports combustion) and water. Skeleton Equation: H2O2(aq) → O2(g) + H2O(l) Hydrogen peroxide - decomposition reaction demonstration - predict products will be oxygen gas (which supports combustion) and water. Skeleton Equation: H2O2(aq) → O2(g) + H2O(l) 2H 2O 2O + 1O = 3O 2H Hydrogen peroxide - decomposition reaction demonstration - predict products will be oxygen gas (which supports combustion) and water. Skeleton Equation becomes balanced equation: 2H2O2(aq) 4H 4O → O2(g) + 2H2O(l) 2O + 2O = 4O 4H Copper(II) carbonate - decomposition reaction demonstration - we predict products will be ... Skeleton Equation: CuCO3(s) → (g) + (s) Copper carbonate - decomposition reaction demonstration - we predict products will be carbon dioxide gas (which does not support combustion) and copper (II) oxide. Skeleton Equation is also balanced equation: CuCO3(s) 1Cu 1C 3O → CO2(g) 1C 2O + O = 3O + CuO(s) 1Cu Copper carbonate - decomposition reaction demonstration - we predict products will be carbon dioxide gas (which does not support combustion) and copper (II) oxide. Skeleton Equation is also balanced equation: Turn in your CuCO3(s) → CO (g) + CuO(s) Chemical Reactions 2 1Cu 1Cu Observation Sheet Now 1C 1C 3O 2O + O = 3O Try balancing equations at home: http://phet.colorado.edu/en/simulation/balancin g-chemical-equations Just be aware that when we write balanced equations on paper, we don’t put 1 coefficients (by writing a formula down, we are stating that there is one of those molecules present ).