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Scientific Measurement 1 Quantitative vs. Qualitative Qualitative measurement: Descriptive “This person feels feverish.” Quantitative measurement: Number + units “This person has a temperature of 102.3 F.” 2 Precise: how close a group of measurements are. Accurate: how close to the true value a measurement is. accurate & precise precise only neither 3 Precision vs. Accuracy ? A student measured her height to be 153, 155 and 156 cm. Her true height is 168 cm. Precise and/or accurate? (Instruments are calibrated to give accurate measurements) 4 Error Student measures temperature of boiling water to be 103.2oC. The true value is 100.0oC. Error = measured - accepted = 103.2oC – 100.0oC = 3.2oC 5 Percent Error error x 100 Percent error = accepted oC 3.2 x 100 = 100oC = 3.2% 6 Percent Error: Try It A Quality Control technician measures that there are only 1.92 L of soda in a bottle that should contain 2.00 L. What is the % error in filling the bottle? 7 Scientific Notation Avogadro’s Number: 602,200,000,000,000,000,000,000 6.022 x 23 10 Mass of H atom 0.00000000000000000000000166 g 1.66 x -24 10 g 8 Scientific Notation N. x coefficient 6.02 x m 10 exponent 23 10 9 Scientific Notation 1.Start with number in decimal form. 2.Count number of places to move decimal point to get one digit to the left of the decimal point. •shift decimal left exp. increases •shift decimal right exp. decreases 0.00083 = 8.3 x -4 10 10 Scientific Notation: Try It ! Express in proper scientific notation: 2001. 0.00345 40230000. 5 34.5 x 10 -5 34.5 x 10 -6 0.029 x 10 11 Scientific Notation Can you go backwards? Express as decimal numbers. 3.3 x -3 10 6.2 x 4 10 12 Using Scientific Notation Multiplication (& division): •multiply (divide) coefficients and add (or subtract) exponents (8.0 x -2 10 ) x 5 (7.0 x 10 ) = 3 = 56 x 10 4 = 5.6 x 10 13 Using Scientific Notation Try it ! (8.0 x -2 10 ) (7.0 x 5 10 ) =? Note: x divided by y: xy x/y x y per 14 Using Scientific Notation Addition & subtraction: •convert to same exponents, then just add (or subtract) coefficients (3.42 x 10-5) - (2.5 x 10-6) = (3.42 x 5 10 ) -5 10 ) - (0.25 x = -5 = 3.17 x 10 15 Using a Scientific Calculator (3.42 x 10-5) - (2.5 x 10-6) = 3.42E-5 - Do not use the 2.5E-6 x 10 enter button! 16 Scientific Notation Try It! Try with & without scientific calc. (6.2 x -3 10 ) x (1.5 x 1 10 ) (8.8 x 106) (2.2 x 10-1) (6.7 x -2 10 ) (7.32 x + (3.0 x 4 10 ) -3 10 ) – (6.10 x 3 10 ) 17 Significant Figures If I asked you to measure the width of this room, how many digits would you write down? 30 ft 32 ft 32.4 ft 32.43 ft 32.437 ft 18 Significant Figures: --read the scale --estimate one more digit --always use units 0.6m . . . . . . . . . . . . . . 0.61m . . 0.607m . . 19 Significant Figures --read the scale --estimate one more digit --always use units 20 Reading Sig Fig: Rules All non-zeros are significant. 1.234 ft Zeros between non-zero numbers are significant. 40,501 ft 21 Significant Figures Zeros to the left of the first nonzero number are not significant. 0.00349 ft Zeros to right of the last non-zero number are significant if there is a decimal point. 0.09030 ft 22 Significant Figures 300 ft 1 sig fig 300. ft 3 sig figs How would you show 2 sig figs? Need scientific notation: 3. x 1 sig fig 3.0 x 102 ft 2 sig figs 3.00 x 102 ft 3 sig figs 2 10 ft 23 “Exact” Numbers (unlimited sig figs) Counting: for example, 8 people 24 “Exact” Numbers (unlimited sig figs) Many conversion factors: 12 inches = 1 foot 12.000… in = 1.0000… ft 25 How Many Sig Figs ? 123 m 0.123 m 40506 m 4 9.800 x 10 m 0.07080 m 98000 m 6 bottles 26 Rounding If digit after the last sig fig is >5, increase the last sig fig by 1. 32.6 to 2 sig figs is 33. 314.721 to 4 sig figs is ? 0.001775 to 2 sig figs is ? 9792 to 2 sig figs is ? 27 Sig Figs in Calculations Addition & Subtraction: Sig figs of answer determined by number with fewest digits to right of decimal. 12.52 + 349.0 361.52 28 Addition & Subtraction: Try It! 3.467 + 6.7 = ? Honors: (3.467 x 10-3) + (6.7 x 10-2) = ? 29 Sig Figs in Calculations Multiplication & Division: Sig figs of answer determined by number with the least number of sig figs. 2.4526 8.3 = ? = 0.295493976 = 0.30 30 Multiplication / Division: Try It! (8.2 x 10-3) x (7.25 x 108) = ? (6.234 x 10-5) (4.3 x 10-2) = ? 31 Sig Figs in Calculations With your backpack on, your mass is 72.1 kg. Your mass is 65.42 kg. What is the mass of your backpack? 32 Sig Figs in Calculations How many fluid ounces are there per glass if a 32 oz. soda bottle is divided evenly among 7 glasses? 33 Metric (SI) Units Add 9 3 in 8 + 1 yd 2 ft 3 416 in compared to: Add 16.54 cm + 1.0160 m Which is easier? 34 Metric System Regents Table D Quantity Length Volume Mass Temp Time Energy Units Meter Cubic Meter, Liter Gram, Kilogram Kelvin, Celsius Second Joule 35 Prefixes (Regents Table C) Prefix Symbol Factor 3 10 kilo k -1 deci d 10 -2 centi c 10 -3 milli m 10 -6 micro m 10 e.g. 1 cm = 10-2 m = 0.01 m 36 Prefixes (Regents Table C) Write an equality for the following units: 1 mm = ? m 4.3 cg = ? g 3 kg = ? g 6.9 ms = ? s 37 Metric Length Unit kilometer (km) meter (m) centimeter(cm) millimeter (mm) micrometer (mm) Examples ~5/8 mile ~ yard width of button thickness of dime diameter of cell 38 Metric Volume Volume related to length: (length3 = V) Unit Examples Cubic centimeter Cube of sugar 3 (cm = cc) Liter (L) Quart of milk Milliliter (mL) 20 drops water Note: 1cm3 = 1mL 39 Metric Mass Unit Examples Kilogram (kg) Small textbook Gram (g) Paperclip Milligram (mg) Ten grains of salt 1 mL = 1 cm3 = 1g H2O 40 Density Sink or float? Reading assignment handout. 41 Question ???? Which is heavier: a pound of lead or a pound of feathers ? vs. ? 42 Density mass Density = volume Density of a substance is independent of the mass and volume. Density of 2 kg of Pb is 11.4 Density of 9 kg of Pb is 11.4 3 g/cm 3 g/cm 43 Density Density scale is defined by water. Recall: 3 1 mL = 1 cm = 1g H2O g Thus DH2O = 1.00 3 cm 44 Density Density in g/cm3 at 25oC Au 19.3 Hg 13.5 Pb 11.4 Fe 7.87 Al 2.70 Bone 1.7-2.0 H2O 0.997 H2O 1.00 (4oC) Ice 0.917 (0oC) Gasoline 0.66-0.69 Wood 0.11-1.33 Air 0. 00119 45 Density A plastic ball with a volume of 19.7 3 cm has a mass of 15.8 g. Would this ball sink or float in a container of gasoline? 3 (Density of gasoline is 0.68 g/cm .) 46 Temperature Atoms & molecules are always in motion. Recall: temperature is a measure of the average kinetic energy of atoms & molecules. 47 Temperature Is there a temperature where motion stops ? Yes! absolute zero 48 Temperature Scales Water boils Celsius 100 Water freezes No motion -273 0 0 Kelvin 373 273 (Size of degree is the same) 49 Temperature Scales Converting: Celsius K= Kelvin oC + 273 Regents Table T 50 Temperature Scales K= oC + 273 Convert: •25oC to K •150K to oC What is the difference between the B.P. and F.P. of water in oC & in K? 51 Heat Heat, a form of energy, flows between two objects if they are at different temperatures. Hot Cold 52 Heat Heat (energy) is not temperature (a measurement). Which burns more: spoonful of boiling water or pot of boiling water ? 53 54 Warm-up Which is bigger? 102 or 103 -2 10 Note: 2 10 or -3 10 =1x 2 10 55 Warm-up Express in scientific notation: 0.000745 6,283,000,000 Do the following calculations: 6.2E-4 / 8.1E-3 = 7.1E-2 + 6.0E-3 = Note: 6.2 x 10-4 = 6.2E-4 56 Warm-up What are sig figs? How many sig figs in: 0.090300 m? 42 sandwiches? 57 Warm-up Do the calculation, express in proper scientific notation and sig figs: 5.41cm + .27568 cm = 2.772E-2 cm / 8.1E3 cm = Honors: 5.417E-2 cm + 2.7E-3 cm = 58 Warm-up Do the calculation, express in proper scientific notation and sig figs: 4.61 – 0.3472 = 6.77E-2 * 3.17841E3 = How many meters are in 6.4 mm? 59 Warm-up •How many grams are in 7.9 ng? •What is the relationship between volume in cm3, volume in mL, and mass? 60