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Multiple choice questions Unit III: Synthetic organic polymers 1.Polymer formed by the polymerization of hexamethylene diamine and adipic acid is i)Teflon ii)Nylon 6,10 iii)Nylon 6,6 iv)Bakelite 2.Polymer obtained by the polymerization of only one type of monomer molecule is i)Homopolymer ii)Copolymer iii)Heteropolymer iv)Addition polymer 3.Polymer obtained by the polymerization of two or more different types of monomer molecules is i)Homopolymer ii)Copolymer iii)Heteropolymer iv)Addition polymer 4.Stereoregular polymers are i)Isotactic, syndiotactic, atactic ii)Natural and synthetic iii)Addition and condensation iv)Elastomers, plastics and fibres 5.Compounding converts i)Plastics in to resins ii)Resins in to plastics iii)Vulcanized rubber iv)All the above 6.Polymerisation of tetra fluoro ethylene yields i)PTFE ii)PMMA iii)Butyl rubber iv)Bakelite 7.Plexi glass (PMMA) is obtained by the polymerization of i)Methyl meth acrylate ii)Isobutylene iii)Isocyanate iv)Urethane 8.Teflon is made soft by adding i)Di -iso n –butyl phthalate ii)Quartz iii)Silicate iv)Camphor 1 9.Disproportionation of polymer chain growth yields i)Polymer with longer chain length ii)Two polymers with shorter chain lengths iii)Three Polymers iv)Any of the above is possible 10.Degree of crystallinity i)Decreases Tg value ii)Stabilises Tg value iii)Increases Tg value iv)Does not affect Tg value 11.Mol wt of a polymer usually i)Decreases Tg value ii)Stabilises Tg value iii)Increases Tg value iv)Does not affect Tg value 12.Branching in the polymer chain i)Decreases Tg value ii)Stabilises Tg value iii)Increases Tg value iv)Does not affect Tg value 13.Which of the following polymer is a very good insulator i)Nylon 6,6 ii)Teflon iii)Polyethylene iv)Neoprene 14.Repeating unit present in natural rubber is i)Isoprene ii)Chloroprene iii)Butane iv)Propene 15.Repeating unit present in neoprene rubber is i) Isoprene ii)Chloroprene iii)Butane iv)Propene 16.Polyureathane is formed by the polymerization of i)Isobutylene and isoprene ii)Phenol and formaldehyde iii)Di isocyanate and diol iv)Urethane 17.Bakelite is a polymer of i)Phenol and formaldehyde ii)Urea and formaldehyde iii)2-methyl, 1,3-butadiene iv)Di isocyanate and diol 18.Polymer used as cement to hold electric bulb to hold their metal holders is i)Bakelite ii)Novolac iii)Butyl rubber iv)Polyurethane 19.Polymer used in army weapons is i)Bakelite ii)Teflon iii)Urea-formaldehyde resin iv)None of the above 20.IUPAC name of chloroprene is i)2-chloro-1,3-butadiene ii)2-methyl-1,3-butadiene iii)Isobutene iv)Isobutene and isoprene 21.IUPAC name of isoprene is i)2-chloro-1,3-butadiene ii)2-methyl-1,3-butadiene iii)Isobutene iv)Isobutene and isoprene 22.Conducting polymers can be obtained from the following reaction i)Doping ii)Chlorination iii)Polymerisation iv)Bromination 23.The most suitable oxidizing agent for oxidative doping of polyacetylene is i)Acidified potassium dichromate ii)Iodine vapours iii)Iodine in carbon tetrachloride iv)Sodium naphthalide in THF 24.The most suitable reducing agent for reductive doping of polyacetylene is i)Acidified potassium dichromate ii)Iodine vapours iii)Iodine in carbon tetrachloride iv)Sodium naphthalide in THF 25. Oxidative doping of polymers is i)p-doping ii)n-doping iii)Both i) and ii) iv)None of tha above 26.Following polymer is an organic metal i)Conducting polyacetylene ii)Conducting polyaniline iii)Conducting polythiophene iv)All the conducting polymers 27.Which of the following polymers is used in smart windows i)Conducting polyacetylene ii)Conducting polyaniline iii)Conducting polythiophene iv)All the conducting polymers 28.Commercial name of epoxy resin is i)Epon & Araldite ii)Teflon iii)Plexi glass iv)Novolac 29.Epoxy resin is prepared by the polymerization of i)Bisphenol A ii)Epichlorohydrin iii)Bisphenol A and epichlorohydrin iv)Phenol and formaldehyde 30.Which of the following polymers has higher Tg value i)Teflon ii)Polyethylene iii)PVC iv)Nylon66 31.The polymers used in telecommunication system, air crafts wiring, solar cells is i)Conducting polymers ii)Synthetic rubbers iii)Epoxy resins iv)All the polymers 32.Polymers containing polar groups dissolve in or readily attacked by i)Non polar solvents ii)Polar solvents iii)All the organic solvents iv)Water 33.Polymers containing non polar groups dissolve in/readily attacked by i) Non polar solvents ii)Polar solvents iii)All the organic solvents iv)Water 34.Starch is a polymer of i)α –glucose ii)β-glucose iii)Fructose iv)Galactose 35.Cellulose is a polymer of i) α –glucose ii) β-glucose iii) Fructose iv)Galactose 36.The process of adding plasticizers is called i)Plasticization ii)Polymerisation iii)Condensation iv)None of these 37.Proteins are natural polymers containing i)α- amino acids ii)β-amino acids iii)Both i) and ii) iv)None of the above 38.Bakelite is a thermosetting polymer because i)It consists of 2 different monomer molecules ii)Long linear chain iii)The different chains of Bakelite are held together through strong covalent(Sigma) bonds iv)Reason is not clear 39.Polymer used in the preparation of automobile tyres and tubes is i)Buna-s ii)Polysytrene iii)Neoprene rubber iv)Butyl rubber 40.Excellent substitute for glass is i)PMMA (plxiglass/Lucite) ii)Buna-s iii)Teflon iv)Polyurethane 41.Polymer used in artificial eye parts, airplane cockpit, signal light lens and Televisionscreens is i)PMMA ii)Buna-S iii)Polycarbonate iv)Polyurethane 42.Bullet proof polymer is i)Polycarbonate ii)P-F resin iii)Polyurethane iv)Conducting polymers 43.The polymer which is used for making non stick utensils is i)Polyurethane ii)Bakelite iii)Teflon iv)All the above 44.The function of sulphur in the vulcanization of rubber is i)It decreases the elasticity ii)More ductile iii)Less plastic and non stick iv)All the above 45.Addition polymerization reactions i)Need initiators ii)Acid catalysed reactions iii)Base catalysed reactions iv)Will initiate without initiators 46.Bisphenol A is manufactured by the reaction of i)Phenol and acetone ii)Phenol and aromatic aldehyde iii)Phenol and formaldehyde iv)Phenol and aniline 47.Collodion is i)Cellulose nitrate ii)Cellulose acetate iii)Ethyl and methyl cellulose iv)Cellulose 48.Celluloids are i)Cellulose nitrate ii)Cellulose acetate iii)Ethyl and methyl cellulose iv)Cellulose 49.When P/F is less than 1, the product formed is i)Novolac ii)Bakelite iii)Mixture of Novolac and Bakelite iv)None of the above 50.When P/F is greater than 1, the product formed is i)Novolac ii)Bakelite iii)Mixture of Novolac and Bakelite iv)None of the above 51.Arrange the following polymers in increasing order of their intermolecular forces: Nylon-66, Buna-S, Plythene i)Polythene < Buna-S < Nylon-66 ii)Polythene < Nylon-66 < Buna-S iii)Nylon-66 < Buna-S < Poythene iv)Buna-S < Polythene <Nylon-66 52.Tg value of which of the following polymers is very high: Polyethylene,Polypropylene, PVC, PTFE i)PTFE ii)PVC iii)Polyethylene iv)Polypropylene 53.Colloids are used in i)Emulsion polymerization ii)Bulk polymerization iii)Suspension polymerization iv)Solution polymerization 54.Surfactant/is used in i)Emulsion polymerization ii)Bulk polymerization iii)Suspension polymerization iv)Solution polymerization 55.Preparation of Novolac is an i)Acid catalysed reaction ii)Base catalysed reaction iii)Dibenzoyl peroxide initiates the reaction iv)Any of the above 56. Bakelite preparation is i) Acid catalysed reaction ii) Base catalysed reaction iii) Dibenzoyl peroxide initiates the reaction iv) Any of the above 57. Number of monomer molecules which take part in polymerization is i) Degree of polymerization ii) Molecular weight of polymer iii) Tg of polymer iv) None of the above 58. Tetra fluoro ethylene is the monomer of i) Nylon66 ii) Neoprene iii) Teflon iv) PVC 59. Sulphur is used particularly in i) Manufacture of buna-S ii) Corrosion control iii) Compounding of resin iv) Vulcanisation of rubber 60. The monomer phenol is i) monofunctional ii) bifunctional iii) trifunctional iv) polyfunctional 61. The polymer used as electrodes in rechargeable batteries is i) Conducting polyaniline ii) Teflon iii) Polyacetylene iv) Polyaniline 62. Compounding of resins i) Modifies the properties of polymer ii) Imparts additional properties iii) Helps in polymer processing iv) All the above 63. The polymers used in aerospace components, telecommunication systems, conductivefabrics, photovoltaic cells are i) Teflon ii) Conducting polymers iii) Bakelite & Novolac iv) None of the above 64. Which of the following polymer has ozone resistance i) Butyl rubber ii) Neoprene rubber iii) Natural rubber iv) both i and ii 65. which of the following polymer can hold organic solvents i) Natural rubber ii) butyl rubber iii) polysulphide rubber iv) all the above 66. Polymer used as corrosion control paint is i) PMMA ii) Bakelite iii) Teflon iv) all the above 67. Conducting polyaniline is prepared by the i) Oxidative doping of polyanilne ii) Reductive doping of polyanilne iii) Protonic acid doping of polyaniline iv) all the above 68. The commonly used reagent in protonic acid doping is i) Sulphuric acid & Ammonium sulphate ii) HCl and Ammonium sulphate iii) Sodium naphthalide inTHF iv) Iodine in CCl Answer: 1)iii6) i11) iii16) iii2)i7) i12) i17) i3)ii8) I13) ii18) ii4)i9) ii14) i19) iii5)ii10) iii15) ii20) i21) ii22) i23) iii 24) iv25) i26) ii27) ii28) i29) iv30) i31) i32) ii33) i34) i35) i36) i37) i38) iii39) iv40) i41) i42) i43) iii44) i v45) i46) i47) i48) ii49) i50) ii51) i52) i53) iii54) i55) i56) ii57) i 58) iv59) iv60) iii61) I62) iv63) ii64) iv 65) iii66) iii67) iii68) i