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Collection of Problems about RCL “Millikan’s Experiment” S. Gröber University of Technology Kaiserslautern (Germany) January 2007 Table of Content 0. Suggestions for teaching applications and data of experiment 2 I. Problems about theory 4 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Stokes frictional force Discrete values History of Millikan’s experiment Calculation of values in Millikan’s experiment Model experiment to the Millikan experiment Different types of Millikan’s experiment Selection of oil droplets Acceleration phase of oil droplets Cunningham correction R. A. Millikan 4 4 5 5 5 5 6 6 7 7 II. Problems about experimental setup 8 1. 2. 3. 4. 5. Experimental setup of RCL “Millikan’s Experiment” Observation of oil droplets Generation of oil droplets Control of the electric field in the capacitor Millikan’s original experimental setup 8 8 9 9 10 III. Problems about measurements and data analysis 11 1. 2. 11 11 Performing Millikan’s experiment Evaluation of Millikan’s experiment IV. Solutions to problems I 13 - 21 V. Solutions to problems II 22 - 25 VI. Solution to problems III 26 VII. References 27 1 0. Suggestions for teaching applications and data of experiment 1. Suggestions for teaching applications To consolidate the usage of this RCL we offer a wide and enduring collection of problems: either for differently educated, interested students or thematically problems to all components of the experiment, such as theory (I.), experimental setup (II.), performance and evaluation (III.). From methodological point of view we offer problems of different categories: pure problem solving, planning and performing qualitative pre-experiments to prepare the main one, internet research, students presentations, learning stations within a learning circle etc. The following table is containing topics of all problems, so the teacher is getting a quick survey to the content of each problem. Additionally, we offer suggestions how to implement each problem into a teaching environment. No. Topic Content Teaching application • I.1 Stokes frictional force I.2 Discrete values I.3 History of Millikan’s experiment I.4 I.5 I.6 Calculation of values in Millikan’s experiment Model experiment to the Millikan experiment Different types of Millikan’s experiment • Uniform motion under the influence of Stokes frictional force • Difference between discrete and continuous values • Problem of the existence and proof of the elementary charge When to teach Millikan’s experiment • • Presentation by students or teacher Stations in a learning circle Mathematical-physical relations between magnitudes Determination of microscopically small values • • Exercises to deepen theory Stations in a learning circle • Inspection of the qualitative understanding of Millikan’s experiment • Differentiation of students groups according to their mathematical competence Competition between students groups in calculating • • • • • • • • I.7 Selection of oil droplets • • • I.8 Acceleration phase of oil droplets I.9 Cunningham correction I.10 R. A. Millikan II.1 Experimental set up of RCL Millikan’s experiment Preparation of a more independent experimenting with Millikan’s experiment Introduction of Stokes frictional force Repetition of motion with friction Develop and check hypothesis • • • • • • • • Form analogies between the two classes of experiments Limitations of analogy Handling of a system of equations in the physical context Mathematical transformations Dependence of results in measurements on selected oil droplets Make a difference between statistical and analytical relations Evaluation of Millikan’s data with respect to new insight • • • Introduction of the concept and notion of quantization Preparation of a more independent experimenting with Millikan’s experiment Mini research for advanced students Evaluation of possible acceleration under the action of varying forces • Exact calculation with differential equation Problems for the application of learned, known content in a new context Average free path length and viscosity of gases Validity of Cunningham correction Extreme value of functions • Independent acquisition of new learning context with suited learning materials for students • Millikan as a researcher, as a teacher and as private person • • Presentation by student or teacher Station in a learning circle • Assignment and functions of experimental components • As a problem when experimenting with this RCL for the first time 2 • • II.2 Observation of oil drop- • lets • • • II.3 Generation of oil droplets II.4 Generation and control • of the electric field • • • • II.5 Millikan’s original experimental set up • • III.1 Performing Millikan’s experiment • • • III.2 2. Evaluation of Millikan’s experiment • Difference between dark field and bright field microscopy Difference between Rayleigh and Mie scattering Measurement of distances by ocular and object micrometer Path of optical rays in microscope and teleobjective Evaluation of transfer rate of digital video data • • Static and dynamic pressure in liquids, hydrodynamic paradoxon • Bernoulli equation Evaporation rate of liquids Calculation of electric field strength Charging and discharging a capacitor • Work with overlapping topics Internet search with web quest in student groups Presentation of teacher Problems for the application of learnt, known content in a new context Difference between experimental set up as a demonstration experiment and the original version • Wiring for the charge and discharge of a capacitor Work with overlapping topics Setup and test of a spreadsheet for measuring data Description of performing the experiment Explanation for raising and falling oil droplets Homework for the preparation of measurements Examination of the comprehension of theory Presentation of measured data in a histogram or point diagram Determination of error for the charges according to error propagation rules • • • Homework for the preparation of evaluation of measurements Data of experiment To solve problems assignments of variables and technical data about Millikan’s experiment can be found in the following tables. Variables Mass of oil droplet Radius of oil droplet Stokes frictional force Gravitational force Electric force Buoyancy force Voltage capacitor Raising voltage Falling voltage Floating voltage Electric field strength Raising time Falling time Raising velocity Falling velocity Viscosity of oil Charge of oil droplet Corrected viscosity of air moil r Fs Fg Fe Fb U Urise Ufall Ufloat E trise tfall vrise vfall ηoil Q ηcorr,air Constant values 3 Density of oil droplet ρoil = 1.03 g/cm3 Distance of capacitor plates d = 6 mm Density of air ρair = 1.3 kg/m3 Viscosity of air ηair = 1.81·10-5 Ns/m2 Elementary charge e = 1.6·10-19 C Diameter of capacitor plates D = 8 cm Number of scale units 1 unit ≡ 120 μm Cunningham constant A = 0.864 I. Problems about theory 1. Stokes frictional force The video (download from RCL-website, Material, 2.) is showing a falling glass sphere (ρglass = 2.23 g/cm3, r = 2 mm) in oil (density ρoil = 0.922 g/cm3, viscosity ηoil = 0.09 Ns/m2 of oil made out of sun flowers). a) Plot a qualitatively correct stroboscope picture of the motion of the glass sphere and assign all forces acting on that sphere: Which type of all forces are constant or variable starting with the free fall? Explain, why the glass sphere is falling down with constant velocity shortly after letting off. b) Study the trajectory of the moving glass sphere by means of video analysis. Show that the motion of the glass sphere happens under the action of the Stokes frictional force ( Fs = 6πηoilrv ) and determine all acting forces. c) How one may modify the experiment to demonstrate Fs ~ v? d) How one may modify the experiment to demonstrate Fs ~ r? 2. Discrete values Characteristic of discrete values is that the suited value may not assume any possible value but only certain discrete ones. Three examples from every day life, technique and from mathematics are: staircase (width of steps 20 cm, height of steps 10 cm), soda machine (Cola 1 €, water 0.8 €, mix drink 1.3 €) in Fig. 1 and series of numbers f(n) = 1/n (n ∈ lN). Fig. 1: Discrete or continious? a) Specify which value is discrete in these examples and display the sequence on a numbered line. b) What is the difference of the discretization of the staircase with respect to the other examples? c) How one can technically overcome the discretization in case of the staircase? d) Specify similar examples of every day life, technique and mathematics with continuous values. 4 3. History of Millikan’s experiment Millikan’s experiment is at the end of a series of experiments (Improved method to determine elementary charge from water droplets, laws of electrolysis, determination of specific charge e/me, determination of elementary charge e of oil droplets, hypothesis about atomic character of electricity, determination of elementary charge e of water droplets, particles of electricity are called an „electron“) by several physicists (H. A. Wilson, J. J. Thomson, B. Franklin, M. Faraday, R. A. Millikan, G. J. Stoney, J. S. E. Townsend) since 1750 (1903, 1881, 1909 - 1913, 1897, 1747, 1897, 1833). a) Put this information (serious of experiments, physicist, time) in a temporal table. b) Describe in detail one of these pre-experiments. 4. Calculation of values in Millikan’s experiment Systematic measurements gave the following measured values with technical parameters: density of oil ρoil = 1.03 g/cm3, distance between capacitor plates d = 6 mm, viscosity of air ηair = 1.81·10-5 Ns/m2, applied voltage U = 600 V, time interval for raising trise = 17.4 s and falling tfall = 6.8 s between 5 scale units (1 unit ≡ 120 μm). a) Calculate the values from all these given parameters for the specific kind of Millikan’s experiment used here in the RCL variant. 5. Model experiment to Millikan’s experiment The main components of such a model experiment for Millikan’s experiment are oil, spheres and pieces of certain mass. a) Make a sketch of a possible experimental setup for such a model experiment. b) Put together in a table the analogies and main differences between the real experiment of Millikan and the model experiment. 6. Different types of Millikan’s experiment In the following we study different types of Millikan’s experiment. Buoyancy force and Cunningham correction are not considered: a) What forces are relevant for the motion of the oil droplet? Write down the mathematical dependency between the forces for a constant vector of velocity. b) To describe the direction of forces and motion during a first (index 1) state of motion of the oil droplet by scalars we introduce a vertically upwards directed y-axes. Assignments for oil droplet: Charge Q < 0, velocity v1, radius r, density ρÖl. Assignments for capacitor: distance between plates d, voltage U1, viskosity of air ηair: Write down the scalar equation for the balance of forces. What conditions for U1 and v1 must be fulfilled for the states of motion „floating“, „raising“ and „falling“? 5 c) One needs always two states of motion (1 and 2) of the oil droplet to determine the charge Q of the oil droplet: why? d) In textbooks one can find three types of Millikan’s experiment with state of motion 1/state of motion 2 of the oil droplet: • Floating/Falling without E-field • Raising with E-field/Falling without E-field (used in RCL) • Raising with E-field/Falling with E-field in opposite direction and the same electric field strength Derive for at least one type the formula to determinate the charge Q of the oil droplet. e) The most general type of Millikan’s experiment is „Raising with E-field/Falling with E-field“ at different electric field strengths: Derive the formula for Q. Proof the formula by the choosen special case in d). f) How all formulas for Q must be modified, if one considers either buoyancy and the Cunningham correction? Show why the force of buoyancy can be indeed neglected. g) Why are all types of the experiment belonging to the floating case less suited to determine Q than all others? 7. Selection of oil droplets The histogram (Fig. 2) shows the distribution of relative charges k = Q/e of about n = 230 oil droplets of the Millikan experiment. a) For small values of k the distribution shows discrete values: why is this discrete pattern smeared out for larger values of k? b) Search for a relation between charge and velocity of oil droplets looking up data material in the RCL-website, Analysis, 1. respective theoretical considerations or using the data material itself. c) What is the proper recommendation for the performance of Millikan’s experiment according to the results and experiences of problem a) and b). 8. Acceleration phase of oil droplets Fig. 2: Histogram for absolut frequency h of measured oil droplets versus relativ charge Q/e. Under the action of gravitational and electric forces (buoyancy will be neglected here) oil droplets will be accelerated in air to a final constant velocity vfall (during falling without an electric field) or velocity vrise (during raising with an electric field): 6 a) Explain the existence of such final stationary velocities. b) Estimate the time interval during acceleration of an oil droplet (ρoil = 1.03 g/cm3, r ≈ 0.8 μm, Q = 3e) till it reaches the final constant velocity during falling and raising motion (U = 600 V, d = 6 mm, ηair = 1.81·10-5 Ns/m2). Hint: suppose a constant force in Newton’s axiom acting on the oil droplet. c) The velocity of a spherical body (radius r, density ρ) during falling in a medium (viscosity η) with initial velocity v0 = 0 is given by v(t) = g (1 − e −kt ) k k= 9η : 2r 2ρ Show that v(t) is a solution of the differential equation mv& (t) = mg − 6πηrv (balance of forces). Display a graph of v(t) with the given values in b), determine the time interval for acceleration and explain the difference to result found in b). d) Do we have to consider this acceleration time interval for the determination of Q? 9. Cunningham correction In Millikan’s experiment we have to use a corrected viscosity for the motion of a spherical body (radius r) through a medium (dynamical viscosity η, average free path length λ, Cunningham constant A) ηcorr (r) = η Aλ 1+ r a) What is the average free path length λ in gases? What is the relation between viscosity of a gas and the average free path length λ in that gas? b) Under which real conditions do we have to use instead dynamical viscosity η the corrected one ηcorr for the motion of a body with radius r through a medium? Applying this correction do we increase or decrease the Stokes frictional force? c) Plot ηcorr,air/ηair for air at normal conditions (A = 0.864, ηair = 1.81·10-5 Ns/m2, λair = 68 nm) as a function of radius r of oil droplets. Looking at the formula for ηcorr or at this graph: what is the influence of ηair? 10. R. A. Millikan Millikan (Fig. 3) was a interesting and many-sided person: a) Search for information about Millikan as a researcher, as a private person or as a teacher. Fig. 3: Robert Andrews Millikan (1868 - 1953), (VII.6.) 7 II. Problems about experimental setup 1. Experimental setup of the RCL “Millikan’s Experiment” Fig. 4 shows numbered parts of the RCL “Millikan’s Experiment”. Fig. 4: Pictures of experimental setup (left), control panel (middle), webcam picture and stop watch (right). a) Set up a table with three columns such as number, assignment and its function and fill it up looking at the pictures. 2. Observation of oil droplets a) What is the difference between bright field and dark field illumination? Which one is used in the RCL? b) If light is scattered by oil droplets which kind of scattering exists in the RCL - Rayleigh or Mie scattering? Give a typical example for both kinds of scattering. c) Fig. 5: Webcam and microscope to observe the oil droplets in the RCL. The webcam has a teleobjective with 13.5 cm focal length, the focal length of the microscope objective is 5 cm, the focal length of the ocular is 2.5 cm (Fig. 5): Make a sketch of the optical rays between oil droplets and the CCD chip of the camera. d) How can one measure distances in the μm-range with a microscope? e) In the RCL a bulb of the illumination unit was replaced by a white LED. At the real Millikan experiment a glass container with copper chloride water solution was positioned between arc lamp and capacitor: What do one want to avoid in both cases? Without both improvements one would expect perturbing influences on the determination of charge Q. Which kind of perturbations? f) How many pictures can be transmitted by ISDN (8 kB/s) or by DSL 1000 (128 kB/s) using a compression factor of 20 in JPEG format with a resolution of 320 x 240 pixels and 24 bit colour depth? 8 3. Generation of oil droplets An airbrush compressor is used to blow a pulsed stream of air to the atomizer (Fig. 6), controlled by mouse click to open a magnetic valve. a) Quote and describe an experiment which demonstrates, that the static pressure in flow of liquid or gas is as smaller as the large becomes the velocity of the flowing liquid or gas. b) Explain qualitatively how one can succeed in atomizing the oil into small droplets. c) Which velocity of air vair (ρair = 1.3 kg/m3) must be produced by the airbrush compressor at the glass nozzle (2 cm as distance to the inlet for oil droplets of the capacitor) to atomize the oil (ρoil = 1.03 g/cm3). d) Why one uses oil of high vacuum pumping systems in the Millikan experiment for the oil droplet? 4. Fig. 6: Atomizer in the RCL. Control of the electric field in the capacitor Fig. 7 shows the module and Fig. 8 the circuit to control the electric field in the capacitor (distance between plates d = 6 mm, diameter of plates D = 8 cm). The high voltage power supply (output voltage 0 < Vout < 1 kV, maximum current IA,max = 1 mA) is controlled by the PC via DA converter: a) In which range one can vary the electric field strength? Fig. 7: Module to control the electric field in the capacitor and to steer the blow in of oil droplets into the capacitor. b) How quickly one can recharge the capacitor? c) For what do we need in that circuit the relay? Fig. 8: Wiring circuit to steer the electric field in the capacitor. 9 5. Millikan’s original experimental setup Fig. 9 shows a cut through Millikan’s original apparatus for the determination of the elementary charge: Fig. 9: Schematic drawing of Millikan’s original apparatus (VII.5., p 103). a) Assign in a table the numbers in the sketch to the names of all components including the function of each of the components: arc lamp, toggle switch, pump connections, manometer, water cell, battery, atomizer, chamber, telescope, air condenser, copper chloride cell, x-ray tube, oil tank, isolator, voltmeter, connection bar. Functions: measurement of voltage of capacitor, reverse voltage of capacitor, measurement of pressure in chambers, production of light for illumination, variation of charge of oil droplets, generation of oil droplets, keeping constant temperature, connection to the pump to vary pressure of chamber, observation of oil droplets, absorption of heat radiation, generation of high voltage, generation of a homogeneous electric field, charge and discharge capacitor. b) Describe in a table the functions for the possible positions of component 10 (Fig. 10) to the connections of component 18: Position of component 10 Circuit connection of component 18 Function Fig. 10: Enlargement of component 10. 10 III. Problems about measurements and data analysis 1. Performing Millikan’s experiment a) Establish a spreadsheet table for the following measured values U, trise and tfall and the calculated ones vrise, vfall, r, ηcorr and Q. Control the correctness of the table calculating one final result as an example. b) Write a precisely formulated manual to perform the measurements with this RCL experiment. c) How big is this part of the capacitor observable by the webcam picture? d) After applying the electric field some of the oil droplets are rising, but some of them are falling: what is the reason? How one can separate between both cases during falling? 2. Evaluation of Millikan’s experiment a) Quote two kinds of graphically presenting the measured values in the Millikan experiment. Which are the advantages respective disadvantages of each presentation? b) If the accumulations around Q = ke are clearly separated in the histogram then one can determine the elementary charge (nk is the number of Q values in class k): n1 e= n2 ∑ Qi + ∑ i=1 Qj + ... 2 n1 + n2 + ... j =1 Explain the formula. Determine the elementary charge from own measured values or as an exercise with data from website. c) A function depending on n variables is given in the following form f(x1,x 2,...,xn ) = C ⋅ x1a1 ⋅ x 2a2 ⋅ ... ⋅ xnan . If each variable xi deviates by Δxi than the total deviation Δf is given by 2 2 2 ⎛ Δx ⎞ ⎛ Δx ⎞ ⎛ Δx ⎞ Δf = f(x1,x 2 ,...,xn ) ⋅ ⎜ a1 1 ⎟ + ⎜ a1 2 ⎟ + ... + ⎜ an n ⎟ . x1 ⎠ ⎝ x2 ⎠ xn ⎠ ⎝ ⎝ In the following the absolute error ΔQ and relative error ΔQ/Q of the elementary charge shall be estimated in the specific kind of experimenting of the RCL experiment here. Since the raising and falling velocities are almost equal one can put for simplicity vrise = vfall = v in the formula for the determination of charge Q. One must put v = s/t (trise = tfall = t), where either the falling and raising distances s or the falling and raising time intervals t possess errors. Transform the formula for the definition of Q in the following form f(x1,x 2,...,x n ) = C ⋅ x1a1 ⋅ x 2a2 ⋅ ... ⋅ x nan . 11 Establish a table with respect to the determination of charge Q and determine ΔQ/Q. Some of the deviations Δxi must be estimated or taken from manuals. Value and its abbreviation Unit xi 12 Δxi Δx i xi ⎛ Δx i ⎞ ⎜ ai ⎟ xi ⎠ ⎝ 2 IV. Solutions to problems I 1. Stokes frictional force a) See Fig.11. The only changing term along this distance is the Stokes frictional force Fs. At the time when the glass sphere is released its velocity is v = 0. The sphere starts falling, because the gravitational force Fg is larger than the force due to buoyancy Fb. The sphere will be accelerated till the increasing Stokes frictional force – increasing with increasing velocity during falling – is reaching a dynamical balance of forces. The resulting total force F on sphere is now zero and the ball is falling with constant velocity. b) If the formula for the Stokes frictional force is correct, then the experimentally determined velocity during falling vexp is like the theoretically determined velocity during falling vtheo: with Δs = 10 cm and Δt = 0.833 s from the video we get vexp = 12 cm/s. For vtheo we get Fg = Fs + Fb ⇒ v theo = 2r 2g(ρglass − ρoil ) 9ηoil = 12.6 cm . s Inserting all technical parameters we get for the forces Fs = 0.4 mN, Fg = 0.733 mN and Fb = 0.33 mN. c) Fig. 11: Stroboscopic view of a falling sphere of glass. One must use a set of balls with identical radius r but different density ρ of ball material (different mass m of ball). We measure the radius r and the constant velocity vexp during falling. We can determine the frictional force Fs from the dynamical balance of forces (for vexp = constant) according to Fs = mg − moilg = (m − moil )g = 4 3 πr g(ρ − ρoil ) 3 Alternatively one can use different kinds of oils with different oil densities. This is problematic, because each kind of oil with different density possesses also different viscosity. Unless one is looking for oils with different density but the same viscosity. d) To show Fs ~ r one has to vary the sphere radius r and keep the velocity constant. But increasing r k-times at constant density ρ of balls will increase velocity v quadratically. v = k2 ⋅ 2r 2 g(ρ − ρoil ) 9ηoil So to keep v = constant the difference in densities must be put k2 smaller if the radius is increasing by a factor of k. 13 2. Discrete values a) Staircase, height of steps with respect to horizontal: 20 cm, 40 cm, … Soda machine, costs for beverages: 0.8 €, 1.0 €, 1.3 €, … series 1/n, values for this function: 1, 0.5, 0.25, … . b) The difference between succeeding discrete steps are constant. c) Build up an inclined plane. d) Every day life: time interval for taking a shower. Technique: velocity of a car. Mathematics: values for the function f(x) = x with x ∈ lR. 3. History of Millikan’s experiment a) Year Physicist Development or contribution 1747 B. Franklin Hypothesis about atomic nature of electricity 1833 M. Faraday Laws of electrolysis 1881 G. J. Stoney Particles of electricity are called electron 1897 J. J. Thomson Determination of specific charge e/me 1897 J. S. E. Townsend Determination of e by water droplets 1903 H. A. Wilson Improvement of last technique 1909 - 1913 R. A. Millikan Determination of e by oil droplets b) Links about the history of the electrons (checked 01-15-2010): • http://www.aip.org/history/electron • http://www.egglescliffe.org.uk/physics/particles/electron/electron.html • http://www-istp.gsfc.nasa.gov/Education/whelect.html • http://www.historyofelectronics.com 4. Calculation of values in Millikan’s experiment a) vfall = 8.82·10-5 m/s r = 0.84 μm Q = 3.14·10-19 C moil = 2.55·10-15 kg Fe = 3.14·10-14 N Fs,rise = 0.923·10-14 N. vrise = 3.45·10-5 m/s ηcorr,air = 1.69·10-5 Ns/m2 E = 100000 V/m Fg = 2.5·10-14 N Fs,fall = 2.3·10-14 N 14 5. Model experiment to Millikan’s experiment a) This model experiment is a variation of the Atwood’s machine with weight-force of the sphere Fg,m, with weight-force of mass Fg,M and Stokes frictional force Fs (Fig. 12). In the dynamic balance of forces r r r r Fg,m + Fg,M + Fs = 0 . The difference between the two weight-forces is equivalent to the Stokes frictional force. b) 6. Millikan’s experiment Model experiment Weight-force of oil droplet Weight-force of sphere Electric force Weight-force of mass M Medium air Medium oil Buoyancy can be neglected Buoyancy must be considered Raising (U > Ufloat), floating (U = Ufloat), falling (U < Ufloat) Raising (M > m), floating (M = m), falling (M < m) Stokes frictional force Fs with Cunningham correction Stokes frictional force Fs (Reynolds number Re << 1) Fig. 12: Model experiment to Millikan’s experiment. Different types of Millikan’s experiment r r a) On the oil droplet are acting three forces: Weight force Fg , electric force Fe and r r r Stokes frictional force Fs . At constant velocity the resulting force F = 0 and therer r r r fore Fg + Fe + Fs = 0 . Fig. 13: Balance of forces for different states of motion of oil droplet. b) Fig. 13 shows the direction and r balance of forces for a floating, falling and raising oil droplet. FG < 0, because FG is opposite directed to the y-axis. The scalar equation U U 4 4 − πr 3ρoilg − Q 1 − 6πηair rv1 = 0 ⇔ πr 3ρoilg + Q 1 + 6πηair rv1 = 0 3 d 3 d 15 describes all states of motions of the oil droplet correctly, if we consider some conditions for U1 and v1: • Floating oil droplet: It´s v1 = 0 and Fe > 0. We can define the sign of U1 with the arithmetic operator before QU1/d (Q < 0): 4πr 3ρoilgd U 4 3 πr ρoilg + Q 1 = 0 ⇔ U1 = Ufloat = − > 0. 3 d 3Q Therefore for a electric force in y-direction we have U1 > 0. The voltage Ufloat > 0, when the oil droplet is floating, we call floating voltage. • Raising oil droplet: It´s v1 > 0 and U1 > Ufloat > 0. • Falling oil droplet: It´s v1 < 0 and U1 < Ufloat. We can differentiate between three cases: Falling with electric force in opposite to direction of motion (0 < U1 < Ufloat) Falling without electric force (U1 = 0) Falling with electric force in direction of motion (U1 < 0). c) The radius r of the specific oil droplet cannot be measured. In the respective equations either radius r or both radius r and charge Q are not known. To determine the charge Q we need a system of equations with two equations and to unknown values r and Q. d) As an example we derive the formula for the the type of Millikan’s experiment used in the RCL. During the oil droplet is raising we have U 4 − πr 3ρoilg − Q 1 − 6πηair rv1 = 0 . 3 d During the oil droplet is falling we have 9η v 4 3 4 πr 3ρoilg − πr ρoilg − 6πηair rv 2 = 0 ⇔ 6πηair r = − ⇔ r 2 = − air 2 . 3 3 v2 2ρoilg Inset of this equation in the first equation delivers U 4 πr 3ρoilg v U 4 4 − πr 3ρoilg − Q 1 + v1 = 0 ⇔ πr 3ρoilg( 1 − 1) = Q 1 3 d 3 v2 3 v2 d 9η v v U 4 9η v ⇔ − π ⋅ air 2 ⋅ − air 2 ⋅ ρoilg( 1 − 1) = Q 1 3 2ρoilg 2ρoilg v2 d ⇔Q=− η v 18πd − air 2 ⋅ (v1 − v 2 ) U1 2ρoilg Because of U1 > 0 and v2 < 0 the charge Q < 0. e) For raising (state of motion 1) and falling (state of motion 2) we have U 4 3 πr ρoilg + Q 1 + 6πηair rv1 = 0 3 d U 4 3 πr ρoilg + Q 2 + 6πηair rv 2 = 0 . 3 d Subtraction of the second equation from the first equation delivers 16 Q(U1 − U2 ) Q (U1 − U2 ) + 6πηair r(v1 − v 2 ) = 0 ⇔ r = − . d 6πηair d(v1 − v 2 ) Inset of this equation in the first equation for raising of the oil droplet delivers Q3 (U1 − U2 )3 U Q(U1 − U2 ) 4 v1 = 0 . − πρoilg +Q 1 − 3 3 3 (6πηair d) (v1 − v 2 ) d d(v1 − v 2 ) After division by Q ≠ 0, multiplication by d(v1-v2) and transformations we get 3π2 (6ηair )3 d2 (v1 − v 2 )2 (U2 v1 − v 2U1 ) ηair 3 (U2 v1 − v 2U1 ) ⋅ (v1 − v 2 ) . Q = ⇔ Q = −18πd 4π(U1 − U2 )3 ρoilg 2ρoilg(U1 − U2 )3 2 • Because of U1 > 0 and U2 < 0 is (U1 – U2)3 > 0 • Because of v2 < 0 and U1 > 0 is –v2U1 > 0 • Because of v1 > 0 and v2 < 0 is v1 – v2 > 0 • Because of v1 > 0 is U2v1 > 0 for 0 < U2 < Ufloat and U2v1 < 0 for U2 < 0 Therefore the radicant is positive. Because of Q < 0 we choose the negative sign during extraction. We proof the formula with the simplest type of Millikan’s experiment containing the states of motion „Floating/Falling without E-field“. For floating is v1 = 0 and U1 = Ufloat, for falling is U2 = 0. Therefore we get Q= 18πdηair v 2 Ufloat −ηair v 2 . 2ρoilg Because of v2 < 0 the radicant is positive and Q < 0. The formula is the same as in d) or in textbooks. f) Since ρair is about a factor 1000 smaller than ρoil: Fg − Fb = 4 3 4 πr g(ρoil − ρair ) ≈ πr 3 gρoil = Fg . 3 3 The density of oil must be replaced by ρoil – ρair, because in the balance of forces Fg must be replaced by Fg – Fb. In addition, the viscosity of air must be corrected too, i.e. the frictional force Fs must contain ηcorr,air. g) The velocity v is hardly influenced by changes of the acceleration voltage U: For a typical oil droplet (Q = 2e and r = 1 μm), i.e. the floating condition is hardly to be realized and to be watched. QU 4 3 − πr ρoilg 4 3 QU d 3 πr ρoilg = − 6πηair rv ⇔ v(U) = 3 d 6πηair r μm dv Q = = 0.156 s dU 6πηair rd V A change in voltage by 10 V causes a change in velocity of 1.5 μm/sec. The oil droplet will need about 8 sec moving slightly by 0.1 scale units (0.1 scale unit = 0.1 17 x 120 μm = 12 μm), i.e. the floating condition is hardly to be realized and to be watched. Brownian motion: Because of the thermal motion of air molecules the floating oil droplet is performing a zig-zag motion by the collisions with air molecules. If s is the distance between two changes in direction than Δx may be its projection in an arbitrary direction: for the average of squared projections Δx 2 = kTτ . 3πηr For a temperature T = 300 K, a time interval of observation τ = 8 s between two positions (viscosity ηair = 1.81·10-5 Ns/m2 and radius r = 0.8 μm of oil droplet) we get Δx 2 = 15 μm . The zig-zag motion due to Brownian motion is several times larger than the dimension of this oil droplet. 7. Selection of oil droplets a) Oil droplets with larger charges are moving much faster. Therefore, the error in determining the velocity and therefore in charge Q is increasing. b) The charging of oil droplets by friction is a statistical process similar to the process of charge separations of particles in clouds. Therefore, there is no deterministic condition given for that process. Due to empirical data oil droplets, which are closer together than 0.45 μm, will be charged negatively: in addition one supposes empirically that the amount of charge Q is increasing with increasing radius of oil droplets. This hypothesis is confirmed by the fact that the capacity No. Radius r in 10-7 m Velocity vfall in 10-5 m/s Velocity vrise in 10-5 m/s Charge Q in 10-19 C 1 7.86 7.66 5.30 3.05 2 5.34 3.53 7.16 1.60 3 8.44 8.83 3.50 3.14 4 8.51 8.97 3.26 3.15 5 10.6 13.9 20.1 11.19 6 7.47 6.92 7.83 3.28 7 7.23 6.47 8.12 3.12 8 6.26 4.86 12.8 3.19 9 9.68 11.6 20.1 9.42 10 6.99 6.06 9.07 3.11 12 10 8 Csphere = 4πε0r 6 is increasing with radius r. 4 Using Fig. 14 we can model in a simple linear model the negative charge of an oil droplet (for r > 0.45 μm): 2 Q(r) = 1.823 ⋅ 10 −12 0 0 2 4 6 8 10 12 -7 Radius r in 10 mm Öltröpfchenradius r / 10-7 Fig. 14: Measured charge Q of oil droplets versus radius r of oil droplet. C (r − 0.45 μm) . m 18 We have to distinguish between raising and falling of an oil droplet. The velocity of falling vfall depends on the radius r only. 12 2ρ g 4 3 πr ρoilg = 6πηair rv fall ⇔ v fall = oil r 2 3 9ηair 10 8 An oil droplet with double radius is falling four times as fast. In general, larger oil droplets possess on average also larger charge Q, therefore, all those quickly falling droplets possess larger charge. 6 4 2 0 0 According to empirical data (Fig. 15) the charge Q depends also on the velocity of raising vrise. What do we expect for vrise(Q,r) in such a simple linear model? 5 10 15 20 St eiggeschwindigkeit in um/s Raising velocity vrisevs in μm/s Fig. 15: Measured charge Q of oil droplets versus raising velocity vrise. U 4 3 πr ρoilg = Q rise − 6πηair rv rise ⇔ v rise = 3 d Q Urise 4 3 − πr ρoilg d 3 6πηair r and Q(r) = 1.823 ⋅ 10 −12 C m (r − 0.45 μm) ⇔ r(Q) = 5.485 ⋅ 1011 ⋅ Q + 0.45 μm . m C If we insert both dependencies vrise(Q,r) and r(Q) into the definition equation of the raising velocity vrise we get as graphical dependence vrise(r) in Fig. 16 and vrise(Q) in Fig. 17: vrise in m/s vrise in m/s Fig. 16: Raising velocity vrise versus radius r of oil droplet. Fig. 17: Raising velocity vrise versus charge Q of oil droplet. Because the gravitational force Fg is increasing with radius r larger than the electric force Fe with Q the raising velocity vrise is decreasing again for oil droplets with radius r > 1 μm or Q ~ 6e. c) Since only a few oil droplets in the Millikan experiment are larger than r > 1 μm or possess a charge Q ≥ 6e it is suggested to select only smaller oil droplets to guarantee a possibly accurate determination of charges. 19 25 8. Acceleration phase of oil droplets a) See I.1a. b) In the very beginning of the falling process the resultant acceleration is a(t = 0) = g. The velocity of falling is 2ρ g 4 3 μm πr ρoilg = 6πηair rv fall ⇔ v fall = oil r 2 = 0.8 . 3 9ηair s The time interval of the acceleration phase is Δt fall = v fall = 8 μs . g During raising at the beginning the balance of forces is F = Fe – Fg using the velocity of raising vrise from I.7b: Δt rise c) 4 F πr 3ρoil v rise 2r 2ρoil = = 3 = = 8.1 μs . a 6πηair rF 9ηair The evolution of the falling velocity v(t) is 6πηrv 9η v = g − 2 = g − kv 4 2r ρK ρK πr 3 3 g = g − k (1 − e−kt ) k & = mg − 6πηrv ⇔ v(t) & = g− mv(t) g − ( −k)e−kt k Using all measured values we get for k = 1.23·105 s-1. The time interval Δtfall, till the falling velocity is constant, is ≈ 40 μs (Fig. 18). The time interval, till the falling velocity is about 63 % of the final velocity v∞ = vfall, is about 1/k = 8 μs considering vfall in μm/s 1 g (1 − ) ⋅ = 0.63 ⋅ v ∞ . e k Comparing both results Δtfall ~ 8 μs, Δtfall ~ 40 μs from b) the time interval for acFig. 18: Falling velocity vfall versus time t. celeration is too large in c) than in b), because in c) we used a too high constant gravitational force during the whole phase of acceleration. d) Therefore the acceleration times in the falling and raising phases can be neglected with respect to the reaction times of the user, if an oil droplet changes its direction under the action of an applied voltage. 20 9. Cunningham correction a) In a gas the number of collisions per second of one particle (gas molecule) is proportional to the number density n, to the radius r of particle and to the average velocity of particles v (see VII.1.): Z = 4 2πnr 2 v At ambient conditions (n = NA/Vmol, r ≈ 10-10 m und v ≈ 103 m/s) the number of collisions per second of a gas particle with other ones is ~ 48⋅106. Therefore, the mean free path length λ of one particle between two collisions is λ= v = 210 nm Z The viscosity of a gas is proportional to the mean free path length: η= 1 nmvλ . 3 b) If the radius r is of order of the mean free path length λ one has to correct the viscosity. In our case λ ~ 0.068 μm and r ~ 0.1 μm to 1 μm. Stokes force decreases. c) The (empirical found) Cunningham correction is ηcorr < η if the following inequality holds Aλ > 0 ⇒ ηcorr < η r ηcorr,air/ηair Fig. 19: Factor of correction for viscosity of air versus radius r of oil droplet. with A constant. Fig. 19 shows the dependence between the correction and radius of oil droplet. The Stokes force will be smaller, since the oil droplets may fall down easier between the air molecules. Viscosity η is the limes for infinitely large sphere. 10. R. A. Millikan a) Links to the life of Millikan: • http://nobelprize.org/nobel_prizes/physics/laureates/1923/millikan-bio.html • http://millikan.kegli.net/Millikan.htm • http://scienzapertutti.lnf.infn.it/biografie/millikan-bio_fra.html 21 V. Solutions to problems II 1. Experimental setup of RCL “Millikan’s Experiment” a) 2. No. Assignment Function 1 Microscope To magnify oil droplets 2 Capacitor To produce an electric field 3 Stepper motor To focus on one oil droplet 4 Oil atomizer To generate oil droplets 5 Light source To illuminate oil droplets from aside (dark field) 6 Button To change electric force 7 Button To blow droplets into capacitor 8 Buttons To shift focal plane inside capacitor 9 Buttons To displace horizontally the section of picture 10 Button To turn on or off the electric field 11 Microscope picture Enlarged representation of oil droplets 12 Oil droplet Object under investigation 13 Ocular micrometer To measure distances in the range of μm 14 Stop watch To measure raising time 15 Stop watch To measure falling time Observation of oil droplets a) In bright field illumination light transmitted through an object is collected by the microscope objective. In dark field illumination only the light scattered by an object is collected by the microscope objective. b) We are speaking of Rayleigh scattering, if the dimension d of a scattering object is smaller than the wavelength λ of scattered light (e.g. light scattering by gas molecules, this fact is explaining the blue colour of sky, the red colour of sun rise and sun dawn). We are speaking of Mie scattering if the dimension d of an object is of the same order or larger than the wavelength λ (e.g. scattering by aerosols, by fog (0.01 mm – 0.1 mm) or by rain drops (0.1 mm – 5 mm). In the Millikan experiment the diameter of oil droplets (0.1 μm < 2r < 1 μm) is of the same order as the wavelength (0.4 μm < λ < 0.8 μm) which means this scattering is between the one of Rayleigh or of Mie. c) Optical ray diagram of a microscope and of a telescope (functions). d) We use an ocular micrometer to measure distances in the microscope, which we calibrate by an objective micrometer in the following way (Fig. 20): • Insert ocular micrometer (transparent plate with scale divisions, low part of 22 Fig. 20: Ocular micrometer. Fig. 19) at the focal plane of objective respective at the object plane of the ocular: focussing by means of the ocular lens. • Put object micrometer (scale division of 1 mm for 100 parts i.e. 1 part = 1 μm, upper part of Fig. 20) on object carrier of microscope, focussing by rough and fine drive, than rotate ocular micrometer till it is parallel to objective micrometer. • Count scale units of both objective and ocular micrometer over a maximum wide coinciding distance s. In Fig. 19 m = 20 scale units of the object micrometer represents n = 90 scale units of the ocular micrometer. • Length x of one scale unit of ocular micrometer: s = 20 Skt ⋅ 10 μm 20 μm μm = 90 Skt ⋅ x ⇔ x = = 2,222 scale unit 9 scale unit scale unit e) The heat transfer from the light source by heat radiation to the air in the capacitor will be prevented by the absorption of the heat radiation by copper chloride. Consequence of this heat transfer is convection in the air inside capacitor, which may cause a side drift motion of oil droplets and therefore additional vertical forces on the oil droplets. This side drift motion is influencing the vertical motion of the oil droplet. In that case for a motion with friction the principle of independency is not valid any more. But there is not influence of this side drift motion on the measurement of falling – and raising velocity, because one is measuring only the vertical (i.e. projected) distance of the motion of a droplet in the ocular micrometer. f) Transport of data: x ⋅ 320 ⋅ 240 ⋅ 3 B ⋅ 1 = y B/s 20 For y = 8000 we get α = 0.7 pictures/s, for y = 128 000 we get x = 11.1. 3. Generation of oil droplets a) The vertical tubes are measuring the static pressure p of the liquid (p = ρgh, h height). At the reduced part (cross section) of the horizontal flow tube the static pressure is smaller than elsewhere: since the total pressure p0 is constant everywhere the dynamical pressure p = ρv2/2 is larger at that position. Fig. 21: Static and dynamic pressure in tubes. b) The principle of an atomizer is based on two mechanisms: • According to Bernoulli equation rapidly moving air at the narrow nozzle will produce a lower pressure at the bottom of the vertical tube with respect to atmospheric pressure p0. The atmospheric pressure, therefore, will press the liquid into the vertical tube. • Liquid will be strongly perturbed by the turbulent flow of air, such that the liquid will decay into small droplets. 23 Fig. 22: Atomizer. c) The minimum velocity will be determined for the case that oil has voil = 0 at the upper end of the vertical tube: p0 − p = ρoilgh The air-brush compressor will accelerate the air at rest to a velocity vair at the upper end of the vertical tube. Following Bernoulli p0 = p + ρair v air 2 2 consequently ρair v air 2 = ρoilgh ⇔ v air = 2 2ρoilgh m . = 17.6 ρair s d) The saturation vapour pressure of high vacuum oil at T = 20° C is 10-4 kPa much smaller than the one from water (2.34 kPa). Therefore, the mass of oil droplets will be constant during measurements. 4. Control of the electric field in the capacitor a) Under the assumption of an homogeneous electric field and according to E = U/d the minimum field strength is Emin = 0 V/m and the maximum is Emax ~ 170 000 V/m. b) The capacity of the plate capacitor is πD2 = 7.4 pF . C = ε0 4d The internal resistor of the voltage source is Ri = 1 kV/1 mA = 1 MΩ, the resistor of cables is negligible. To charge a capacitor to the voltage V0 via the resistor R is VC (t) = V0 (1 − e− t / τ ) with characteristic time constant τ = RC = 7.4 μs. The charging time is much smaller than the reaction time of user. The current at the beginning of the charging process is U0/R = 1 mA. c) If we switch off the voltage at the capacitor for the falling process then a high voltage relay guarantees that the capacitor will be short circuited. As a consequence the electric force on the oil droplet disappears immediately, the remaining forces are in a dynamical balance. 24 5. Millikan’s original experimental setup a) No. Assignment Function 1 Atomizer Generation of oil droplets 2 Chamber Space inside capacitor 3 Pinhole Inlet for oil droplets at capacitor 4 Air condenser Production of a homogeneous electric field 5 Isolator Isolation between plates of capacitor 6 Stripe Protection of capacitor space 7 Arc lamp Production of light to illuminate oil droplets 8 Telescope Magnification of oil droplets 9 Battery Production of high voltage 10 Toggle switch Charge and discharge capacitor 11 Water cell Absorption of heat radiation 12 Copper chloride cell Absorption of heat radiation 13 Manometer To measure pressure in chamber 14 Oil tank To keep constant temperature 15 Pump connection Pump connection to chamber pressure 16 X-ray tube Generation of additional charges of oil droplets 17 Voltmeter To measure voltage at capacitor 18 Connection bar Reverse charging of capacitor b) Position of switch of 10 (1 or 2) Connection of electrodes of 18 (e.g. 1-2) Function 1 2 2-3 Discharge capacitor 2 1,2, 3-4 Charge upper plate of capacitor (-) 2 1,3, 2-4 Charge upper plate of capacitor (+) 25 VI. Solutions to problems III 1. Performing Millikan’s experiment a) See I.4a. b) Look up RCL-website, Tasks. c) Approximately 18 scale units x 12 scale units = 2.16 mm x 2.46 mm (with 1 scale unit ≡ 120 μm). d) At given connection of the capacitor with positively charged upper plate of the capacitor only negatively charged droplets will raise, whereas either negatively or positively charged oil droplets will fall down. Increasing voltage negatively charged droplets are falling more slowly than positively charged ones. 2. Evaluation of Millikan’s experiment a) Histogram Point diagram Absolute abundance of measurements versus charge Charge of oil droplets versus number of oil of oil droplets droplets respective no. of measurement Scattering around multiple of elementary charge recog- Quantization (point belonging to Q = ke nizable increase of this scattering with larger Q with k = 1,2,3) recognizable Representation is depending on the width of the class Meaningful representation with already chosen very few data points b) From groups of data with k-multiple of the elementary charge we will get the elementary charge by division with k. From all these values we determine the average. As a result for the web site we get e = 1.58 · 10-19 C. c) According to VII.4: Q = 36πd 3 3 3 − ηair 3 s3 36π − 21 − 21 −1 2 2 2 = g ρ U d ⋅ t s η oil rise air 2 3 2ρoilgUrise t 2 Name of unit Dimension xi Δxi Gravitational acceleration g* Density of oil ρoil Voltage during raising Urise Distance of plates in capacitor d Time interval t Distance s Viscosity ηair m/s2 kg/m3 V m s m Ns/m2 9.8094 1030 600 0.006 8 6·10-4 1.81·10-5 0.0001 0.5 10 0.0005 0.2 1.2·10-5 5·10-7 ⎛ Δx i ⎞ ⎜ ai ⎟ xi ⎠ ⎝ 1·10-5 4.8·10-4 0.0166 0.083 0.025 0.02 0.027 Σ 2.5·10-11 5.78·10-8 2.75·10-4 6.8·10-3 1.4·10-3 9.0·10-4 1.64·10-3 0.011 Σ * for Kaiserslautern, Germany 2 Δx i xi 0.104 Consequently we get ΔQ/Q ≈ 11 % and ΔQ ≈ 0.16·10-19 C. Our value from b) is lying within the error bars 1.6·10-19 C ± 0.16·10-19 C. 26 VII. References Since this collection of problems is translated from German version the literature is due to German sources. Similar literature of * is available in English language. 1. Gobrecht, H. (1974): Bergmann-Schaefer, Lehrbuch der Experimentalphysik, Mechanik-Akustik-Wärme. De Gruyter, Berlin & New York, S. 652. * 2. Millikan, R. A.: On the elementary electrical charge and the Avogadro constant, Physical Review 2 (1913) 2, pp 109-143, http://authors.library.caltech.edu/6438/01/MILpr13b.pdf, 01-07-10. 3. Millikan, R. A. (1924): The Electron – Its isolation and measurement and the determination of some of its properties. University of Chicago Press, Chicago & London. 4. Vogel, D.: Die Auswertung des Millikan-Versuches. PhiS 34 (1996) 3, S. 110-114. 5. Wilke, H.-J. (1987): Historische physikalische Versuche. Aulis, Köln, S. 101-106. * 6. http://physics.hallym.ac.kr/~physics/reference/physicist/frankfurt/gif/phys/millikan.jp g, 01-07-10. 27