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FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Wednesday, January 29, 2003 — 9:15 a.m. to 12:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Part A and Part B–1 Allow 1 credit for each correct response. Part A PartPart B–1B–1 1 . . . . . . 4. . . . . . 11 . . . . . . 3. . . . . . 21 . . . . . .3. . . . . 31 . . . . .1. . . . . . . 41 . . . . .2. . . . . . . 2 . . . . . . 3. . . . . . 12 . . . . . . 2. . . . . . 22 . . . . . .3. . . . . 32 . . . . .1. . . . . . . 42 . . . . .1. . . . . . . 3 . . . . . . 1. . . . . . 13 . . . . . . 2. . . . . . 23 . . . . . .1. . . . . 33 . . . . .4. . . . . . . 43 . . . . .3. . . . . . . 4 . . . . . . 4. . . . . . 14 . . . . . . 2. . . . . . 24 . . . . . .4. . . . . 34 . . . . .3. . . . . . . 44 . . . . .2. . . . . . . 5 . . . . . . 3. . . . . . 15 . . . . . . 3. . . . . . 25 . . . . . .1. . . . . 35 . . . . .2. . . . . . . 45 . . . . .3. . . . . . . 6 . . . . . . 4. . . . . . 16 . . . . . . 4. . . . . . 26 . . . . . .3. . . . . 36 . . . . .3. . . . . . . 46 . . . . .2. . . . . . . 7 . . . . . . 2. . . . . . 17 . . . . . . 4. . . . . . 27 . . . . . .4. . . . . 37 . . . . .1. . . . . . . 47 . . . . .2. . . . . . . 8 . . . . . . 3. . . . . . 18 . . . . . . 4. . . . . . 28 . . . . . .2. . . . . 38 . . . . .1. . . . . . . 48 . . . . .3. . . . . . . 9 . . . . . . 2. . . . . . 19 . . . . . . 1. . . . . . 29 . . . . . .1. . . . . 39 . . . . .4. . . . . . . 49 . . . . .2. . . . . . . 10 . . . . . . 1. . . . . . 20 . . . . . . 1. . . . . . 30 . . . . . .4. . . . . 40 . . . . .4. . . . . . . 50 . . . . .4. . . . . . . [1] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Administering and Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart printed at the end of this Scoring Key and Rating Guide. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided in the scoring key for that administration be used to determine the student’s final score. The chart in this scoring key is usable only for this administration of the examination. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 14 credits for this part. The student must answer all questions in this part. 51 [2] a Allow 1 credit for correctly drawing two different compounds. At least two different particles must be touching in each drawing and there must be different combinations drawn of touching atoms. Acceptable responses include, but are not limited to, these examples: Note: No specific bond angle is necessary. b Allow 1 credit for correctly drawing a mixture of the two kinds of particles drawn in part a. There must be at least one drawing of each particle. Acceptable responses include, but are not limited to, this example: 52 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Lower the temperature to condense ammonia. Place all three gases in water. Ammonia will dissolve (is soluble). distillation [4] PHYSICAL SETTING/CHEMISTRY – continued 53 [1] Voltaic Cell Wire V Voltmeter Wire Salt bridge Zinc strip Electrolyte Copper strip Electrolyte Allow 1 credit for a correct response. All arrows must be drawn in the correct direction from zinc toward copper through the wire. 54 [1] Allow 1 credit for Zn0 → Zn2+ + 2e– or Zn0 – 2e– → Zn2+. Zn instead of Zn0 is acceptable. Indicating states is acceptable but not required for credit. 55 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: migration of ions maintains neutrality prevents polarization 56 [3] a Allow 1 credit for fission. b Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, this example: The mass is converted to energy. c Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: fusion nuclear decay radioactive decay natural transmutation [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 57 [1] Allow 1 credit for a correct response. Pairs of dots and/or Xs or single dashes are acceptable for any shared pair. Acceptable responses include, but are not limited to, these examples: •• H •• N •• H •• H •• H x• N x• H •x H •• — H—N—H H Note: Accept a correct structure in any rotational orientation. 58 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The molecule is symmetrical in shape and/or charge. Electrons are evenly distributed. All polar covalent dipoles cancel — no dipole moments. no dipoles 59 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: NH3 has polar molecules that attract each other. NH3 has an unshared pair of electrons around the center atom. NH3 is capable of hydrogen bonding. unequal distribution of electrons — in strong attraction [6] PHYSICAL SETTING/CHEMISTRY – continued 60 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: KCl — ionic bond; A, B, C — no ionic bonds Atoms do not share electrons when bonding. There is a transfer of electrons from K to Cl. KCl forms by electrostatic attraction. Bonding involves a metal with a nonmetal. 61 [1] Allow 1 credit for a correct response that refers to both saturated and unsaturated compounds. Acceptable responses include, but are not limited to, these examples: Unsaturated hydrocarbons — double or triple bonds (multiple bonds) and saturated hydrocarbons — all single bonds An unsaturated hydrocarbon has at least one multiple covalent bond between carbon atoms, and a saturated hydrocarbon has single covalent bonds between carbon atoms. Unsaturated hydrocarbons have more than one shared pair of electrons between carbon atoms, and saturated hydrocarbons have only one shared pair of electrons between carbon atoms. [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 21 credits for this part. The student must answer all questions in this part. 62 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The atom is mostly empty space. The volume of the atom is mostly unoccupied. 63 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Alpha particles were deflected by the positively charged nucleus. nucleus — charged 64 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The atom has a positively charged nucleus; negative electrons surround the outside. The positive charges are in the nucleus; electrons are not mixed in the nucleus. nucleus smaller than atom 65 [1] Allow 1 credit for a correct response. A reference to solubility and pressure must be in the answer. Acceptable responses include, but are not limited to, this example: Solubility of CO2(g) decreases with a decrease in pressure. Note: Do not allow credit for “Soda goes flat.” [8] PHYSICAL SETTING/CHEMISTRY – continued 66 [1] Allow 1 credit for a correct response. A reference to solubility and temperature must be in the answer. Acceptable responses include, but are not limited to, this example: Solubility decreases as temperature increases. Note: Do not allow credit for “Soda goes flat.” or Temperature [2] a Solubility 67 Temperature Solubility Allow 1 credit for a correctly drawn and labeled set of axes. or Temperature Solubility b Solubility Temperature Allow 1 credit for a line that starts toward the top of the y-axis and goes downward toward the right end of the x-axis. Note: Assume the origin to be zero unless otherwise labeled. 68 [2] Allow 1 credit for 710 (±10). and Allow 1 credit for mm Hg as the unit. 69 [2] Allow 1 credit for 114 (±2). and Allow 1 credit for °C as the unit. [9] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded 70 [2] Allow 1 credit for liquid A. and Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, this example: The higher vapor pressure of liquid A indicates that the intermolecular forces between its molecules are weaker, allowing the molecules to escape more readily to the vapor phase. 71 [2] Allow 1 credit for 12 mL or 12.0 mL. and Allow 1 credit if the setup is correct, but a computational error is made. 72 [2] Allow 1 credit for phenolphthalein or bromthymol blue or litmus. and Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Strong acid and strong base reach an end point at pH = 7. Phenolphthalein goes from colorless to pink after pH = 7. Bromthymol blue (or litmus) reaches an intermediate color around pH = 7. 73 [3] Allow 1 credit for 1.01 or 1.0 or 1. and Allow 1 credit for two significant figures consistent with the student’s calculated answer. and Allow 1 credit for M or moles per liter or an equivalent as the unit. 74 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Multiple trials help to cancel out experimental error in each trial. Each trial involves errors either above or below the true value. Therefore, the average value would contain the least error. Multiple trials ensure better accuracy of results. to correct for inconsistencies between trials (in measurement) [10] Regents Examination in Physical Setting/Chemistry January 2003 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) Raw Scaled Raw Scaled Raw Scaled Raw Scaled Score Score Score Score Score Score Score Score 85 100 63 74 41 60 19 39 84 98 62 73 40 60 18 38 83 97 61 72 39 59 17 36 82 95 60 72 38 58 16 35 81 93 59 71 37 57 15 33 80 92 58 70 36 57 14 31 79 91 57 70 35 56 13 30 78 89 56 69 34 55 12 28 77 88 55 68 33 54 11 26 76 87 54 68 32 54 10 24 75 85 53 67 31 53 9 22 74 84 52 67 30 52 8 20 73 83 51 66 29 51 7 18 72 82 50 66 28 50 6 15 71 81 49 65 27 49 5 13 70 80 48 64 26 48 4 11 69 79 47 64 25 47 3 8 68 78 46 63 24 46 2 5 67 77 45 63 23 44 1 3 66 76 44 62 22 43 0 0 65 75 43 61 21 42 64 75 42 61 20 41 To determine the student’s final examination score, find the student’s total test raw score in the column labeled “Raw Score” and then locate the scaled score that corresponds to that raw score. The scaled score is the student’s final examination score. Enter this score in the space labeled “Final Score” on the student’s answer sheet. [11] Map to Core Curriculum Key Ideas January 2003 Physical Setting/ Chemistry Question Numbers Part A Part B Standard 1 Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Sci. Inq. Key Idea 1 Sci. Inq. Key Idea 2 Sci. Inq. Key Idea 3 Eng. Des. Key Idea 1 8,22 Part C 43 71,73 67 51,57,58,59 62,63,64 39,40 68,69,71,74 Standard 2 Key Idea 1 Key Idea 2 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 45 50 38,47 Standard 7 Key Idea 1 Key Idea 2 Standard 4 Process Skills 33,34,36,37,40,41, 42,44,45,46,48,49, 50,51,52,53,54,55, 56a,61 31,32,38,47,56c Key Idea 3 Key Idea 4 Key Idea 5 65,66,71,72,73 35,39,56b,57,59,60 70 32,34,36,37,40,41, 42,44,45,46,48,49, 50,51,52,53,61 31,33,38,47,56a, 56c 35,39,56b,57,58, 59,60 62,63,64,65,66, 67,71,72,73,74 Standard 4 Key Idea 3 1,2,3,4,5,7,8,9,11,13, 16,18,19,21,22,23,24, 25,26,27,28,30 Key Idea 4 12,17,20 Key Idea 5 6,10,14,15,29 68,69,70 Reference Tables 2002 Edition 3,4,6,7,20 31,37,44,45,46,53 72 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Tuesday, June 24, 2003 — 9:15 a.m. to 12:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part B–1 Part A 1 . . . . . . 1. . . . . . 13 . . . . . . 3. . . . . . 25 . . . . . .3. . . . . 36 . . . . .1. . . . . . . 44 . . . . .3. . . . . . . 2 . . . . . . 3. . . . . . 14 . . . . . . 4. . . . . . 26 . . . . . .3. . . . . 37 . . . . .1. . . . . . . 45 . . . . .4. . . . . . . 3 . . . . . . 4. . . . . . 15 . . . . . . 2. . . . . . 27 . . . . . .1. . . . . 38 . . . . .4. . . . . . . 46 . . . . .1. . . . . . . 4 . . . . . . 3. . . . . . 16 . . . . . . 4. . . . . . 28 . . . . . .2. . . . . 39 . . . . .1. . . . . . . 47 . . . . .1. . . . . . . 5 . . . . . . 2. . . . . . 17 . . . . . . 1. . . . . . 29 . . . . . .2. . . . . 40 . . . . .3. . . . . . . 48 . . . . .3. . . . . . . 6 . . . . . . 3. . . . . . 18 . . . . . . 1. . . . . . 30 . . . . . .4. . . . . 41 . . . . .4. . . . . . . 49 . . . . .4. . . . . . . 7 . . . . . . 4. . . . . . 19 . . . . . . 2. . . . . . 31 . . . . . .3. . . . . 42 . . . . .3. . . . . . . 50 . . . . .2. . . . . . . 8 . . . . . . 1. . . . . . 20 . . . . . . 4. . . . . . 32 . . . . . .1. . . . . 43 . . . . .2. . . . . . . Part B–1 Score 9 . . . . . . 2. . . . . . 21 . . . . . . 4. . . . . . 33 . . . . . .1. . . . . 10 . . . . . . 2. . . . . . 22 . . . . . . 2. . . . . . 34 . . . . . .2. . . . . 11 . . . . . . 3. . . . . . 23 . . . . . . 3. . . . . . 35 . . . . . .1. . . . . 12 . . . . . . 4. . . . . . 24 . . . . . . 4. . . . . . Part A Score [1] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Administering and Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart printed at the end of this Scoring Key and Rating Guide. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided in the scoring key for that administration be used to determine the student’s final score. The chart in this scoring key is usable only for this administration of the examination. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 15 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for 2. 52 [1] Allow 1 credit for Y or 2–8–7–3. 53 [1] Allow 1 credit for Na and Rb. 54 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: same number of valence electrons Group 1 Elements in the same group (family) have similar chemical properties. Both lose one electron when they react. 55 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: C C O H H H C H H C C O C C H H 56 C H H H [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: H OH H H H C C C C H H H H H C C C C OH C C C C OH C C C OH C or Allow 1 credit for a response consistent with the student’s answer to question 55. [4] PHYSICAL SETTING/CHEMISTRY – continued 57 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Cu is less active than hydrogen gas. Zn more reactive Cu is below H2 on the activity series and Zn is above H2. 58 [1] Allow 1 credit for any metal other than Zn, that is above H2 on Table J. Acceptable responses include, but are not limited to, these examples: magnesium or Mg aluminum or Al 59 [2] Allow 1 credit for correctly drawing four particles and one particle. and Allow 1 credit for showing any particles in a gaseous state. Acceptable responses include, but are not limited to, this example: Box B System After Reaction Has Gone to Completion 60 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: gets bigger increases The ion is larger than the atom. 61 [1] Allow 1 credit for –2 or negative. [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 62 [2] a Allow 1 credit for a correct setup. Writing the formula in the setup is not required. Acceptable responses include, but are not limited to, these examples: q = mHf = (25.0 g)(334 J/g) 25.0(334) b Allow 1 credit for 8350 J or 8350 joules. or Allow 1 credit for a response consistent with the student’s setup and that has an appropriate unit. Note: Significant figures do not need to be shown. 63 [1] Allow 1 credit for a correct response. Students must discuss both voltaic and electrolytic cells. Acceptable responses include, but are not limited to, these examples: Voltaic cells produce energy; electrolytic cells consume energy. voltaic changes chemical to electrical, electrolytic opposite Voltaic cells involve spontaneous redox reactions; electrolytic cells involve nonspontaneous redox reactions. voltaic spontaneous/electrolytic not [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 20 credits for this part. The student must answer all questions in this part. 64 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: V P P 65 V [2] a Allow 1 credit for a correct setup. Writing the formula in the setup is not required. Units and significant figures do not need to be shown. Acceptable responses include, but are not limited to, these examples: (6.2 mL)(1.4 atm) = (3.1 mL)(P2) P2 = 6.2 mL(1.4 atm) 3.1 mL The volume is halved so pressure must double. b Allow 1 credit for 2.8. or Allow 1 credit for a response consistent with the student’s setup. Note: Significant figures do not need to be shown. 66 [2] a Allow 1 credit for a correct setup. Writing the formula and/or the unit in the setup is not required. Acceptable responses include, but are not limited to, these examples: MKOH = (0.100 M)(10.01 mL) 5.01 mL MAVA = MBVB (0.100 M)(10.01 mL) = (MB)(5.01 mL) b Allow 1 credit for 0.200. The response must contain three significant figures. or Allow 1 credit for a response containing two or three significant figures consistent with the student’s setup. [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 67 [3] a Allow 1 credit for identifying one experiment. Acceptable responses include, but are not limited to, these examples: gold foil (Rutherford) cathode rays (Thomson) electron bombardment (Moseley) b Allow 1 credit for a description consistent with the experiment chosen by the student. Acceptable responses include, but are not limited to, this example: In the gold-foil experiment, gold foil was bombarded with alpha particles. Some alpha particles were deflected. c Allow 1 credit for stating a conclusion drawn from the experiment chosen by the student. Acceptable responses include, but are not limited to, these examples: The gold-foil experiment shows that an atom is mostly empty space. An atom has a small dense core. An atom has a positively charged center. 68 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: corrosion rates of the waste containers the area’s vulnerability to earthquakes climate changes that increase rainfall 69 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: pollution of fresh water in the area adverse effects on humans, fish, and wildlife Radioactivity would get into the food chain. Groundwater would become contaminated. 70 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The other sites may be in more populated areas so more people would be at risk. Leaving radioactive waste in sites spread around the country would expose more regions to contamination. terrorism 71 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: any response from 150 to 152 5 half-lives [8] PHYSICAL SETTING/CHEMISTRY – continued 72 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The half-life of cesium-137 is short, and the sample would almost be entirely decayed after 10,000 years. The half-life of strontium-90 is short, and the sample would almost be entirely decayed after 10,000 years. 73 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: because water may transport the radioactive materials cause containers to corrode 74 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: concentration of HCl HCl(aq) HCl [HCl] 75 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: temperature surface area of Zn amount of Zn Zn concentration of Zn [Zn] 76 [1] Allow 1 credit for a response with a correct justification. Acceptable responses include, but are not limited to, these examples: rate ↑, more collisions The rate will increase because the higher concentration of HCl will lead to a greater number of collisions. [9] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded – 77 [1] Allow 1 credit for H+ or hydrogen or H3O+ or hydronium or NO3 or nitrate. 78 [1] Allow 1 credit for 5. Significant figures do not need to be shown. 79 [1] Allow 1 credit for yellow. or Allow 1 credit for a response consistent with the student’s answer to question 78. [10] Regents Examination in Physical Setting/Chemistry June 2003 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) Raw Score 85 84 83 82 81 80 79 78 77 76 75 74 73 72 71 70 69 68 67 66 65 64 Scaled Score 100 98 97 95 94 93 91 90 89 87 86 85 84 83 82 81 80 79 78 77 76 75 Raw Score 63 62 61 60 59 58 57 56 55 54 53 52 51 50 49 48 47 46 45 44 43 42 Scaled Score 74 73 72 72 71 70 69 68 68 67 66 66 65 64 63 62 62 61 60 59 59 58 Raw Score 41 40 39 38 37 36 35 34 33 32 31 30 29 28 27 26 25 24 23 22 21 20 Scaled Score 57 56 55 55 54 53 52 51 50 49 48 47 46 45 44 43 42 41 40 38 37 36 Raw Score 19 18 17 16 15 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 Scaled Score 35 33 32 30 29 27 26 24 22 21 19 17 15 13 11 9 7 5 2 0 To determine the student’s final examination score, find the student’s total test raw score in the column labeled “Raw Score” and then locate the scaled score that corresponds to that raw score. The scaled score is the student’s final examination score. Enter this score in the space labeled “Final Score” on the student’s answer sheet. Map to Core Curriculum Key Ideas June 2003 Physical Setting/ Chemistry Question Numbers Part A Part B Standard 1 Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Sci. Inq. Key Idea 1 Sci. Inq. Key Idea 2 Sci. Inq. Key Idea 3 Eng. Des. Key Idea 1 Part C 66b,74,75 54,60,61 67 56 71,72 Standard 2 Key Idea 1 Key Idea 2 40,41 68 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 77 Standard 7 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 69,70,73 Standard 4 Process Skills 36,37,38,41,42, 44,45,46,48,50, 51,52,53,55,57, 58,59,63 39,43,49,62 Key Idea 5 Key Idea 4 Key Idea 5 11,12,13,33,34 2002 Edition 71,72 47 Standard 4 1,2,3,4,5,6,8,9, 36,37,38,42,44, 10,14,15,16,18, 45,46,48,50,51, 19,20,21,23,24, 52,53,54,55,56, 25,26,27,28,29, 57,58,59,63 30,31,32,35 7,17,22 39,43,49,62 Key Idea 3 64,65,66a,76,78, 79 64,65,66,67,74, 75,76,77,78,79 69,70,71,72,73 40,41,47,60,61 Reference Tables 2,7,10,13,14, 36,37,40,41,44, 64,65,66,71,72,79 19,24,26,32 47,48,49,52,53, 54,55,56,57,58, 62 [12] FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Wednesday, August 13, 2003 — 12:30 to 3:30 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part B–1 Part AA Part 1 . . . . . . 1. . . . . . 13 . . . . . . 2. . . . . . 25 . . . . . .4. . . . . 36 . . . . .2. . . . . . . 44 . . . . .3. . . . . . . 2 . . . . . . 4. . . . . . 14 . . . . . . 1. . . . . . 26 . . . . . .3. . . . . 37 . . . . .1. . . . . . . 45 . . . . .2. . . . . . . 3 . . . . . . 1. . . . . . 15 . . . . . . 1. . . . . . 27 . . . . . .1. . . . . 38 . . . . .1. . . . . . . 46 . . . . .3. . . . . . . 4 . . . . . . 3. . . . . . 16 . . . . . . 4. . . . . . 28 . . . . . .4. . . . . 39 . . . . .4. . . . . . . 47 . . . . .2. . . . . . . 5 . . . . . . 1. . . . . . 17 . . . . . . 2. . . . . . 29 . . . . . .3. . . . . 40 . . . . .4. . . . . . . 48 . . . . .1. . . . . . . 6 . . . . . . 3. . . . . . 18 . . . . . . 1. . . . . . 30 . . . . . .4. . . . . 41 . . . . .3. . . . . . . 49 . . . . .4. . . . . . . 7 . . . . . . 2. . . . . . 19 . . . . . . 1. . . . . . 31 . . . . . .4. . . . . 42 . . . . .2. . . . . . . 50 . . . . .3. . . . . . . 8 . . . . . . 1. . . . . . 20 . . . . . . 3. . . . . . 32 . . . . . .3. . . . . 43 . . . . .2. . . . . . . Part B–1 Score 9 . . . . . . 1. . . . . . 21 . . . . . . 2. . . . . . 33 . . . . . .4. . . . . 10 . . . . . . 3. . . . . . 22 . . . . . . 3. . . . . . 34 . . . . . .2. . . . . 11 . . . . . . 2. . . . . . 23 . . . . . . 2. . . . . . 35 . . . . . .2. . . . . 12 . . . . . . 4. . . . . . 24 . . . . . . 4. . . . . . Part A Score [1] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Administering and Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart printed at the end of this Scoring Key and Rating Guide. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided in the scoring key for that administration be used to determine the student’s final score. The chart in this scoring key is usable only for this administration of the examination. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 14 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: lowers activation energy provides an alternate reaction pathway brings particles together forms a different activated complex at lower activation energy 52 [2] Allow 1 credit for showing a peak that is higher than the beginning and the end of the curve. and Allow 1 credit for showing that the end of the curve is higher than the beginning of the curve. Potential Energy Acceptable responses include, but are not limited to, this example: Reaction Coordinate Note: The labeling of the activation energy and/or the potential energy of the reactants and products does not need to be shown. However, if labels are shown, they must be consistent with a correct answer. 53 [1] Allow 1 credit for a correctly balanced equation showing atoms, ions, electrons, and appropriate coefficients. Acceptable responses include, but are not limited to, these examples: Cl2 + 2e– → 2 Cl– Cl2 → 2 Cl– – 2e– C1 + e– → Cl– 54 [1] Allow 1 credit for C6H12O6 enzyme 2 C2H5OH + 2 Note: Allow credit even if the coefficient 1 is written in front of C6H12O6. [4] CO2. PHYSICAL SETTING/CHEMISTRY – continued 55 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: fermentation decomposition redox 57 [1] Allow 1 credit only if all values are correct. Atomic Number Element First Ionization Energy (kJ/mol) 2 He 2372 10 Ne 2081 18 Ar 1521 36 Kr 1351 54 Xe 1170 [2] Allow 1 credit for marking an appropriate scale on the axis labeled “First Ionization Energy.” Note: An appropriate scale is one that allows a trend to be seen. and Allow 1 credit for correctly plotted (± 0.3 grid space) and connected points. Allow credit even if the points are not circled on the graph. or Allow 1 credit for plotted (±0.3 grid space) and connected points that are consistent with the student’s response to question 56. Allow credit even if the points are not circled on the graph. Acceptable responses include, but are not limited to, this example: 3000 First Ionization Energy (kJ/mol) 56 2500 2000 1500 1000 10 20 30 Atomic Number [5] 40 50 [OVER] PHYSICAL SETTING/CHEMISTRY – continued 58 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: As atomic number increases within Group 18, the first ionization energy decreases. decreases or Allow 1 credit for a description that is consistent with the student’s graph in question 57. 59 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: boiling vaporization liquid – vapor equilibrium 60 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: AB CD EF Note: The lines over the letters do not need to be shown. 61 [1] Allow 1 credit for a drawing with particles appearing in the gas phase. Acceptable responses include, but are not limited to, this example: 62 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The potential energy of the particles increases. PE increases. KE remains the same. particles more disordered Particles are spreading farther apart. Intermolecular forces of attraction decrease. [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 21 credits for this part. The student must answer all questions in this part. 63 [2] Allow 2 credits, 1 credit each for H and He or hydrogen and helium. 64 [2] Allow 1 credit for a correct response involving the change from the excited state to the ground state. and Allow 1 credit for a correct response involving the release of energy. Acceptable responses include, but are not limited to, these examples: Excited state to ground state releases energy. energy released — excited to ground An electron absorbs energy and moves to a higher shell (energy level). As the electron returns to a lower shell (energy level), it releases energy in the form of a bright-line spectrum. Note: An accurate drawing or sketch may be used in the student’s explanation. 65 [3] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: (19.91)(10.01) + 80.09(11.01) 100 (.1991)(10.01) + (.8009)(11.01) and Allow 1 credit for 10.81 or for a response that is consistent with the student’s setup. and Allow 1 credit for a response that is consistent with the student’s setup. 66 [2] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, this example: 7.56 – 7.14 × 100 7.14 and Allow 1 credit for a correct response. Significant figures are not needed. Acceptable responses include, but are not limited to, these examples: 5.88 5.9 6 or Allow 1 credit for a response that is consistent with the student’s setup. [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 67 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Entropy increases. more entropy Entropy changes. 68 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: NaCl(s) ions cannot move (are not mobile). no charged particles free to move 69 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: An endothermic process absorbs heat energy. Heat flows from the surroundings to the mixture. heat absorbed by system 70 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: 4He 2 4α 2 Note: Do not allow credit for α. 71 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Emitted particles alter genetic information. change DNA 72 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: both Group 2 metals Radium is a more active metal. similar chemical properties They are both alkaline earth metals. It also has two valence electrons. [8] PHYSICAL SETTING/CHEMISTRY – concluded 73 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: acts as the scintillator It emits visible light in response to ionizing radiation. 74 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Zinc sulfide is not soluble in water. insoluble 75 [1] Allow 1 credit for H3O+ or H+ or hydronium or hydrogen. 76 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: to increase CO2 solubility in H2O to force CO2 into the solution 77 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Very little carbon dioxide will dissolve in water. low solubility 78 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: CO2: nonpolar H2O: polar CO2: symmetrical in shape and charge H2O: asymmetrical in shape and charge or Allow 1 credit for a response that is consistent with the student’s response to question 77. [9] [10] Regents Examination in Physical Setting/Chemistry August 2003 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) Raw Score 85 84 83 82 81 80 79 78 77 76 75 74 73 72 71 70 69 68 67 66 65 64 Scaled Score 100 98 96 94 93 91 90 88 87 85 84 83 81 80 79 78 77 76 75 74 73 72 Raw Score 63 62 61 60 59 58 57 56 55 54 53 52 51 50 49 48 47 46 45 44 43 42 Scaled Score 71 71 70 69 68 68 67 67 66 66 65 64 64 63 62 62 61 61 60 60 59 58 Raw Score 41 40 39 38 37 36 35 34 33 32 31 30 29 28 27 26 25 24 23 22 21 20 Scaled Score 58 57 57 56 55 55 54 53 53 52 51 50 49 48 47 46 45 44 43 42 41 40 Raw Score 19 18 17 16 15 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 Scaled Score 38 37 35 34 32 31 29 27 25 23 21 19 17 15 13 10 8 5 3 0 To determine the student’s final examination score, find the student’s total test raw score in the column labeled “Raw Score” and then locate the scaled score that corresponds to that raw score. The scaled score is the student’s final examination score. Enter this score in the space labeled “Final Score” on the student’s answer sheet. Map to Core Curriculum 2002 Edition [12] FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Wednesday, January 28, 2004 — 9:15 a.m. to 12:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Part A and Part B–1 Allow 1 credit for each correct response. Part A Part B–1 Part B–1 1 . . . . . .2 ...... 12 . . . . . . 3 ...... 23 . . . . . .4. . . . . 32 . . . . .4. . . . . . . 42 . . . . .4. . . . . . . 2 . . . . . .2 ...... 13 . . . . . . 2 ...... 24 . . . . . .2. . . . . 33 . . . . .2. . . . . . . 43 . . . . .3. . . . . . . 3 . . . . . .1 ...... 14 . . . . . . 4 ...... 25 . . . . . .1. . . . . 34 . . . . .1. . . . . . . 44 . . . . .2. . . . . . . 4 . . . . . .4 ...... 15 . . . . . . 3 ...... 26 . . . . . .2. . . . . 35 . . . . .1. . . . . . . 45 . . . . .2. . . . . . . 5 . . . . . .2 ...... 16 . . . . . . 4 ...... 27 . . . . . .3. . . . . 36 . . . . .2. . . . . . . 46 . . . . .1. . . . . . . 6 . . . . . .3 ...... 17 . . . . . . 3 ...... 28 . . . . . .4. . . . . 37 . . . . .3. . . . . . . 47 . . . . .1. . . . . . . 7 . . . . . .3 ...... 18 . . . . . . 3 ...... 29 . . . . . .3. . . . . 38 . . . . .1. . . . . . . 48 . . . . .3. . . . . . . 8 . . . . . .1 ...... 19 . . . . . . 3 ...... 30 . . . . . .1. . . . . 39 . . . . .4. . . . . . . 49 . . . . .2. . . . . . . 9 . . . . . .3 ...... 20 . . . . . . 1 ...... 31 . . . . . .2. . . . . 40 . . . . .1. . . . . . . 50 . . . . .2. . . . . . . 10 . . . . . . 4 ...... 21 . . . . . . 4 ...... 11 . . . . . . 4 ...... 22 . . . . . . 4 ...... Part A Score [1] 41 . . . . .1. . . . . . . Part B–1 Score [OVER] PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Administering and Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart printed at the end of this Scoring Key and Rating Guide. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided in the scoring key for that administration be used to determine the student’s final score. The chart in this scoring key is usable only for this administration of the examination. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 13 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for C5H12(g) + 8 O2(g) → 5 if the coefficient “1” is written in front of C5H12(g). 52 [2] a Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: CO2(g) + 6 H2O(g). Allow credit even 8 O2 5.0 O2 = 6 H2O X H2O 5 moles O2 X moles H2O = 8 6 5 mol O2 × 6 mol H2O 8 mol O2 or Allow 1 credit for a numerical setup consistent with the student’s response to question 51. b Allow 1 credit for 3.75 or 3.8. or Allow 1 credit for a response consistent with the student’s numerical setup for question 52a. 53 [1] Allow 1 credit for at least six correctly listed electronegativities as shown below. Atomic Number Electronegativity 11 0.9 or .9 12 1.3 13 1.6 14 1.9 15 2.2 16 2.6 17 3.2 [4] PHYSICAL SETTING/CHEMISTRY – continued 54 and 55 An example of an acceptable response is shown below. 3.2 3.0 2.8 2.6 Electronegativity 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 11 12 13 14 15 16 17 Atomic Number 54 [1] Allow 1 credit for a correctly scaled y-axis. 55 [1] Allow 1 credit for correctly plotting (±0.3 grid space) and connecting the points. Allow credit even if the points are not circled. 56 [1] Allow 1 credit for KCl or potassium chloride. 57 [1] Allow 1 credit for 90 (±2). 58 [1] Allow 1 credit for 30 (±2). or Allow 1 credit for a response consistent with the student’s answer to question 57. [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 59 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: half-cell 1 Pb left lead 60 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: from the Pb electrode to the Ag electrode left to right cell 1 → cell 2 Note: Allow credit for “right to left” or for its equivalent only if it is consistent with the student’s response to question 59. Do not allow credit for a response that indicates that electrons flow through the salt bridge. 61 [1] Allow 1 credit for Pb(s) → Pb2+(aq) + 2e–. Allow credit even if the labels (s) and (aq) are not included. 62 [1] Allow 1 credit for P or for any other acceptable arrangement of five dots around the element symbol P.. [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 22 credits for this part. The student must answer all questions in this part. 63 [2] Allow 1 credit for A. and Allow 1 credit for D. 64 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Energy is released when an electron falls from a high state (excited) to a low state (ground). excited state to ground state high energy to low energy 65 [1] Allow 1 credit for 3. 66 [1] Allow 1 credit for 2. 67 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: A compound must contain two or more different elements. only 1 kind of atom present 68 [1] Allow 1 credit for esterification or making an ester. 69 [1] Allow 1 credit for alcohol. [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 70 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: H OH H H C C C H H H H H H H H C C O C H H H H OH C C C Note: Do not allow credit if the student has placed the —OH group on an end carbon. 71 [2] Allow 1 credit for indicating 42He or 42α or α on the right side of the arrow. and Allow 1 credit for having mass/charge balanced. Acceptable responses include, but are not limited to, this example: 241Am 95 72 → 42He + 237 93 Np [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: 85Kr undergoes beta decay and 241Am undergoes alpha decay. Decay mode and half-life are different. half-lives different 73 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Radioactivity can be used in medical diagnosis and/or treatment. food irradiation radioactive dating [8] PHYSICAL SETTING/CHEMISTRY – continued 74 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Extensive exposure can make people sick. contamination of environment introduction of radioactive materials into the ecosystem 75 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: 172 172.2 76 [2] a Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: 36 g × 100 172 g 36 x = 172 100 or Allow 1 credit for a numerical setup consistent with the student’s response to question 75. b Allow 1 credit for a correct response. Significant figures do not need to be used. Acceptable responses include, but are not limited to, these examples: 21 20.9 20.93 or Allow 1 credit for a response consistent with the student’s setup. Significant figures do not need to be used. 77 [1] Allow 1 credit for D. 78 [1] Allow 1 credit for C. [9] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded 79 [1] Allow 1 credit for KNO3 or NaCl or NH4Cl or NH4NO3, or potassium nitrate or sodium chloride or ammonium chloride or ammonium nitrate. 80 [1] Allow 1 credit for 7. 81 [1] Allow 1 credit for Ba(OH)2 or Sr(OH)2 or barium hydroxide or strontium hydroxide. Allow credit for just barium or strontium. [10] Regents Examination in Physical Setting/Chemistry January 2004 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) Raw Scaled Raw Scaled Raw Scaled Raw Scaled Score Score Score Score Score Score Score Score 85 100 63 72 41 58 19 39 84 98 62 71 40 58 18 37 83 96 61 70 39 57 17 36 82 95 60 70 38 57 16 34 81 93 59 69 37 56 15 33 80 91 58 68 36 55 14 31 79 90 57 68 35 55 13 29 78 88 56 67 34 54 12 27 77 87 55 67 33 53 11 26 76 85 54 66 32 52 10 24 75 84 53 66 31 51 9 22 74 83 52 65 30 51 8 20 73 82 51 64 29 50 7 17 72 80 50 63 28 49 6 15 71 79 49 63 27 48 5 13 70 78 48 62 26 47 4 10 69 77 47 62 25 46 3 8 68 76 46 61 24 45 2 5 67 75 45 61 23 44 1 3 66 74 44 60 22 42 0 0 65 74 43 60 21 41 64 73 42 59 20 40 To determine the student’s final examination score, find the student’s total test raw score in the column labeled “Raw Score” and then locate the scaled score that corresponds to that raw score. The scaled score is the student’s final examination score. Enter this score in the space labeled “Final Score” on the student’s answer sheet. [11] [OVER] Map to Core Curriculum January 2004 Physical Setting/ Chemistry Question Numbers Key Ideas Part A Standard 1 Math Key Idea 1 Part B 34,39,40,41, 52a,54,55 36,42,57,58 33,45,47,52b Math Key Idea 2 Math Key Idea 3 Sci. Inq. Key Idea 1 Sci. Inq. Key Idea 2 Sci. Inq. Key Idea 3 60 32,35,37,38,43, 44,48,49,51,56, 59 Part C 76a 75,76b 64,67,72 63,68,77,78,79,81 Eng. Des. Key Idea 1 Standard 2 Key Idea 1 Key Idea 2 53 69,72 61 65,66,70,71 80 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 Standard 7 Key Idea 1 Key Idea 2 Key Idea 3 73,74 Standard 4 Process Skills 32,33,34,35,36, 38,39,40,41,42, 43,44,45,48,49, 50,51,52,56,57, 58,59,60,61,62 Key Idea 4 46,47 Key Idea 5 Key Idea 3 Key Idea 4 Key Idea 5 2002 Edition 63,65,66,67,68, 69,70,75 71,77,78 37 Standard 4 1,2,3,4,5,6,8, 11,12,13,14,15, 16,17,18,19,21, 22,23,24,25,26, 27,28,29 32,33,34,35,36, 38,39,40,41,42, 43,44,45,48,49, 50,51,52a, 52b,53,56,57, 58,59,60,61 30 46,47 7,9,10,20,31 37,62 Reference Tables 3,4,6,15,22 33,34,35,37,40, 41,45,47,48,53, 57,58,59 [12] 63,64,65,66,67, 68,69,70,75,76a, 76b,80,81 71,72,73,74,77, 78,79 69,71,72,75,79,81 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Wednesday, June 23, 2004 — 9:15 a.m. to 12:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Visit the site http://www.emsc.nysed.gov/osa/ and select the link “Latest Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and at least one more time before the final scores for the examination are recorded. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . . .4 ...... 12 . . . . . . 4 ...... 23 . . . . . .1. . . . . 34 . . . . . 1. . . . . . . 43 . . . . . 2. . . . . . . 2 . . . . . .3 ...... 13 . . . . . . 3 ...... 24 . . . . . .4. . . . . 35 . . . . . 3. . . . . . . 44 . . . . . 1. . . . . . . 3 . . . . . .1 ...... 14 . . . . . . 1 ...... 25 . . . . . .1. . . . . 36 . . . . . 2. . . . . . . 45 . . . . . 4. . . . . . . 4 . . . . . .3 ...... 15 . . . . . . 2 ...... 26 . . . . . .1. . . . . 37 . . . . . 4. . . . . . . 46 . . . . . 4. . . . . . . 5 . . . . . .2 ...... 16 . . . . . . 3 ...... 27 . . . . . .2. . . . . 38 . . . . . 1. . . . . . . 47 . . . . . 4. . . . . . . 6 . . . . . .3 ...... 17 . . . . . . 4 ...... 28 . . . . . .2. . . . . 39 . . . . . 1. . . . . . . 48 . . . . . 2. . . . . . . 7 . . . . . .2 ...... 18 . . . . . . 4 ...... 29 . . . . . .1. . . . . 40 . . . . . 2. . . . . . . 49 . . . . . 2. . . . . . . 8 . . . . . .2 ...... 19 . . . . . . 3 ...... 30 . . . . . .2. . . . . 41 . . . . . 2. . . . . . . 50 . . . . . 1. . . . . . . 9 . . . . . .4 ...... 20 . . . . . . 3 ...... 31 . . . . . .1. . . . . 42 . . . . . 3. . . . . . . Part B–1 Score 10 . . . . . . 3 ...... 21 . . . . . . 1 ...... 32 . . . . . .1. . . . . 11 . . . . . . 3 ...... 22 . . . . . . 3 ...... 33 . . . . . .3. . . . . [1] 2 1 PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Administering and Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, June 23, 2004. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided in the scoring key for that administration be used to determine the student’s final score. The chart in this scoring key is usable only for this administration of the examination. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 14 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: decomposition analysis redox endothermic electrolysis 52 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: 4 H and 2 O on both sides 4 H = 4 H and 2 O = 2 O same number of each element on both sides 53 [1] Allow 1 credit for 4. 54 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Ag+ + e– → Ag 2 Ag+ + 2e– → 2 Ag 55 [1] Allow 1 credit for Cu(s) + 2 AgNO3(aq) → Cu(NO3)2(aq) + 2 Ag(s). Allow credit even if the coefficient “1” is written in front of Cu(s) and Cu(NO3)2(aq). 56 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: colorless to pink no color to red [4] PHYSICAL SETTING/CHEMISTRY – continued 57 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: (0.30 M)(42.2 mL) 60.0 mL (x)(60) = (.3)(42.2) 58 [1] Allow 1 credit for 2. 59 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Each isotope has a different number of neutrons. different number of neutrons Ne-22 has two more neutrons than Ne-20 and one more neutron than Ne-21. 60 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: (0.909)(19.99) + (0.003)(20.99) + (0.088)(21.99) (90.9%)(19.99) + (0.3%)(20.99) + (8.8%)(21.99) (90.9)(19.99) + (0.3)(20.99) + (8.8)(21.99) 100 61 [1] Allow 1 credit for 20. 62 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: They have the same number of valence electrons. form 1+ ions are located in same group both alkali metals [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 63 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: H H H H H C C C C H Br Br H H Br C C C C Br CH3 CH CH Br Br CH3 CH3CHBr CHBr CH3 64 + [1] Allow 1 credit for+01e or +01β or β or positron. [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 21 credits for this part. The student must answer all questions in this part. 65 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: 8.40 g × 1 mole = 58.3 g 8.4 58.3 66 [1] Allow 1 credit for 0.025. 67 [1] Allow 1 credit for NaHCO3. 68 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Naphthalene has weak intermolecular forces. They are weak. 69 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Naphthalene is nonpolar; water is polar. Nonpolar won’t dissolve in polar. Like dissolves like. 70 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: C10H8 H8C10 [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 71 and 72 An example of a correct response is shown below. Solubility Curve 50 Solute per 100 g of H2O(g) 40 30 20 10 0 10 20 30 40 50 60 70 80 90 100 Temperature (°C) 71 [1] Allow 1 credit for marking an appropriate scale. An appropriate scale is one that allows a trend to be seen. 72 [1] Allow 1 credit for plotting all the points correctly (±0.3 grid space). Plotted points do not need to be circled or connected. 73 [1] Allow 1 credit for 9. 74 [1] Allow 1 credit for a response in the range of 6–8. [8] PHYSICAL SETTING/CHEMISTRY – continued 75 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Particles move slower. The molecules will slow down as the temperature decreases. The average kinetic energy of the particles decreases. decreases 76 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: (100.8 kPa)(52.5 L) (45.6 kPa)(X) = (295 K) (252 K) 52.5 × 252 100.8 × 295 45.6 77 [1] Allow 1 credit for –21. 78 [1] Allow 1 credit for .45 or 0.45. Significant figures do not need to be shown. 79 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Removing CO2 disrupts equilibrium and thus the system must shift to create more CO2 from the H2CO3 in order to restore equilibrium. Equilibrium shifts to the right. H2CO3 decreases to remove the stress of changing the CO2. 80 [1] Allow 1 credit for +4 or 4. 81 [1] Allow 1 credit for a correct response. Brackets do not need to be shown. Acceptable responses include, but are not limited to, this example: [F] – [9] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded 82 [1] Allow 1 credit for SnF2. 83 [1] Allow 1 credit for 1.43. Significant figures do not need to be shown. 84 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The water has a fluoride level of 1.43 ppm, which is below the maximum contaminant level for fluoride, so it is safe to drink. F– below 4 ppm, safe, below max level Safe: 1.43 ppm < 4 ppm or Allow 1 credit for a response consistent with the student’s answer to question 83. 85 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Perform tests under ventilation (fume) hood. Avoid spills. no open-toed shoes [10] The Chart for Determining the Final Examination Score for the June 2004 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, June 23, 2004. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. [11] [OVER] Map to Core Curriculum Key Ideas Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Sci. Inq. Key Idea 1 Sci. Inq. Key Idea 2 Sci. Inq. Key Idea 3 Eng. Des. Key Idea 1 June 2004 Physical Setting/ Chemistry Question Numbers Part A Part B Standard 1 58 Part C 71,72,77,78 52,62 41,49,61 85 67,74,80,82 Standard 2 Key Idea 1 Key Idea 2 41,49 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 Standard 7 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 84 Standard 4 Process Skills 34,35,36,37,38, 42,43,44,45,46, 47,48,50,51,53, 54,55,56,57,59, 60,63 40,49,64 Key Idea 5 Key Idea 3 Standard 4 1,2,3,4,5,6,7,8, 14,16,18,19,20, 21,22,23,24,25, 26,27,28,29,30, 31,33 Key Idea 4 15 Key Idea 5 9,10,11,12,13, 17,32 2002 Edition 39,41 68,81 34,35,36,37,38, 42,43,44,45,46, 47,48,50,51,52, 53,54,55,56,57, 58,59,60,61,62, 63 40,49,64 65,66,67,69,70, 71,72,73,74,75, 76,78,79,80,82, 83,84,85 34,39,41 68,81 Reference Tables 2,4,5,8,10,11, 34,35,37,39,41, 13,23,24,25,26, 48,49,50,54,56, 31 57 [12] 65,66,69,70,73, 74,75,76,79,83 77 67,74,76,77,78, 80,81,82,83 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Tuesday, August 17, 2004 — 12:30 to 3:30 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Visit the site http://www.emsc.nysed.gov/osa/ and select the link “Latest Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and at least one more time before the final scores for the examination are recorded. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . . .2 ...... 12 . . . . . . 4 ...... 23 . . . . . .2. . . . . 34 . . . . . 3. . . . . . . 43 . . . . . 2. . . . . . . 2 . . . . . .4 ...... 13 . . . . . . 3 ...... 24 . . . . . .3. . . . . 35 . . . . . 3. . . . . . . 44 . . . . . 4. . . . . . . 3 . . . . . .3 ...... 14 . . . . . . 1 ...... 25 . . . . . .2. . . . . 36 . . . . . 1. . . . . . . 45 . . . . . 2. . . . . . . 4 . . . . . .1 ...... 15 . . . . . . 2 ...... 26 . . . . . .2. . . . . 37 . . . . . 1. . . . . . . 46 . . . . . 2. . . . . . . 5 . . . . . .4 ...... 16 . . . . . . 4 ...... 27 . . . . . .3. . . . . 38 . . . . . 3. . . . . . . 47 . . . . . 1. . . . . . . 6 . . . . . .3 ...... 17 . . . . . . 2 ...... 28 . . . . . .2. . . . . 39 . . . . . 3. . . . . . . 48 . . . . . 2. . . . . . . 7 . . . . . .3 ...... 18 . . . . . . 3 ...... 29 . . . . . .4. . . . . 40 . . . . . 3. . . . . . . 49 . . . . . 3. . . . . . . 8 . . . . . .4 ...... 19 . . . . . . 4 ...... 30 . . . . . .3. . . . . 41 . . . . . 4. . . . . . . 50 . . . . . 3. . . . . . . 9 . . . . . .3 ...... 20 . . . . . . 4 ...... 31 . . . . . .3. . . . . 42 . . . . . 3. . . . . . . Part B–1 Score 10 . . . . . . 3 ...... 21 . . . . . . 1 ...... 32 . . . . . .2. . . . . 11 . . . . . . 4 ...... 22 . . . . . . 1 ...... 33 . . . . . .2. . . . . [1] 2 1 PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Administering and Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a check mark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Tuesday, August 17, 2004. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided in the scoring key for that administration be used to determine the student’s final score. The chart in this scoring key is usable only for this administration of the examination. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 15 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for Group 13 and Period 4. 52 [1] Allow 1 credit for 16 or 16.0. 53 [1] Allow 1 credit for a correct numerical setup. Units do not need to be shown. Acceptable responses include, but are not limited to, these examples: 1.2 M = 1.2 = 0.50 mole x 0.50 x 0.50 mol × 1L 1.2 mol 1.2 mole .5 mole = 1L x 54 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Both samples are at the same temperature. Samples B and C are both at 273 K (or at 0°C). both at STP 55 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Sample A has only one type of molecule. All particles are the same. not a mixture [4] PHYSICAL SETTING/CHEMISTRY – continued 56 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Sample C represents a diatomic element and a compound. shows an element and a compound mixed = F2 and 57 = HCl [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Particles in sample A show molecules of a compound whereas particles in sample B show two compounds as a mixture. A – compound, B – mixture A – 1 compound, B – 2 compounds 58 and 59 An example of a correct response is shown below. Electronegativity 4 3 2 1 0 10 20 30 40 50 60 Atomic Number 58 [1] Allow 1 credit for marking an appropriate scale. An appropriate scale is one that allows a trend to be seen. 59 [1] Allow 1 credit for plotting all the points correctly (±0.3 grid space). Plotted points do not need to be circled or connected. [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 60 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The difference in electronegativity for the H–F bond is 1.9 and the electronegativity difference for the H–I bond is 0.6. The difference for H–F is greater and therefore H–F is more polar. H–F is more polar because F is more electronegative than I. 61 [1] Allow 1 credit for 96. 62 [1] Allow 1 credit for a correct numerical setup. Units do not need to be shown. Acceptable responses include, but are not limited to, these examples: 11 g × 1 mole 44 g 11 44 63 [1] Allow 1 credit for a correct response. Do not allow credit for answers only citing Reference Table G. Acceptable responses include, but are not limited to, these examples: Increasing the temperature favors the forward, endothermic reaction. Adding heat shifts the reaction to the right. 64 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The rate of dissolving KNO3 is equal to the rate of recrystallizing KNO3. The KNO3 is going into the solution at the same rate it precipitates out of the solution. 65 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: H H H H C C C H H H O C OH O C C C C OH [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 20 credits for this part. The student must answer all questions in this part. [1] Allow 1 credit for Fe2O3 + 3 CO → 2 Fe + 3 CO2. Allow credit even if the coefficient “1” is written in front of Fe2O3. 67 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, this example: Potential Energy 66 Reaction Coordinate 68 [1] Allow 1 credit for +4 or 4. 69 [1] Allow 1 credit for 1535. 70 [1] Allow 1 credit for 18. 71 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: potassium atom 2-8-8-1 and potassium ion 2-8-8 The K+ ion has only three electron shells. 72 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: charge mobility size [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 73 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: polymerization addition polymerization synthesis addition 74 [1] Allow 1 credit for two correct responses. The responses must be two different consumer products. Acceptable responses include, but are not limited to, these examples: synthetic fibers clothing carpeting antifreeze (ethylene glycol) food wrap plastic bottles high-density polyethylene low-density polyethylene 75 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: has a carbon-carbon double bond Two carbons share four electrons. C 76 C [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: 2 Zn anode right [8] PHYSICAL SETTING/CHEMISTRY – continued 77 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, this example: Pb2+ + 2e– → Pb or Allow 1 credit for a response consistent with the student’s answer to question 76. 78 [1] Allow 1 credit for a correct response indicating direction. Acceptable responses include, but are not limited to, these examples: from anode to cathode Zn electrode to Pb electrode to the left from half-cell 2 to half-cell 1 – to + or Allow 1 credit for a response consistent with the student’s answer to question 76. 79 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: insoluble not soluble 80 81 [1] Allow 1 credit for a correct numerical setup. Correct numerical substitutions must be shown for all three brands. Units do not need to be shown. Acceptable responses include, but are not limited to, these examples: X: 25.20 mL 2.00 g Y: 18.65 mL 1.20 g Z: 22.50 mL 1.75 g [1] Allow 1 credit for Y. or Allow 1 credit for a response consistent with the student’s setup for brands X, Y, and Z in question 80. [9] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded 82 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: cause bone tumors damage bone marrow can cause leukemia or anemia radioactive DNA damage death 83 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: 226Ra 88 → 24He + 222 86Rn 226Ra 88 4 → 222 86 Rn + 2α 84 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Radium and calcium are both located in Group 2 on the Periodic Table. same family 2 valence electrons 85 [1] Allow 1 credit for 1600. [10] The Chart for Determining the Final Examination Score for the August 2004 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Tuesday, August 17, 2004. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. [11] [OVER] Map to Core Curriculum Key Ideas Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Sci. Inq. Key Idea 1 Sci. Inq. Key Idea 2 Sci. Inq. Key Idea 3 Eng. Des. Key Idea 1 August 2004 Physical Setting/Chemistry Question Numbers Part A Part B Standard 1 42,50,58,59,60 54 Part C 69,80 80,81 71,75,84 68,85 Standard 2 Key Idea 1 Key Idea 2 79 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 Standard 7 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 74,80,81,82 Standard 4 Process Skills 34,35,36,37,39, 40,44,45,46,47, 48,51,52,53,55, 56,57,61,62,63, 64,65 43,49 Key Idea 5 66,70,73,76, 77,78,83 67,85 38,41 72 34,35,36,37,39, 40,44,45,46,47, 48,50,51,52,53, 55,56,57,58,59, 61,62,63,64,65 42,43,49,54 66,68,72,73, 74,75,76,77, 78,79,80,81, 84 Key Idea 4 Standard 4 1,2,3,4,7,8,9,11, 12,13,15,17,18, 20,21,22,23,24, 25,26,27,28,29, 30,32,33 14,19,31 67,69,82,83,85 Key Idea 5 5,6,9,10,16 38,40,41,60 70,71,72 Key Idea 3 2002 Edition Reference Tables 2,4,7,10,14, 34,35,36,38,39, 27,31,32 40,41,42,44,47, 48,49,50,51,53, 58,59,60,61,62 [12] 68,69,70,75, 79,83,84,85 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Thursday, January 27, 2005 — 9:15 a.m. to 12:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Visit the site http://www.emsc.nysed.gov/osa/ and select the link “Latest Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and at least one more time before the final scores for the examination are recorded. Part A and Part B–1 Allow 1 credit for each correct response. Part A Part B–1 1 . . . . . .1 ...... 11 . . . . . . 1 ...... 21 . . . . . .4. . . . . 31 . . . . . 2. . . . . . . 41 . . . . . 3. . . . . . . 2 . . . . . .3 ...... 12 . . . . . . 4 ...... 22 . . . . . .4. . . . . 32 . . . . . 3. . . . . . . 42 . . . . . 3. . . . . . . 3 . . . . . .1 ...... 13 . . . . . . 4 ...... 23 . . . . . .1. . . . . 33 . . . . . 1. . . . . . . 43 . . . . . 1. . . . . . . 4 . . . . . .1 ...... 14 . . . . . . 2 ...... 24 . . . . . .1. . . . . 34 . . . . . 1. . . . . . . 44 . . . . . 4. . . . . . . 5 . . . . . .2 ...... 15 . . . . . . 2 ...... 25 . . . . . .1. . . . . 35 . . . . . 4. . . . . . . 45 . . . . . 3. . . . . . . 6 . . . . . .2 ...... 16 . . . . . . 4 ...... 26 . . . . . .4. . . . . 36 . . . . . 1. . . . . . . 46 . . . . . 4. . . . . . . 7 . . . . . .3 ...... 17 . . . . . . 2 ...... 27 . . . . . .1. . . . . 37 . . . . . 1. . . . . . . 47 . . . . . 1. . . . . . . 8 . . . . . .4 ...... 18 . . . . . . 4 ...... 28 . . . . . .1. . . . . 38 . . . . . 3. . . . . . . 48 . . . . . 4. . . . . . . 9 . . . . . .2 ...... 19 . . . . . . 4 ...... 29 . . . . . .3. . . . . 39 . . . . . 1. . . . . . . 49 . . . . . 2. . . . . . . 10 . . . . . . 4 ...... 20 . . . . . . 3 ...... 30 . . . . . .1. . . . . 40 . . . 3. . . . . . . 50 . . . . . 4. . . . . . . Part A Score [1] P B 1S PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Administering and Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, January 27, 2005. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 15 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: S sulfur 52 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: CO2 is symmetrical. CO2 has an even distribution of charge. CO2 is linear with O at each end. 53 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The electronegativity difference in a carbon-oxygen bond is greater than the electronegativity difference in a fluorine-fluorine bond. The EN difference for C and O is 0.9 and the EN difference for F and F is 0. 54 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: remains the same It does not change. 55 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: DE is longer than BC . more time to boil than to melt [4] PHYSICAL SETTING/CHEMISTRY – continued 56 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: C2H2 C2H2(g) 57 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: 3 three 58 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Arrow 2 gets shorter. The activation energy would be lower. The peak of the curve is lower. 59 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: H H H H C C C H H C C C H H C C [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 60 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, this example: 2-chlorobutane 61 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: ester esters 62 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: alkene alkenes CnH2n olefins 63 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: (1.4)(15.40) 22.10 (1.4 M)(15.40 mL) = MB(22.10 mL) (1.4)(15.40) = X(22.10) 64 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Multiple trials improve precision of results. to see if results are repeatable more trials, less error 65 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: 14.46 14.5 14 [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 20 credits for this part. The student must answer all questions in this part. 66 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: (12.00)(0.9893) + (13.00)(0.0107) (12.00)(98.93) + (13.00)(1.07) 100 67 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Carbon-12 has six neutrons and carbon-13 has seven neutrons. Carbon-13 has one more neutron than carbon-12. C-12 has 6n; C-13 has 7n. 68 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: dinitrogen pentoxide nitrogen(V) oxide 69 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, this example: 32 46 × 100 [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 70 and 71 An example of an acceptable response is shown below. Change in Temperature During the Dissolving of a Solid 50 Temperature (°C) 40 30 20 10 0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Time (min) 70 [1] Allow 1 credit for marking an appropriate scale on the axis labeled “Temperature (°C).” An appropriate scale is one that allows a trend to be seen. 71 [1] Allow 1 credit for plotting six or seven points correctly (±0.3 grid space). Plotted points do not need to be circled or connected. [8] PHYSICAL SETTING/CHEMISTRY – continued 72 [2] a Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: The data show an increase in temperature, which indicates an exothermic reaction. solution temperature goes up, exothermic b Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Table I shows that ∆H is negative for NaOH and LiBr, which indicates an exothermic reaction. ∆H is negative for both. NaOH: ∆H = – 44.51 kJ/mol 73 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Heat is transferred from the copper to the water. Heat flows from the hotter object to the cooler object. copper heat → water [9] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 74 [1] Allow 1 credit if all values are correctly placed in the data table as shown below. Data Table Data (units are given) Quantity Measured Mass of copper 75 50.0 or 50 g Temperature of hot copper 100.0 or 100°C Mass of H2O in calorimeter 100.0 or 100 g Initial temperature of H2O in calorimeter 23.2°C Final temperature of H2O and copper 26.3°C [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: q = (100.0 g) (4.18 J/g•°C) (3.1°C) (100)(4.18) (26.3-23.2) or Allow 1 credit for a setup consistent with the student’s data in question 74. 76 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: heat lost to surroundings heat absorbed by the thermometer heat absorbed by the calorimeter 77 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Both 2-propanol and water are polar. 2-propanol has an uneven distribution of charge. —OH functional group is polar. Like dissolves like. [10] PHYSICAL SETTING/CHEMISTRY – continued 78 [1] Allow 1 credit for a correct response. Significant figures do not need to be shown. Acceptable responses include, but are not limited to, these examples: 62 62.06864 62.1 79 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to, these examples: 10.0 M = x mol 2.50 L (2.5) (10) 80 [1] Allow 1 credit for a correct response. The half-reaction must include electrons. Acceptable responses include, but are not limited to, these examples: Cu → Cu2+ + 2e– Cu – 2e– → Cu2+ 81 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Iron is a more active metal. Fe above Cu Iron metal loses electrons more easily than copper metal. copper less active 82 83 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: 137Cs 55 → –10 e + 137 56Ba 137Cs 55 → –10 + 137 56Ba [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: one hundred 100 [11] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded 84 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to, these examples: Iodine-131 would decay faster. Iodine has a much shorter half-life. Most of the I-131 would be gone. [12] The Chart for Determining the Final Examination Score for the January 2005 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, January 27, 2005. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. [13] Map to Core Curriculum 66,67,68,69,70,71, [14] FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Wednesday, June 22, 2005 — 1:15 to 4:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Visit the site http://www.emsc.nysed.gov/osa/ and select the link “Latest Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and at least one more time before the final scores for the examination are recorded. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . .3 ....... 12 . . . . . 1 ....... 23 . . . . .2. . . . . . 34 . . . . . 4. . . . . . . 43 . . . . . 3. . . . . . . 2 . . . . .4 ....... 13 . . . . . 2 ....... 24 . . . . .3. . . . . . 35 . . . . . 3. . . . . . . 44 . . . . . 1. . . . . . . 3 . . . . .1 ....... 14 . . . . . 1 ....... 25 . . . . .4. . . . . . 36 . . . . . 1. . . . . . . 45 . . . . . 4. . . . . . . 4 . . . . .4 ....... 15 . . . . . 2 ....... 26 . . . . .3. . . . . . 37 . . . . . 2. . . . . . . 46 . . . . . 1. . . . . . . 5 . . . . .3 ....... 16 . . . . . 1 ....... 27 . . . . .3. . . . . . 38 . . . . . 3. . . . . . . 47 . . . . . 2. . . . . . . 6 . . . . .4 ....... 17 . . . . . 2 ....... 28 . . . . .1. . . . . . 39 . . . . . 2. . . . . . . 48 . . . . . 4. . . . . . . 7 . . . . .1 ....... 18 . . . . . 3 ....... 29 . . . . .3. . . . . . 40 . . . . . 3. . . . . . . 49 . . . . . 2. . . . . . . 8 . . . . .4 ....... 19 . . . . . 2 ....... 30 . . . . .2. . . . . . 41 . . . . . 1. . . . . . . 50 . . . . . 2. . . . . . . 9 . . . . .1 ....... 20 . . . . . 2 ....... 31 . . . . .4. . . . . . 42 . . . . . 1. . . . . . . Part B–12 Score 10 . . . . . 4 ....... 21 . . . . . 1 ....... 32 . . . . .3. . . . . . 11 . . . . . 1 ....... 22 . . . . . 3 ....... 33 . . . . .2. . . . . . [1] 1 PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Administering and Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, June 22, 2005. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 15 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for 2 or two. 52 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: Mg-26 nucleus 2 2 53 8 7 1 1 3 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: Germanium atoms and silicon atoms both have the same number of valence electrons. _ 4 valence e in each same number of valence electrons 54 [1] Allow 1 credit for 6.0 or 6 or six. Significant figures do not need to be shown. [4] PHYSICAL SETTING/CHEMISTRY – continued 55 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: CI CI CI–CI 56 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: The sodium atom transfers its one valence electron to the chlorine atom. Na CI Metal loses e– to nonmetal. [2] Allow a maximum of 2 credits, allocated as follows: Allow 1 credit for showing a peak that is higher than the beginning and the end of the curve. and Allow 1 credit for showing that the PE of products is lower than the PE of reactants. Acceptable responses include, but are not limited to: Potential Energy 57 2NO2(g) + 7H2(g) Reaction Coordinate [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 58 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: An increase in temperature favors the endothermic (reverse) reaction, consuming more NH3(g). temperature ↑, reaction shifts left 59 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: addition chlorination halogenation redox synthesis 60 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: H H H H H C C C C H Cl Cl H H CI C C C C Cl 61 [1] Allow 1 credit for all three correct responses shown below. Element Number of Protons Number of Neutrons Mass Number Nuclide C 6 6 12 C-12 N 7 9 16 N-16 Ne 10 9 19 Ne-19 or S 16 16 32 S-32 [6] 19 Ne PHYSICAL SETTING/CHEMISTRY – continued 62 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: The neutron-to-proton ratio causes the nuclide to be stable. The nuclide has an equal number of neutrons and protons. because of neutron-proton ratio 63 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: 9:7 9 7 64 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: 0 –1e + 168 O – β + 168 O [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 20 credits for this part. The student must answer all questions in this part. 65 [2] Allow a maximum of 2 credits, 1 credit for each correct conclusion. Acceptable conclusions include, but are not limited to: The nucleus is small. The nucleus is positively charged. The atom is mostly empty space. The nucleus is dense. 66 and 67 An example of an acceptable response is shown below. Heating Curve Temperature (°C) 70 60 50 40 30 20 10 0 1 2 3 4 5 6 7 8 9 10 11 12 Time (min) 66 [1] Allow 1 credit for marking an appropriate scale. An appropriate scale is one that allows a trend to be seen. 67 [1] Allow 1 credit for plotting all the points correctly (±0.3 grid space). Plotted points do not need to be circled or connected. 68 [1] Allow 1 credit for 53°C. [8] PHYSICAL SETTING/CHEMISTRY – continued 69 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: The temperature of the substance is increasing. temperature ↑ positive slope for this section of graph 70 [1] Allow 1 credit for 915 J. Significant figures do not need to be shown. 71 [1] Allow 1 credit for 12 mol or 12.0 mol or twelve mol. Significant figures do not need to be shown. 72 [1] Allow 1 credit for the symbol or name of one of the following metals from Reference Table J: 73 Li Ba Rb Sr K Ca Cs Na [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: The salt bridge allows ions to flow between the half-cells. maintains electrical neutrality prevents polarization 74 [1] Allow 1 credit for 2 HNO3 + Ca(OH)2 → Ca(NO3)2 + 2 H2O. Allow credit even if the coefficient 1 is written in front of Ca(OH)2 and Ca(NO3)2. 75 [1] Allow 1 credit for 6.0 or 6 or six. Significant figures do not need to be shown. 76 [1] Allow 1 credit for a correct response. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 0.0033 M 3.25 × 10–3 M 77 [1] Allow 1 credit for 0.500 mol. Significant figures do not need to be shown. [9] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded 78 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: Equal volumes of two gases at the same temperature and pressure contain equal number of particles. both gases — same conditions 79 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: (1.0 atm)(12.3 L) (P )(12.3 L) = 2 (300 K) (450 K) 1 x = 300 450 450 300 80 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: As the number of carbon atoms in these molecules increases, the boiling point increases. carbon atoms ↓, boiling point ↓ 81 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: The intermolecular forces are weaker for molecules that have fewer carbon atoms. greater number of carbon atoms, stronger intermolecular forces 82 [1] Allow 1 credit for a correct response. Acceptable responses include, but are not limited to: methane ethane propane methyl propane butane 83 [1] Allow 1 credit for 18 or eighteen. [10] The Chart for Determining the Final Examination Score for the June 2005 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, June 22, 2005. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. [11] Map to Core Curriculum Key Ideas Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Sci. Inq. Key Idea 1 Sci. Inq. Key Idea 2 Sci. Inq. Key Idea 3 June 2005Physical Setting/ Chemistry Question Numbers Part A Part B Standard 1 63 39,42 56,62 36,38,43,45,53, 57,61 Part C 66,67,68,79 81 78 78 65,72,80,82,83 Eng. Des. Key Idea 1 Standard 2 Key Idea 1 Key Idea 2 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 52 75 58 Standard 7 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Standard 4 Process Skills 34,35,37,41,47, 71,73,74,76,77,79 48,49,50,51,52, 53,54,58,59,60, 64 68,69,70 44,57 Key Idea 5 40,46,55 Standard 4 1,2,3,4,5,6,7,9, 10,13,14,15,16, 18,19,20,21,22, 23,24,25,26,27, 28,31,33 34,35,36,37,38, 39,41,42,43,45, 47,48,49,50,51, 52,53,54,58,59, 60,61,62,63 65,71,72,73,74, 75,76,77,78,79, 80,82,83 Key Idea 4 17,29,31,32 44,57,64 66,67,68,69,70 Key Idea 5 8,11,12,23,30 34,40,46,55,56 81 Key Idea 3 2002 Edition Reference Tables 2,3,4,5,7,9,10, 34,35,36,38,39, 11,12,14,21,22, 40,41,42,44,47, 23,24,25,27,29, 48,50,51,53,55, 30,31 56,60,61,63,64 [12] 65,70,72,76,79, 82,83 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Tuesday, August 16, 2005 — 12:30 to 3:30 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Visit the site http://www.emsc.nysed.gov/osa/ and select the link “Latest Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and at least one more time before the final scores for the examination are recorded. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . . .2. . . . . . 11 . . . . . .1. . . . . . 21 . . . . . 4. . . . . . 31 . . . . . 4. . . . . . . 41 . . . . . 3. . . . . . . 2 . . . . . .2. . . . . . 12 . . . . . .2. . . . . . 22 . . . . . 1. . . . . . 32 . . . . . 4. . . . . . . 42 . . . . . 4. . . . . . . 3 . . . . . .4. . . . . . 13 . . . . . .4. . . . . . 23 . . . . . 1. . . . . . 33 . . . . . 1. . . . . . . 43 . . . . . 4. . . . . . . 4 . . . . . .2. . . . . . 14 . . . . . .3. . . . . . 24 . . . . . 4. . . . . . 34 . . . . . 3. . . . . . . 44 . . . . . 2. . . . . . . 5 . . . . . .4. . . . . . 15 . . . . . .2. . . . . . 25 . . . . . 4. . . . . . 35 . . . . . 4. . . . . . . 45 . . . . . 4. . . . . . . 6 . . . . . .1. . . . . . 16 . . . . . .1. . . . . . 26 . . . . . 3. . . . . . 36 . . . . . 2. . . . . . . 46 . . . . . 4. . . . . . . 7 . . . . . .4. . . . . . 17 . . . . . .3. . . . . . 27 . . . . . 3. . . . . . 37 . . . . . 3. . . . . . . 47 . . . . . 2. . . . . . . 8 . . . . . .2. . . . . . 18 . . . . . .3. . . . . . 28 . . . . . 4. . . . . . 38 . . . . . 4. . . . . . . 48 . . . . . 2. . . . . . . 9 . . . . . .1. . . . . . 19 . . . . . .2. . . . . . 29 . . . . . 1. . . . . . 39 . . . . . 1. . . . . . . 49 . . . . . 1. . . . . . . 10 . . . . . .3. . . . . . 20 . . . . . .1. . . . . . 30 . . . . . 3. . . . . . 40 . . . . . 1. . . . . . . 50 . . . . . 4. . . . . . . [1] PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Tuesday, August 16, 2005. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 17 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: 6(12.0) + 12(1.0) + 6(16.0) 6(12) + 12(1) + 6(16) 52 [1] Allow 1 credit for CH2O. The order of the elements can vary. 53 [1] Allow 1 credit for +80 kJ or 80 kJ. 54 [1] Allow 1 credit for +100 kJ or 100 kJ. 55 [1] Allow 1 credit. Acceptable responses include, but are not limited to: A catalyst provides an alternate reaction pathway that has a lower activation energy than an uncatalyzed reaction. A catalyst speeds up the reaction. lower activation energy 56 [1] Allow 1 credit. Examples of 1-Credit Responses H O H H C C C H H H C C O C [4] PHYSICAL SETTING/CHEMISTRY – continued 57 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As the temperature increases, more molecules have enough energy to escape the liquid phase. 58 [1] Allow 1 credit for 45°C (±2). 59 [1] Allow 1 credit for 18. 60 [1] Allow 1 credit for 1 or one. 61 [1] Allow 1 credit. Acceptable responses include, but are not limited to: same number of protons, different number of neutrons K-37 has fewer neutrons than K-42. same element; different number of neutrons 62 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: V2 = (20.0 mL)(101.3 kPa)(283 K) (94.6 kPa)(297 K) (101.3)(20.0) (94.6)V2 = 297 283 63 [1] Allow 1 credit. The angle of atom arrangements may vary. Examples of 1-Credit Responses CI P CI CI CI CI P CI [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 64 [1] Allow 1 credit for marking an appropriate linear scale. An appropriate scale is one that allows a trend to be seen. 65 [1] Allow 1 credit for plotting all the points correctly (±0.3 grid space). Plotted points do not need to be circled or connected. 64 and 65 Example of a 2-Credit Graph for Questions 64 and 65 First Ionization Energy Versus Atomic Number of Selected Elements First Ionization Energy (kJ/mol) 520 500 480 460 440 420 400 380 360 3 7 11 15 19 23 27 31 35 39 43 47 51 55 Atomic Number 66 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As atomic number increases, first ionization energy decreases. Ionization energy decreases. 67 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As atomic radius increases, valence electrons are more easily removed. The force of attraction between the nucleus and the valence electrons decreases down the group. cesium has more shells, easier to remove electrons [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 18 credits for this part. The student must answer all questions in this part. NaN3(s) → 2 68 [1] Allow 1 credit for 2 Na(s) + 3 N2(g). 69 [1] Allow 1 credit. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 0.800 mol 70 [1] Allow 1 credit. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 62.5 g 71 [1] Allow 1 credit. Acceptable responses include, but are not limited to: conducts heat high melting point It is malleable. 72 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The aqueous solution has mobile ions. Charged particles can move in water. 73 [1] Allow 1 credit for +2 or 2 or two. 74 [1] Allow 1 credit. Acceptable responses include, but are not limited to: negative electrode cathode one on the right [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 75 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Electrolytic cells require energy. The battery forces the nonspontaneous reaction to occur. 76 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Na+ + e– → Na 2Na+ + 2e– → 2Na 77 [1] Allow 1 credit for 18.21 mL. 78 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: MA = (3.00 M)(18.21 mL) 25.00 mL MA(25) = (3)(18.21) or Allow 1 credit for a numerical setup consistent with the student’s response to question 77. 79 [1] Allow 1 credit for 3 or three. 80 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Stream A has more hydronium ions. Stream B has a lower concentration. A is higher. 100 times higher 81 [1] Allow 1 credit for yellow. [8] PHYSICAL SETTING/CHEMISTRY – concluded 82 [1] Allow 1 credit. Also allow credit for a correctly written chemical formula of an acceptable compound. Acceptable responses include, but are not limited to: sodium hydroxide lime NH3 any base 83 [1] Allow 1 credit for 147 N. 84 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The half-life of N-16 is too short. decays too fast Too little N-16 remains in the sample. 85 [1] Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: 17 190 y 3(5730) y [9] The Chart for Determining the Final Examination Score for the August 2005 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Tuesday, August 16, 2005. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. [11] Map to Core Curriculum Key Ideas August 2005 Physical Setting/ Chemistry Question Numbers Part A Part B Standard 1 Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Sci. Inq. Key Idea 1 Sci. Inq. Key Idea 2 Sci. Inq. Key Idea 3 Eng. Des. Key Idea 1 41,58,64,65 Part C 70,78,79 31,36,41 61 50,58 73,74,82,84 Standard 2 Key Idea 1 Key Idea 2 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 80 58 Standard 7 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 Key Idea 3 Standard 4 Process Skills 32,33,34,35,37, 38,39,40,41,43, 45,46,47,48,49, 51,52,56,59,60, 61,62,66,67 44,53,54,55,57 68,69,71,72,75, 76,77,78,81 83,85 42,57,58,63 Standard 4 1,2,3,4,5,6,7,8, 9,10,12,17,18, 19,20,21,22,23, 24,25,26,27,28, 30 31,32,33,34,35, 36,37,38,39,40, 41,43,45,46,47, 48,49,50,51,52, 56,59,60,61,62, 64,65,66,67 68,69,70,71,72, 73,74,75,76,77, 78,79,80,81,82 Key Idea 4 16,29 44,53,54,55,57 83,84,85 Key Idea 5 7,11,13,14,15 42,58,63 72 2002 Edition Reference Tables 1,2,4,6,7,8,9, 31,32,33,34,35, 19,20,28 36,39,42,43,44, 47,48,49,50,51, 56,57,58,59,60, 61,62,63 [12] 73,76,78,81,82, 83,84,85 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Thursday, January 26, 2006 — 1:15 to 4:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Visit the site http://www.emsc.nysed.gov/osa/ and select the link “Latest Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and at least one more time before the final scores for the examination are recorded. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . . .3 ...... 11 . . . . . . 4 ...... 21 . . . . . .1. . . . . 31 . . . . . 2. . . . . . . 41 . . . . . 1. . . . . . . 2 . . . . . .2 ...... 12 . . . . . . 3 ...... 22 . . . . . .4. . . . . 32 . . . . . 1. . . . . . . 42 . . . . . 3. . . . . . . 3 . . . . . .4 ...... 13 . . . . . . 2 ...... 23 . . . . . .3. . . . . 33 . . . . . 2. . . . . . . 43 . . . . . 2. . . . . . . 4 . . . . . .1 ...... 14 . . . . . . 2 ...... 24 . . . . . .1. . . . . 34 . . . . . 3. . . . . . . 44 . . . . . 1. . . . . . . 5 . . . . . .2 ...... 15 . . . . . . 3 ...... 25 . . . . . .1. . . . . 35 . . . . . 2. . . . . . . 45 . . . . . 4. . . . . . . 6 . . . . . .3 ...... 16 . . . . . . 3 ...... 26 . . . . . .3. . . . . 36 . . . . . 4. . . . . . . 46 . . . . . 1. . . . . . . 7 . . . . . .1 ...... 17 . . . . . . 3 ...... 27 . . . . . .4. . . . . 37 . . . . . 2. . . . . . . 47 . . . . . 1. . . . . . . 8 . . . . . .2 ...... 18 . . . . . . 2 ...... 28 . . . . . .2. . . . . 38 . . . . . 2. . . . . . . 48 . . . . . 3. . . . . . . 9 . . . . . .2 ...... 19 . . . . . . 2 ...... 29 . . . . . .1. . . . . 39 . . . . . 3. . . . . . . 49 . . . . . 2. . . . . . . 10 . . . . . . 4 ...... 20 . . . . . . 4 ...... 30 . . . . . .1. . . . . 40 . . . . . 4. . . . . . . 50 . . . . . 4. . . . . . . Part B 1 Score [1] PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Administering and Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, January 26, 2006. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 17 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for 14. 52 [1] Allow 1 credit. Acceptable responses include, but are not limited to: An iodine atom has more electron shells than a fluorine atom. A fluorine atom has fewer electron shells. Note: Do not allow credit for a response indicating greater atomic number. 53 [1] Allow 1 credit. The correct symbol and six electrons must be shown. The location of single electrons and electron pairs may vary. Example of a 1-credit response: Se 54 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Electrons in liquid mercury are mobile. valence electrons free to move and conduct electric current 55 [1] Allow 1 credit. Examples of a 1-credit response: H H C H H H H H C C C C H H H H H C C C C C [4] PHYSICAL SETTING/CHEMISTRY – continued 56 1 [1] Allow 1 credit for 32 or 0.03125. Significant figures do not need to be shown. 57 [1] Allow 1 credit for 1.24 mol. Significant figures do not need to be shown. 58 [1] Allow 1 credit for 1250 J. Significant figures do not need to be shown. 59 [1] Allow 1 credit. Acceptable responses include, but are not limited to: An increase in temperature favors the endothermic reaction, which produces more SO2(g). The reaction shifts to the left, increasing the concentration of SO2(g). 60 [1] Allow 1 credit. Acceptable responses include, but are not limited to: A higher concentration of O2(g) causes more collisions and reactions with SO2(g) molecules, decreasing SO2(g) concentration. More collisions between reactants shift the reaction to the right. 61 [1] Allow 1 credit for 3.61 g/L. Significant figures do not need to be shown. 62 [1] Allow 1 credit for 0.090 g/L or 9.0 × 10–2 g/L. 63 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The electronegativity difference for HCl is 1.1, which is higher than the 0.6 for HI. The difference for HCl is greater. 64 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Hydrogen has weaker intermolecular forces than HBr. hydrogen — weaker forces [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 65 [1] Allow 1 credit. Acceptable responses include, but are not limited to: HCl’s molecular polarity is more similar to water’s polarity than H2’s polarity compared to water’s. HCl and water both polar, H2 nonpolar, like dissolves like HCl polarity is more similar to water’s polarity. 66 [1] Allow 1 credit for 50°C. Significant figures do not need to be shown. 67 [1] Allow 1 credit. Acceptable responses include, but are not limited to: AB from time 0 to 2 minutes [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 18 credits for this part. The student must answer all questions in this part. 68 [1] Allow 1 credit. Acceptable responses include, but are not limited to: If the water temperature is higher, the tablet will dissolve at a faster rate. higher temperature, less time to dissolve lower rate in cold water 69 [1] Allow 1 credit. Acceptable responses include, but are not limited to: At higher temperatures the water molecules collide more often and more effectively with the tablet, so the tablet dissolves faster. high temperature → more collisions → dissolves faster or Allow 1 credit for a response consistent with the student’s answer to question 68. 70 [1] Allow 1 credit. Acceptable responses include, but are not limited to: crushing the tablet stirring/shaking/agitating 71 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The pH goes down because there are more hydronium ions in solution. [H3O+] ↑ – – 72 [1] Allow 1 credit for NO3 or NO31– or NO3–1 or OH . 73 [1] Allow 1 credit. Acceptable responses include, but are not limited to: There will be a decrease in the number of fish eggs that hatch. fewer eggs produced more deformities [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 74 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As the water temperature increases, the solubility of sulfur dioxide decreases. The solubility of SO2 decreases. 75 [1] Allow 1 credit for 164 g/mol. Significant figures do not need to be shown. 76 [1] Allow 1 credit. Acceptable responses include, but are not limited to: (0.2001 Lmol) 0.250 L 0.2 = 77 x 0.25 [1] Allow 1 credit. Acceptable responses include, but are not limited to: mass of Ca(NO3)2 mass of solute mass 78 [1] Allow 1 credit for all five correctly listed boiling points shown below. Allow credit even if the degree sign is shown for the boiling points. Data Table Symbol Atomic Number Boiling Point (K) He Ne Ar Kr Xe 2 10 18 36 54 4 27 87 121 166 [8] PHYSICAL SETTING/CHEMISTRY – continued 79 [1] Allow 1 credit for plotting all the points correctly (±0.3 grid space). Plotted points do not need to be circled or connected. Example of a 1-credit response: Boiling Point Versus Atomic Number for He, Ne, Ar, Kr, and Xe 200. Boiling Point (K) 150. 100. 50. 0 0 20 40 60 Atomic Number or Allow 1 credit for a response consistent with the student’s answer to question 78. 80 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As atomic number increases, boiling point increases. or Allow 1 credit for a response consistent with the student’s graph in question 79. or Allow 1 credit for a response consistent with the student’s data in question 78. [9] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded 81 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 75 kPa x = 295 K 418 K (75)(418) 295 P2 = 82 [1] Allow 1 credit for 145°C. 83 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Copper is less reactive than iron. Cu below H2 on Table J 84 [1] Allow 1 credit for electrolytic or electrolysis. 85 [1] Allow 1 credit. Acceptable responses include, but are not limited to: ions charged particles + H3O 2– SO4 [10] The Chart for Determining the Final Examination Score for the January 2006 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, January 26, 2006. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. [11] [OVER] Map to Core Curriculum Key Ideas Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Sci. Inq. Key Idea 1 Sci. Inq. Key Idea 2 Sci. Inq. Key Idea 3 Eng. Des. Key Idea 1 January 2006 Physical Setting/ Chemistry Question Numbers Part A Part B Standard 1 39,43,48,56,57,58, 61,62,64 34,35 33,51,61 52,59,60 76,77,79,81,82 31,41,47,63,66,67 68,72,78,83,84 Part C 80 69,70,75 71,85 Standard 2 Key Idea 1 Key Idea 2 73 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 32,36,49,53,55 41 80 Standard 7 Key Idea 1 Key Idea 2 Standard 4 Process Skills Key Idea 3 34,35,36,37,38,39, 41,42,44,45,46,47, 48,51,52,53,55,57, 59,65 69,74,75,76,77, 81,83,84 Key Idea 4 40,43,49,50,56,58, 66,67 82 Key Idea 5 54,63,64,65 Key Idea 3 Key Idea 4 Key Idea 5 2002 Edition Standard 4 1,2,3,4,5,6,7,8, 31,32,33,34,35,36, 9,10,13,14,15, 37,38,39,41,42,44, 17,18,20,21,22, 45,46,47,48,51,52, 23,24,28,30 55,57,59,60,61 68,69,70,71,72, 73,74,75,76,77, 78,80,81,83,84, 85 16,27 40,43,49,50,56,58, 66,67 11,12,19,25,26, 53,54,63,64,65 29 Reference Tables 3,6,7,8,12,19, 31,33,39,40,44,45, 21,24,26,28 47,48,49,51,52,53, 56,57,58,61,63 [12] 72,74,75,76,78, 81,82,83 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Wednesday, June 21, 2006 — 1:15 to 4:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Check this web site http://www.emsc.nysed.gov/osa/ and select the link “Examination Scoring Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and several times throughout the Regents examination period. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . .1. . . . . . . 11 . . . . .1. . . . . . . 21 . . . . 2 ....... 31 . . . . . 4. . . . . . . 41 . . . . . 2. . . . . . . 2 . . . . .4. . . . . . . 12 . . . . .3. . . . . . . 22 . . . . 4 ....... 32 . . . . . 4. . . . . . . 42 . . . . . 2. . . . . . . 3 . . . . .4. . . . . . . 13 . . . . .2. . . . . . . 23 . . . . 3 ....... 33 . . . . . 3. . . . . . . 43 . . . . . 1. . . . . . . 4 . . . . .2. . . . . . . 14 . . . . .3. . . . . . . 24 . . . . 2 ....... 34 . . . . . 4. . . . . . . 44 . . . . . 2. . . . . . . 5 . . . . .4. . . . . . . 15 . . . . .3. . . . . . . 25 . . . . 4 ....... 35 . . . . . 3. . . . . . . 45 . . . . . 2. . . . . . . 6 . . . . .3. . . . . . . 16 . . . . .2. . . . . . . 26 . . . . 4 ....... 36 . . . . . 1. . . . . . . 46 . . . . . 3. . . . . . . 7 . . . . .2. . . . . . . 17 . . . . .2. . . . . . . 27 . . . . 4 ....... 37 . . . . . 4. . . . . . . 47 . . . . . 3. . . . . . . 8 . . . . .3. . . . . . . 18 . . . . .2. . . . . . . 28 . . . . 1 ....... 38 . . . . . 3. . . . . . . 48 . . . . . 3. . . . . . . 9 . . . . .2. . . . . . . 19 . . . . .4. . . . . . . 29 . . . . 4 ....... 39 . . . . . 1. . . . . . . 49 . . . . . 2. . . . . . . 10 . . . . .1. . . . . . . 20 . . . . .1. . . . . . . 30 . . . . 1 ....... 40 . . . . . 1. . . . . . . 50 . . . . . 2. . . . . . . Part B 1 Score PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, June 21, 2006. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 16 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for 6 or six. 52 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Iron is more active than hydrogen. Fe is higher on Table J than H2. 53 [1] Allow 1 credit for 10 or ten. 54 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The third shell has one electron before the second shell is completely filled. The electron configuration is not 2-7, which is the ground state for an atom with atomic number 9. Note: Do not allow credit for a response that simply restates that the electron configuration is 2-6-1. 55 [1] Allow 1 credit. Acceptable responses include, but are not limited to: alkanes CnH2n+2 56 [1] Allow 1 credit for 781 g. Significant figures do not need to be shown. 57 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Heat flows from the student’s hand to the test tube. The test tube absorbs heat from the hand. [4] PHYSICAL SETTING/CHEMISTRY – continued 58 [1] Allow 1 credit. Acceptable responses must show at least two water molecules with at least one hydrogen atom of each water molecule facing toward the Cl– ion. Example of a 1-credit response: Cl 59 – [1] Allow 1 credit. Acceptable responses include, but are not limited to: Potential energy of the product is less than potential energy of the reactant. More energy is released than absorbed. Energy appears on the right. 60 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Equilibrium shifts toward the fewer number of moles of gas. The reaction shifts to the side that would result in a reduction of pressure. fewer moles of gas, less pressure 61 [1] Allow 1 credit. Acceptable responses include, but are not limited to: substitution chlorination halogenation [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 62 [1] Allow 1 credit. Examples of a 1-credit response: H H H H Cl C C C C H H H H H Cl C C C C 63 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Particles move slower and collide less frequently. fewer effective collisions between molecules 64 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Ethanol’s boiling point is lower than the boiling point of the solution. The solution’s boiling point is higher than 78.2°C. 65 [1] Allow 1 credit for 2730 kJ. Significant figures do not need to be shown. 66 [1] Allow 1 credit. Acceptable responses include, but are not limited to: soluble in water boiling point volatility [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 19 credits for this part. The student must answer all questions in this part. 67 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The greater the total number of carbon atoms in a molecule of a primary alcohol, the less soluble the alcohol is in water. number of carbons ↓, solubility ↑ 68 [1] Allow 1 credit for 2.5 g ± 0.1 g. 69 [1] Allow 1 credit for 2 NaN3(s) → 2 Na(s) + 3 N2(g). 70 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: V2 = (273 K)(1.30 atm)(40.0 L) (301 K)(1.00 atm) (273)(1.30)(40.0) (301)(1.00) • Allow 1 credit for 47.2 L. Significant figures do not need to be shown. or Allow credit for a response consistent with the student’s numerical setup. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. 71 [1] Allow 1 credit. Acceptable responses include, but are not limited to: This compound contains an —SH functional group. There is a sulfur atom instead of an oxygen atom in the functional group. [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 72 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Oxygen and sulfur atoms have the same number (six) of valence electrons. Atoms of both elements need two more valence electrons to complete their outer shells. 73 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 10–4 M 0.0001 M 74 [1] Allow 1 credit for blue. 75 [1] Allow 1 credit for seawater. 76 [1] Allow 1 credit. Acceptable responses include, but are not limited to: density mass volume 77 [1] Allow 1 credit. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 3.9 cm3 3.88 cm3 78 [1] Allow 1 credit. All three oxidation states must be correct to receive credit. Acceptable responses include, but are not limited to: Na: +1 Al: +3 F: 79 –1 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Al3+ + 3e– → Al [8] PHYSICAL SETTING/CHEMISTRY – concluded 80 [1] Allow 1 credit. Acceptable responses include, but are not limited to: There are freely moving ions in the molten cryolite. Ions are no longer held together in a crystal lattice. 81 [1] Allow 1 credit for a correct response that includes both processes. Acceptable responses include, but are not limited to: A voltaic cell produces electrical energy and an electrolytic cell used in the Hall process requires electrical energy. Electrolysis uses electrical energy. Voltaic cells produce electrical energy. 82 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The electron of hydrogen absorbs energy and jumps to a higher energy state. The excited electron returns to a lower energy state, releasing light energy. The e– absorbs energy and jumps to a higher level. The e– falls back to a lower level and releases energy related to a particular color. 83 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The spectrum from a star is compared to spectra of known elements. 84 [1] Allow 1 credit. Acceptable responses include, but are not limited to: % error = 647 nm – 656 nm × 100 656 nm 647 – 656 × 100 656 [9] [OVER] The Chart for Determining the Final Examination Score for the June 2006 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, June 21, 2006. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. The Teacher Evaluation of State Examinations forms will also be posted on the same web site. Please select the link “Teacher Evaluation Forms” and then the examination title to complete the evaluation form for the June 2006 Regents Examination in Physical Setting/Chemistry. [10] Map to Core Curriculum [11] FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Wednesday, August 16, 2006 — 12:30 to 3:30 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Check this web site http://www.emsc.nysed.gov/osa/ and select the link “Examination Scoring Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and several times throughout the Regents examination period. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . .2. . . . . . . 11 . . . . .3. . . . . . . 21 . . . . 3 ....... 31 . . . . . 3. . . . . . . 41 . . . . . 1. . . . . . . 2 . . . . .4. . . . . . . 12 . . . . .1. . . . . . . 22 . . . . 4 ....... 32 . . . . . 2. . . . . . . 42 . . . . . 3. . . . . . . 3 . . . . .1. . . . . . . 13 . . . . .2. . . . . . . 23 . . . . 1 ....... 33 . . . . . 4. . . . . . . 43 . . . . . 3. . . . . . . 4 . . . . .2. . . . . . . 14 . . . . .1. . . . . . . 24 . . . . 2 ....... 34 . . . . . 3. . . . . . . 44 . . . . . 1. . . . . . . 5 . . . . .3. . . . . . . 15 . . . . .3. . . . . . . 25 . . . . 4 ....... 35 . . . . . 1. . . . . . . 45 . . . . . 1. . . . . . . 6 . . . . .3. . . . . . . 16 . . . . .2. . . . . . . 26 . . . . 1 ....... 36 . . . . . 2. . . . . . . 46 . . . . . 4. . . . . . . 7 . . . . .4. . . . . . . 17 . . . . .3. . . . . . . 27 . . . . 3 ....... 37 . . . . . 1. . . . . . . 47 . . . . . 3. . . . . . . 8 . . . . .3. . . . . . . 18 . . . . .2. . . . . . . 28 . . . . 4 ....... 38 . . . . . 2. . . . . . . 48 . . . . . 1. . . . . . . 9 . . . . .3. . . . . . . 19 . . . . .4. . . . . . . 29 . . . . 4 ....... 39 . . . . . 4. . . . . . . 49 . . . . . 2. . . . . . . 10 . . . . .2. . . . . . . 20 . . . . .4. . . . . . . 30 . . . . 2 ....... 40 . . . . . 4. . . . . . . 50 . . . . . 4. . . . . . . Part B 1 Score PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, August 16, 2006. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 15 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit. Examples of a 1-credit response: S xx x xS xx 52 [1] Allow 1 credit. Acceptable responses include, but are not limited to: An atom of each element has six electrons in its outer shell. same number of valence electrons 53 [1] Allow 1 credit. Acceptable responses include, but are not limited to: heterogeneous nonuniform 54 [1] Allow 1 credit for compound or compounds. 55 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The water molecules, sodium ions, and chloride ions are uniformly mixed together. All particles distribute evenly. 56 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Evaporate the water. Decant the water. filtration [4] PHYSICAL SETTING/CHEMISTRY – continued 57 [1] Allow 1 credit for marking an appropriate scale. An appropriate scale is linear and allows a trend to be seen. 58 [1] Allow 1 credit for plotting all four points correctly ± 0.3 grid space. Plotted points do not need to be circled or connected. 57 and 58 Example of a 2-credit graph for questions 57 and 58: Reaction Time Versus Initial Concentration 80. 70. Reaction Time (s) 60. 50. 40. 30. 20. 10. 0.000 0.005 0.010 0.015 0.020 0.025 Initial Concentration (M) 59 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As concentration of the reactant decreases, the rate of the reaction decreases. As concentration increases, the rate of reaction increases. 60 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The greater the kinetic energy of the reactant particles, the greater the frequency and effectiveness of the collisions. Increasing the temperature causes more collisions. more effective collisions [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 61 [1] Allow 1 credit for propene. 62 [1] Allow 1 credit. Acceptable responses include, but are not limited to: addition halogenation bromination 63 [1] Allow 1 credit. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 202 g/mol 201.9 g/mol 64 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 4 2He alpha particle α 65 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The nucleus of Pb-206 is stable. Pb-206 is not radioactive. If Pb-206 were not stable, it would spontaneously decay. [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 20 credits for this part. The student must answer all questions in this part. 66 67 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 59 26 Fe → –10 e + 59 27 Co 59 26 Fe → + –10  59 27 Co [1] Allow 1 credit. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 1 16 0.0625 6 14 % 68 [1] Allow 1 credit for solid. 69 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Metals have freely moving valence electrons. mobile valence electrons sea of mobile electrons Electrons are delocalized. 70 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The ionic radius is smaller because the atom loses two electrons. The ion has one less occupied energy level. 71 [1] Allow 1 credit for MI2. 72 [1] Allow 1 credit for 50.ºC ± 2ºC. [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 73 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The average kinetic energy of the particles remains the same. KE remains constant. no change 74 [1] Allow 1 credit. Temperature (°C) Example of a 1-credit response: Time (min) 75 [1] Allow 1 credit for 288 K. 76 [1] Allow 1 credit. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 9.50 mL HCl(aq) and 3.80 mL NaOH(aq) 9.5 mL HCl(aq) and 3.8 mL NaOH(aq) 77 [1] Allow 1 credit. Acceptable responses include, but are not limited to: (0.10 M)(9.50 mL) = MB(3.80 mL) (0.1)(9.5) 3.8 or Allow credit for a response consistent with the student’s answer to question 76. [8] PHYSICAL SETTING/CHEMISTRY – continued 78 [1] Allow 1 credit. Examples of a 1-credit response: H H H H O C C C C H H H H O C H H O C O C C C C O CH O 3 79 C CH CH CH 2 2 3 [1] Allow 1 credit. Acceptable responses include, but are not limited to: ethanol ethyl alcohol 80 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Drain cleaner contains KOH or NaOH, which are bases with a pH value greater than 7. A pH of 12.8 indicates a base. A base has a pH above 7. 81 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The liquids in bottle 1 and bottle 2 both have a pH below 8, but thymol blue does not change color until the pH value reaches at least 8.0. The pH range for the thymol blue color change is too high. 82 [1] Allow 1 credit for _____ Mg(s) + 2 HCl(aq) → _____ MgCl2(aq) + _____ H2(g). Allow credit even if the coefficient “1” is written in front of Mg(s), MgCl2(aq), or H2(g). [9] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded 83 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The reaction is single replacement. single displacement redox 84 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 2.50 g × 1 mol 24.3 g 2.50 24 85 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Ag is below H2 in the activity series. Ag is more difficult to oxidize. [10] Regents Examination in Physical Setting/Chemistry August 2006 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) The Chart for Determining the Final Examination Score for the August 2006 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, August 16, 2006. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. Submitting Teacher Evaluations of the Test to the Department Suggestions and feedback from teachers provide an important contribution to the test development process. The Department provides an online evaluation form for State assessments. It contains spaces for teachers to respond to several specific questions and to make suggestions. Instructions for completing the evaluation form are as follows: 1. Go to www.emsc.nysed.gov/osa/exameval. 2. Select the test title. 3. Complete the required demographic fields. 4. Complete each evaluation question and provide comments in the space provided. 5. Click the SUBMIT button at the bottom of the page to submit the completed form. [11] Map to Core Curriculum Key Ideas Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Sci. Inq. Key Idea 1 Sci. Inq. Key Idea 2 Sci. Inq. Key Idea 3 August 2006 Physical Setting/ Chemistry Question Numbers Part A Part B Standard 1 Part C 39,42,48,55,57,58 74,75,77,84 59 37,39,42 67,70,76 43,51,52,55 69,70,81,85 5,23,24 36,40,41,47,48, 53,54,61,64,65 68,71,72,73,74, 79,80,81,82 Eng. Des. Key Idea 1 Standard 2 Key Idea 1 Key Idea 2 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 33 50 45 41,46,65 Standard 7 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 Key Idea 3 Standard 4 Process Skills 33,34,35,38,40, 41,42,45,47,48, 49,51,52,56,60, 61,62,63,64 39,44,46 Standard 4 1,2,3,4,5,6,7,12, 13,14,15,16,17, 18,19,20,21,22, 23,24,25,26,27, 30 69 31,32,33,34,35, 36,37,38,39,40, 41,42,43,45,48, 49,50,52,53,54, 55,56,57,58,59, 60,61,62,63,65 68,71,76,77,78, 79,80,81,82,83, 84,85 66,67,72,73,74, 75 69,70 28 44,46,64 Key Idea 5 4,8,9,10,11 47,51 Reference Tables 2,5,8,9,10,13, 34,35,39,41,42, 14,17,20,26, 44,47,51,52,61, 28,29 63,64,65 [12] 66,67,72,73,74, 43 Key Idea 4 2002 Edition 68,75,76,77,78, 79,80,81,82,83, 84,85 66,67,68,71,75, 77,78,79,84,85 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Thursday, January 25, 2007 — 1:15 to 4:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Check this web site http://www.emsc.nysed.gov/osa/ and select the link “Examination Scoring Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and several times throughout the Regents examination period. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . .3. . . . . . . 11 . . . . .4. . . . . . . 21 . . . . 4 ....... 31 . . . . . 4. . . . . . . 41 . . . . . 3. . . . . . . 2 . . . . .1. . . . . . . 12 . . . . .2. . . . . . . 22 . . . . 4 ....... 32 . . . . . 2. . . . . . . 42 . . . . . 1. . . . . . . 3 . . . . .1. . . . . . . 13 . . . . .4. . . . . . . 23 . . . . 3 ....... 33 . . . . . 1. . . . . . . 43 . . . . . 3. . . . . . . 4 . . . . .2. . . . . . . 14 . . . . .1. . . . . . . 24 . . . . 4 ....... 34 . . . . . 4. . . . . . . 44 . . . . . 4. . . . . . . 5 . . . . .4. . . . . . . 15 . . . . .1. . . . . . . 25 . . . . 1 ....... 35 . . . . . 3. . . . . . . 45 . . . . . 1. . . . . . . 6 . . . . .1. . . . . . . 16 . . . . .2. . . . . . . 26 . . . . 4 ....... 36 . . . . . 2. . . . . . . 46 . . . . . 2. . . . . . . 7 . . . . .3. . . . . . . 17 . . . . .4. . . . . . . 27 . . . . 3 ....... 37 . . . . . 1. . . . . . . 47 . . . . . 2. . . . . . . 8 . . . . .4. . . . . . . 18 . . . . .3. . . . . . . 28 . . . . 1 ....... 38 . . . . . 4. . . . . . . 48 . . . . . 4. . . . . . . 9 . . . . .2. . . . . . . 19 . . . . .4. . . . . . . 29 . . . . 4 ....... 39 . . . . . 2. . . . . . . 49 . . . . . 1. . . . . . . 10 . . . . .2. . . . . . . 20 . . . . .1. . . . . . . 30 . . . . 3 ....... 40 . . . . . 2. . . . . . . 50 . . . . . 1. . . . . . . Part B 1 Score PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a checkmark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, January 25, 2007. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 18 credits for this part. The student must answer all questions in this part. 51 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: (10.013)(0.199) + (11.009)(0.801) (19.9)(10.013) + (80.1)(11.009) 100 (10.013)(19.9%) + (11.009)(80.1%) • Allow 1 credit. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 10.8 atomic mass units 10.81 atomic mass units 10.8108 atomic mass units or Allow 1 credit for a response consistent with the student’s numerical setup. Note: Do not allow credit for a numerical setup and a calculated result that are not related to the concept assessed by the question. 52 [1] Allow 1 credit for ZnCl2. 53 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Cu Ag gold [4] PHYSICAL SETTING/CHEMISTRY – continued 54 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 21.4% – 20.9% × 100 20.9% 21.4 – 20.9 × 100 20.9 • Allow 1 credit. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 2% 2.4% 2.39% or Allow 1 credit for a response consistent with the student’s numerical setup. Note: Do not allow credit for a numerical setup and a calculated result that are not related to the concept assessed by the question. 55 [1] Allow 1 credit. Acceptable responses include, but are not limited to: AQ2 Q2 A 56 [1] Allow 1 credit. Acceptable responses include, but are not limited to: polar covalent covalent [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 57 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The total mass of reactants equals the total mass of product. Mass of reactants equals mass of product. Mass is conserved. 58 [1] Allow 1 credit for a correct response that shows an activation energy that is higher than the potential energy of the reactants and lower than the original activation energy. Potential Energy Example of a 1-credit response: Reaction Coordinate 59 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As molecules acquire more kinetic energy, the number of effective collisions increases. higher temperature, greater frequency of collisions 60 [1] Allow 1 credit for 0.300 g. Significant figures do not need to be shown. 61 [1] Allow 1 credit for 62 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 3 Cu2+(aq) + 2 Al(s) → 3 Cu(s) + 2 Al3+(aq). Aluminum atoms are losing electrons and becoming aluminum ions that are entering the solution. [6] PHYSICAL SETTING/CHEMISTRY – continued 63 [1] Allow 1 credit. Acceptable responses include, but are not limited to: It allows migration of ions. maintains neutrality prevents polarization 64 [1] Allow 1 credit for any two of the following responses: methyl orange bromthymol blue thymol blue 65 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Methane is nonpolar because its molecules are symmetrical. Charges are evenly distributed throughout the molecule. 66 [1] Allow 1 credit for 97°C ± 1°C. [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 17 credits for this part. The student must answer all questions in this part. 67 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Group 18 noble gases 68 [1] Allow 1 credit for 173. 69 [1] Allow 1 credit for 118. 70 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Reproducing results verifies that the results are valid. reliability of results [8] PHYSICAL SETTING/CHEMISTRY – continued 71 [1] Allow 1 credit for correctly plotting all five points ± 0.3 grid space. Plotted points do not need to be circled or connected. Example of a 1-credit response: Surface Tension Versus Water Temperature Surface Tension (mN/m) 75.0 70.0 65.0 60.0 55.0 0 20. 40. 60. 80. 100. Water Temperature (°C) 72 [1] Allow 1 credit for 66.1 mN/m ± 0.3 mN/m. Significant figures do not need to be shown. or Allow 1 credit for a response consistent with the student’s graph in question 71. 73 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Surface tension will decrease as temperature increases. as temperature ↑, surface tension ↓ Note: Do not allow credit for “inverse relationship.” [9] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 74 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Tetrachloromethane, CCl4, has weaker intermolecular forces than water, H2O. Surface tension of water at 25°C is greater than 26.3 mN/m, so the intermolecular forces of water are stronger. The forces between water molecules are greater. 75 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 0.1250 L 0.125 L 1.25 × 10–1 L 76 [1] Allow 1 credit. Acceptable responses include, but are not limited to: V2 = (1.0 atm)(125.0 mL) 1.5 atm (1.0)(125) = (1.50)(V2) or Allow 1 credit for a response consistent with the student’s answer to question 75. 77 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Both samples have the same number of particles. Equal volumes of gases at the same temperature and pressure contain the same number of particles. 78 [1] Allow 1 credit for hydrochloric acid. [10] PHYSICAL SETTING/CHEMISTRY – concluded 79 [1] Allow 1 credit. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 0.833 M 8.3 × 10–1 M 80 [1] Allow 1 credit for 3 or three. 81 [1] Allow 1 credit. Acceptable responses include, but are not limited to: wearing gloves no open-toed shoes 82 [1] Allow 1 credit. Examples of a 1-credit response: H H C H H H H H H C C C C C H H H H H C H H C H H C H C C C C C C C 83 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The arrangement of molecules in the vapor state are more random or disordered. Particles in the vapor state are farther apart and move more freely. [11] [OVER] Regents Examination in Physical Setting/Chemistry January 2007 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) The Chart for Determining the Final Examination Score for the January 2007 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, January 25, 2007. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. Submitting Teacher Evaluations of the Test to the Department Suggestions and feedback from teachers provide an important contribution to the test development process. The Department provides an online evaluation form for State assessments. It contains spaces for teachers to respond to several specific questions and to make suggestions. Instructions for completing the evaluation form are as follows: 1. Go to www.emsc.nysed.gov/osa/exameval. 2. Select the test title. 3. Complete the required demographic fields. 4. Complete each evaluation question and provide comments in the space provided. 5. Click the SUBMIT button at the bottom of the page to submit the completed form. [12] [13] FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Wednesday, June 20, 2007 — 1:15 to 4:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Check this web site http://www.emsc.nysed.gov/osa/ and select the link “Examination Scoring Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and several times throughout the Regents examination period. n n n n Part A and Part B–1 Allow 1 credit for each correct response. PartPB–1 Part A 1 . . . . .4. . . . . . . 11 . . . . .4. . . . . . . 21 . . . . 2 ....... 31 . . . . . 2. . . . . . . 41 . . . . . 2. . . . . . . 2 . . . . .3. . . . . . . 12 . . . . .1. . . . . . . 22 . . . . 2 ....... 32 . . . . . 1. . . . . . . 42 . . . . . 3. . . . . . . 3 . . . . .3. . . . . . . 13 . . . . .3. . . . . . . 23 . . . . 2 ....... 33 . . . . . 2. . . . . . . 43 . . . . . 3. . . . . . . 4 . . . . .4. . . . . . . 14 . . . . .2. . . . . . . 24 . . . . 1 ....... 34 . . . . . 1. . . . . . . 44 . . . . . 3. . . . . . . 5 . . . . .1. . . . . . . 15 . . . . .3. . . . . . . 25 . . . . 4 ....... 35 . . . . . 1. . . . . . . 45 . . . . . 4. . . . . . . 6 . . . . .2. . . . . . . 16 . . . . .4. . . . . . . 26 . . . . 3 ....... 36 . . . . . 1. . . . . . . 46 . . . . . 2. . . . . . . 7 . . . . .1. . . . . . . 17 . . . . .2. . . . . . . 27 . . . . 3 ....... 37 . . . . . 4. . . . . . . 47 . . . . . 3. . . . . . . 8 . . . . .1. . . . . . . 18 . . . . .2. . . . . . . 28 . . . . 3 ....... 38 . . . . . 3. . . . . . . 48 . . . . . 2. . . . . . . 9 . . . . .4. . . . . . . 19 . . . . .2. . . . . . . 29 . . . . 4 ....... 39 . . . . . 4. . . . . . . 49 . . . . . 3. . . . . . . 10 . . . . .2. . . . . . . 20 . . . . .4. . . . . . . 30 . . . . 3 ....... 40 . . . . . 3. . . . . . . 50 . . . . . 2. . . . . . . P PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a check mark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, June 20, 2007. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 15 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for marking an appropriate scale on the axis labeled “Volume (mL).” An appropriate scale is linear and allows a trend to be seen. 52 [1] Allow 1 credit for all five points plotted correctly ± 0.3 grid space. Plotted points do not need to be circled or connected. Examples of 2-credit responses to questions 51 and 52: Pressure Versus Volume of a Gas Sample 6.0 6.0 5.0 5.0 4.0 4.0 Pressure (atm) Pressure (atm) Pressure Versus Volume of a Gas Sample 3.0 2.0 1.0 3.0 2.0 1.0 0 0 300 600 900 1200 Volume (mL) 300 600 900 1200 Volume (mL) 53 [1] Allow 1 credit for 3.0 atm or for a response consistent with the student’s graph ± 0.3 grid space. Significant figures do not need to be shown. 54 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As temperature increases, the rate of a chemical reaction increases because the reactant particles move faster and collide more often. More reactant molecules have sufficient activation energy. The number of effective collisions per unit time increases. [4] PHYSICAL SETTING/CHEMISTRY – continued 55 [1] Allow 1 credit for 53.3%. Significant figures do not need to be shown. 56 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: q = mC∆ T = (5.00 g)(4.71 J/g•K)(30. K) (5)(4.71)(30) • Allow 1 credit for 710 J or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. 57 [1] Allow 1 credit. Both potential energy and kinetic energy must be included in the student’s response to receive credit. Acceptable responses include, but are not limited to: The potential energy of the ammonia molecules increases and the average kinetic energy of the ammonia molecules remains the same. PE increases and KE is constant. 58 [1] Allow 1 credit for 6850 J. Significant figures do not need to be shown. 59 [1] Allow 1 credit for 60 [1] Allow 1 credit for +5. 2 KClO3(s) → 2 KCl(s) + [5] 3 O2(g). [OVER] PHYSICAL SETTING/CHEMISTRY – continued 61 [1] Allow 1 credit for 42 20Ca. 62 [1] Allow 1 credit. Acceptable responses include, but are not limited to: A P–Cl bond is more polar than a P–S bond because the electronegativity difference for P–Cl is 1.0 and the electronegativity difference for P–S is 0.4. Cl has a higher electronegativity value than S. A chlorine atom has a greater attraction for electrons in a bond than a sulfur atom. 63 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: d= m 20.179 g = V 24.4 L 20 24.4 • Allow 1 credit for 0.827 g/L or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 20 credits for this part. The student must answer all questions in this part. 64 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The sample is an unsaturated solution. unsaturated 65 [1] Allow 1 credit. Both oxygen and water must be included in the student’s response to receive credit. Acceptable responses include, but are not limited to: Oxygen molecules are nonpolar and water molecules are polar. Because H2O and O2 have different polarities, O2 has low solubility in H2O. oxygen nonpolar, water polar 66 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: ppm = 0.0070 gram O2 × 1 000 000 (1000. grams of water + 0.0070 gram of O2 ) (0.0070 / 1000.0070) × 1 000 000 • Allow 1 credit for 7.0 ppm or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. 67 [1] Allow 1 credit for a pH value that is greater than or equal to 4.4, but is less than or equal to 5.5. 68 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Ca(OH)2 KOH Na2CO3 [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 69 [1] Allow 1 credit. Molecules of the gas must be drawn farther apart than molecules of the liquid. Example of a 1-credit response: 70 [1] Allow 1 credit. Potential Energy Example of a 1-credit response: Reaction Coordinate 71 [1] Allow 1 credit. Significant figures do not need to be shown. Acceptable responses include, but are not limited to: 5550 kJ 5.5 × 103 kJ [8] PHYSICAL SETTING/CHEMISTRY – continued 72 [1] Allow 1 credit. Examples of 1-credit responses: H H C SH H C SH 73 [1] Allow 1 credit for 4 or four. 74 [1] Allow 1 credit for 1 or one. 75 [1] Allow 1 credit for a temperature value below 64°C. 76 [1] Allow 1 credit for D or He. 77 [1] Allow 1 credit for 0.20 mol. Significant figures do not need to be shown. 78 [1] Allow 1 credit. Acceptable responses include, but are not limited to: substitution bromination halogenation 79 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Ozone is better to use because it is safer than bromomethane. O3 is more environmentally friendly. [9] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded 80 [1] Allow 1 credit. Acceptable responses include, but are not limited to: natural transmutation transmutation beta decay radioactive decay 81 [1] Allow 1 credit for 28 650 y. Significant figures do not need to be shown. 82 [1] Allow 1 credit. Acceptable responses include, but are not limited to: A C-13 atom has seven neutrons and a C-12 atom has six neutrons. An atom of C-13 and an atom of C-12 have different numbers of neutrons. The number of neutrons is different. [10] Regents Examination in Physical Setting/Chemistry June 2007 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) The Chart for Determining the Final Examination Score for the June 2007 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, June 20, 2007. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. Submitting Teacher Evaluations of the Test to the Department Suggestions and feedback from teachers provide an important contribution to the test development process. The Department provides an online evaluation form for State assessments. It contains spaces for teachers to respond to several specific questions and to make suggestions. Instructions for completing the evaluation form are as follows: 1. Go to www.emsc.nysed.gov/osa/exameval. 2. Select the test title. 3. Complete the required demographic fields. 4. Complete each evaluation question and provide comments in the space provided. 5. Click the SUBMIT button at the bottom of the page to submit the completed form. [11] [OVER] Map to Core Curriculum June 2007 Physical Setting/Chemistry Key Ideas/Performance Indicators Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Science Inquiry Key Idea 1 Science Inquiry Key Idea 2 Science Inquiry Key Idea 3 Engineering Design Key Idea 1 Question Numbers Part A Part B Standard 1 42, 43, 51, 52, 56, 63 53 55, 58, 60, 62, 63 37, 62 36, 48, 49, 60 Part C 66, 77 64, 74, 75 66, 71, 77, 81 68 67, 73, 76 Standard 2 Key Idea 1 Key Idea 2 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 72 69 44 Standard 7 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 Key Idea 3 Key Idea 4 Key Idea 5 2002 Edition 79 Standard 4 Process Skills 31, 32, 33, 34, 35, 38, 39, 40, 43, 44, 45, 46, 47, 48, 49, 54, 59 50, 56, 57, 58, 61 41 Standard 4 1, 2, 3, 4, 5, 6, 7, 31, 32, 33, 34, 13, 14, 15, 16, 36, 37, 38, 39, 17, 19, 20, 22, 42, 43, 44, 45, 23, 24, 25, 26, 28 46, 47, 48, 49, 51, 52, 53, 54, 55, 59, 60, 63 12, 18, 27, 29 50, 57, 58, 61 8, 9, 10, 11, 21, 35, 40, 41, 62 30 Reference Tables 2, 5, 6, 9, 13, 18, 31, 34, 36, 40, 19, 21, 27 42, 43, 45, 46, 47, 48, 49, 55, 56, 58, 60, 61, 62, 63 [12] 64, 66, 67, 68, 69, 72, 73, 74, 75, 76, 77, 78, 80, 82 70, 81 65 64, 66, 67, 68, 69, 72, 73, 74, 75, 76, 77, 78, 82 70, 71, 80, 81 65, 79 66, 67, 68, 71, 72, 73, 74, 75, 76, 77, 81, 82 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Thursday, August 16, 2007 — 12:30 to 3:30 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Check this web site http://www.emsc.nysed.gov/osa/ and select the link “Examination Scoring Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and several times throughout the Regents examination period. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . .2. . . . . . . 11 . . . . .4. . . . . . . 21 . . . . 1 ....... 31 . . . . . 3. . . . . . . 41 . . . . . 1. . . . . . . 2 . . . . .1. . . . . . . 12 . . . . .2. . . . . . . 22 . . . . 1 ....... 32 . . . . . 3. . . . . . . 42 . . . . . 3. . . . . . . 3 . . . . .2. . . . . . . 13 . . . . .4. . . . . . . 23 . . . . 2 ....... 33 . . . . . 1. . . . . . . 43 . . . . . 2. . . . . . . 4 . . . . .3. . . . . . . 14 . . . . .2. . . . . . . 24 . . . . 2 ....... 34 . . . . . 1. . . . . . . 44 . . . . . 2. . . . . . . 5 . . . . .3. . . . . . . 15 . . . . .3. . . . . . . 25 . . . . 2 ....... 35 . . . . . 3. . . . . . . 45 . . . . . 4. . . . . . . 6 . . . . .4. . . . . . . 16 . . . . .3. . . . . . . 26 . . . . 1 ....... 36 . . . . . 3. . . . . . . 46 . . . . . 4. . . . . . . 7 . . . . .3. . . . . . . 17 . . . . .3. . . . . . . 27 . . . . 1 ....... 37 . . . . . 2. . . . . . . 47 . . . . . 2. . . . . . . 8 . . . . .3. . . . . . . 18 . . . . .2. . . . . . . 28 . . . . 2 ....... 38 . . . . . 1. . . . . . . 48 . . . . . 2. . . . . . . 9 . . . . .1. . . . . . . 19 . . . . .3. . . . . . . 29 . . . . 3 ....... 39 . . . . . 4. . . . . . . 49 . . . . . 4. . . . . . . 10 . . . . .1. . . . . . . 20 . . . . .4. . . . . . . 30 . . . . 4 ....... 40 . . . . . 4. . . . . . . 50 . . . . . 3. . . . . . . PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a check mark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, August 16, 2007. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 16 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for +2. 52 [1] Allow 1 credit for an excited state configuration indicating a total of 13 electrons that has no more than 2 electrons in shell 1 and no more than 8 electrons in shell 2. Acceptable responses include, but are not limited to: 2-7-4 1-8-4 2-6-2-3 Note: Do not allow credit for the configuration 2-8-3. 53 [1] Allow 1 credit for blue. 54 [1] Allow 1 credit for 15 or fifteen. 55 [1] Allow 1 credit. Acceptable responses include, but are not limited to: (27.98)(0.9222) + (28.98)(0.0469) + (29.97)(0.0309) (27.98)(92.22) + (28.98)(4.69) + (29.97)(3.09) 100 56 [1] Allow 1 credit for 6.5%. Significant figures do not need to be shown. 57 [1] Allow 1 credit for 120.°C ± 2°C. [4] PHYSICAL SETTING/CHEMISTRY – continued 58 [1] Allow 1 credit. Example of a 1-credit response: 59 [1] Allow 1 credit for 3.0 min ± 0.2 min. Significant figures do not need to be shown. 60 [1] Allow 1 credit for 30. kJ ± 3 kJ. Significant figures do not need to be shown. 61 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Heat term is on the right side of the equation. The 571.6 kJ is a product. [1] Allow 1 credit. Example of a 1-credit response: Potential Energy 62 Reaction Coordinate [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 63 [1] Allow 1 credit. Acceptable responses include, but are not limited to: A liquid is formed from gases. A compound is formed from its elements. The number of gas particles in the system decreases. 64 [1] Allow 1 credit. Examples of a 1-credit response: H O C OH H C H H O C OH H C H 65 [1] Allow 1 credit. Acceptable responses include, but are not limited to: ethanoic acid acetic acid 66 [1] Allow 1 credit. Examples of a 1-credit response: H HO H H H C C C OH H H H C C C [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 19 credits for this part. The student must answer all questions in this part. 67 [1] Allow 1 credit. Positions of the three dots can vary. Examples of a 1-credit response: Uut x x Uut x 68 [1] Allow 1 credit for +113. 69 [1] Allow 1 credit for any element in Group 13. Acceptable responses include, but are not limited to: Tl boron 70 [1] Allow 1 credit. Acceptable responses include, but are not limited to: synthesis redox oxidation 71 [1] Allow 1 credit for 160. g/mol. Significant figures do not need to be shown. 72 [1] Allow 1 credit for iron(III) oxide. 73 [1] Allow 1 credit for 3 or three. [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 74 [1] Allow 1 credit. Acceptable responses include, but are not limited to: % H2O = 0.76 g × 100 2.13 g 0.76 × 100 2.13 75 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Until the sample reaches a constant mass, the student cannot be sure that all the water has been removed. to make sure all of the water is heated out of the sample 76 [1] Allow 1 credit. Acceptable responses must show at least two water molecules with at least one hydrogen atom of each water molecule facing toward the chloride ion. Example of a 1-credit response: CI- 77 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The concentration of OCl–(aq) increases because there will be a greater number of effective collisions between the Cl2(g) and the OH–(aq). more collisions between Cl2(g) and OH–(aq) 78 [1] Allow 1 credit for OH– or hydroxide ion. [8] PHYSICAL SETTING/CHEMISTRY – concluded 79 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: molarity = moles of solute = 0.500 mol NaOH 0.400 L solution liters of solution 0.5 0.4 • Allow 1 credit for 1.25 M or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. 80 [1] Allow 1 credit. Acceptable responses include, but are not limited to: NaOH(aq) + HNO3(aq) → NaNO3(aq) + H2O(ᐉ) NaOH(aq) + HNO3(aq) → HOH + NaNO3 81 [1] Allow 1 credit for 22 920 y. Significant figures do not need to be shown. 82 [1] Allow 1 credit for 147N. 83 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Silver nitrate produces more ions than silver chloride in water. AgNO3 readily dissolves in H2O; AgCl dissolves only slightly in H2O. 84 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The battery provides the electrical energy necessary for the reaction to occur. [9] [OVER] Regents Examination in Physical Setting/Chemistry August 2007 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) The Chart for Determining the Final Examination Score for the August 2007 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, August 16, 2007. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. Submitting Teacher Evaluations of the Test to the Department Suggestions and feedback from teachers provide an important contribution to the test development process. The Department provides an online evaluation form for State assessments. It contains spaces for teachers to respond to several specific questions and to make suggestions. Instructions for completing the evaluation form are as follows: 1. Go to www.emsc.nysed.gov/osa/exameval. 2. Select the test title. 3. Complete the required demographic fields. 4. Complete each evaluation question and provide comments in the space provided. 5. Click the SUBMIT button at the bottom of the page to submit the completed form. [11] Map to Core Curriculum August 2007 Physical Setting/Chemistry Key Ideas/Performance Indicators Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Science Inquiry Key Idea 1 Science Inquiry Key Idea 2 Science Inquiry Key Idea 3 Question Numbers Part A Part B Standard 1 37, 40, 56 31, 37, 40, 51, 60 41, 46 45 37, 44, 47, 63, 64, 65 Part C 73, 74, 79, 81 71, 79, 81 83, 84 68, 69, 72, 75, 78, 80, 83 Engineering Design Key Idea 1 Standard 2 Key Idea 1 Key Idea 2 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 61 76 48 62 Standard 7 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 Key Idea 3 Key Idea 4 Key Idea 5 2002 Edition Standard 4 Process Skills 32, 33, 34, 35, 36, 38, 39, 42, 43, 44, 45, 46, 47, 49, 52, 53, 54, 55, 58, 63, 66 57, 59, 60, 61, 62 41 Standard 4 1, 2, 3, 4, 5, 7, 8, 32, 33, 34, 35, 9, 10, 11, 15, 17, 37, 38, 39, 42, 18, 19, 20, 22, 43, 44, 45, 46, 23, 24, 25, 26, 47, 48, 51, 52, 27, 29, 30 53, 54, 55, 56, 58, 63, 64, 65, 66 28 40, 50, 57, 59, 60, 61, 62 6, 12, 13, 14, 16, 31, 36, 41, 49, 50 21 Reference Tables 4, 5, 7, 11, 12, 31, 33, 34, 39, 16, 22, 23, 25, 40, 47, 52, 53, 26, 27, 28, 30 54, 64, 65, 66 [12] 67, 70, 71, 77, 79, 80 82 67, 68, 69, 70, 71, 72, 73, 74, 75, 77, 78, 79, 80, 83, 84 81, 82 76 67, 68, 69, 71, 72, 78, 79, 80, 82, 83 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Thursday, January 24, 2008 — 1:15 to 4:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Check this web site http://www.emsc.nysed.gov/osa/ and select the link “Examination Scoring Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and several times throughout the Regents examination period. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . .1. . . . . . . 11 . . . . .4. . . . . . . 21 . . . . 1 ....... 31 . . . . . 4. . . . . . . 41 . . . . . 1. . . . . . . 2 . . . . .2. . . . . . . 12 . . . . .3. . . . . . . 22 . . . . 2 ....... 32 . . . . . 1. . . . . . . 42 . . . . . 2. . . . . . . 3 . . . . .3. . . . . . . 13 . . . . .3. . . . . . . 23 . . . . 1 ....... 33 . . . . . 4. . . . . . . 43 . . . . . 1. . . . . . . 4 . . . . .2. . . . . . . 14 . . . . .1. . . . . . . 24 . . . . 3 ....... 34 . . . . . 4. . . . . . . 44 . . . . . 3. . . . . . . 5 . . . . .2. . . . . . . 15 . . . . .3. . . . . . . 25 . . . . 4 ....... 35 . . . . . 2. . . . . . . 45 . . . . . 2. . . . . . . 6 . . . . .4. . . . . . . 16 . . . . .4. . . . . . . 26 . . . . 4 ....... 36 . . . . . 2. . . . . . . 46 . . . . . 4. . . . . . . 7 . . . . .1. . . . . . . 17 . . . . .2. . . . . . . 27 . . . . 1 ....... 37 . . . . . 1. . . . . . . 47 . . . . . 2. . . . . . . 8 . . . . .4. . . . . . . 18 . . . . .3. . . . . . . 28 . . . . 1 ....... 38 . . . . . 2. . . . . . . 48 . . . . . 4. . . . . . . 9 . . . . .3. . . . . . . 19 . . . . .2. . . . . . . 29 . . . . 1 ....... 39 . . . . . 2. . . . . . . 49 . . . . . 4. . . . . . . 10 . . . . .3. . . . . . . 20 . . . . .3. . . . . . . 30 . . . . 4 ....... 40 . . . . . 2. . . . . . . 50 . . . . . 2. . . . . . . PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a check mark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, January 24, 2008. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 15 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit. Acceptable responses include, but are not limited to: form 1+ ions react vigorously with water easily lose one electron form ionic bonds with nonmetals form halides with the general formula MX 52 [1] Allow 1 credit. Potential Energy Example of a 1-credit response: Reaction Coordinate 53 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 2–7–4–1 2–7–5 2–8–3–1 1–8–5 Note: Do not allow credit for 2–8–4. [4] PHYSICAL SETTING/CHEMISTRY – continued 54 [1] Allow 1 credit for C4H9. 55 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The electron-shell diagram shows the total number of protons and the total number of neutrons in an atom. shows number of electrons in each inner shell shows total number of protons in an atom shows the number of electron shells 56 [1] Allow 1 credit for 23. 57 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Lewis electron-dot diagrams only show valence electrons, which are involved in bonding. shows only electrons involved in bonding 58 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 801°C to 1465°C 59 [1] Allow 1 credit. Acceptable responses include, but are not limited to: AB CD 60 [1] Allow 1 credit for CD. 61 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The rate of the forward reaction equals the rate of the reverse reaction. [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 62 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The H+(aq) concentration increases. [H3O+] increases. Concentration increases. 63 [1] Allow 1 credit. Examples of 1-credit responses: O H HO C C H H O C C OH 64 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The solubility of KNO3(s) is not affected by an increase in pressure. When the pressure on the solution increases, the solubility of KNO3 remains the same. 65 [1] Allow 1 credit for 62 g ± 2 g. [6] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 20 credits for this part. The student must answer all questions in this part. 66 [1] Allow 1 credit. Acceptable responses include, but are not limited to: alcohol 67 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Water and 1,2-ethanediol molecules are both polar. Both molecules have similar polarity. 68 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: 6690 g 62.0 g/mol 6690 62 • Allow 1 credit for 108 mol or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. 69 [1] Allow 1 credit for 3 S(s) + 2 KClO3(s) → 3 SO2(g) + 2 KCl(s) + energy. 70 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The activation energy results from striking the balls together. heat produced as the balls collide mechanical energy friction [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 71 [1] Allow 1 credit for +5. 72 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Methanol does not conduct an electric current. Bromthymol blue tests blue in a base and yellow in an acid, so bottle B must be methanol. Bromthymol blue would be green in methanol because methanol is not an acid or a base. 73 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Test: bromthymol blue Test result: yellow Test: reactivity with Mg Test result: reaction 74 [1] Allow 1 credit. Acceptable responses include, but are not limited to: All three solutions have a pH greater than 4.4. Methyl orange changes to yellow at a pH of 4.4, which is still in the acid range. A solution with a pH greater than 4.4 could be acidic, basic, or neutral. 75 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: q = mCΔT = (100.0 g)(4.18 J/g•°C)(57.0°C − 22.0°C) (100)(4.18)(35) • Allow 1 credit for 14 600 J or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. 76 [1] Allow 1 credit for −14% or 14%. Significant figures do not need to be shown. [8] PHYSICAL SETTING/CHEMISTRY – continued 77 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 12 × 100 (2 × 23) + 12 + (3 × 16) 12 g /mol × 100 106 g / mol 78 [1] Allow 1 credit. Acceptable responses include, but are not limited to: decomposition endothermic 79 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 3.5 mol 3 1 mol 2 7 2 80 mol [1] Allow 1 credit. Acceptable responses include, but are not limited to: melting vaporization solidification 81 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The burning candle releases heat and light. A cobalt chloride test indicates water is produced. A limewater test indicates carbon dioxide gas is produced. [9] [OVER] PHYSICAL SETTING/CHEMISTRY – concluded 82 [1] Allow 1 credit for 124°C ± 2°C. 83 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As molar mass increases, there are stronger intermolecular forces. The forces are greater between heavier molecules. [10] Regents Examination in Physical Setting/Chemistry January 2008 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) The Chart for Determining the Final Examination Score for the January 2008 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, January 24, 2008. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. Submitting Teacher Evaluations of the Test to the Department Suggestions and feedback from teachers provide an important contribution to the test development process. The Department provides an online evaluation form for State assessments. It contains spaces for teachers to respond to several specific questions and to make suggestions. Instructions for completing the evaluation form are as follows: 1. Go to www.emsc.nysed.gov/osa/exameval. 2. Select the test title. 3. Complete the required demographic fields. 4. Complete each evaluation question and provide comments in the space provided. 5. Click the SUBMIT button at the bottom of the page to submit the completed form. [11] [OVER] Map to Core Curriculum January 2008 Physical Setting/Chemistry Question Numbers Key Ideas Part A Standard 1 Math Key Idea 1 Math Key Idea 2 Part B 38, 41, 46 34, 43, 49, 54, 56, 58, 65 55, 57, 61, 64 Math Key Idea 3 Sci. Inquiry Key Idea 1 Sci. Inquiry Key Idea 2 35, 37, 39, 40, 47, 53, 65 Sci. Inquiry Key Idea 3 Part C 68, 75, 76, 77, 82 68, 69, 71, 79 70, 72, 80, 81 66, 69, 71, 72, 73 Eng. Design Key Idea 1 Standard 2 Key Idea 1 Key Idea 2 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 41 48 62 64, 65 82, 83 Standard 7 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Standard 4 Process Skills 31, 32, 33, 34, 38, 41, 42, 44, 45, 46, 47, 51, 53, 54, 55, 56, 61, 62, 63, 65 49, 50, 52, 58, 59, 60 Key Idea 5 Key Idea 3 36, 57 Standard 4 1, 2, 3, 4, 5, 6, 7, 8, 9, 13, 14, 15, 16, 17, 18, 19, 21, 22, 23, 24, 25, 27, 29 Key Idea 4 20, 28, 30 Key Idea 5 10, 11, 12, 26 31, 32, 33, 34, 37, 38, 39, 41, 42, 43, 44, 45, 46, 47, 48, 51, 53, 54, 55, 56, 61, 62, 63, 64, 65 40, 49, 50, 52, 58, 59 66, 67, 68, 69, 73, 74, 77, 78, 79, 80, 81 70, 75 83 66, 67, 68, 69, 71, 72, 73, 74, 77, 78, 79, 80, 81, 82 70, 75, 76 35, 36, 57, 60 83 34, 35, 36, 37, 38, 40, 41, 42, 43, 46, 47, 49, 50, 51, 53, 63, 64, 65 66, 71, 74, 75, 76, 77 Reference Tables 2002 Edition 2, 3, 6, 8, 14, 15, 19, 22, 25, 27, 28 [12] FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Wednesday, August 13, 2008 — 12:30 to 3:30 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Check this web site http://www.emsc.nysed.gov/osa/ and select the link “Examination Scoring Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and several times throughout the Regents examination period. Part A and Part B–1 Allow 1 credit for each correct response. Part B–1 Part A 1 . . . . .4. . . . . . . 11 . . . . .2. . . . . . . 21 . . . . 2 ....... 31 . . . . . 2. . . . . . . 41 . . . . . 1. . . . . . . 2 . . . . .3. . . . . . . 12 . . . . .3. . . . . . . 22 . . . . 1 ....... 32 . . . . . 1. . . . . . . 42 . . . . . 1. . . . . . . 3 . . . . .1. . . . . . . 13 . . . . .4. . . . . . . 23 . . . . 2 ....... 33 . . . . . 2. . . . . . . 43 . . . . . 4. . . . . . . 4 . . . . .2. . . . . . . 14 . . . . .4. . . . . . . 24 . . . . 3 ....... 34 . . . . . 4. . . . . . . 44 . . . . . 3. . . . . . . 5 . . . . .1. . . . . . . 15 . . . . .3. . . . . . . 25 . . . . 1 ....... 35 . . . . . 2. . . . . . . 45 . . . . . 4. . . . . . . 6 . . . . .4. . . . . . . 16 . . . . .4. . . . . . . 26 . . . . 1 ....... 36 . . . . . 1. . . . . . . 46 . . . . . 3. . . . . . . 7 . . . . .4. . . . . . . 17 . . . . .1. . . . . . . 27 . . . . 4 ....... 37 . . . . . 3. . . . . . . 47 . . . . . 2. . . . . . . 8 . . . . .1. . . . . . . 18 . . . . .3. . . . . . . 28 . . . . 3 ....... 38 . . . . . 2. . . . . . . 48 . . . . . 4. . . . . . . 9 . . . . .2. . . . . . . 19 . . . . .2. . . . . . . 29 . . . . 3 ....... 39 . . . . . 3. . . . . . . 49 . . . . . 3. . . . . . . 10 . . . . .1. . . . . . . 20 . . . . .3. . . . . . . 30 . . . . 4 ....... 40 . . . . . 2. . . . . . . 50 . . . . . 3. . . . . . . PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a check mark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, August 13, 2008. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 18 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Cl– sulfate carbonate ion any halide sulfide OH– CrO42– PO43– 52 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Place the sample on a solid surface. Strike the sample with a hammer several times to see if the sample flattens. Try to bend the sample to change the shape. 53 [2] Allow a maximum of 2 credits, 1 credit for each acceptable response. Acceptable responses include, but are not limited to: Increasing the temperature of the reaction causes the reacting particles to move faster and collide more frequently. Increasing the concentration increases the number of particle collisions. Increasing the surface area (solid reactant) allows a greater number of particles to collide. Adding a catalyst provides an alternate way for the particles to react. [4] PHYSICAL SETTING/CHEMISTRY – continued 54 [1] Allow 1 credit. Acceptable responses include, but are not limited to: An atom of copper-63 has two fewer neutrons than an atom of copper-65. An atom of Cu-63 has 34 neutrons and an atom of Cu-65 has 36 neutrons. 55 [1] Allow 1 credit for 29. 56 [1] Allow 1 credit for 5 or five. 57 [1] Allow 1 credit. Acceptable responses include, but are not limited to: (0.6917)(62.930 u) + (0.3083)(64.928 u) (69.17)(62.930) + (30.83)(64.928) 100 58 [1] Allow 1 credit for 79°C ± 1°C. Significant figures do not need to be shown. 59 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: 65.0 g 838 J 1g (65)(838) • Allow 1 credit for 5.45 × 104 J or 54 500 J or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 60 [1] Allow 1 credit. Acceptable responses include, but are not limited to: esterification dehydration synthesis 61 [1] Allow 1 credit for C6H12O2. The order of the elements can vary. 62 [1] Allow 1 credit. Examples of 1-credit responses: H H H C C OH H H HO C C 2 63 [1] Allow 1 credit for ____Mg(s) + ____HCl(aq) → _____MgCl2(aq) + _____H2(g). Allow credit even if the coefficient “1” is written in front of Mg(s), MgCl2(aq), and/or H2(g). 64 [1] Allow 1 credit. Acceptable responses include, but are not limited to: nonpolar covalent bond covalent bond nonpolar [6] PHYSICAL SETTING/CHEMISTRY – continued 65 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: V2 = (99.5 kPa)(45.6 mL)(273 K ) (293 K)(101.3 kPa) (99.5)(45.6) (101.3) x = 293 273 • Allow 1 credit for 41.7 mL or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 17 credits for this part. The student must answer all questions in this part. 66 [1] Allow 1 credit for plotting all four points correctly ± 0.3 grid space. Plotted points do not need to be circled or connected. Example of a 1-credit response: Light Energy Versus Frequency 5.0 Energy (× 10–19 J) 4.0 3.0 2.0 1.0 0 0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 Frequency (× 1014 Hz) 67 [1] Allow 1 credit for 1.5 × 10–19 J ± 0.1 × 10–19 J or for a response consistent with the student’s graph. 68 [1] Allow 1 credit. Acceptable responses include, but are not limited to: When the electron in a hydrogen atom moves from a higher energy state to a lower energy state, a specific amount of energy is emitted. Light is emitted when electrons drop from higher electron shells to lower electron shells. 69 [1] Allow 1 credit. Acceptable responses include, but are not limited to: high temperature [8] PHYSICAL SETTING/CHEMISTRY – continued 70 [1] Allow 1 credit. Acceptable responses include, but are not limited to: In graphite, the electrons in the bonds between carbon atoms in different layers are only loosely held, but in diamond all of the electrons in the bonds are strongly held. Graphite has electrons that can move more freely than the electrons in diamond. 71 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: V= 0.200 g m = d 3.51 g /cm3 0.200 g 1 cm3 3.51 g 0.2 3.51 • Allow 1 credit for 0.0570 cm3 or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. 72 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The boiling point of O3 is 161 K, and the boiling point of O2 is 90 K. Therefore, intermolecular forces between O3 molecules are stronger than between O2 molecules. The intermolecular forces between oxygen molecules are weaker than those between molecules of ozone. 73 [1] Allow 1 credit for a diagram with at least six molecules drawn far apart and in a random arrangement. Example of a 1-credit response: Key = propane molecule [9] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 74 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: mass = (number of moles) (gram molecular mass) = (5.0 mol)((3)(12 g/mol) + (8)(1 g/mol)) 5.0 mol × 44 g 1.0 mol (5)(44) • Allow 1 credit for 220 g or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. 75 [1] Allow 1 credit for 15 mol. 76 [1] Allow 1 credit for Y(OH)3. 77 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 0.055 g × 1000 250. g 0.055 × 100 250 78 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Energy flows from the skin to the surroundings. Heat is transferred from the skin to the water in sweat. [10] PHYSICAL SETTING/CHEMISTRY – concluded 79 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Charged particles are free to move when salts dissolve in water. The ions in the salts dissociate and are free to move. The salts form aqueous solutions that can conduct electric current. 80 [1] Allow 1 credit. Examples of 1-credit responses: Na+ K + Note: Do not accept a response that has dots around the element symbol. [11] [OVER] Regents Examination in Physical Setting/Chemistry August 2008 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) The Chart for Determining the Final Examination Score for the August 2008 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Wednesday, August 13, 2008. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. Submitting Teacher Evaluations of the Test to the Department Suggestions and feedback from teachers provide an important contribution to the test development process. The Department provides an online evaluation form for State assessments. It contains spaces for teachers to respond to several specific questions and to make suggestions. Instructions for completing the evaluation form are as follows: 1. Go to www.emsc.nysed.gov/osa/exameval. 2. Select the test title. 3. Complete the required demographic fields. 4. Complete each evaluation question and provide comments in the space provided. 5. Click the SUBMIT button at the bottom of the page to submit the completed form. [12] Map to Core Curriculum August 2008 Physical Setting/Chemistry Key Ideas/Performance Indicators Question Numbers Part A Standard 1 Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Science Inquiry Key Idea 1 Science Inquiry Key Idea 2 Science Inquiry Key Idea 3 Part B Part C 37, 43, 47, 56, 57, 59, 65 36, 43 35, 47, 49, 59, 63, 65 53 52 31, 32, 33, 41, 42, 43, 45, 46, 51, 58, 60, 61, 62 66, 67, 71, 73, 74, 76, 77 51 68 71, 74, 75, 76 68, 70, 72 76, 79 Engineering Design Key Idea 1 Standard 2 Key Idea 1 Key Idea 2 Standard 6 78 69, 73 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 Standard 7 Key Idea 1 Key Idea 2 Standard 4 Process Skills Key Idea 3 Key Idea 4 Key Idea 5 Key Idea 3 Standard 4 1, 2, 3, 4, 5, 6, 7, 8, 9, 11, 14, 15, 16, 17, 19, 20, 21, 22, 23, 24, 25, 26, 27, 29 Key Idea 4 28, 30 Key Idea 5 10, 12, 13, 18 ESRT 2001 Edition (Revised) 3, 4, 5, 6, 7, 8, 9, 10, 15, 19, 21, 25 [13] 31, 32, 33, 34, 37, 38, 39, 40, 45, 47, 53, 54, 55, 57, 60, 62, 63, 65 44, 48, 49, 50, 59 64 73, 74, 75, 77 31, 32, 33, 34, 35, 38, 39, 40, 41, 42, 43, 45, 46, 47, 51, 52, 53, 54, 55, 56, 57, 60, 61, 62, 63, 65 37, 44, 48, 49, 50, 58, 59 36, 64 66, 67, 68, 69, 71, 73, 74, 75, 76, 77, 79 31, 32, 33, 35, 36, 37, 39, 41, 43, 47, 48, 51, 55, 58, 59, 61, 62, 64, 65 69, 71, 72, 74, 76, 77, 80 72, 80 78 70, 72, 80 FOR TEACHERS ONLY The University of the State of New York REGENTS HIGH SCHOOL EXAMINATION PS–CH PHYSICAL SETTING/CHEMISTRY Thursday, January 29, 2009 — 1:15 to 4:15 p.m., only SCORING KEY AND RATING GUIDE Directions to the Teacher: Refer to the directions on page 3 before rating student papers. Updated information regarding the rating of this examination may be posted on the New York State Education Department’s web site during the rating period. Check this web site http://www.emsc.nysed.gov/osa/ and select the link “Examination Scoring Information” for any recently posted information regarding this examination. This site should be checked before the rating process for this examination begins and several times throughout the Regents examination period. Part A and Part B–1 Allow 1 credit for each correct response. Part AA Part PartPart B–1B–1 1 . . . . .2. . . . . . . 11 . . . . .2. . . . . . . 21 . . . . 1 ....... 31 . . . . . 2. . . . . . . 41 . . . . . 4. . . . . . . 2 . . . . .3. . . . . . . 12 . . . . .3. . . . . . . 22 . . . . 4 ....... 32 . . . . . 2. . . . . . . 42 . . . . . 1. . . . . . . 3 . . . . .2. . . . . . . 13 . . . . .4. . . . . . . 23 . . . . 3 ....... 33 . . . . . 4. . . . . . . 43 . . . . . 1. . . . . . . 4 . . . . .3. . . . . . . 14 . . . . .1. . . . . . . 24 . . . . 2 ....... 34 . . . . . 3. . . . . . . 44 . . . . . 2. . . . . . . 5 . . . . .4. . . . . . . 15 . . . . .3. . . . . . . 25 . . . . 3 ....... 35 . . . . . 3. . . . . . . 45 . . . . . 1. . . . . . . 6 . . . . .4. . . . . . . 16 . . . . .1. . . . . . . 26 . . . . 4 ....... 36 . . . . . 4. . . . . . . 46 . . . . . 1. . . . . . . 7 . . . . .2. . . . . . . 17 . . . . .4. . . . . . . 27 . . . . 3 ....... 37 . . . . . 4. . . . . . . 47 . . . . . 3. . . . . . . 8 . . . . .2. . . . . . . 18 . . . . .3. . . . . . . 28 . . . . 2 ....... 38 . . . . . 2. . . . . . . 48 . . . . . 2. . . . . . . 9 . . . . .2. . . . . . . 19 . . . . .3. . . . . . . 29 . . . . 3 ....... 39 . . . . . 3. . . . . . . 49 . . . . . 3. . . . . . . 10 . . . . .1. . . . . . . 20 . . . . .1. . . . . . . 30 . . . . 1 ....... 40 . . . . . 4. . . . . . . 50 . . . . . 3. . . . . . . PHYSICAL SETTING/CHEMISTRY – continued Directions to the Teacher Follow the procedures below for scoring student answer papers for the Physical Setting/Chemistry examination. Additional information about scoring is provided in the publication Information Booklet for Scoring Regents Examinations in the Sciences. Use only red ink or red pencil in rating Regents papers. Do not correct the student’s work by making insertions or changes of any kind. On the detachable answer sheet for Part A and Part B–1, indicate by means of a check mark each incorrect or omitted answer. In the box provided at the end of each part, record the number of questions the student answered correctly for that part. At least two science teachers must participate in the scoring of each student’s responses to the Part B–2 and Part C open-ended questions. Each of these teachers should be responsible for scoring a selected number of the open-ended questions on each answer paper. No one teacher is to score all the open-ended questions on a student’s answer paper. Students’ responses must be scored strictly according to the Scoring Key and Rating Guide. For open-ended questions, credit may be allowed for responses other than those given in the rating guide if the response is a scientifically accurate answer to the question and demonstrates adequate knowledge as indicated by the examples in the rating guide. Complete sentences are not required. Phrases, diagrams, and symbols may be used. In the student’s answer booklet, record the number of credits earned for each answer in the box printed to the right of the answer lines or spaces for that question. Fractional credit is not allowed. Only whole-number credit may be given to a response. Units need not be given when the wording of the questions allows such omissions. Raters should enter the scores earned for Part A, Part B–1, Part B–2, and Part C on the appropriate lines in the box printed on the answer booklet and then should add these four scores and enter the total in the box labeled “Total Written Test Score.” Then, the student’s raw score should be converted to a scaled score by using the conversion chart that will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, January 29, 2009. The student’s scaled score should be entered in the labeled box on the student’s answer booklet. The scaled score is the student’s final examination score. All student answer papers that receive a scaled score of 60 through 64 must be scored a second time. For the second scoring, a different committee of teachers may score the student’s paper or the original committee may score the paper, except that no teacher may score the same open-ended questions that he/she scored in the first rating of the paper. The school principal is responsible for assuring that the student’s final examination score is based on a fair, accurate, and reliable scoring of the student’s answer paper. Because scaled scores corresponding to raw scores in the conversion chart may change from one examination to another, it is crucial that for each administration, the conversion chart provided for that administration be used to determine the student’s final score. [3] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part B–2 Allow a total of 16 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit. The specific positioning of the dots may vary. Examples of 1-credit responses: B B 52 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Neon has atoms with a complete outer shell of electrons. Neon has a complete octet. Neon has eight valence electrons. 53 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The rate of the forward reaction decreases because there are fewer N2 molecules to collide with H2 molecules. The rate slows down because collisions are less frequent. fewer effective collisions [4] PHYSICAL SETTING/CHEMISTRY – continued 54 [1] Allow 1 credit for 1.94 g. 55 [1] Allow 1 credit. Acceptable responses include, but are not limited to: A Ca2+ ion has two fewer electrons than a Ca atom, so the ion is smaller. Ca has an electron configuration of 2-8-8-2, and Ca2+ has an electron configuration of 2-8-8, so the ion is smaller. 56 [1] Allow 1 credit for correctly plotting all six points ± 0.1 grid space. Plotted points do not need to be circled or connected. Example of a 1-credit response: Solubility of NH4Br in H2O Versus Temperature Mass of NH4Br per 100. g of H2O (g) 150. 120. 90. 60. 30. 0 0 10. 20. 30. 40. 50. 60. 70. 80. 90. 100. Temperature (°C) 57 [1] Allow 1 credit for 210. g or for a response consistent with the student’s graph in question 56. Significant figures do not need to be shown. 58 [1] Allow 1 credit. Acceptable responses include, but are not limited to: As temperature increases, the solubility of NH4Br(s) in H2O increases and the solubility of NH3(g) in H2O decreases. NH4Br becomes more soluble and NH3 becomes less soluble. [5] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 59 [1] Allow 1 credit for identifying one physical property and one chemical property of CS2. Acceptable responses include, but are not limited to: Physical property: liquid at room temperature colorless odor boiling point above room temperature Chemical property: CS2 can be decomposed into C and S. flammable 60 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The potential energy of the CO2 molecules increases. PE increases. 61 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Carbon disulfide has stronger intermolecular forces than carbon dioxide. CO2 has weaker intermolecular forces. 62 [1] Allow 1 credit. Examples of 1-credit responses: H H H H H C C C C H H H H H C C C C [6] PHYSICAL SETTING/CHEMISTRY – continued 63 [1] Allow 1 credit. Acceptable responses include, but are not limited to: pentane C5H12 64 [1] Allow 1 credit for 231 K. 65 [1] Allow 1 credit for 3 or three. 66 [1] Allow 1 credit. Acceptable responses include, but are not limited to: V2 112 mL = 298 K 273 K (112)(273)(1) (298)(1) [7] [OVER] PHYSICAL SETTING/CHEMISTRY – continued Part C Allow a total of 19 credits for this part. The student must answer all questions in this part. 67 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Electrons flow from the magnesium block to the iron pipe. Electrons flow from the Mg to the Fe through the wire. Electrons flow from the anode to the cathode in a voltaic cell. from the block to the pipe 68 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Magnesium atoms lose electrons more easily than zinc atoms. Mg oxidizes more readily than Zn. Mg is more active than Zn. 69 [1] Allow 1 credit. Acceptable responses include, but are not limited to: 2HI(g) → H2(g) + I2(g) 2HI → I2 + H2 70 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The concentration of each product and the concentration of the reactant remain the same. The concentrations have reached constant levels. The horizontal lines on the graph show that the concentrations are constant. Note: Do not allow credit for a response stating the color of the gas is not changing, without including a reference to concentration. [8] PHYSICAL SETTING/CHEMISTRY – continued 71 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: 126.905 × 2 = 253.810 g/mol (0.013 M)(1.00 L)(253.810 g/mol) mass = 0.013 × 254 • Allow 1 credit for 3.3 g or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. 72 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The hydroxide ion concentration is greater than the hydrogen ion concentration. The H3O+ concentration is less than the OH− concentration. [OH−] > [H3O+] 73 [1] Allow 1 credit. Acceptable responses include, but are not limited to: The pH is between 4.4 and 6.0, which indicates an acidic soil. The pH of the soil surrounding the plant is below 6.0. For chlorosis, the soil pH must be above 7. 74 [1] Allow 1 credit. Acceptable responses include, but are not limited to: H3O+(aq) + OH−(aq) → 2H2O(ᐉ) H+ + OH− → HOH hydrogen ions + hydroxide ions → water hydroxide ions + hydronium ions → water 75 [1] Allow 1 credit. Acceptable responses include, but are not limited to: yttrium oxide [9] [OVER] PHYSICAL SETTING/CHEMISTRY – continued 76 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: (11)(26.981 54 g /mol) × 100 (140.12 g /mol) + (24.305 g /mol) + 11(26.981 54 g /mol) + 19(15.9994 g /mol) 297 × 100 765 • Allow 1 credit for 38.8% or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. 77 [1] Allow 1 credit. Acceptable responses include, but are not limited to: Electrons move from the ground state to an excited state as the compounds gain energy. Light energy is released when the electrons return to lower states. Electrons lose energy as they move to lower shells. Light is emitted as electrons return from higher to lower energy states. 78 [2] Allow a maximum of 2 credits, allocated as follows: • Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to: (0.000 156)(3.78 kg) 0.0156 × 3.78 100 • Allow 1 credit for 5.90 × 10−4 kg or 0.000 590 kg or for a response consistent with the student’s numerical setup. Significant figures do not need to be shown. Note: Do not allow credit for a numerical setup and calculated result that are not related to the concept assessed by the question. [10] PHYSICAL SETTING/CHEMISTRY – concluded 79 [1] Allow 1 credit for 10n. 80 [2] Allow a maximum of 2 credits, 1 credit for each acceptable response. Acceptable responses include, but are not limited to: A butanoic acid molecule has four carbon atoms and an ethanol molecule has two carbon atoms. Butanoic acid has a different functional group than ethanol. A butanoic acid molecule has more hydrogen atoms than an ethanol molecule. In a butanoic acid molecule, one oxygen atom has a double bond and in an ethanol molecule, the oxygen atom has two single bonds. 81 [1] Allow 1 credit. Acceptable responses include, but are not limited to: esterification dehydration synthesis [11] [OVER] Regents Examination in Physical Setting/Chemistry January 2009 Chart for Converting Total Test Raw Scores to Final Examination Scores (Scaled Scores) The Chart for Determining the Final Examination Score for the January 2009 Regents Examination in Physical Setting/Chemistry will be posted on the Department’s web site http://www.emsc.nysed.gov/osa/ on Thursday, January 29, 2009. Conversion charts provided for previous administrations of the Regents Examination in Physical Setting/Chemistry must NOT be used to determine students’ final scores for this administration. Online Submission of Teacher Evaluations of the Test to the Department Suggestions and feedback from teachers provide an important contribution to the test development process. The Department provides an online evaluation form for State assessments. It contains spaces for teachers to respond to several specific questions and to make suggestions. Instructions for completing the evaluation form are as follows: 1. Go to www.emsc.nysed.gov/osa/exameval. 2. Select the test title. 3. Complete the required demographic fields. 4. Complete each evaluation question and provide comments in the space provided. 5. Click the SUBMIT button at the bottom of the page to submit the completed form. [12] Map to Core Curriculum January 2009 Physical Setting/Chemistry Key Ideas/Performance Indicators Question Numbers Part A Standard 1 Math Key Idea 1 Math Key Idea 2 Math Key Idea 3 Science Inquiry Key Idea 1 Science Inquiry Key Idea 2 Science Inquiry Key Idea 3 Part B Part C 37,38,49,56,64,65 35,58 37,44,54,57,64,66 41,53,55 76 70 71,76,78 68,77,80 32,36,37,46,48,49, 57,63 68,69,72,73,75 Engineering Design Key Idea 1 Standard 2 59 Key Idea 1 Key Idea 2 Standard 6 Key Idea 1 Key Idea 2 Key Idea 3 Key Idea 4 Key Idea 5 42 Standard 7 Key Idea 1 Key Idea 2 Standard 4 Process Skills 31,32,33,34,39,40, 41,43,45,47,52,53, 54,57,58,62,66 38,39,42,50,60 45,51,61 Key Idea 3 Key Idea 4 Key Idea 5 67,69,70,71,73,74, 80,81 79 Standard 4 Key Idea 4 1,2,3,4,5,6,7,8,9, 10,11,15,16,17,18, 20,21,22,23,24,25, 26,27,28,30 14,19,29 Key Idea 5 12,13 2002 Edition 2,6,7,8,9,12,13,15, 25,27,28,30 Key Idea 3 31,32,33,34,36,40, 41,43,44,46,47,49, 53,54,56,57,58,59, 62,65,66 35,38,39,42,48,50, 60,63,64 37,45,51,52,55,61 67,68,69,70,71,72, 73,74,75,76,77,78, 80,81 79 Reference Tables [13] 33,34,37,38,43,44, 45,46,47,48,49,51, 55,62,64,66 67,68,71,73,74,75, 76,78,79,80,81