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Atomic Structure Cathode Ray and Electrons Rutherford and the Nucleus • Ancient Greek Philosopher (460-370 BC) • “Father of modern science” • Theorized that everything was composed of “atoms” which are indivisible and indestructible. • There are an infinite number of atoms and kinds of atoms. • French chemistry; 1743-1794 • Transformed chemistry from qualitative to quantitative. • Helped construct the metric system. • Proved the conservation of mass, replacing current theory with fact. • Guillotined during French Revolution. • English chemist; 1766-1844 • Elements are made of extremely small particles called atoms. • Atoms of a given element are identical in size, mass, and other properties; atoms of different elements differ in size, mass, and other properties. • Atoms cannot be subdivided, created, or destroyed. • Atoms of different elements combine in simple whole-number ratios to form chemical compounds. • In chemical reactions, atoms are combined, separated, or rearranged. J.J. Thomson • British physicist; 1856-1940 • Credited with discovery of the electron. • Used Cathode Ray Tubes (CRT) to show electron beam or cathode ray. • Invented the mass spectrometer. Cathode Ray Tube Experiment1 • The electrometer verified that the charge on the stream of particles was negative. Cathode Ray Tube Experiment2 • The ‘rays’ can be deflected with both a magnetic and electrical field. Thomson Atomic Model • Thomson put forth the ‘plum pudding’ model. • Electrons were scattered throughout a positive sphere. Ernest Rutherford • New Zealand Physicist; 1791-1867 • Credited with discovery of the nucleus and the proton. • Proved transmutation during radioactive decay. • First to split an atom. • Famous Gold Foil Experiment. Ernest Rutherford, Hans Geiger, Ernest Marsden Rutherford’s view of an atom. R.G.F Experimental Conclusions • Rejected JJ Thomson’s Plum Pudding Model. • Small positively charged center, nucleus. • Electrons surround the center in a cloud. • The atom is mostly empty space. Robert Millikan • American Physicist; 1868-1953 • Credited with finding the electronic charge on a single electron. • Famous oil drop experiment. • Proved existence of cosmic radiation. Oil Drop Experiment James Chadwick • British Physicist; 1891-1974 • Credited with the discovery of the neutron and its mass while working with Rutherford. • Worked on the Manhattan Project. • Studied radiation under Hans Geiger. Niels Bohr • Danish Physicist; 1885-1962 • Developed the orbital model of electron movement around the nucleus. • Developed quantum mechanics – the theory that electrons move between energy levels in discrete steps. • Proved that light can act like a wave and a particle. • Worked on the Manhattan Project.