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New Unit Energy and Reactions 1. Energy What is energy? Energy = ability to do work What is work? Work = TRANSFER of energy from one object to another. 1. Energy Energy exists in many forms - Kinetic Potential Thermal/Heat Chemical Electrical Electromagnetic/Light Mechanical Nuclear Sound 1. Energy IMPORTANT Energy CANNOT be created or destroyed 1. Energy IMPORTANT Energy CANNOT be created or destroyed Energy is CONVERTED from one form to another. 1. Energy IMPORTANT Energy CANNOT be created or destroyed Energy is CONVERTED from one form to another. 1. Energy IMPORTANT Energy CANNOT be created or destroyed Energy is CONVERTED from one form to another. 1. Energy IMPORTANT Energy CANNOT be created or destroyed Energy is CONVERTED from one form to another. 1. Energy In this class: changes in bond energy in reactions and physical changes 1. Energy 1. Explain the conservation of energy 2. Why might a one-step energy conversion be preferred over a two-step conversion? 2. Physical vs Chemical Changes 2. Physical Changes and Reactions How is a physical change different from a chemical change? Physical Changing outfits Chemical Example: Changing DNA 2. Physical Changes and Reactions Signs of a chemical change 1. Evolution of a gas 2. Formation of something solid 3. Change in appearance 4. Change in energy 2. Physical Changes and Reactions Both physical and chemical changes need energy or release energy Add energy to ice = water Ice melts = water and releases energy 2. Physical Changes and Reactions Both physical and chemical changes need energy or release energy Add energy to match Match burns = releases energy as fire 2. Physical Changes and Reactions Endothermic absorbs/needs energy Exothermic releases energy 2. Physical Changes and Reactions Show chemical changes with equations Reactants Products means “produces” 2. Physical Changes and Reactions Writing Reactions Baking soda, NaHCO3 combines with acetic acid, HC2H3O2 to produce sodium acetate NaC2H3O2, carbon dioxide CO2, and water H2O. Page 266 # 1,3,4,5,9,10,11,12 3. Types of Reactions 5 main categories Synthesis Decomposition Combustion Single Replacement Double Replacement 3. Types of Reactions Combustion Explanation: something with carbon + oxygen Example: C6H12O6 + 6O2 6CO2 + 6H2O Pattern: Carbon + O2 CO2 + H2O 3. Types of Reactions Synthesis Explanation: when two or more become one Example: H2 + O2 2H2O Pattern: A + B AB 3. Types of Reactions Decomposition Explanation: when one becomes two or more/breakup Example: 2H2O H2 + O2 Pattern: AB A + B 3. Types of Reactions Single Replacement Explanation: Love Triangle Example: Zn + CuSO4 Cu + ZnSO4 Pattern: A + BC B + AC 3. Types of Reactions Double Replacement Explanation: Soap Opera Drama Example:KCl+ NaNO2 NaCl + KNO2 Pattern: AB + CD AD + BC 4. Balancing Reactions OBJECTIVE: Applying Conservation of Mass to Reactions 4. Balancing Reactions Conservation of Mass: cannot create or destroy mass this means: there needs to be the same number of atoms on both sides of reaction 4. Balancing Reactions frame + wheels + chain + handlebars + pedals 1 bicycle 1 frame + 2 wheels + 1 chain + 1 handlebar + 2 pedals 1bicycle What are those numbers? COEFFICIENTS 4. Balancing Reactions H 2 + O 2 H 2O 4. Balancing Reactions H2 + O2 2H2O 4. Balancing Reactions 2H2 + O2 2H2O 4. Balancing Reactions 2H2 + O2 2H2O NEVER change subscripts 4. Balancing Reactions 2H2 + O2 2H2O CH4 + 2O2 CO2 + 2H2O Cu + 2AgNO3 2Ag + Cu(NO3)2 2KI + Pb(NO3)2 PbI2 + 2KNO3 What are those numbers? COEFFICIENTS 4. Balancing Reactions Strategy for Balancing Reactions 1. Start with compound 2. Add coefficients to balance 3. Leave single elements, like O2, H2, Al, Cu, etc. for last. 4. Use fractions if necessary. 5. Simplify if necessary. If fractions used, simplify fractions as well. 6. Check work. NEVER CHANGE SUBSCRIPTS! DO NOT SPLIT COMPOUNDS! A) Identify type of rxn B) Balance 1. Na + O2 Na2O2 2. Al + S8 Al2S3 3. O2 + C6H12O6 CO2 + H2O 4. Na + NaNO3 Na2O + N2 5. H3PO4 + KOH K3PO4 + H2O 6. NH3 + O2 N2 + H2O 4. Balancing Reactions Balancing Reactions with Polyatomic Ions Mg + OH Mg(OH)2 HgCl2 + AgNO3 Hg(NO3)2 +AgCl Al + Hg(CH3COO)2 Al(CH3COO)3 + Hg A) Identify type of rxn B) Balance 1. C2H6 + O2 CO2 + H2O 2. Al + HAsO3 H2 + Al(AsO3) 3 3. H3PO4 + Mg(OH) 2 2 Mg3 (PO4) + H2O 4. NH4OH + H3PO4 (NH4)3PO4 + H2O 5. Al(OH)3 + H2SO4 Al2(SO4)3 + H2O 6. C10H22 + O2 CO2 + H2O (fractions?) 4. Balancing Reactions How are coefficients different from subscripts? 2H2 + O2 2H2O subscripts = # of atoms 4. Balancing Reactions How are coefficients different from subscripts? 2H2 + O2 2H2O coefficients = how many 4. Balancing Reactions 2H2 + O2 2H2O subscripts = # of atoms coefficients = how many 4. Balancing Reactions H2 + O2 H2O2 subscripts = # of atoms coefficients = how many End of Chapter 8 Topics Covered 1. Energy 2. Physical vs. Chemical Changes 3. Types of Reactions 4. Balancing Reactions Sample Problem Methane, CH4, reacts with O2 to combust and produce the following: CO2 and H2O. This reaction results in the release of a large amount of energy. 1. Write a balanced reaction. 2. This is what type of reaction? 3. This reaction resulted in 49.1 grams of CO2. This is equal to how many moles? 4. CH4 is a covalent compound. Draw its Lewis Structure