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9-2 Single Replacement Reactions (SR) What happens if you put a piece of Aluminum foil into an aqueous solution of copper II chloride? Al (s) + CuCl2 (aq) → Cu (s) + AlCl3 (aq) Balance the above equation DEF: Single Replacement Reactions (SR) = A single, “morr” reactive substance replaces another in a compound. • Metals (potentially) replace metals. Use the Activity Series of the Metals. The higher up, the morr reactive. • Halogens (potentially) replace halogens. Use the periodic table or, the Activity Series of the Halogens. The higher up, the morr reactive. Decreasing Activity Activity Series of the Metals – See p 293 Element Lithium Rubidium Potassium Calcium Sodium Magnesium Aluminum Manganese Zinc Iron Nickel Tin Lead *Hydrogen Copper Mercury Silver Platinum Gold Symbol Li Rb K Ca Na Mg Al Mn Zn Fe Ni Sn Pb H (H2) Cu Hg Ag Pt Au Metals from Magnesium to Lead will replace H from ACIDS ONLY!! You will be given a copy of this chart for your test. There is also an activity series for the halogens (7A’s). They are already in order from most to least active on the periodic table, so there is no need to look at another chart. When working problems, you need to decide if your “alone” substance is a metal or a halogen. As stated above, metals potentially replace metals, and halogens potentially replace halogens. In our demo equation, 2 Al (s) + 3 CuCl2 (aq) → 3 Cu (s) + 2 AlCl3 (aq) Al was above Cu on the table, so the reaction did happen. If you are asked for the type of equation, even if the reaction doesn’t happen due to reactivity issues, you still classify it as a Single Replacement reaction (SR). Try These! Ex 1: Mg + Zn(NO3)2 → Ex 2: Li + Zn(NO3)2 → Ex 3: Ca + LiOH → Ex 4: Zn + H2SO4 → Ex 5: Zn + H2O → Ex 6: Cl2 + KBr → Ex 7: I2 + NaCl → Ex 8: Mg + H3PO4 → Ex 9: Rb + → H2O Let’s see some videos on the reactivity of rubidium in water! http://www.youtube.com/watch?v=m55kgyApYrY http://www.youtube.com/watch?v=GVoJZkmAAfA http://www.youtube.com/watch?v=sS3cIK9jlB8&feature=related http://www.youtube.com/watch?v=qliI4LXdqpQ&feature=related