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One-mole Amounts Periodic Table Group 1A: Alkali Metals Li, Na, K, Rb, Cs • Solids at room temp • Reactive • React with water to produce hydrogen and alkaline solutions. • Found in nature only in compounds, not as free element. Group 1A: Alkali Metals Li, Na, K, Rb, Cs Reaction of potassium + H2O Cutting sodium metal Group 2A: Alkaline Earth Metals Be, Mg, Ca, Sr, Ba, Ra • React similarly to alkali metals with water (except Be) • Occur inC nature only as compounds • Abundance: Ca – 5th Mg – 7th • Calcium carbonate – limestone, coral, marble, chalk, sea shells • Radium – radioactive, medicinal use Group 2A: Alkaline Earth Metals Be, Mg, Ca, Sr, Ba, Ra Magnesium Magnesium oxide Group 3A: B, Al, Ga, In, Tl • Aluminum most important; abundant in Earth’s crust • B only metalloid, the rest are metals Group 3A: B, Al, Ga, In, Tl Cu Al Al resists corrosion (here in nitric acid). Gallium is one of the few metals that can be liquid at room temp. Gems & Minerals • Sapphire: Al2O3 with Fe3+ or Ti3+ impurity gives blue whereas V3+ gives violet. • Ruby: Al2O3 with Cr3+ impurity Group 4A: C, Si, Ge, Sn, Pb • Form oxides of the form XO2 • Carbon – in living organisms – Has different elemental forms: allotropes • Diamond, Graphite, Buckyballs • Silicon oxides – clay quartz, gems Group 4A: C, Si, Ge, Sn, Pb Quartz, SiO2 Diamond Group 5A: N, P, As, Sb, Bi • Nitrogen (N2) – 75% of the atmosphere – In proteins, DNA, chlorophylls – Ammonia, NH3 • Phosphorous - can glow in the dark – In DNA and RNA – Red and White allotropes • Red – match tips • White – ignites spontaneously so stored under water Group 5A: N, P, As, Sb, Bi Ammonia, NH3 White and red phosphorus Group 6A: O, S, Se, Te, Po • Oxygen – 20% of the atmosphere – Powers most life on Earth • Sulfur – In proteins – Burning sulfur – brimstone Group 6A: O, S, Se, Te, Po Sulfuric acid dripping from snot-tite in cave in Mexico Elemental S has a ring structure. Group 7A: Halogens F, Cl, Br, I, At • Non-metals • Exist as diatomic molecules – F2, Cl2, Br2, I2 – F2, Cl2, Br2 gases at room temperature – I2 solid – At rare – React with alkali metals to form “salts” Group 7A: Halogens F, Cl, Br, I, At Group 8A: Noble Gases He, Ne, Ar, Kr, Xe, Rn • Least reactive – Some have no known compounds • Helium – produces by fusion of hydrogen in the sun Group 8A: Noble Gases He, Ne, Ar, Kr, Xe, Rn Transition Elements • All metals • Most found in compounds • Silver, gold, platinum less reactive and found as pure elements Lanthanides & Actinides •Not very abundant •Uranium is highest atomic number that occurs naturally. Those with greater atomic number are man made and often have short lifetime. Transition Elements Lanthanides and actinides Iron in air gives iron(III) oxide Colors of Transition Metal Compounds Iron Cobalt Nickel Copper Zinc