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Ch. 5 Notes---Scientific Measurement Qualitative vs. Quantitative • Qualitative measurements give results in a descriptive nonnumeric adjective describing form. (The result of a measurement is an _____________ the object.) short heavy cold *Examples: ___________, ___________, long, __________... • Quantitative measurements give results in numeric form. (The number results of a measurement contain a _____________.) 600 lbs. 5 ºC *Examples: 4’6”, __________, 22 meters, __________... Accuracy vs. Precision • single Accuracy is how close a ___________ measurement is to the true __________ value ________ of whatever is being measured. • several measurements are to Precision is how close ___________ each ___________. other _________ Practice Problem: Describe the shots for the targets. Bad Accuracy & Bad Precision Good Accuracy & Bad Precision Bad Accuracy & Good Precision Good Accuracy & Good Precision Significant Figures • Significant figures are used to determine the ______________ precision of a measurement. (It is a way of indicating how __________ precise a measurement is.) *Example: A scale may read a person’s weight as 135 lbs. Another scale may read the person’s weight as 135.13 lbs. The ___________ second more significant figures in the scale is more precise. It also has ______ measurement. • • • Whenever you are measuring a value, (such as the length of an object with a ruler), it must be recorded with the correct number of sig. figs. ALL the numbers of the measurement known for sure. Record ______ Record one last digit for the measurement that is estimated. (This reading in between the means that you will be ________________________________ marks of the device and taking a __________ guess __________ at what the next number is.) Significant Figures • Practice Problems: What is the length recorded to the correct number of significant figures? length = ________cm 11.65 (cm) 10 20 30 40 length = ________cm 58 50 60 70 80 90 100 Rules for Counting Significant Figures in a Measurement • When you are given a measurement, you will need to be aware of how many sig. figs. the value contains. (You’ll see why later on in this chapter.) Here is how you count the number of sig. figs. in a given measurement: #1 (Non-Zero Rule): All digits 1-9 are significant. 3 *Examples: 2.35 g =_____S.F. 2 S.F. 2200 g = _____ #2 (Straddle Rule): Zeros between two sig. figs. are significant. 3 4 *Examples: 205 m =_____S.F. 80.04 m =_____S.F. 5 7070700 cm =_____S.F. #3 (Righty-Righty Rule): Zeros to the right of a decimal point AND anywhere to the right of a sig. fig. are significant. 3 3 *Examples: 2.30 sec. =_____S.F. 20.0 sec. =_____S.F. 4 0.003060 km =_____S.F. Rules for Counting Significant Figures in a Measurement #4 (Bar Rule): Any zeros that have a bar placed over them are sig. (This will only be used for zeros that are not already significant because of Rules 2 & 3.) 4 *Examples: 3,000,000 m/s =_____S.F. 2 20 lbs =____S.F. #5 (Counting Rule): Any time the measurement is determined by simply counting the number of objects, the value has an infinite number of sig. figs. (This also includes any conversion factor involving counting.) ∞ ∞ *Examples: 15 students =_____S.F. 29 pencils = ____S.F. 7 days/week =____S.F. ∞ 60 sec/min =____S.F. ∞ Calculations Using Sig. Figs. • When adding or subtracting measurements, all answers are to be rounded off to the least # of ___________ found in decimal __________ places the original measurements. Example: + ≈ 157.17 • (only keep 2 decimal places) When multiplying or dividing measurements, all answers are to be significant_________ figures found in the rounded off to the least # of _________ original measurements. Practice Problems: (only keep 1 decimal place) 4.7 cm 2.83 cm + 4.009 cm − 2.1 cm = 4.739 cm ≈_____ 98 m2 36.4 m x 2.7 m = 98.28 m2 ≈ _____ (only keep 2 sig. figs) 5.9 g/mL 0.52 g ÷ 0.00888 mL = 5.855855 g/mL ≈ ____ (only keep 2 sig. figs) So What Does This All Mean? • • • When you measure and you then use a calculator you need to think about how many decimal places in your answer. When you use your calculator and multiply or divide give me three to five significant figures (or numbers). Don’t give me tons of decimal places. Practice Problems: 4.7 cm 2.83 cm + 4.009 cm − 2.1 cm = 4.739 cm ≈_____ 98 m2 36.4 m x 2.7 m = 98.28 m2 ≈ _____ (least amount of decimal places) (least amount of sig figs) amount of 0.52 g ÷ 0.00888 mL = 5.855855 g/mL ≈ 5.9 ____ g/mL(least sig figs) For Example • • • Lets say you are finding the average mass of beans. You would count how many beans you had and then find the mass of the beans. 26 beans have a mass of 44.56 grams. 44.56 grams ÷26 =1.713846154 grams So then what should your written answer be? How many decimal points did you have in your measurement? 2 Rounded answer = 1.71 grams • • The SI System (The Metric System) Here is a list of common units of measure used in science: Standard Metric Unit Quantity Measured mass kilogram, (gram) ______________ length meter ______________ volume cubic meter, (liter) ______________ seconds ______________ time temperature Kelvin, (˚Celsius) _____________ The following are common approximations used to convert from our English system of units to the metric system: 1 yard 1 m ≈ _________ 2.2 lbs. 1 kg ≈ _______ 1.609 km ≈ 1 mile mass of a small paper clip 1 gram ≈ ______________________ sugar cube’s volume 1mL ≈ _____________ 1 L ≈ 1.06 quarts dime 1mm ≈ thickness of a _______ The SI System (The Metric System) • Metric Conversions The metric system prefixes are based on factors of _______. Here is a mass list of the common prefixes used in chemistry: kilo- hecto- deka- • • deci- centi- milli- The box in the middle represents the standard unit of measure such as grams, liters, or meters. Moving from one prefix to another involves a factor of 10. cm = 10 _____ dm = 1 _____ m *Example: 1000 millimeters = 100 ____ • The prefixes are abbreviated as follows: k h da g, L, m d grams c Liters m meters *Examples of measurements: 5 km 2 dL 27 dag 3 m 45 mm Metric Conversions • To convert from one prefix to another, simply count how many places you move on the scale above, and that is the same # of places the decimal point will move in the same direction. Practice Problems: 380,000 380 km = ______________m 0.00145 1.45 mm = ______________m 4.61 461 mL = ____________dL 0.0004 dag 0.4 cg = ______________ 260 mg 0.26 g =_____________ 230 230,000 m = _______km Other Metric Equivalents 1 mL = 1 cm3 1 L = 1 dm3 For water only: 1 L = 1 dm3 = 1 kg of water or 1 mL = 1 cm3 = 1 g of water Practice Problems: 0.3 L (1) How many liters of water are there in 300 cm3 ? ___________ 50 kg (2) How many kg of water are there in 500 dL? _____________ Metric Volume: Cubic Meter (m3) 10 cm x 10 cm x 10 cm = Liter Area and Volume Conversions • If you see an exponent in the unit, that means when converting you will move the decimal point that many times more on the metric conversion scale. *Examples: twice cm2 to m2 ......move ___________ as many places 3 times as many places m3 to km3 ......move _____ 2 380,000,000 Practice Problems: 380 km2 = _________________m 3 0.00461 4.61 mm3 = _______________cm k h da g, L, m d c m grams Liters meters • Scientific Notation Scientific notation is a way of representing really large or small numbers using powers of 10. *Examples: 5,203,000,000,000 miles = 5.203 x 1012 miles 0.000 000 042 mm = 4.2 x 10−8 mm Steps for Writing Numbers in Scientific Notation (1) Write down all the sig. figs. (2) Put the decimal point between the first and second digit. (3) Write “x 10” (4) Count how many places the decimal point has moved from its original location. This will be the exponent...either + or −. (5) If the original # was greater than 1, the exponent is (__), + and if the − original # was less than 1, the exponent is (__)....(In other words, large + exponents, and small numbers have (_) − exponents. numbers have (__) Scientific Notation • Practice Problems: Write the following measurements in scientific notation or back to their expanded form. 477,000,000 miles = _______________miles 4.77 x 108 0.000 910 m = _________________ 9.10 x 10−4 m − 9 6,300,000,000 6.30 x 10 miles = ___________________ miles 0.00000388 kg 3.88 x 10−6 kg = __________________ • • • • Mass vs. Weight Mass depends on the amount of ___________ in the object. matter Weight depends on the force of ____________ acting on the object. gravity Weight ______________ may change as you move from one location to another; mass ____________ will not. Mass = 80 kg mass You have the same ____________ on the moon as on the earth, but you weigh ___________ less since there is less gravity on the moon. _________ Weight = 176 lbs. Mass = 80 kg Weight = 29 lbs. Density • • • • • Density is a ___________ ratio of an object’s mass and its volume. size Density does not depend on the _________ of the sample you have. The density of an object will determine if it will float or sink in less dense than the other another phase. If an object floats, it is _______ more substance. If it sinks, it is ________ dense. The density of water is 1.0 g/mL, and air has a density of 0.00129 g/mL (or 1.29 g/L). Density = Mass/Volume Mass = D x V Density = m/V Volume = m/D m D X V Density Practice Problems: • The density of gold is 19.3 g/cm3. How much would the mass of a bar of gold be? Assume a bar of gold has the following dimensions: L= 27 cm W= 9.0 cm H= 5.5 cm Volume = L x W x H Volume = 27 x 9.0 x 5.5 = 1336.5 cm3 mass = D x V mass = 19.3 g/cm3 x 1336.5 cm3 = 25,794.45 g mass ≈ 26,000 g = 26 kg ≈ 57 lbs. (2) Which picture shows the block’s position when placed in salt water? (3) Will the following object float in water? _______ No! It will sink. (D > 1) Object’s mass = 27 g Object’s volume= 25 mL Measuring Temperature • • Temperature is the ____________ hotness or ____________ coldness of an object. The Celsius temperature scale is based on the freezing point and water boiling point of __________. F.P.= 0˚C B.P.= 100˚C • The Kelvin temperature scale, (sometimes called the “absolute temp. lowest scale” is based on the ____________ temperature possible, absolute stop zero. (All molecular motion would __________.) Absolute Zero = 0˚ Kelvin = −273˚ C • To convert from one temp. scale to another: ˚C = Kelvin − 273 K= Celsius + 273 Practice Problems: Convert the following 298 K 25˚C = _______ 200 473 K = _______˚C Temperature Scales Liquid Nitrogen Evaluating the Accuracy of a Measurement • The “Percent Error ” of a measurement is a way of representing the accuracy of the value. (Remember what accuracy tells us?) % Error = (Accepted Value) − (Experimentally Measured Value) x 100 (Accepted Value) (Absolute Value) Practice Problem: A student measures the density of a block of aluminum to be approximately 2.96 g/mL. The value found in our textbook tells us that the density was supposed to be 2.70 g/mL. What is the accuracy of the student’s measurement? % Error = |2.70−2.96| ÷ 2.70 0.096296…x 100 = 9.63% error =