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Do First Actions: Turn in your lab to the drawer What is wrong with the drawn molecules below? 1. 2. O=O F-F Agenda 1. Notes 2. Practice Naming and Writing Ionic and Covalent Compounds What to write on your periodic table: 1+ 1VE 2+ 2VE 3+ 3- 2- 13VE 4VE 5VE 6VE 7VE 0 8VE NAMING Binary (2 elements) Ionic Compounds • Ionic compounds are made of a metal/nonmetal combination • The metal (positive ion) is written first followed by the nonmetal (negative ion) • A binary compound always ends with the suffix “-ide” NAMING Binary (2 elements) Ionic Compounds • For example, NaCl: – This compound contains two elements: sodium and chlorine – Sodium is the cation and chlorine is the anion – The oxidation number (charge) of sodium (Na) is 1+ – The oxidation number (charge) of chlorine (Cl) is 1– Name the metal (cation) first, and then the nonmetal (anion) with the ending changed to “ide” – NaCl = Sodium Chloride – Some tricky ones include: • Nitrogen = Nitride; Phosphorus = Phosphide; Oxygen = Oxide; Sulfur = Sulfide WRITING Ionic Compounds – Criss Cross Method • Used to write ionic formulas using oxidation numbers (charge) • Steps 1. Write the symbol for each element 2. Assign the oxidation number (charge) for each element in the upper right hand corner of the symbol 3. Cross the NUMBER, NOT the (+) or (-) sign 4. Check the TOTAL charges. A molecule is neutral – the positive and negative charges are equal WRITING Ionic Compounds – Criss Cross Method • For example: Magnesium Chloride – Magnesium = Mg; Chlorine = Cl – Mg2+; Cl1- 2+ –Mg ; 1Cl – Mg1Cl2 – BUT, don’t leave “1” as a subscript... Just leave it out… so… – MgCl2 WRITING Ionic Compounds – Criss Cross Method • For example: Magnesium Oxide – Magnesium = Mg; Oxygen = O – Mg2+; O2- 2+ –Mg ; 2O – Mg2O2 – BUT, if the numbers can be simplified, do so! – MgO WRITING Ionic Compounds – Criss Cross Method • For example: Magnesium Phosphide – Magnesium = Mg; Phosphorus = P – Mg2+; P3- 2+ –Mg ; – Mg3P2 3P Transition Metals • Most transition metals form cations with different charges • A Roman Numeral is used to indicate the charge – Fe2+ = iron (II) – Fe3+ = iron (III) • The Roman Numeral MUST be used in the name! – FeO = iron (II) oxide – Fe2O3 = Iron (III) oxide Transition Metals • EXCEPTIONS!!! – Silver (Ag) is ALWAYS 1+ and Zinc (Zn) is ALWAYS 2+. Do NOT use roman numerals with these elements – Tin (Sn) and Lead (Pb) from group 14 can have a 2+ OR 4+ charge. YOU MUST ALWAYS use a roman numeral with these elements. Practice • Complete the white section of your worksheet WRITE THE FORMULA AND NAME THE COMPOUND DYL 1. In naming an ionic compound, does the anion or cation written first? 2. When in naming do you use Roman Numerals? Polyatomic Ions • A polyatomic ion consists of more than one element covalently bonded together that has a charge • The name of the ion is not changed when it forms a compound • Examples of polyatomic ions include: – OH-1 = Hydroxide It’s important to think of these as “Packages”!!!!!!! – SO4-2 = Sulfate – (A common polyatomic ions chart has been given to you) Writing Formulas for Compounds with Polyatomic Ions • Write the chemical formula for lithium acetate – Lithium = Li+1; Acetate = C2H3O2-1 – Cross the number NOT the charge! –Li+1 C2H3O2-1 – LiC2H3O2 Writing Formulas for Compounds with Polyatomic Ions • Write the chemical formula for sodium carbonate – Sodium= Na+1; Carbonate = CO3-2 – Cross the number NOT the charge! –Na+1 CO3-2 – Na2CO3 Writing Formulas for Compounds with Polyatomic Ions • Write the chemical formula for aluminum bicarbonate – aluminum= Al+3; Bicarbonate = HCO3-1 – Cross the number NOT the charge! –Al+3 HCO3-1 – Be careful!!!!!! If you have more than one polyatomic ion, put parentheses around it before you assign it a number! – Al(HCO3)3 Naming Covalent Compounds • Covalent bonds occur between two or more nonmetals • NO ions are formed; therefore, there is no need to write charges (or roman numerals) • Covalently bonded molecules may have different whole number combinations of the same elements Naming Covalent Compounds • In naming covalent compounds – The 1st element only gets a prefix IF THERE IS MORE THAN ONE ATOM – The 2nd element ALWAYS gets a prefix and ALWAYS ends in “-ide” • Prefixes 1 = mono 2 = di 3 = tri 4 = tetra 5 = penta 6 = hexa 7 = hepta 8 = octa 9 = non 10 = deca Practice • • • • • • • • • • SO3 ICl3 PBr5 C3H6 CI4 PCl3 N2O3 PF5 CCl4 CO2 Sulfur Trioxide Iodine Trichloride Phosphorous pentabromide tricarbon hexahydride carbon tetraiodide Phosphorus trichloride dinitrogen trioxide phosphorus pentafluoride carbon tetrachloride carbon dioxide Practice • • • • • • • • • • Disulfur trichloride Diphosphorus trioxide Carbon diselenide Carbon tetraiodide Diarsenic trisulfide Dinitrogen pentoxide Tetraphosphorus decoxide Selenium hexafluoride Disilicon hexabromide Diboron monosilicide S2Cl3 P2O3 CSe2 CI4 As2S3 N2O5 P4O10 SeF6 Si2Br6 B2Si