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Arnoldi Honors Chemistry Atomic Theory One Review 1. Definitions a. Atoms b. Atomic Number c. Mass Number d. Nucleons e. anion f. cation g. ion h. isotopes i. Quantum j. Quanta k. Photon l. Radioactivity m. Electromagnetic Radiation n. Half-Life 2. How do we see individual atoms? 3. Which of the following appear on the periodic table? Atomic Number Atomic Mass Mass Number 4. What controls the identity of the atom? 5. Subatomic Particles: Particle Charge Mass (Two Ways) Proton Electron Neutron 6. What controls the charge of the particle? 7. How do we form cations? 8. How do we form anions? 9. Describe Quarks 10. Why do isotopes have different masses? 11. What are the three isotopes of hydrogen? Location in Atom In Nucleus 12. Fill in the following table: Isotope Protons Electrons Neutrons 41 Ca+2 2 8 235 2 10 U P-3 13. Compare Continuous and Discontinuous matter theories. 14. Fill in the Blanks _______________ was a Greek philosopher who first used the term “atom”, which means __________________. He thought atoms were tiny and __________________. He created the __________________ theory of matter, which stated that matter is _____ one continuous piece. 15. Fill in the Blanks In the 18th century, we had the first ______________ evidence that could support the idea of an atom. Antoine Lavoisier discussed the Law of _____________________________, and Joseph Proust discussed the Law of _____________________________, which states that a chemical compound contains the elements in exactly the same proportions by _____________, regardless of the size of the sample or source of the compound. 16. Fill in the Blanks John Dalton discussed the Law of _________________________ which stated that if two or more different compounds are composed of the same two elements, then the ratio of the masses of the second element, combined with a certain mass of the first element, is always a ratio of __________________________. Dalton stated four thoughts about atomic theory: (1) All matter is made up of atoms which are ___________________ and _______________________, (2) Atoms of the same element are identical – in particular their ______________ are the same, (3) Atoms of different elements are completely different, in particular their _______________ are different, and (4) Atoms combine in ______________________________ to form compounds. (They due this via chemical reactions which are the result of the _______________ or _________________ of atoms. Dalton’s atomic model was a ____________________. 17. Fill in the Blanks Today, we agree that matter is made of ____________________, atoms do combine in _____________________________ ratios, and chemical reactions are the result of the _____________________ / ____________________ of atoms. 18. Fill in the Blanks However, we disagree with some of Dalton’s ideas, because we know that atoms are divisible into _____________________, and atoms are destructible via ___________________reactions (we can create atoms in nuclear reactions, also). Also, atoms of different elements can have the ______________ mass, and atoms of the same element can have _________________ masses because of ____________________. 19. Fill in the Blanks A guy named William Crookes had the next impact on atomic theory. Crooke’s studied the behavior of gases in vacuum tubes (aka ____________________), which were the forerunners of picture tubes in _________________. Crookes theorized that some kind of radiation or particles was traveling from the cathode across the tube. He called this radiation __________________. Draw a cathode ray tube below. Label the + and - charges, the cathode ray, and the cathode and anode. cathode ray (must start at the cathode and move toward the anode) 20. Fill in the Blanks J.J. Thomson used Crookes tube to discover the ___________________. He determined that the electron had a ___________________ charge by bending the ray in the Cathode Ray tube using + and – fields. The ray bent _____________________ the positive field. The ray bent _________________ the negative field. From this data, and knowing that likes repel and opposites attract, Thomson decided that since the ray is attracted to the positive field, and repelled by the negative field, it must be ____________________. Thus, he determined that the _________________ is a stream of negatively charged which he called __________________. His atomic model was called the ______________________ model. 21. Fill in the Blanks Thomson and Milliken worked together on the ____________________ in which they discovered the mass of the electron to be 9.11 X 10-28 grams which is nearly ___________________. This can also be expressed as 1/1837 amu. (protons and neutrons have a mass of ___________________). They also determined that the charge is 1.602X10-19 coulomb which this is the smallest charge ever detected. 22. Fill in the Blanks The next major contributor to Atomic Theory was Eugene Goldstein who in 1886 found evidence for the ____________________. 23. Fill in the Blanks Rutherford used the ___________________________ to discover the atom’s _______________. Give a basic rendering of this experiment below. Rutherford bombarded gold foil with ___________________ which are _______________________ Helium atoms. He saw that most of the particles ___________________, but a few were ___________________. Since alpha particles are positive, they must have hit something __________________ inside of the atom (likes ________________). From these results, Rutherford concluded that there is a _________________________________________________ center in the atom, which he called the ____________________. He also concluded that the atom is mostly __________________, and that the bulk of the mass of the atom is in the center. Rutherford knew that the electrons where __________________ the nucleus, occupying most of the volume of the atom. However, he couldn’t explain why, if electrons are negative, and the center of the atom is positive, they weren’t attracted to the center of the atom. Draw the Gold Foil Experiment. Include: alpha particles, what most particles do, and what a few particles do. 24. Fill in the Blanks James Chadwick confirmed the existence of the _______________ by bombarding beryllium atoms with alpha particles via the following equation: 4 9 He 2 + 12 Be 4 1 C 6 + n 0 25. Fill in the Blanks Niels Bohr said that electrons reside in ______________________, aka energy shells. The energy of the level ___________________ as the distance from the nucleus increases, and electrons fill the energy levels from the inside out, or from ____________ to _____________ energy. Atoms can be found in the ground state or the excited state. A _______________ state atom will fill the first shell before moving to the second, the second before moving to the third, etc. The last shell (the outermost shell) may or may not be filled. This is the lowest possible energy state. An _________________ state atom has an inside shell that is NOT filled before moving to the next shell. It is NOT in the lowest possible energy state. Another name for the ground state is the ________________ state. Another name for the excited state is the _________________ state. To move from one shell to another, or to move from one energy level to another, you must gain or lose the exact amount of energy between those two levels. 26. Draw a Bohr Diagram for each of the following: a. Lithium Atom b. Phosphorus Ion c. Potassium Ion 27. What is an alpha particle? Complete the following alpha particle radiation equation below: 4 He 2 + 9 Be 4 1 + n 0 28. What is a beta particle? Complete the following beta particle radiation equation below: 234 Th 90 0 + e -1 29. What is a Gamma Ray? 30. The half-life of iodine-131 is 8 days. What mass of this isotope remains from a 4.00 g sample after 32 days? 31. The starting mass of a radioactive isotope was 20.0g. Its half-life is two days. The mass is now 2.5g. How old is the sample? 32. A sample of radioactive matter has a mass of 10.5g. It is 24 hours old, and its half-life is 6 hours. What was the original mass of the sample? PROBLEMS 1. What is the atomic mass for element B? 2. Find the %’s of 2 isotopes of element X given the following information: 3. Element Q consists of two naturally occurring isotopes: Isotope One’s abundance is 43.55 % and its mass is 40.009 amu. If the average atomic mass of the element is 41.956 amu, what is the percent abundance and exact mass of the other isotope?