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Scientific Method Mass vs. Weight • First we will define Matter… – Matter – anything that has mass & takes up space • Mass – measurement that tell how much matter you have (kg) • Weight – measurement of the amount of matter you have with the effect of gravity For Example… • Let’s say a guy weighs 150 pounds • This is about 54 kg in mass • What would his mass be on the moon if the moon’s gravity is about 1/6 that of the Earth? Hmmmm… • • • • Would it be 1/6 of 150 pounds? Would it be 1/6 of 54 kg? Would it be 150 pounds Or would it be 54 kg? The answer is … 54 kg Some of you are scratching your heads… • The reason is because gravity has NOTHING to do with mass – that’s only for weight • His mass did not change only his weight changed The Scientific Method • Scientific Method – a systematic approach used in scientific study • It is an organized approach for scientists to do research • Provides a method for scientists to verify their work and the work of others Steps for the Scientific Method Step # 1 – Observation • Observation – the act of gathering information (data) – Qualitative data – information with NO numbers • (hot, blue, rainy, cold) – Quantitative data – information with numbers • (98°F, 80% humidity, 0°C) Steps for the Scientific Method Step # 2 – Form a Hypothesis • Hypothesis – tentative explanation for what has been observed – There is no formal evidence at this point – It is just a gut feeling Steps for the Scientific Method Step # 3 – Experimentation Experimentation – a set of controlled observations that test the hypothesis – Independent variable – the thing that you change in the experiment – Dependant variable – the thing that changes because you changes the independent variable – Constant – something that does not change during the experiment – Control – the standard for comparison For example… • Let’s say we are going to do an experiment testing what happens when you heat and cool a balloon… We will start with a balloon at room temperature Now we will change something… I will add heat to one balloon It will expand What will happen to the balloon’s size? Now let’s cool things down I will add cool down the balloon It will get smaller What will happen to the balloon’s size? So what is what? • What variable did YOU change? – Temperature (Independent Variable) • What variable changes BECAUSE you changed the temperature? – Size of the balloon (Dependent Variable) • What is did not change in the experiment? – Amount of air in the balloon, what the balloon is made of… (Constant) • What balloon did you use to compare the others to? – The room temperature balloon (Control) Steps for the Scientific Method Step # 4 – Conclusion • Conclusion – judgment based on the information obtained Introduction to Significant Figures & Scientific Notation Significant Figures • Scientist use significant figures to determine how precise a measurement is • Significant digits in a measurement include all of the known digits plus one estimated digit For example… • Look at the ruler below • Each line is 0.1cm • You can read that the arrow is on 13.3 cm • However, using significant figures, you must estimate the next digit • That would give you 13.30 cm Let’s try this one • Look at the ruler below • What can you read before you estimate? • 12.8 cm • Now estimate the next digit… • 12.85 cm The same rules apply with all instruments • The same rules apply • Read to the last digit that you know • Estimate the final digit Let’s try graduated cylinders • Look at the graduated cylinder below • • • • What can you read with confidence? 56 ml Now estimate the last digit 56.0 ml One more graduated cylinder • Look at the cylinder below… • What is the measurement? • 53.5 ml Rules for Significant figures Rule #1 • All non zero digits are ALWAYS significant • How many significant digits are in the following numbers? •274 •3 Significant Figures •25.632 •5 Significant Digits •8.987 •4 Significant Figures Rule #2 • All zeros between significant digits are ALWAYS significant • How many significant digits are in the following numbers? 504 3 Significant Figures 60002 5 Significant Digits 9.077 4 Significant Figures Rule #3 • All FINAL zeros to the right of the decimal ARE significant • How many significant digits are in the following numbers? 32.0 3 Significant Figures 19.000 5 Significant Digits 105.0020 7 Significant Figures Rule #4 • All zeros that act as place holders are NOT significant • Another way to say this is: zeros are only significant if they are between significant digits OR are the very final thing at the end of a decimal For example How many significant digits are in the following numbers? 0.0002 6.02 x 1023 100.000 150000 800 1 Significant Digit 3 Significant Digits 6 Significant Digits 2 Significant Digits 1 Significant Digit Rule #5 • All counting numbers and constants have an infinite number of significant digits • For example: 1 hour = 60 minutes 12 inches = 1 foot 24 hours = 1 day How many significant digits are in the following numbers? 0.0073 100.020 2500 7.90 x 10-3 670.0 0.00001 18.84 2 Significant Digits 6 Significant Digits 2 Significant Digits 3 Significant Digits 4 Significant Digits 1 Significant Digit 4 Significant Digits Rules Rounding Significant Digits Rule #1 • If the digit to the immediate right of the last significant digit is less that 5, do not round up the last significant digit. • For example, let’s say you have the number 43.82 and you want 3 significant digits • The last number that you want is the 8 – 43.82 • The number to the right of the 8 is a 2 • Therefore, you would not round up & the number would be 43.8 Rounding Rule #2 • If the digit to the immediate right of the last significant digit is greater that a 5, you round up the last significant figure • Let’s say you have the number 234.87 and you want 4 significant digits • 234.87 – The last number you want is the 8 and the number to the right is a 7 • Therefore, you would round up & get 234.9 Let’s try these examples… 200.99 (want 3 SF) 201 18.22 (want 2 SF) 18 135.50 (want 3 SF) 136 0.00299 (want 1 SF) 0.003 98.59 (want 2 SF) 99 Significant Digits Calculations Significant Digits in Calculations • Now you know how to determine the number of significant digits in a number • How do you decide what to do when adding, subtracting, multiplying, or dividing? Rules for Addition and Subtraction • When you add or subtract measurements, your answer must have the same number of decimal places as the one with the fewest • For example: 20.4 + 1.322 + 83 = 104.722 Addition & Subtraction Continued • Because you are adding, you need to look at the number of decimal places 20.4 + 1.322 + 83 = 104.722 (1) (3) (0) • Since you are adding, your answer must have the same number of decimal places as the one with the fewest • The fewest number of decimal places is 0 • Therefore, you answer must be rounded to have 0 decimal places • Your answer becomes • 105 Addition & Subtraction Problems 1.23056 + 67.809 = 69.03956 69.040 23.67 – 500 = - 476.33 -476 40.08 + 32.064 = 72.1440 72.14 22.9898 + 35.453 = 58.4428 58.443 95.00 – 75.00 = 20 20.00 Rules for Multiplication & Division • When you multiply and divide numbers you look at the TOTAL number of significant digits NOT just decimal places • For example: 67.50 x 2.54 = 171.45 Multiplication & Division • Because you are multiplying, you need to look at the total number of significant digits not just decimal places 67.50 x 2.54 = 171.45 (4) (3) • Since you are multiplying, your answer must have the same number of significant digits as the one with the fewest • The fewest number of significant digits is 3 • Therefore, you answer must be rounded to have 3 significant digits • Your answer becomes • 171 Multiplication & Division Problems 890.15 x 12.3 = 10948.845 1.09 x 104 88.132 / 22.500 = 3916.977 3917.0 (48.12)(2.95) = 141.954 142 58.30 / 16.48 = 3.5376 3.538 307.15 / 10.08 = 30.47123 30.47 More Significant Digit Problems 18.36 g / 14.20 cm3 = 1.293 g/cm3 105.40 °C –23.20 °C = 82.20 °C 324.5 mi / 5.5 hr = 59 mi / hr 21.8 °C + 204.2 °C = 226.0 °C 460 m / 5 sec = 90 or 9 x 101 m/sec Scientific Notation • Scientific notation is used to express very large or very small numbers • I consists of a number between 1 & 10 followed by x 10 to an exponent • The exponent can be determined by the number of decimal places you have to move to get only 1 number in front of the decimal Large Numbers • If the number you start with is greater than 1, the exponent will be positive • Write the number 39923 in scientific notation • First move the decimal until 1 number is in front – 3.9923 • Now at x 10 – 3.9923 x 10 • Now count the number of decimal places that you moved (4) • Since the number you started with was greater than 1, the exponent will be positive • 3.9923 x 10 4 Small Numbers • If the number you start with is less than 1, the exponent will be negative • Write the number 0.0052 in scientific notation • First move the decimal until 1 number is in front – 5.2 • Now at x 10 – 5.2 x 10 • Now count the number of decimal places that you moved (3) • Since the number you started with was less than 1, the exponent will be negative • 5.2 x 10 -3 Scientific Notation Examples Place the following numbers in scientific notation: 99.343 9.9343 x 101 4000.1 4.0001 x 103 0.000375 3.75 x 10-4 0.0234 2.34 x 10-2 94577.1 9.45771 x 104 Going from Scientific Notation to Ordinary Notation • You start with the number and move the decimal the same number of spaces as the exponent. • If the exponent is positive, the number will be greater than 1 • If the exponent is negative, the number will be less than 1 Going to Ordinary Notation Examples Place the following numbers in ordinary notation: 3 x 106 6.26x 109 5 x 10-4 8.45 x 10-7 2.25 x 103 3000000 6260000000 0.0005 0.000000845 2250 Conversions And Density Problems Accuracy vs. Precision • Accuracy – How close you are to the correct answer • Precision – How close your answers are together For Example… • Let’s say we had the following dart board Is the accuracy good or bad? Accuracy - GOOD Is the precision good or bad? Precision - GOOD Try this one • Let’s say we had the following dart board Is the accuracy good or bad? Accuracy - BAD Is the precision good or bad? Precision - GOOD Try this one • Let’s say we had the following dart board Is the accuracy good or bad? Accuracy - BAD Is the precision good or bad? Precision - BAD Dimensional Analysis • Dimensional analysis is just a big word for going from one unit to another. • Have you ever converted inches into feet or years into days? • If so, then you have done dimensional analysis Dimensional Analysis • Dimensional Analysis – method of problemsolving that focuses on changing units • Conversion Factor – a ratio of equal values used to go from one unit to another – Example: 1 foot = 12 inches – Can be written as 1 foot 12 inches Rules for Dimensional Analysis 1. 2. 3. 4. ALWAYS start with the given!!! Draw a multiplication sign and a line Place the unit to be canceled on the bottom Place a conversion factor on the line you have drawn 5. Cross out units and see what you have left. 6. You must have one on top & one on the bottom A/ x B A/ Let’s try an example… Let’ s convert 32.5 inches to feet. 1. Start with your given 32.5 inches 2. Draw your line and multiplication sign 32.5 inches x ___________ 3. Put the unit to be crossed out on the bottom 32.5 inches x __________ inches 4. Write a conversion factor to switch units 32.5 inches x __1_foot___ 12 inches Keep going… 5. Cross out top and bottom units / 32.5 inches x __1_foot___ 12 inches / 6. Are you left with the unit that you wanted? YES 7. If so, work the problem & you are done / 32.5 inches x __1_foot___ = 2.70833 feet 12 inches / You’re not really done yet… • What did we forget? – SIGNIFICANT DIGITS !!! • What operation are we doing? – Multiplication • So what do we look at? – The total number of Sig. Figs • Our answer should have the same number of Sig. Figs as the given, which in this case is 3 • The answer becomes… 2.71 feet Try this example… • How many seconds are in 82.95 minutes? • Start with the given 82.95 minutes • Draw your line 82.95 minutes x ___________ • Place the unit to be crossed out on the bottom 82.95 minutes x ___________ minutes Keep going… • Place the conversion factor on the line 82.95 minutes x _60 seconds_ 1 minute • Cross out the units / 82.95 minutes x _60 seconds_ 1 minute / • Are you left with the unit you wanted? Yes! • Just work the problem & check Sig. Figs 82.95 minutes x _60 seconds_ = 4977 seconds 1 minute What if you need to Change 2 Units? Convert 65 miles per hour to kilometers per second (0.625 miles = 1 Km) Start with your given 65 miles x 1 km x 1 hr x 1 min = 0.029 Km / sec 1 hour 0.625 mi 60 min 60 sec Conversions with Prefixes • Conversions with prefixes are done in exactly the same manner • You just have to know the prefixes Prefixes Prefix Symbol Value Giga G 1 x 10 9 Mega M 1 x 10 6 Kilo K 1 x 10 3 Deci d 1 x 10 - 1 Centi c 1 x 10 - 2 Milli m 1 x 10 - 3 Micro µ 1 x 10 - 6 Nano n 1 x 10 - 9 Pico P 1 x 10 - 12 Femto f 1 x 10 - 15 Rules with Prefixes • • • • • The rules are the same… Start with the given Place the cross out unit on the bottom Place conversion unit on top Keep crossing out until you get what you want A few differences • Always remember that the # 1 will go with your Prefix • The number with in scientific notation will go with your base unit • You can only go from a prefix to a base unit Let’s try one • Convert 100 nm into m Start with your given 100 nm x 1 x 10 -9 m = 1 x 10 – 7 m 1 nm Try this one… • Convert 785 mm to km 785 mm x 1 x 10 -3 m x 1 mm 1 km 1 x 10 3 m = 7.85 x 10 – 4 km Temperature Conversions • The three units for measuring temperature are… – Celsius – Fahrenheit – Kelvin To Convert Among Temperatures Use These Formulas • ºF = 1.8 ºC + 32 • ºC = 0.56 (ºF – 32) • K = ºC + 273 Try these examples • • • • Convert 35 °C to Kelvin K = ºC + 273 K = 35 + 273 K = 308 K Example • • • • Convert 55 ºC to ºF ºF = 1.8 ºC + 32 ºF = 1.8 (55) + 32 ºF = 131 = 130 ºF Example • • • • Convert 95.8 ºF to ºC ºC = 0.56 (ºF – 32) ºC = 0.56 (95.8 – 32) ºC = 35.7 ºC Example • Convert 75.0 °F to Kelvin • You must first convert to °C and then go to Kelvin • ºC = 0.56 (ºF – 32) • ºC = 0.56 (75 – 32) • ºC =24.1 ºC • K = ºC + 273 • K = 24 + 273 • K = 297 K Density • Density - mass per unit volume (g/cm3) M D= V M D V Density • An object has a volume of 825 cm3 and a density of 13.6 g/cm3. Find its mass. GIVEN: WORK: V = 825 cm3 D = 13.6 g/cm3 M=? M = DV M D V M = (13.6 g/cm3)(825cm3) M = 11,220 g = 11,200 g Density A liquid has a density of 0.87 g/mL. What volume is occupied by 25 g of the liquid? GIVEN: WORK: D = 0.87 g/mL V=? M = 25 g V=M D M D V V= 25 g 0.87 g/mL V = 28.7 mL = 29 mL Density You have a sample with a mass of 620 g & a volume of 753 cm3. Find density. GIVEN: WORK: M = 620 g V = 753 cm3 D=? D=M V M D V D= 620 g 753 cm3 D = 0.82 g/cm3 Density • The good thing about density is that it is an intensive property • That means that the density of a substance is the same regardless of the amount • If you find the density of an unknown material, you can look it up in a density chart to find its identity Density • I have a block that measures 5.25 cm by 2.25 cm by 8.50 cm. • I weigh the block and find its mass to be 5.85 g • Calculate the density of the block in g/cm3 Density • • • • • • • • • • D=M/V We know the mass and we want to find the density. Therefore we must also find the volume. How do you find the volume of a cube? V cube = l x w x h V cube = (5.25) x (2.25) x (8.50) = 100.4 cm3 Now we can calculate the density D=M/V D = 5.85 g / 100.4 cm3 0.0583 g / cm3 What of you have an odd shaped object? • The density of an odd shaped object can be found by the same equation • D=M/V • To find the mass, you just weigh the odd shaped object • To find the volume, you place water in a graduated cylinder and get an initial volume • Then you place the object into the graduated cylinder. • The volume of the object is the difference in the two volumes For example • A chunk of metal has a mass of 5.25 g. It is placed in a graduated cylinder containing 25.0 ml of water. Once the metal is placed in the graduated cylinder, the water rises to 38.2 ml. What is the density of the metal? • M = 5.25 g • V = 38.2-25.0 = 13.2 ml • D = M / V = 5.25 g / 13.2 ml = 0.398 g / ml