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Semiconductor Photoconductive Detectors S W McKnight and C A DiMarzio Types of Photoconductivity • “Intrinsic photoconductors” – Absorption across primary band-gap, Eg, creates electron and hole photocarriers • “Extrinsic photoconductors” – Absorption from (or to) impurity site in gap creates photocarriers in conduction or valence band E Intrinsic and Extrinsic Photoconductors Ef1 1 Eg 2 Intrinsic Photoconductor Ef2 Extrinsic Photoconductor 1. Donor level to conduction band 2. Valence band to acceptor level Impurities Levels in Si Photoconductors Material Eg (max) Material Eg (max) Si 1.1eV(i) (1.2μ) PbS 0.37eV (3.3μ) GaAs 1.43eV (0.87μ) InSb 0.18eV (6.9μ) Ge 0.67eV(i) (1.8μ) PbTe 0.29eV (4.3μ) CdS 2.42eV (0.51μ) CdTe 1.58eV (0.78μ) 0.24eV (5.2μ) (77K) 0.083eV (15μ) (77K) Hg0.3Cd0.7 Te Hg0.2Cd0.8 Te Indirect Gap Semiconductors hνphonon hνphoton Eg Direct Gap Semiconductors E hνphoton Eg k Optical Constants of Silicon 8 Optical Constants (n, k) 7 6 5 n k k*1000 4 3 2 1 0 0 200 400 600 Wavelength (nm) 800 1000 1200 GaAs Optical Constants 6 5 n, k 4 n 3 k 100*k 2 1 0 0 200 400 600 Wavelength (nm) 800 1000 1200 Optical Electric Field and Power q=ω (ε)1/2 = (ω/c) (n+ik) Optical Electric Field and Power A x (B x C) = B(A·C) – C(A·B) α = absorption coefficient = 2 ω k/c Absorption Coefficient for Si and GaAs Reflection at Front Surface For Silicon, near 600 nm: n=3.95 k=0.026 → R = 0.35 (Can be reduced by anti-reflection coating) Absorption in Semiconductor α=2ωk/c For Silicon near 600 nm: α = 4 π 0.026 / 600 x 10-9 = 5.44 x 105 m-1 For GaAs near 600 nm: α = 4.76 x 106 m-1 1 0.9 Optical Power 0.8 In(z)=Io e- z 0.7 0.6 0.5 Si 0.4 0.3 GaAs 0.2 0.1 0 0 1 2 3 4 5 6 Z (microns) 7 8 9 10 Carrier Generation/Recombination Units: g = e-h excitations/sec/m3 r = m3/sec 1. Thermal Equilibrium: 2. Direct recombination of excess carriers: Direct Recombination of Excess Carriers Direct recombination (low level)→ δn = δp << no Photogenerated Carriers 3. Steady-state optical excitation: Neglect for δn<<no Differential Optical Excitation Rate Photoconductivity length=l Area=A Φp = photon flux (photon/sec) η = quantum efficiency Hole Trapping Hole trapping at recombination centers: a. hole is trapped b. electron trapped, completing recombination c. hole detraps to valence band (c) Photoconductivity with Hole Trapping (Steady-state) # of current-carrying photoelectrons = # of trapped holes Photoconductive Gain G = photocurrent (electron/sec) / rate of e-h generation length=l Area=A Photoconductive Gain → Effect of Carrier Lifetime on Detector Frequency Response Photoconductor Bias Circuit Photoconductive Voltage Photoconductor Responsivity Responsivity Factors • Photocarrier lifetime – Tradeoff with response frequency • Quantum efficiency (anti-reflection coating) Detector area=A • Carrier mobility • Detector current Detector current, i • Dark resistance d – R= ℓ / σ A – Detector area: Ad = ℓ w – Sample thickness w t length=ℓ Cross-section area=A Photoconductive Noise Factors • 1/f Noise – Contact related • Thermal noise (Johnson noise) – Statistical effect of thermal fluctuations – <In2> ~ kT/R • Generation-Recombination noise – Statistical fluctuations in detector current – Dark current (thermal electron-hole pairs) – Background photogenerated carriers – <In2> ~ Id / e Noise Sources Johnson noise: G-R noise: Ep = photon irradiance=Φp / Ad G = photoconductive gain Background-Limited Photoconductive Detection Johnson-Noise-Limited Photoconductive Detection Noise Sources for IR Detectors