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CH. 9 review 1 Ch. 9 Review Terms/definitions Composition stoichiometry Reaction stoichiometry Mole ratio Molar mass Theoretical yield Actual yield Percent yield Problems Moles to moles Mass to moles Moles to mass Mass to mass Percent yield 2 Matching 1. 2. 3. 4. 5. 6. 7. DEALS WITH THE MASS RELATIONSHIPS OF ELEMENTS IN COMPOUNDS INVOLVES THE MASS RELATIONSHIPS BETWEEN REACTANTS AND PRODUCTS IN A CHEMICAL REACTION A CONVERSION FACTOR THAT RELATES THE AMOUNTS IN MOLES OF ANY TWO SUBSTANCES INVOLVED IN A CHEMICAL REACTION MASS, IN GRAMS, OF ONE MOLE OF A SUBSTANCE THE MAXIMUM AMOUNT OF PRODUCT THAT CAN BE PRODUCED FROM A GIVEN AMOUNT OF REACTANT (RESULT OF MASS-MASS PROBLEM) THE MEASURED AMOUNT OF A PRODUCT OBTAINED FROM A REACTION RATIO OF ACTUAL YIELD TO THE THEORETICAL YIELD, MULTIPLIED BY 100 mole ratio actual yield molar mass composition stoichiometry percent yield reaction stoichiometry theoretical yield 3 Ch. 9 Test: 45 points 7 matching: terms/def. 2 multiple choice: coefficients & mole ratio 8 problems moles to moles (2) moles to grams grams to moles grams to grams (2) percent yield with grams to grams percent yield, with grams to grams, find actual yield given percent yield 4 Practice all 4 types Do p. 287 Section Review # 2 – 5 2a) 182 g HCl b) 238 g MgCl2; 5.05 g H2 3a) 0.998 mol H2O 3b) 0.499 mol C2H2; 0.499 mol Ca(OH)2 4) NaCl + AgNO3 AgCl + NaNO3 4) 63.3 g AgCl 5) 8.45 x 104 g CO2; 1.73 x 104 g H2O 5 Review Problems pp. 930 - 935 Mixed Stoichiometry problems # 176 – 199 176) 15 mol (NH4)2SO4 177a) 51 g Al b) 101 g Fe 177c) 1.83 mol Fe2O3 178) 0.303 g H2 179) H2SO4 + 2 KOH K2SO4 + 2 H2O 1.11 g H2SO4 180a) H3PO4 + 2 NH3 (NH4)2HPO4 b) 0.293 mol (NH4)2HPO4 c) 970 kg NH3 = 970 000 g NH3 6 Review Problems pp. 930 - 935 Mixed Stoichiometry problems # 176 – 199 181a) 90.0 mol ZnCO3; 60.0 mol C6H8O7 b) 13.5 kg (13500 g) H2O; 33.0 kg (33 000 g) CO2 182a) 60.9 g methyl butanoate b) 3261 g H2O 183a) 0.450 mol N2 b) 294 g NH4NO3 184) Pb(NO3)2 + 2 KI PbI2 + 2 KNO3 0.751 mg KNO3 (0.000751 g) 185) 3.3 mol PbSO4 7 Review Problems pp. 930 - 935 Mixed Stoichiometry problems # 176 – 199 186) 2 LiOH + CO2 H2O + Li2CO3 360 g H2O 187a) 38.1 g H2O b) 40.1 g H3PO4 c) 0.392 mol H2O 188) C2H5OH + 3 O2 2 CO2 + 3 H2O 81.0 g C2H5OH 189) 76.5 g H2SO4; 12.5 g O2 190) 2 NaHCO3 Na2CO3 + H2O + CO2 1.31 g CO2 8 Review Problems pp. 930 - 935 Mixed Stoichiometry problems # 176 – 199 191a) 2 N2H4 + N2O4 3 N2 + 4 H2O b) 1 mol N2O4 to 3 mol N2 c) 30 000 mol N2 d) 3.52 x 105 g H2O 192) 2 HgO 2 Hg + O2 1.1954 mol O2 193) 2 Fe + 3 Cl2 2 FeCl3 30.0 g Fe 194) 9.26 mg CdS (0.00926 g) 195a) 1.59 mol CO2 b) 0.0723 mol C3H5(OH)3 c) 535 g Mn2O3 d) 833 g C3H5(OH)3 4.97 g CO2 9 Review Problems pp. 930 - 935 Mixed Stoichiometry problems # 176 – 199 196a) 3.29 x 103 kg of HCl (329 000 000 g) b) 330 g CO2 197a) 6.53 x 105 g NH4ClO4 b) 160 kg NO (160 000 g) 198a) 1.70 x 106 mol H3PO4 b) 666 kg CaSO4 . 2 H2O (666 000 g) c) 34 metric tons of H3PO4 199) 1670 kg (1 670 000 g) 10 Review Problems pp. 930 - 935 Percent yield # 218 – 236 218a) 83.8 % b) 93 % c) 69.1 % d) 46 % 219a) 79.3 % b) 76 % 220a) 64.3 % b) 58.0 % c) 69.l5 % skip d 221a) 69.5 % b) 79.0 % c) 48 % d) 85 % 222a) 59 % b) 81.0 % c) 2.3 x 105 mol P 223a) 91.8 % b) 0.0148 mol W c) 16.1 g WO3 11 Review Problems pp. 930 - 935 Percent yield # 218 – 236 224a) 86.8 % b) 92.2 % skip c 225a) 81 % b) 2.0 x 102 g N2O5 226) 80.1 % 227a) 95 % b) 910 g Au skip c 228a) 87.5 % b)0.25 g CO 229a) 71 % b) 26 metric tons c) 47.8 g NaCl skip d 230a) 2 Mg + O2 2 MgO b) 87.7 % c) 3 Mg + N2 Mg3N2 d) 84 % 12 Review Problems pp. 930 - 935 Percent yield # 218 – 236 231a) 80 % b) 66.2 % c) 57.1 % 232) 2 C3H6 + 2 NH3 + 3 O2 2 C3H3N + 6 H2O 91 % 233a) CO + 2 H2 CH3OH 3410 kg or 3 410 000 g b) 91.5 % 234) 96.9 % 13 Review Problems pp. 930 - 935 Percent yield # 218 – 236 235) 6 CO2 + 6 H2O C6H12O6 + 6 O2 6320 g O2 236) 27.6 kg O2 = 27 600 g O2 14 15