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Igneous, sedimentary and metamorphic rocks The building blocks of landforms Silicate Minerals • • • Most igneous rocks contain silicate minerals Silicate minerals are combinations of Si-O tetrahedra plus one or more metallic elements A silicon-oxygen tetrahedron is an anion that consists of a single silicon atom surrounded by four oxygen atoms (SiO4-4) arranged so that they define the corners of a pyramid From: Marshack, S. 2001:Earth,Portrait of a Planet. WW Norton & Company, New York. Fig 5.21 Rocks • We have now seen the relationship between elements and minerals: • Elements combine chemically to form minerals • How does this fit into our understanding of what rocks are? • Rocks are aggregates of different minerals Silicate minerals (cont.) • Silicate minerals containing feldspar and silicon combinations are referred to as felsic minerals • Feldspars are alluminium silicates in combination with Ca, Na, and K • Silicate minerals containing magnesium and iron(Fe) combinations are referred to as mafic minerals • Most igneous rocks are built up of one or more of only seven major silicate minerals or silicate mineral groups 1 Major silicate mineral groups Major silicate mineral groups (cont.) Mafic Group Felsic Group 1.Quartz (SiO2) 2.Potash Feldspar (K,Na)AlSi3O8 Density 2.6g/cc 2.6g/cc 3.Plagioclase Feldspar NaAlSi3O8 2.6g/cc CaAl2Si2O8 2.8g/cc 4. Mica (K,Mg,Fe)AlSi3O8 (Biotite, Muscovite) 5. Amphibole(Ca,Mg,Fe)AlSi3O8 (Hornblende) 6. Pyroxene (Ca,Mg,Fe)AlSi3O8 (Augite) 7. Olivine (Mg,Fe)SiO4 (Olivine) Density 2.9g/cc 3.2g/cc 3.2g/cc 3.3g/cc Additional Minerals Magmas • Besides silicate minerals, igneous rocks also have additional minerals that are not silicates Magnetite (Fe2O4) Ilmenite (FeTiO3) • These are known as heavy minerals because they have high densities of 4.5 – 5.5g/cc • Igneous rock solidifies from molten rock material consisting mainly of silicate magmas under high pressure(6000-12000 atmospheres) and high temperature(500-1200ºC) • Included in silicate magmas are the volatiles, which are mainly gasses and liquids like water vapor (H2O), carbon dioxide (CO2), sulphur dioxide (SO2), nitrogen (N2) and Hydrogen (H2) • Most of the volatiles are released during crystallization 2 Classification of igneous rocks Texture Extrusive Intrusive • The physical characteristics of an igneous rock are closely related to the size, form and orientation of individual minerals in the rock • Intrusive rocks (plutonic) form at great depth, slow crystallization, large crystals therefore they will have coarse texture • Extrusive rocks form at shallow depth, rapid crystallization, small crystals, therefore they will have fine texture • TEXTURE and COMPOSITION are combined to order or classify igneous rock (Diagram from: Marshack, S. 2001:Earth, Portrait of a Planet. W Norton & Company, New York. Fig 6.17 Chemical alteration of igneous rocks • Igneous rock forms under high temperature and pressure somewhere in the crust as a magma cools down • Exposure of igneous rock at the surface brings it into a totally different environment of low temperature and pressure • It comes into contact with water and solutions containing oxygen and carbon dioxide that will react with some of the minerals in the rock • This chemical change in response to an alien environment is called mineral alteration, a process of weathering Essential process • It is essential that rocks be broken into smaller fragments for chemical reactions to function properly • WHY? 3 Chemical alteration processes Clay minerals • Oxidation – a process whereby minerals react with oxygen dissolved in soil or groundwater • Oxidation converts silicate minerals to very stable oxides found abundantly in many rocks and sediments • Hydrolysis – a chemical process where water reacts with minerals producing totally new and very stable minerals • Combinations of oxidation and hydrolysis very often produce clay minerals • Most important component of soils • Clay minerals have plastic properties when moist meaning they can be deformed • Deformation is possible because thin flakes of mica become lubricated by layers of water molecules in between them Chemical alteration processes (cont.) • Carbonation – a process of solution where atmospheric CO2 dissolves in rainwater to form a weak acid, (carbonic acid H2CO3) that will react with any carbonate such as Calcium carbonate CaCO3 • Any limestone or dolomite area is therefore a target for carbonation. WHY? Sediments and sedimentary rocks • Sediments are the unconsolidated mineral matter produced by weathering that is capable of being transported by a fluid medium such as air, water and glacial ice • Sediments can be subdivided into: – Clastic sediments – Non-clastic sediments – Piro-clastic sediments 4 Sediments • Clastic sediments consist of particles derived directly from the original bedrock without being altered • Non-clastic sediments are newly created mineral matter derived from chemical precipitation or organic activity • Piro-clastic sediments consist of solid particles derived from volcanic action Clastic sediments • Are composed of quartz, feldspar, heavy minerals, clay minerals and any other rock fragments • Particle size is an important role player during sediment transport and during the settling of sediments Wentworth Scale for grain size Sorting • Due to the difference in settling velocity of particles of different grain size, sorting of sediments will occur • Sorting is the process whereby similar grain sizes group together From: Marshack, S. 2001:Earth,Portrait of a Planet. WW Norton & Company, New York. Fig 7.18 From: Boggs, S., 1995: Principles of Sedimentology and Stratigraphy, Prentice Hall. New Jersey. Table 4.1 5 Flocculation • Particles can only settle in water when they are “heavy” enough • They will stay in suspension indefinitely unless they clot together, a process called flocculation Igneous vs. sedimentary landscapes Lithification • To change from a sediment to a sedimentary rock, sediments need to undergo a process of compaction and hardening called lithification • Sand will change to sandstone • Mud will change to mudstone • Clay will change to claystone • Finely laminated mudstone is called a shale when it is fissile • Sedimentary rocks are characterized by their layered appearance and the layers are called strata Non-clastic sediments • Are divided into two groups Igneous Bornhardt Namibia – Chemical precipitates derived from the evaporation of water (also called hydrogenic sediments or evaporites) – Organically derived sediments created by the life processes of plants and animals (also called biogenic or carbonates) Colorado Plato Utah, USA 6 Examples • Examples of evaporites: Gypsum(CaSO4·2H2O) Halite (NaCl) Anhydrite (CaSO4) • Examples of carbonates: calsite (CaCO3) Aragonite (CaCO3) Dolomite (Ca,Mg(CO3)2) Salt playa,Eastern California Limestone, Yugoslavia Metamorphic rocks (cont.) • Since new minerals are created during metamorphism, the end product (metamorphic rock) will also be new • Shale slate schist • Schists are the most advanced grade of metamorphic rocks • Schists have a texture called foliation which mean they have thin but irregular planes of parting in the rock (mica minerals are arranged more or less parallel to each other). Metamorphic rocks • Metamorphic rocks are rocks from sedimentary and igneous origin that have been changed through high pressures and temperatures during orogenesis (mountain building) or during igneous intrusion (contact metamorphism) Some rocks and their metamorphic equivalents Sandstone Siltstone Conglomerate Limestone Granite Quartzite Marble Gneiss 7 The Rock Cycle 8