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Transcript
Lipids: Focus on Waxes Lipids are a diverse group of molecules. However, all lipids are hydrophobic: that’s the one property they have in common. Therefore, they are insoluble in water. This group of molecules includes fats and oils, waxes, phospholipids, steroids (like cholesterol), and some other related compounds. These are macromolecules, and do not necessarily fit into the definition of polymers. Waxes The word "wax" is derived from the Anglo-Saxon word "weax" for beeswax, so a practical definition of a wax may therefore be "a substance similar in composition and physical properties to beeswax.” All waxes have the same structure. They are formed by a linkage between a saturated, long-chain fatty acid and a long- chain alcohol. Commercial Waxes A number of waxes are produced commercially in large amounts for use in cosmetics, lubricants, polishes, surface coatings, inks and many other applications. Some of these are of mineral origin and only those from living organisms are discussed here. Amongst them are – Beeswax - Glands under the abdomen of bees secrete a wax, which they use to construct the honeycomb. The wax is recovered as a by-product when the honey is harvested and refined. Carnauba - The leaves of the carnauba palm, Copernicia cerifera that grows in Brazil, have a thick coating of wax, which can be harvested from the dried leaves. You may have heard of Carnauba car wax, which people use to make their automobiles shiny. Plant Surface Waxes Plant leaf surfaces are coated with a thin layer of waxy material that has a myriad of functions. This layer forms the outer boundary of the cuticular membrane; it is the interface between the plant and the atmosphere. It serves many purposes, for example to limit the diffusion of water and solutes, while permitting a controlled release of gaseous molecules that may deter pests or attract pollinating insects. The wax provides protection from disease and insects, and helps the plants resist drought. As plants cover much of the earth's surface, it seems likely that plant waxes are the most abundant of all natural lipids. Waxy leaves Skin Lipids In most animals, the main wax production is associated with the sebaceous glands of the skin. Most of these glands are associated with hair follicles, but there are also related structures on the eyelids. Sebaceous glands secrete mainly non-polar lipids in the form of sebum onto the skin surface. Sebum acts to protect and waterproof hair and skin, and keep them from becoming dry, brittle and cracked. It can also inhibit the growth of microorganisms on skin. You know that oily feeling you get after not showering for a few days? Or the shiny forehead you get when you haven’t washed up? Source: http://www.lipidlibrary.co.uk/Lipids/waxes/index.htm