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USC Aiken FALL, 2009 PHYSICAL CHEMISTRY ACHM 541 LECTURE MWF Noon – 12:50PM Dr. M. Fetterolf SBDG 307 SBDG 325 OFFICE HOURS MTThF 10:00 – 11:00AM W 2:00 – 3:00PM All other times are subject to my availability. Please see my posted schedule on my office door. I know in PChem it is important to have your questions answered as they arise. I usually have time to help unless I am preparing for a class, lab or meeting. I will also be available at home by phone (not too early or late) or email. Please contact me with your PChem questions or if you will be missing a lecture or lab. REQUIRED MATERIALS Physical Chemistry Vol. 1 & 2, 8th Edition; Atkins and de Paula, Freeman, 2006. Student Solutions Manual; Atkins, Trapp, Cady & Giunta, Freeman, 2006. Survival Guide for Physical Chemistry, Michelle Francl; Physics Curriculum&Instruction, 2001. Routine access to Blackboard through VIP and a scientific calculator with which you are familiar. HOMEWORK PROBLEM SETS Homework exercises and problems, to practice and apply skills, will be distributed for each exam period and a due date will be assigned. Any homework assignment turned in after that date will receive a 50% point penalty. After the homework key is posted, which is never more that two days after the due date, late homework sets will not be accepted for grading and no points will be received for that set. Please turn in whatever homework you have done by the due date and then finish what you can afterwards. It is more advantageous to do so in the long run. The assignments will come from other texts books and will be appropriate for the material we are covering. The required Student Solutions Manual contains worked out solutions to half of the problems located at the end of each chapter in the text. This and the examples throughout the text will provide a guide for solving homework problems. You will need to use whatever skills you have acquired from the lecture, the lab and the text to design solutions to the homework problems. The homework assignments are to be considered small take-home exams and your work with other students should be limited to initial consultation only. If I see any evidence of greater interaction, no credit will be received for that homework problem set by each of the collaborators. The homework problem set key will be available on the web site in time to study for the upcoming exam. The text by Francl is an excellent review of the mathematics required for all aspects of chemistry, not just this course. There are also study tips and suggestions for being successful in a physical chemistry course. Please become familiar with this book and use it as needed. I will present several applications of multivariable calculus from this book in lab so that their use will be more straightforward. COMPUTER USAGE Some homework problems are perfect for solving using software programs that help explore aspects of physical chemistry. Programs such as Maple, Mathcad, and Mathematica should become a routine part of your work in both lecture and lab. I encourage you to use software programs as an integral part of homework and for all chemistry and physics calculations in any of your classes. Mathcad is available on the computers in SBDG 315 and Maple is available in the Math labs. Please develop a habit of working with software. You may want to purchase a physical science application text for your software of choice. QUIZZES Every Friday, except for exam weeks, during the last five minutes of class we will have a brief quiz that draws from the week’s lecture materials, suggested text problems, and recent topics from the text. The purpose here is to get everyone to review the most recent topics and to keep up in their studies. Because we will have seven to nine of these quizzes at 5 points each, the impact on one’s grade for poor performance is not major but can make a difference in borderline grade cases. EXAMS I am planning four midterm exams this semester. These exams will include questions similar to the assigned homework problems/exercises. I will supply the data tables and figures needed for each exam. There will also be brief discussion questions that cover the assigned reading. Exams are scheduled during a lab period. The exam length will be roughly two and half hours. The final exam will be given at the scheduled time of Friday, December 11, 2009 at 11:00AM in our regular class room. The Final Exam will contain comprehensive material as well as material covered after the last midterm exam. One 3” x 5” notecard containing any equations or information you would like may be brought with you to use during each exam. However the cards cannot contain text passages, examples or problem solutions. I will check each card prior to the exam and collect them with the exam. Answer keys will be available on Blackboard as soon as the exam is over. LECTURE TOPICS I plan to cover most of the material in Volume 1 in order. These chapters are full of specific information and details that time will not allow me to address. Since the text is readable and straightforward, lectures will enhance understanding of the material we cover, not simply follow what is stated in the text. These chapters deal with the topic of equilibrium thermodynamics - an extensive and involved subject - and the last chapters introduce the important topic of chemical kinetics. Therefore it is very important that you read the text for understanding and stay ahead of my lectures. For planning purposes, I am targeting an average of 10 – 12 pages of text material per lecture. Based on my experience, this lecture schedule is entirely possible but will require commitment on our part to keep up. You must read the text. Extra informationa and lecture notes that are meant to enhance the course are present on the course website found off of the department homepage. I often add material to this site as the semester proceeds and I will announce these additions in lecture or lab. You must be, and I expect you to be, an active participant in PChem. This class attempts to provide the physical basis for all chemical phenomena and observations, and as such, becomes a foundational course. As chemistry majors, I expect you to have an active interest in the subjects of this course and a curiosity that leads to questions and a desire to obtain understanding. Physical chemistry in general has a national reputation of being a very difficult and incomprehensible subject for the beginner. I feel that this reputation is due in part to the usual teaching approach which is to cover as many topics as possible in as much detail as possible from the instructor’s perspective, without regard to how many students are staying with the material. This is not my approach. I try to provide enough in-depth coverage of the essential topics so that you can build from them later in your careers as the need arises. At the completion of the entire ACHM 541/542 series, the nationally normalized American Chemical Society PChem exam will be administered (this is also the only exam where a note card is not allowed). Good students in the past have done above the national average on that exam so my approach seems to have merit. But you must do your work if the class is to be successful. In a small class, your participation and activity do influence the other students. GRADING FORMAT An "A" student in this class is expected to perform well in all test areas including the homework exercises/problems and workbook exercises. The average student will be able to perform basic physical chemistry calculations and make basic chemical judgments based on their experience and familiarity with the text, lectures, and problems. Student performance on the homework problems and workbook exercises is meant to distinguish between the “A” and “C”student groups. Past students who have received an "A" have been interested in all of the subject areas, dedicated enough to ask questions, probed the text for more information than is discussed directly in lecture, and attempted to understand physical chemistry as a whole. This personal goal of these students drove them to excellent performance in the course. As juniors in college you should realize by now that one of your major goals in any course, and certainly this course, is to understand the material and not merely to perform tasks. Most students cannot understand a subject such as PChem quickly. Sometimes maintaining a high level of dedication to the course is the only goal a student can accomplish quickly. But understanding must be your goal and if it is, then good grades follow. You will feel more satisfied about your efforts because they were aimed at the proper target and therefore feel better about your classroom efforts in general. That dedication is required in PChem. The subject is too extensive and complex to not require dedication. Understanding a subject requires reading and rereading your textbook and notes, looking at and doing examples and exercises in the text that aren't part of the assignments so that you can gain confidence, and integrating your thoughts about lab into lecture and vice versa. Thinking about, integrating, and applying your acquired knowledge is key. The point breakdown for each performance area is given below. The course grade will be based on the percentage of total points received. My usual guideline is: above 85% an “A”, 72% - 85% a “B”, 60% - 72% a “C”, etc. Homework Exercises (Approx.) 150 pts (20%) Quizzes (9 @ 5 pts) 45 pts ( 7%) Midterm Exams (4 @ 100 pts) Final Exam Total 400 pts (53%) 150 pts (20%) _________ 745 pts TENTATIVE SCHEDULE For purposes of a schedule, we will have a midterm exam every two or three chapters. Tentatively, Exam I will be 9/17, Exam II will be 10/15, Exam III will be 11/5, and Exam IV will be 12/3. STUDENT RESPONSIBILITIES In total, your responsibilities are 1) the assigned homework problems and workbook exercises turned in on time, 2) the text material, 3) the lecture material, and 4) any other suggested exercises and problems assigned for review. If understanding is your goal, then all of your questions must be answered ahead of time and you must keep delving into the subject. Anything short of that will show up as a lack of confidence, which will translate into lower grades. Lectures will begin promptly and you are responsible for the material covered in lecture. This text is fairly rigorous but many formula derivations may still appear in class. Many data interpretation ideas covered in lecture are not presented in this or any text. Physical chemistry is a very demanding topic and will require a consistent effort on your part to get the most out of each lecture. Should you need help with problem-solving skills, basic chemistry, etc. please see me at office hours, by appointment, or by availability. HAVE A GOOD SEMESTER!!!!!! NOTE: Any student who has a physical, psychological, and/or learning disability that might affect performance in class needs to contact the Office of Disability Services (126A B&E, 803/641-3609) on campus as soon as possible. That office will determine appropriate accommodations based on medical documentation. Thanks. Contacts----------Office Phone: 803/641-3378 Home Phone: 803/642-7125 Office Email: [email protected] Home Email: [email protected] After 7AM and before 10PM Course Web Site URL: http://www.usca.edu/chemistry/pchem/