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ATOMS: THE BUILDING BLOCKS OF MATTER 3-1 The Atom: From Philosophical Idea to Scientific Theory The transformation of one substance or substances into one or more new substances is a _____________________________ ________________________________________________________ - mass is neither destroyed nor created during ordinary chemical reactions or physical changes ________________________________________________________________ - a chemical compound contains the same elements in exactly the same proportions by mass regardless of the size of the sample or source of the compound ________________________________________________________________ - if two or more different compounds are composed of the same two elements, then the ratio of the masses of the second element combined with a certain mass of the first element is always a ratio of small whole numbers ______________________________________________ 1) all matter is composed of extremely small particles called atoms 2) atoms of a given element are identical in size, mass, and other properties; atoms of different elements size, mass, and other properties 3) atoms cannot be subdivided, created, or destroyed 4) atoms of different elements combine in simple whole-number ratios to form chemical compounds 5) in chemical reactions, atoms are combined, separated, or rearranged differ in Modern theory has somewhat revised Dalton’s atomic theory to read: 1) all matter is composed of atoms 2) atoms of any one element differ in properties from atoms of another element 3-2 The Structure of the Atom Atoms are composed of several basic types of smaller particles and that the number and arrangement of these particles within an atom determine that atom’s chemical properties __________________ - smallest particle of an element that retains the chemical properties of that element - has two regions: 1) _________________________ - small region located near the center - contains ________________________, positively charged particle, and _______________________, neutral particle 2) ________________________ - surrounds the nucleus - contains _______________________________, negatively charged particles __________________________________________________ include protons, neutrons, and electrons Cathode ray - particles pass through the tube from the _______________________________, metal disk connected to the negative terminal of the voltage source, to the _______________________, the metal disk connected to the positive terminal. 1) when current was passed through the cathode-ray tube, the surface of the tube directly opposite the cathode glowed. Glow caused by a stream of particles, which they called the cathode ray 2) the ray traveled from the cathode to the anode when current was passed 3) when an object was placed between the cathode and anode, it cast a shadow on the glass and it moved from the cathode toward the anode 4) cathode rays were deflected by a magnetic field away from a negatively charged object 5) hypothesis: particles that compose cathode rays are negatively charged (physicist Joseph John Thomson); later, they named the negatively charged particles electrons The electron has a very large charge for its tiny mass (American physicist Robert A. Millikan). Also confirmed that the electron carries a negative electric charge. ____________________________________________ continued to investigate the atom’s structure: 1) bombarded a thin, gold foil with fast-moving _______________________________________, positively charged particles, 2) found that 1 out of 8000 rebounded back toward the source because alpha particles must have experienced some powerful force within the atom.. The source of this force must occupy a very small amount of space because so few of the total number of alpha particles had been affected by it. The force must be caused by a very densely packed bundle of matter with a positive electric charge and bundle was called the nucleus. Composition of atomic nuclei: 1) made up of 2 kinds of particles: ____________________________ and ________________________________ 2) protons and electrons must be ___________________________________ 3) the __________________________________of protons in a nuclei determines the atom’s identity 4) __________________________________________ - short-range proton-neutron, proton-proton, and neutronneutron forces that hold the particles together Size of atoms - measured in picometer (pm) - 1pm = 10-12 - example: 1 cm would be a fractional part of 600 miles so 100 pm is of 1 cm 3-3 Counting Atoms ____________________________________________________ - the number of protons in the nucleus of each atom of that element - example: in increasing order so H has 1 proton so is #1, He has 2 protons so is #2 _____________________________________ - atoms of the same element that have different masses - ___________________________________ - total number of protons and neutrons in the nucleus of an isotope - example: H 3 isotopes has mass numbers of 1, 2, and 3 respectively - the number of _______________________ varies but not the protons in the nucleus (protons and electrons are equal) - example: H has 3: 1) protium - 99.985% abundance with 1 proton only 2) deuterium - .015% abundance with 1 proton, 1 neutron 3) tritium - very small amounts, radioactive with 1 proton, 2 neutrons - identified by: 1) ________________________ - the name with a hyphen then the number; - EX: hydrogen-1 2) ________________________ - 235U ; superscript = mass number; subscript = atomic number - find # of neutrons by subtracting atomic number from mass number - __________________________ - general term for any isotope of any element - although isotopes have different masses, they do not differ significantly in their chemical behavior _____________________________________________________ - amu - 1/12 the mass of a carbon –12 atom - example: oxygen-16 is 16/12 or 4/3 the mass of carbon12. This is about 15.994915 amu ____________________________________________________________ - weighted average of the atomic masses of the naturally occurring isotope of an element - calculate: (% x weight) + (% x weight) . . . _________________________ - SI unit for amount of substance that contains as many particles as there are atoms in exactly 12 g of carbon-12 ___________________________________________________ - number of particles in exactly one mole of a pure substance - 6.02 x 10 23 ___________________________________________ - mass of one mole of a pure substance written: ________________________________________(symbol) is = to ______________________________________________ example: 1 molar mass = 4 g He calculating conversions of gram/mol: . . . g . . . = 1 mol